The origin of apatite iron oxide ores, like the deposit at Grängesberg in the Bergslagen mining district, has been a subject of much discussion through the years. Some support a formation by hydrothermal fluids while others suggest that the ore is orthomagmatic, i.e. formed directly from a magma as suggested for the iron ore deposits of El Laco in Chile or the deposits in Kiruna, although also these two are still subjected to controversies. In 2009 sampling was done on drillcores through the Grängesberg ore. On these samples an oxygen isotope study on magnetite, quartz and whole rock samples from both the ore and its host rocks was conducted in order to obtain new knowledge about the ore forming processes. The data allowed modeling to simulate a possible origin by different magmas or hydrothermal fluids as well as a possible temperature of formation. In addition, the data set was compared to published oxygen isotope analyses of the possible magmatic iron ores of Kiruna and El Laco. The results of the Grängesberg analysis revealed that the ore in the area seems to have an origin from both magmatic and hydrothermal sources.

Improving our understanding of magma plumbing and storage remains one of the majorchallenges for petrologists and volcanologists today. This is especially true for explosivevolcanoes, where constraints on magma plumbing are essential for predicting dynamicchanges in future activity and thus for hazard mitigation. This study aims to investigate themagma plumbing system at Anak Krakatau; the post-collapse cone situated on the rim of the1883 Krakatau caldera. Since 1927, Anak Krakatau has been highly active, growing at a rateof ~8 cm/week. The methods employed are a.) clinopyroxene-melt thermo-barometry (Putirkaet al., 2003; Putirka, 2008), b.) plagioclase-melt thermo-barometry (Putirka, 2005), c.)clinopyroxene composition barometry (Nimis & and Ulmer, 1998; Nimis, 1999; Putirka,2008) and d.) olivine-melt thermometry (Putirka et al., 2007). Previously, both seismic(Harjono et al., 1989) and petrological studies (Camus et al., 1987; Mandeville et al., 1996a;Gardner et al., in review, J. Petrol.) have addressed the magma plumbing beneath AnakKrakatau. Interestingly, petrological studies indicate shallow magma storage in the region of2-8 km, while the seismic evidence points towards a mid-crustal and a deep storage, at 9 and22 km respectively.This study shows that clinopyroxene presently crystallizes in a mid-crustal storage region(8-12 km), a previously identified depth level for magma storage, using seismic methods(Harjono et al., 1989). Plagioclases, in turn, form at shallower depths (4-6 km), in concertwith previous petrological studies (Camus et al., 1987; Mandeville et al., 1996a; Gardner etal., in review, J. Petrol.). Pre-1981 clinopyroxenes record deeper levels of storage (8-22 km),indicating that there may have been an overall shallowing of the plumbing system over thelast ~40 years. The magma storage regions detected coincide with major lithologicalboundaries in the crust, implying that magma ascent and storage at Anak Krakatau is probablycontrolled by crustal discontinuities and/or density contrasts. Therefore, this study shows thatpetrology has the sensitivity to detect magma bodies in the crust where seismic surveys faildue to limited resolution. Combined geophysical and petrological surveys offer an increasedpotential for the thorough characterization of magma plumbing at active volcanic complexes.

Thesis (Ph.D.)--University of Adelaide, Australian School of Petroleum, 2005? / "October 2004" Includes bibliographical references (leaves 280-291).

Thesis (M.S.)--Humboldt State University, 2008. / Two folded maps in pocket. Includes bibliographical references (leaves 90-95). Also available via Humboldt Digital Scholar.

Thesis (Ph.D.)--Memorial University of Newfoundland. / Typescript. Restricted until November 1996. Bibliography: leaves 253-274. Also available online.

Plagioclase is the most abundant mineral in the lower crust and it is thus important to constrain the behaviour of plagioclase during deformation. Anorthosites, which are plagioclase-rich rocks, are common in Archaean cratons but their origin and rheological importance is still debated. The aims of this thesis are to 1) describe a newly discovered Archaean anorthosite complex (Naajat Kuuat, SW Greenland), investigate its origin and a possible genetic relationship between the anorthosite and associated mafic-ultramafic rocks and 2) to study the rheology and deformation mechanisms in plagioclase-rich rocks. The main focus of this thesis is on the deformation studies. (1) Geochemical whole-rock analyses from the Naajat Kuuat complex are indicative for an origin near a subduction zone setting. A genetic link by crystal fractionation between the anorthosite and associated mafic-ultramafic units is inferred. (2) Deformation behaviour of plagioclase is assessed from analyses of three anorthosite units deformed during different conditions. Samples were analysed using the electron backscatter diffraction technique (EBSD) in combination with optical and chemical analyses. All three case studies show significant strain localisation related to grain size reduction. A wet anorthosite deformed at dry conditions (T ~675-700°C) was dynamically recrystallised. Continuous bands of recrystallised grains developed a texture yet display microstructures and grain relationships indicative for grain size sensitive creep, suggesting that the rheology followed a Newtonian flow law. In the other two studies, samples with initially dry and wet composition, respectively, have experienced deformation during fluid present conditions at T ~550-620°C. These two samples show that fluids effectively caused reactions, replacements and aided strain localisation during deformation at mid crustal conditions. / At the time of the doctoral defence the following papers were unpublished and had a status as follows: Paper 1: Manuscript; Paper 2 Manuscript; Paper 3 Manuscript.

Linking diagenesis to depositional facies and sequence stratigraphy enables better prediction of spatial and temporal distribution of diagenetic alterations, and thus of evolution of reservoir quality in sandstones. This thesis demonstrates that employing this approach is possible because depositional facies and sequence stratigraphy can provide useful information on parameters controlling the near-surface diagenesis, such as changes in: (i) pore-water chemistry, (ii) residence time of sediments under certain geochemical conditions, (iii) detrital composition and proportion of extra- and intra-basinal grains, and (iv) types and amounts of organic matter. Evidence from four case studies enabled the development of conceptual models for distribution of diagenetic alterations and of their impact on evolution of reservoir quality in sandstones deposited in paralic, shallow marine and fluvio-lacustrine environments. Diagenetic alterations that have been constrained within the context of depositional facies and sequence stratigraphy include: (i) carbonate cement (microcrystalline and equant calcite spars dolomite over poikilotopic calcite), pyrite and glaucony are most abundant in progradational braid-delta fan sequences, particularly along the topsets (i.e. maxiumum flooding surface, MFS) and along parasequences boundaries in the deltaic facies of the early highstand systems tract HST, (ii) cementation by coarse spar calcite, dolomite, and the formation of moldic porosity by the dissolution of framework carbonate grains are most abundant in the aggradational fan deltas sequences, (iii) eogenetic kaolinitization of framework silicates is largely restricted to the fluvial and paralic HST sandstones, whereas telogenetic kaolinite may occur in the transgressive systems tract TST sandstones too, (iv) formation of goethite ooids in the TST sediments, (v) formation of glaucony, siderite spherules, and extensive grain-coatings, grain-replacing and ooidal berthierine, more in the TST than in the HST sediments, particularly below the transgressive surface TS and MFS, (vi) cementation by calcite with (δ18OV-PDB = -11.5‰ to -5.4‰) and Fe-dolomite/ankerite (δ18OV-PDB = -10.8‰ to -9.6‰) occurs in both TST and HST sandstones, (vii) syntaxial quartz overgrowths are most extensive in the HST sandstones owing to the presence of incomplete grain-coating berthierine/chlorite, (viii) greater amounts of micro-porosity in the TST sandstones than in the HST sandstones are related to the greater amounts of berthierine/chlorite in the former sandstones, and (ix) chlorite rims around quartz grains retarded the precipitation of quartz overgrowths, and hence prevented a greater loss of primary intergranular porosity in fluvio-lacustrine sandstones. Therefore, constraining the distribution of diagenetic alterations in the contexts of depositional facies and sequence stratigraphic context is a powerful approach to be used in hydrocarbon exploration.

Stockholm är en mycket expansiv region med flera större infrastrukturella projekt plane- rade vilket kommer att medföra arbeten i och vid berg. Utan nödvändiga förundersökningar ökar risken för ras i samband med byggnationen och en fara för framtida stabilitet förelig- ger. En ingenjörsgeologisk förundersökning där man kartlägger strukturer i det påtänkta området bör genomföras och som beskriver de bergtekniska parametrar enligt Q- och RMR-systemen för bergkvalitetsklassificering.  Detta arbete fokuserar på ett område norr om Månskärsvägen och söder om Skär- holmsvägen i södra Stockholm där Huddinge kommun planerat anlägga en gång- och cy- kelväg samt en bro. Området, benämnt kvadraten 3 av Huddinge kommun, karterades mellan den 25 – 27 mars och 2 april 2013 då området fortfarande var snötäckt. Kartering- en, efter projicering av sprickdata i Stereo32, visar att det råder fyra dominerande sprick- riktningar i området; en nordväst-sydostlig, en nordost-sydvästligt, en nord-sydlig sprick- riktning och en foliationsparallell sprickgrupp i öst-västlig riktning. Den sistnämnda böjer av ca 15° mot öst vid förflyttning mot den nordöstra delen av området, möjligtvis förklaras detta av en observerad veckomböj. Övriga sprickgruppers strykningar varierar inom ett spann av 40° och stupar ca 50°. Dessa spricksystem i kombination med hållfasthetssän- kande sprickfyllnadsmineral och metertjocka sprickzoner med i stort sett helt krossat berg kommer att utgöra stora risker vid bygget i form av ras och potentiella kilutglidningar. Arbe- ten i detta berg bör göras under stor försiktighet och i kombination med fortsatta geolo- giska undersökningar under det att projektet fortlöper.

De sulfidgruvor belägna i Långbantrakten som studien behandlar ligger i den västra delen av Bergslagen utanför Filipstad i Värmlands län. Opaka mineral (malm) från två mindre mineraliseringar, Näset och Getberget, har studerats med malmmikroskop och mikrosond för att beskriva mineralogin i området. Båda områdena domineras av olika (Cu-Fe-Pb-Zn)-sulfider, i Näset av kopparkis (CuFeS2), blyglans (PbS) och zinkblände ((Zn,Fe)S) och i Getberget av blyglans, zinkblände, kubanit (CuFe2S3) och magnetkis (Fe1-xS). I Näset finns en del mindre frekventa mineral, två olika faser av Co-pentlandit (en nickelrik och en utan nickel), gedigen Sb och Bi, (Ni-Co)-sulfid, breithauptit (NiSb) och magnetkis. Kubanit är även ett viktigt mineral som speglar mineraliseringens bildning. I Getberget finns liknande mindre frekventa mineral, kopparkis, nickelrik Co-pentlandit, gedigen Bi och Sb, silverglans (Ag2S), breithauptit och magnetit (Fe3O4). En sen utfällning av kubanit har skett i båda områdena och visar att mineraliseringarna har genomgått en liknande bildning och det stämmer även in på mineralogin, som även den är likartad. / The small sulphide mines, Näset and Getberget that have been investigated are located just outside the main mineralization of Långban, near the city of Filipstad in Värmland County. Opaque minerals have been studied in reflected light microscopy and with an electron microprobe analysis to describe the mineralogy. Both areas are dominated by various (Cu-Fe-Pb-Zn)-sulphides, Näset with chalcopyrite (CuFeS2), galena (PbS) and sphalerite ((Zn,Fe)S) and Getberget with, galena, sphalerite, cubanite (CuFe2S3) and pyrrhotite (Fe1-xS). The sulphides are also accompanied by various accessory minerals, in Näset by two different phases of Co-pentlandite (on rich in nickel and one without), native Sb and Bi, a (Ni-Co)-sulphide, breithauptite (NiSb) and pyrrhotite. Cubanite is also a very important mineral that reflects the formation of the mineralization. In Getberget there are similar accessory minerals, chalcopyrite, nickel rich Co-pentlandite, native Bi and Sb, acanthite (Ag2S), breithauptite and magnetite (Fe3O4). A late precipitation of cubanite has occurred in both areas, suggesting that the mineralizations has been formed in similar conditions. This also holds true when comparing the mineralogy, which also is similar.

This work focuses on crustal interaction in magmatic systems, drawing on experimental petrology and elemental and isotope geochemistry. Various magma-chamber processes such as magma-mixing, fractional crystallisation and magma-crust interaction are explored throughout the papers comprising the thesis. Emphasis is placed on gaining insights into the extent of crustal contamination in ocean island magmas from the Canary Islands and the processes of magma-crust interaction observed both in nature and in experiments. This research underscores that the compositions of ocean island magmas, even primitive types which are classically used as probes of the mantle, are susceptible to modification by crustal contamination. The principal mechanisms of contamination identified from work on both Tenerife and Gran Canaria (Canary Islands) are assimilation and partial melting of the pre-existing island edifice and intercalated sediments by newly arriving magma (i.e. “island recycling”). The information that we can gain from studying solidified magma and entrained crustal xenoliths concerning the rates and mechanisms of crustal assimilation is, however, limited. To address this shortcoming, a series of time-variable crustal carbonate assimilation experiments were carried out at magmatic pressure and temperature using natural materials from Merapi volcano, Indonesia. A temporally constrained reaction series of carbonate assimilation in magma has hence been constructed. The experiments were analysed using in-situ techniques to observe the progressive textural, elemental, and isotopic evolution of magma-carbonate interaction. Crucially, carbonate assimilation was found to liberate voluminous crustally-derived CO2 on a timescale of only seconds to minutes in the experiments. This points to the role of rapid crustal degassing in volcanic volatile budgets, and, pertinently, in magnifying hazardous volcanic behaviour. This thesis, therefore, delivers detailed insights into the processes of magma-crust interaction from experiments and geochemistry. The outcomes confirm that crustal processes are significant factors in both, i) ocean island magma genesis, and ii) magma differentiation towards compositions with greater explosive potential which can, in turn, manifest as hazardous volcanism. / Felaktigt tryckt som Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology 707