A description and model of the near-surface hydrothermal system at Casa Diablo, with its implications for the larger-scale hydrothermal system of Long Valley, California, is presented. The data include resistivity profiles with penetrations to three different depth ranges, and analyses of inorganic mercury concentrations in 144 soil samples taken over a 1.3 by 1.7 km area. Analyses of the data together with the mapping of active surface hydrothermal features (fumaroles, mudpots, etc.), has revealed that the relationship between the hydrothermal system, surface hydrothermal activity, and mercury anomalies is strongly controlled by faults and topography. There are, however, more subtle factors responsible for the location of many active and anomalous zones such as fractures, zones of high permeability, and interactions between hydrothermal and cooler groundwater. In addition, the near-surface location of the upwelling from the deep hydrothermal reservoir, which supplies the geothermal power plants at Casa Diablo and the numerous hot pools in the caldera with hydrothermal water, has been detected. The data indicate that after upwelling the hydrothermal water flows eastward at shallow depth for at least 2 km and probably continues another 10 km to the east, all the way to Lake Crowley.

The Kribi-Campo sub-basin is the northernmost of a series of Aptian basins along the coast of West Africa. These extensional basins developed as a result of the northward progressive rifting of South America from West Africa, initiated c. 130 Ma ago. Post-rift sediments of the Kribi-Campo sub -basin contain several regional unconformities and changes in basin-fill architecture that record regional tectonic events. The tectono-stratigraphic evolution and plumbing system has been investigated using a high-quality 3D seismic reflection dataset acquired to image the deep-water Cretaceous-to-Present-day post-rift sediments. The study area is located c. 40 km offshore Cameroon in 600 to 2000 m present-day water depth, with full 3D seismic coverage of 1500 km2, extending down to 6.5 seconds Two-Way Travel time. In the late Cretaceous the basin developed as a result of tectonism related to movement of the Kribi Fracture Zone (KFZ), which reactivated in the late Albian and early Senonian. This led to inversion of the early syn-rift section overlying the KFZ to the southeast. Two main fault-sets - N30 and N120 - developed in the center and south of the basin. These normal faults propagated from the syn-rift sequences: the N120 faults die out in the early post-rift sequence (Albian time) whilst N30 faults tend to be associated with the development of a number of fault-related folds in the late Cretaceous post-rift sequence, and have a significant control on later deposition. The basin is filled by Upper Cretaceous to Recent sediments that onlap the margin. Seismic facies analysis and correlation to analogue sections suggest the fill is predominantly fine-grained sediments. The interval also contains discrete large scale channels and fans whose location and geometry were controlled by the KFZ and fault-related folds. These are interpreted to contain coarser clastics. Subsequently, during the Cenozoic, the basin experienced several tectonic events caused by reactivation of the KFZ. During the Cenozoic, deposition was characterized by Mass Transport Complexes (MTCs), polygonal faulting, channels, fans and fan-lobes, and aggradational gullies. The main sediment feeder systems were, at various times, from the east, southeast and northeast. The plumbing system shows the effects of an interplay of stratigraphic and structural elements that control fluid flow in the subsurface. Evidence for effective fluid migration includes the occurrence of widespread gas-hydrate-related Bottom Simulating Reflections (BSRs) 104 - 250 m below the seabed (covering an area of c. 350 km2, in water depths of 940 m - 1750 m), pipes and pockmarks. Focused fluid flow pathways have been mapped and observed to root from two fan-lobe systems in the Mid-Miocene and Pliocene stratigraphic intervals. They terminate near, or on, the modern seafloor. It is interpreted that overpressure occurred following hydrocarbon generation, either sourced from biogenic degradation of shallow organic rich mudstone, or from effective migration from a thermally mature source rock at depth. This latter supports the possibility also of hydrocarbon charged reservoirs at depth. Theoretical thermal and pressure conditions for gas hydrate stability provide an opportunity to estimate the shallow geothermal gradient. Variations in the BSR indicate an active plumbing system and local thermal gradient anomalies are detected within gullies and along vertically stacked channels or pipes. The shallow subsurface thermal gradient is calculated to be 0.052 oC m-1. With future drilling planned in the basin, this study also documents potential drilling hazards in the form of shallow gas and possible remobilised sands linked with interconnected and steeply dipping sand bodies.

This study is an attempt at achieving Net Zero Energy Building (NZEB) using a solar Organic Rankine Cycle (ORC) based on exergetic and economic measures. The working fluid, working conditions of the cycle, cycle configuration, and solar collector type are considered the optimization parameters for the solar ORC system. In the first section, a procedure is developed to compare ORC working fluids based on their molecular components, temperature-entropy diagram and fluid effects on the thermal efficiency, net power generated, vapor expansion ratio, and exergy efficiency of the Rankine cycle. Fluids with the best cycle performance are recognized in two different temperature levels within two different categories of fluids: refrigerants and non-refrigerants. Important factors that could lead to irreversibility reduction of the solar ORC are also investigated in this study. In the next section, the system requirements needed to maintain the electricity demand of a geothermal air-conditioned commercial building located in Pensacola of Florida is considered as the criteria to select the optimal components and optimal working condition of the system. The solar collector loop, building, and geothermal air conditioning system are modeled using TRNSYS. Available electricity bills of the building and the 3-week monitoring data on the performance of the geothermal system are employed to calibrate the simulation. The simulation is repeated for Miami and Houston in order to evaluate the effect of the different solar radiations on the system requirements. The final section discusses the exergoeconomic analysis of the ORC system with the optimum performance. Exergoeconomics rests on the philosophy that exergy is the only rational basis for assigning monetary costs to a system’s interactions with its surroundings and to the sources of thermodynamic inefficiencies within it. Exergoeconomic analysis of the optimal ORC system shows that the ratio Rex of the annual exergy loss to the capital cost can be considered a key parameter in optimizing a solar ORC system from the thermodynamic and economic point of view. It also shows that there is a systematic correlation between the exergy loss and capital cost for the investigated solar ORC system.

Isotopic investigations combined with geothermal applications represent powerful tools for the exploration of groundwater potential as a drinking or geothermal resource. This Ph.D. Thesis combines both approaches, environmental and radioactive isotopes together with temperature data in deep aquifers, in order to enrich and update the knowledge concerning the aquifer recharge processes in the Aquitaine Basin (France) and the aquifer recharge processes and geothermal potential in the Bohemian Cretaceous Basin (Czech Republic). Stable isotopes (18 O, 2 H, 13 C) combined with radioisotope data (14 C, 3 H) are used to estimate the recharge timing and climatic conditions prevailing during the infiltration from the Late Pleistocene up to modern time. The character of groundwater recharge and regime are necessary to generate relevant source data for the accurate modelling of complex groundwater systems. Three groups of groundwater recharge types can be distinguished throughout Europe - (i) continuous recharge and (ii) interrupted recharge during Last Glacial Maximum and (iii) a group corresponding to particular recharge conditions. The contrasted geographic and climate conditions at both study sites in France and the Czech Republic have entailed a great heterogeneity of the recharge conditions and...

In recent years a growing interest in Borehole Heat Exchangers (BHEs) has been shown in Europe thanks to the increase of installations in systems connected to Ground Source Heat Pumps (GSHPs) used for heating and cooling needs. Different geometries and technical solutions have been de- veloped in order to improve heat exchange with the ground, accompanied by several descriptive models. Recently, innovative technologies as optical fiber for a new Distributed Thermal Response Test (DTRT) have been proposed. This method allows the quantification of the BHE local perfor- mances, so that a more accurate punctual analysis of thermal phenomena is allowed. The aim of this thesis is to locate an analytical model thanks to the most recent data, to achieve the definition of overall efficiency of a single BHE in terms of thermal resistance and of a BHE-GSHP system in terms of evaluation of the Coefficient of Performance. This model accuracy will be verified with new measures in a real installation. A particular attention will be given to the thermal-fluid-dynamics aspects, defining semi-empirical correlation for free and forced convection within the BHE groundwater filling.

El texto completo de este trabajo no está disponible en el Repositorio Académico UPC por restricciones de la casa editorial donde ha sido publicado. / The recent climate change has forced people to live in extreme conditions, either excessive heat or cold, implying that they must adapt to survive in these situations. However, there are people who, because of their geographical condition and lack of resources, lack the means and tools to combat these climate changes. The context of this study is provided in a rural town located in the Arequipa region (Peru), whose inhabitants have to fight against frosts of up to −20 °C in an area without electricity. A viable solution to this problem is found through the design and implementation of a heating system using geothermal and photovoltaic energy, which are resources found in the area, according to a report of the Ministry of Energy and Mines. This study analyzes and researches the geographical and meteorological conditions of the region, for validating, through theory and simulations, whether the proposed system can supply the thermal energy required to maintain the indoor temperature at a minimum of 15 °C under extreme conditions. The system is designed after analyzing the best technological options and techniques currently available in the context studied for its ultimate financing and establishing guidelines and indicators for monitoring results.

El texto completo de este trabajo no está disponible en el Repositorio Académico UPC por restricciones de la casa editorial donde ha sido publicado. / The recent climate change has forced people to live in extreme conditions, either excessive heat or cold, implying that they must adapt to survive in these situations. However, there are people who, because of their geographical condition and lack of resources, lack the means and tools to combat these climate changes. The context of this study is provided in a rural town located in the Arequipa region (Peru), whose inhabitants have to fight against frosts of up to −20 °C in an area without electricity. A viable solution to this problem is found through the design and implementation of a heating system using geothermal and photovoltaic energy, which are resources found in the area, according to a report of the Ministry of Energy and Mines. This study analyzes and researches the geographical and meteorological conditions of the region, for validating, through theory and simulations, whether the proposed system can supply the thermal energy required to maintain the indoor temperature at a minimum of 15 °C under extreme conditions. The system is designed after analyzing the best technological options and techniques currently available in the context studied for its ultimate financing and establishing guidelines and indicators for monitoring results.

Geothermal energy consumption is projected to increase along with other renewable energy in the future. Therefore, it is important to have a better understanding on the evolution of geothermal systems to optimize the exploitation of such resources. Generally, numerical models are used as a fundamental tool to study a potential geothermal field. However, current modeling practices tend to focus on the shallow area around the heat source, while ignoring the deeper part below the heat source. The purpose of this project is to observe the influence of lower boundary at the bottom of intrusion towards the evolution of geothermal system, while changing the permeability and topography of host rock systematically, using a software from USGS called HYDROTHERM. Simulations differed in three main aspects: 1) having a layer below, or having the bottom boundary directly below intrusion, 2) different topographies with volcanic significance, and 3) varying permeabilities of the host rock. The study is based on a fossil geothermal system, the Cerro Bayo laccolith in Chachahuén volcanic complex (Neuquén Basin), Argentina. The input parameters were obtained in several ways. ILMAT Geothermometry analysis provide the temperature value related to the intrusion. The whole rock data is used to determined density of the intrusion by calculating partial molar volume of the oxides. The other parameters, e.g. densities of the host rock and the impermeable layer, permeability, porosity, and thermal conductivity were obtained from literature. The result from numerical modeling shows that the bottom boundary below intrusion strongly affect the entire system evolution. The added layer (with constant permeability) has strong influence on the life-span of the system. Additionally, while taking into account on the variation of topography and permeabilities, the models show two temperature anomalies: 1) A caldera volcano’s geometry “traps” heat below the caldera, whereas shield and strato-volcano geometries “push” heat away from below the volcanic edifice, and 2) a low temperature anomaly develops beneath the intrusion in all high permeability models with an added layer. Finally, this assessment could prove to be useful as prior knowledge for optimizing the extraction of heat from a given geothermal field, as well as future investigations towards geological applicability of numerical models of geothermal systems, hydrothermal alteration, and ore formation processes.

The work in this thesis was based on analyzing water samples collected from three exploratory boreholes drilled during Project Hotspot. The water samples were analyzed for their chemical properties. The chemical properties of the water samples were used as a basis for further analysis.Geophysical logs, mainly temperature logs, were also analyzed for this project. Temperature logs measure temperature in relation to depth within a borehole.All the analyses were made in order to estimate the geothermal potential of the project areas. The exploratory boreholes were all drilled in different areas and each had unique characteristics. The Mountain Home borehole provided the most promising evidence for future geothermal potential. Geothermal energy is a form of renewable energy and potential production areas are difficult and expensive to locate.

The Snake River Plain is located in the southern part of the state of Idaho. The eastern plain, on which this study focuses, is a trail of volcanics from the Yellowstone hotspot. Three exploratory geothermal wells were drilled on the Snake River Plain. This project analyzes basaltic core from the first well at Kimama, north of Burley, Idaho. The objectives of this project are to establish zones of geothermal alteration and analyze the potential for geothermal power production using sub-aquifer resources on the axial volcanic zone of the Snake River Plain. Thirty samples from 1,912 m of core were sampled and analyzed for clay content and composition using X-ray diffraction. Observations from core samples and geophysical logs are also used to establish alteration zones. Mineralogical data, geophysical log data and physical characteristics of the core suggest that the base of the Snake River Plain aquifer at the axial zone is located 960m below the surface, much deeper than previously suspected. Swelling smectite clay clogs pore spaces and reduces porosity and permeability to create a natural base to the aquifer. Increased temperatures favor the formation of smectite clay and other secondary minerals to the bottom of the hole. Below 960 m the core shows signs of alteration including color change, formation of clay, and filling of other secondary minerals in vesicles and fractured zones of the core. The smectite clay observed is Fe-rich clay that is authigenic in some places. Geothermal power generation may be feasible using a low temperature hot water geothermal system if thermal fluids can be attained near the bottom of the Kimama well. (113 pages)