Rocks of the South Island of New Zealand are locally enriched in metalloids, namely arsenic (As), antimony (Sb) and boron (B). Elevated levels of As and Sb can be found in sulphide minerals mostly in association with mesothermal gold deposits, whereas B enrichment occurs in marine influenced coal deposits. The mobility of these metalloids is important because they can be toxic at relatively low levels (e.g. for humans >0.01 mg/L of As). Their mobilisation occurs naturally from background weathering of the bedrock. However, mining and processing of coal and gold deposits, New Zealand's most economically important commodities, can significantly increase metalloid mobility. In particular, historic mines and associated industrial sites are known to generate elevated metalloid levels because of the lack of site remediation upon closure. This work defines and quantifies geological, mining, post-mining and regional processes with respect to metalloid, especially As, mobility. At the studied historic gold mines, the Blackwater and Bullendale mines, Sb levels in mineralised rocks were generally negligible (<14 ppm) compared to As (up to 10,000 ppm). Thus, Sb concentrations in solids and in water were too low to yield any meaningful information on Sb mobility. In contrast, dissolved As concentrations downstream from mine sites were found to be very high (up to 59 mg/L) (background = 10⁻� mg/L). In addition, very high As concentrations were found in residues (up to 40 wt%) and site substrate (up to 30 wt%) at the Blackwater processing sites (background < 0.05 wt%). Here, roasting of the gold ore converted the orginal As mineral, arsenopyrite, into the mineral arsenolite (As[III] trioxide polymorph) and volatilised the sulphur. The resultant sulphur-defficient chemical system is driven by arsenolite dissolution and differs significantly from mine sites where arsenopyrite is the main As source. Arsenolite is significantly more soluble than arsenopyrite. In the surficial environment, arsenolite dissolution is limited by kinetics only, which are slow enough to preserve exposed arsenolite over decades in a temperate, wet climate. This process results in surface waters with up to ca. 50 mg/L dissolved As. In reducing conditions, dissolved As concentrations are also controlled by the solubility of arsenolite producing As concentrations up to 330 mg/L. Field based cathodic stripping voltammetry showed that the As[III]/As[V] redox couple, in particular the oxidation of As[III], has a major control on system pH and Eh. Site acidification is mainly caused by the oxidation of As[III], resulting in a close link between As[V] concentrations and pH. Similarly, a strong correlation between calculated (Nernstian) and measured (electrode) Eh was found in the surface environment, suggesting that the overall Eh of the system is, indeed, defined by the As[III]/As[V] redox couple. Once the metalloid is mobilised from its original source, its mobility is controlled by at least one of the following attenuation processes: (a) precipitation of secondary metalloid minerals, (b) co-precipitation with - or adsorption to - iron oxyhydroxide (HFO), or (c) dilution with background waters. The precipitation of secondary minerals is most favoured in the case of As due to the relatively low solubility of iron arsenates, especially at low pH (~0.1 mg/L). Observations suggest that scorodite can be the precursor phase to more stable iron arsenates, such as kankite, zykaite, bukovskyite or pharmacosiderite and their stability is mainly controlled by pH, sulphur concentrations and moisture prevalence. Empirical evidence indicates that the sulphur-containing minerals zykaite and bukovskyite have a similar pH dependence to scorodite with solubilities slightly lower than scorodite and kankite. If dissolved As concentrations decline, iron arsenates potentially become unstable. Their dissolution maintains a pH between 2.5 and 3.5. This acidification process is pivotal with respect to As mobility, especially in the absence of other acidification processes, because iron arsenates are several orders of magnitude more soluble in circum-neutral pH regimes (~100 mg/L). From this, it becomes apparent that external pH modifications, for example as part of a remediation scheme, can significantly increase iron arsenate solubility and resultant As mobility. In contrast to As, the precipitation of secondary Sb and B minerals is limited by their high solubilities, which are several orders of magnitude higher than for iron arsenates. Thus, secondary Sb and B minerals are restricted to evaporative waters, from which they can easily re-mobilised during rain events. Metalloid adsorption to HFO is mainly controlled or limited by the extent of HFO formation, which in turn is governed by the availability of Fe and prevailing Eh-pH conditions. Thus, mineralisation styles and associated geochemical gradients, in particular pyrite abundance, can control the amount of HFO and consequent metalloid attenuation, and these can vary even within the same goldfleld. Furthermore, it was found that there is a mineralogical gradation between ferrihydrite with varying amounts of adsorbed As, amorphous iron arsenates and crystalline iron arsenates, suggesting that the maturity of mine waste is an important factor in As mineralogy. Once dissolved metalloids enter the hydrosphere, dilution is the main control on metalloid attenuation, which is especially pronounced at the inflow of tributaries. Dilution is, therefore, closely related to the size and frequency of these tributaries, which in turn are controlled by the regional topography and climate. Dilution is a considerably less effective attenuation mechanism and anomalous metalloid concentrations from mining related sites can persist for over 10 km downstream. The complex and often inter-dependent controls on metalloid mobility mean that management decisions should carefully consider the specific site geochemistry to minimize economic, health and environmental risks that can not be afforded. On a regional scale, background metalloid flux determines the downstream impact of an anomalous metalloid source upstream. For example, the Bullendale mine is located in a mountainous region, where rapidly eroding slopes expose fresh rock and limit the extent of soil cover and chemical weathering. Consequently, the background As flux is relatively low and As point sources, such as the Bullendale mine, present a significant contribution to the downstream As flux. In contrast, the bedrock at the Blackwater mine has undergone deep chemical weathering, resulting in an increased background mobilisation of As. Thus, the Prohibition mill site discharge, for example, contributes only about 10% to the downstream As flux. This information is relevant to site management decisions because the amount of natural background metalloid mobilisation determines whether site remediation will influence downstream metalloid chemistry on a regional scale.

Thesis (MEng.(Geotechnical Engineering)(Civil and Biosystems Engineering)) -- University of Pretoria, 2007. / Thesis in English. Includes bibliographical references.

Thesis (M. Sc.) (Hons.) -- University of Western Sydney, Nepean, 1998. / Thesis submitted for the degree of Master of Science (Honours) in the University of Western Sydney. Bibliography : p. 100-105.

Thesis (M.A.)--Miami University, Dept. of Geography, 2008. / Title from first page of PDF document. Includes bibliographical references (p.95-104).

Thesis (Ph. D.)--University of California, Berkeley, 1992. / Includes bibliographical references (leaves 136-140).

Thesis (M. Eng.(Geotechnical Engineering))--University of Pretoria, 2003. / Includes bibliographical references.

This thesis analyses the establishment of a health and safety system on the Witwatersrand gold mines in the period between the end of the South African War and the eve of World War Two. The period has been chosen, firstly, because the South African War had seriously disrupted production and the industry virtually had to start up again from scratch; secondly, because it was during this period that mine and state officials began to seriously investigate the reasons for the appalling mortality and morbidity rates on these mines; and, thirdly, because during this period some improvements did occur which were significant enough to enable the industry to warrant the lifting, in the latter part of the 1930s, of the ban on tropicals, enforced since 1913 as a result of their extremely high mortality rate. In the first thirty years of the twentieth century about 93 000 African miners died disease-related deaths and in the same period some 15000 African miners were killed in work-related deaths. In attempting to establish why so many African miners died, the thesis attempts to identify the diseases and accidents that caused these deaths and considers what attempts were made to bring mortality and morbidity rates down. Whilst the thesis is neither a history of gold mining in South Africa nor an economic history of South Africa in the period 1901 to 1939, it nevertheless, as detailed in the first chapter, places the health and safety system within the context of the wider political and economic forces that shaped the mining industry in this period. The need for a productive and efficient labour force, vital for the industry'S survival during a number of profitability crises in this period, forced the industry to reassess compound structures, nutrition and eventually the health of its work force. These issues of compounds, work and diet are discussed in chapters two, three and four. Appalling living and working conditions led to a high incidence of pulmonary diseases - TB, silicosis and pneumonia - which were the principal killers on the mines. Attempts to cure or prevent their occurrence are discussed in chapter five. Fear of disruptions to production ensured that the mining industry eventually also devoted considerable resources to accident prevention, a theme which is discussed in chapter six. The thesis concludes that the mining industry for much of this period was able to determine the pace of change; neither state officials nor African miners were able to significantly alter the tempo. In fact the industry was so successful that it was able to convince a number of government commissions in the 1940s that the migrant system had to stay, to ensure the wellbeing of the miner. This meant that despite considerable time, money and effort being spent on establishing a health and safety system on the gold mines, the mining industry was still of the opinion that the health of their workers was best served if they were sent home.

Gold exploration was conducted in northern margin, granulite-facies rocks of the Limpopo Belt. Methods used in the prospecting include drainage, soil and rock geochemistry, geophysical surveys, geological mapping, trenching and diamond drilling. These techniques successfully led to the discovery of two medium size, mesothermal gold deposits (Grid 2s and Grid 4). Objectives of this study were to (a) document the exploration methodology used; (b) describe the regional geology; (c) establish a mineral deposit model; (d) outline the methods and results of various exploration techniques; (e) outline follow-up procedures and evaluation of anomalies; and (f) discuss results of the exploration exercise and conclusions. The granulite-facies terrain comprises Charno-enderbites, mafic and felsic to intermediate metavolcanic rocks and meta-sediments. Renco Mine situated immediately east of the study area, was selected as the ore deposit model for the exploration program. Gold mineralization occurs in shear and thrust zones within an enderbite. The gold deposits are structurally controlled by a first-order, Sinistral transcrustal Mauch Shear Zone, which is parallel to a regional east-northeast penetrative foliation. The deposits are in dilation zones where the Mauch Shear (a) is intersected by a dextral east-west shear (Grid 2s), or (b) has a sinistral splay (Grid 4 and Renco). Close to these deposits, the Mauch Shear is in contact with a "greenstone belt", which is a possible source of crustal metamorphic ore fluids and gold. The Grid 2s deposit contains fine-grained, disseminated free gold, and small amounts of pyrrhotite, pyrite and chalcopyrite in quartz veins within third-order shears in K-feldspar granite. K-feldspar, sericitic, silicic, sulphidation and carbonate alteration characterizes the deposit, which has a proposed mantle-degassing model. The Grid 4 deposit is magmatic porphyry-type, with CuMo and Au in third- and fourth-order shears respectively. Mineralization comprises disseminated to semi-massive pyrrhotite, pyrite, chalcopyrite, sphalerite, bismuth, molybdenite and gold. Wall rock alteration includes biotitic, chloritic, silicic, sulphidation and carbonate. In Grid 2s, Grid 4 and Renco deposits, the alteration mineral assemblages are in three facies, which are granulite, amphibolte and greenschist. In the three deposits, the mineralization occurs with the amphibolite-facies, indicating post-peak, retrograde metamorphic conditions. / Illustrations (maps) only available in print form at Cory Library / KMBT_363 / Adobe Acrobat 9.54 Paper Capture Plug-in

Thesis (MTech (Chemical Engineering))--Cape Technikon, 2000. / The large quantities of wood chips produced at mines from damaged underground timber contain gold that cannot be completely recovered by cyanidation. A fungus that can degrade a portion of the wood matrix will allow the gold that was previously locked up, to come into contact with the cyanide solution during beneficiation, thereby improving recoveries. The fungus Phanerochaete chrysosporium produces enzymes that use the organic compounds found in lignin as substrate. Consequently, the fungus is able to selectively break down lignin, which is one of the major components of wood. Chips sampled from Vaal Reef Mine contained between 2 and 5 mg/kg gold. The main source of gold in the chips was determined to be impregnated gold-bearing ore and discrete gold particles. Direct cyanidation resulted in around 60 per cent recovery prior to biological treatment. Despite relatively high weight losses caused to the chips as a result of treatment with Phanerochaete chrysosporium gold recovery only increased 10 per cent after 4 weeks treatment compared to direct recovery without treatment.

The environmental impact of the Robinson Deep mine residue deposit in Johannesburg was assessed by evaluating the water chemistry and surface precipitates, thereby identifying the processes responsible for forming the contamination footprint. Precipitates were compared to a documented paragenetic sequence of mineral formation associated with sulphide rich mine waste. PHREEQC, a geochemical modelling tool, was utilized to predict the formation of precipitates from evaporation ponds. The chemistry of the leachate was analysed and compared to water quality standards in order to determine the possible environmental impact. The chemistry of the water emanating from the mine residue deposit reveals that an Fe-SO4 dominant chemistry persists, this is consistent with acid mine drainage environments. The most toxic cations and anions contained in the water are Fe, Al, Mn, Ca, As, Mg, Cu, Zn, Pb and SO . It is predicted that the impact of toxic metals identified in the water decreases further from the mine residue deposit due to dilution and co-precipitation with different mineral phases such as goethite. Precipitates identified include jarosite group minerals, goethite, melanterite, copiapite, Mg-copiapite, halotrichite, pickeringite, gypsum and alunogen. These secondary minerals may be used as indicator minerals of acid mine drainage. Assessment and prediction of the stage of contamination and possible environmental impact, may, therefore be pursued when comparing the indicator minerals to predicted paragenetic sequences. For example, the precipitation of melanterite is consistent with an early stage of acid mine drainage development. The presence of melanterite thus suggests that oxidation of sulphides is an ongoing process on the Robinson Deep mine residue deposit. Evaporation of water in the evaporation ponds aids in increasing the concentration, hence allowing the predominant precipitation of jarosite group minerals. Alternatively, rainfall dilutes the water allowing dissolution of minerals located on the banks of the evaporation ponds to predominate. This mechanism of precipitation and dissolution is seasonal; formation of precipitates predominates during the dry season, while dissolution is most prominent during the wet season. The development of hardpans indicates that the main mechanism of formation of the associated phases is through capillary action at the sediment surface. Leaching of Fe2+-rich water from the mine residue deposit containment area is indicated by the presence of copiapite, while jarosite and goethite formation tend to form part of a hardpan layer. Goethite is an indication of a late stage mineral predominant at lower sulphate and higher pH conditions. Results of predicted formation of precipitates by PHREEQC are not in very good agreement with actual field observations. This is mainly due to the lack of thermodynamic data for many of the sulphate minerals observed. Hence, precipitates associated with acid mine drainage may be utilized as indicator minerals. Consequently, there identification may facilitate in environmental monitoring and risk assessment. / Prof. J. M. Huizenga Prof. J. Gutzmer