The objective of this research is to determine how the sandwich's physical characteristics have an impact on the mechanical properties, determine under what conditions the specimens will be lighter and mechanically stronger, and determine if the use of an aluminum honeycomb sandwich as a construction material is feasible. The research has aimed at the use of aluminum sandwiches as light and strong material. The study of the structural layers' damage resistance and tolerance demonstrated that the top and bottom layers play a crucial role. The thesis presents three test results from aluminum honeycomb sandwich compression horizontal, compressive vertical, and bending tests. Also, each group was displayed mechanically and simulated in Abaqus. The study determines the mechanical properties such as maximum elastic stress-strain, ultimate stress-strain, fracture point, density, poison ration, young modulus, and maximum deflection was determined. The energy absorbed by the FEA, such modulus of elasticity, resilience, and toughness, the crack propagation, the test's view shows aluminum honeycomb behaved like a brittle material with both compression test. And the maximum deflection, crack propagation, shear forces, bending moment, and images illustrated that the layers play a crucial role in the 3-point bend test.

Thesis advisor: Fazel Tafti / The search for an ideal quantum spin-liquid (QSL) material which can host a QSL ground state as well as exotic excitations has been one of the leading research topics in condensed matter physics over the past few decades. Out of all the proposals to realize the physics of a QSL, the Kitaev model is the most promising proposal with a QSL ground state. The Kitaev Hamiltonian is exactly solvable via fractionalization of its spin degrees of freedom into Majorana excitations, and it can be engineered in real materials. Among all the proposed Kitaev candidates, α-Li2IrO3, Na2IrO3, Li2RhO3, and α-RuCl3 are the most promising candidates. During my Ph.D. research I explored new physics related to Kitaev materials via modification of the symmetry and structural properties of these known Kitaev candidates. First, I studied how modification of the inter-layer chemistry can alter the thermodynamic properties of Kitaev candidate α-Li2IrO3 via an enhancement of the spin-orbit coupling (SOC) effect. The light, octahedrally-coordinated inter-layer Li atoms are replaced with heavier, linearly-coordinated Ag atoms to synthesize Ag3LiIr2O6. In addition to these structural modifications to the parent compound α-Li2IrO3, having heavier elements between the honeycomb layers in the Ag compound increased the effect of SOC in the honeycomb layers and led to a decrease in the long-range ordering temperature in Ag3LiIr2O6 compared to its parent compound. Second, I studied the effect of local crystal distortion in the presence of a weak SOC effect to explore a new spin-orbital state different from the Jeff=1/2 state. Based on theoretical predictions, the ground states of Kitaev materials can be tuned to other exotic spin-orbital states such as an Ising spin-1/2 state. To provide the proper conditions for a competition between the trigonal crystal distortion and the SOC effect, I modified the crystal environment around the magnetic elements in the parent compound Li2RhO3 via a topo-chemical method and synthesized Ag3LiRh2O6. An increase in the strength of trigonal distortion in Ag3LiRh2O6, in the presence of weak SOC, led to a transition from the Jeff=1/2 ground state (Kitaev limit) in the parent compound to an Ising spin-1/2 ground state (Ising limit) in the product. This change in spin-orbital state resulted in a dramatic change in magnetic behavior. Whereas Li2RhO3 shows a spin-freezing transition at 6 K, Ag3LiRh2O6 reveals a robust long-range antiferromagnetic transition at 94 K. This is the first realization of a change of ground state between the Kitaev and Ising limits in the same structural family. Lastly, I studied how the crystal symmetry can be an important factor in the physics of Kitaev materials. Honeycomb layered materials can be crystallized in space groups C2/m, C2/c, and P6_322. However, the crystal symmetry of most Kitaev candidates is described by the C2/m space group. We successfully synthesized a polymorph of a 3d Kitaev candidate, hexagonal Na2Co2TeO6 (P6_322 space group) in space group C2/m. The change in crystal symmetry of this cobalt tellurate replaced three anti-ferromagnetic (AFM) orders at 27, 15, 7 K in the hexagonal polymorph by a single AFM peak at 9.6 K in the monoclinic Na2Co2TeO6. / Thesis (PhD) — Boston College, 2023. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Physics.

Shape morphing in aerospace structures has the potential to reduce noise, improve efficiency, and increase the adaptability of aircraft. Among the many challenges in developing morphing technologies is finding suitable wing skin materials that can be both stiff to support the structural loads, while being elastic and compliant to support this shape morphing an minimize actuation energy. This remains an open challenge, but many possible solutions have been found in smart materials, namely shape memory alloys and polymers. Of these, shape memory polymers have received more attention for wing skins due to their low density and cost, and high elastic limits in excess of 100% strain, but they suffer from generally low overall moduli. Shape memory polymer composites have been considered to address this, typically in the form of particulate/nanoscale reinforcements or by using them as matrix materials in laminate composites. While these can serve to increase the stiffness of the composite, there is still a present need for reinforcement strategies that can also maintain the large changes in stiffness of shape memory polymers. An alternative shape memory composite relies on honeycomb materials with shape memory polymer infills. Previous research has shown that polymer filled honeycombs exhibit greater in-plane moduli greater than the infill or honeycomb alone, but there has been little research focused on understanding this behavior. Moreover, while most engineered cellular structures are comprised of symmetric and periodic cells, cellular structures in nature are commonly spatially varying, asymmetric networks, which have not been considered in these composites. Motivated by these challenges in designing materials for shape morphing, this work seeks to explore the use of shape memory polymer-filled honeycomb composites for use as variable stiffness materials. First, the interaction between infill and the honeycomb, and the relationship between the honeycomb geometry and the effective composite properties is not well understood. This research first investigates the mechanisms of stiffening in these composites through both unit cell finite element models and through experimental characterization. Parametric studies are completed for selected honeycomb geometry design variables, and three key mechanisms of stiffening are identified. Next, these mechanisms are further supported by experimental studies, and comparisons are made showing the limitations of the few existing analytic models. With the knowledge gained from these studies, shape memory polymer infills are considered to create variable stiffness composites. In the first study, sizing design variables are selected to parametric the honeycomb cell geometry, with the designs constrained to be symmetric in-plane. A constrained multiobjective design optimization is completed for two chosen performance objectives, and corresponding local sensitivity studies are completed as well. The results predict that these composites meet and exceed the current bounds of both shape memory polymers and their composites, but also variable stiffness materials in general. A great degree of tailorability is demonstrated, and the model predictions are validated against experimental results from fabricated honeycomb composite samples. Next, generally asymmetric cell geometries are considered by defining shape design variables for the cell geometry. These cells are constrained to be periodic but not symmetric, allowing for the possible benefits of asymmetric to be investigated. Additionally, interconnected and spatially varying multicell unit cells are considered, further allowing for the study of spatially varying cell geometries. Multiobjective optimizations are completed for two unit cell cases, and Pareto fronts are identified. The results are compared to both those from the sizing optimization study and to the current state of the art, and are similarly found to demonstrate high performance and a great degree of tailorability in effective properties. / Doctor of Philosophy / Vehicle shape morphing, the smooth, continuous change of an aircraft's external shape, can greatly improve the efficiency and reduce noise in modern and future vehicles. Among the is challenges in this field is finding suitable skin materials that can be both stiff to support the forces exerted on an aircraft, while being soft and compliant to support this shape morphing. Smart materials, namely shape memory polymers, present many attractive options for this need, but generally need to have a higher stiffness to be suitable for large scale applications. To address this, adding reinforcements to shape memory polymers has been of interest, and current work has largely been focused on using long fiber composites or particulate and nano-reinforcements. As an alternative to these strategies, inspiration can be found in nature where polygon cells are a common means of reinforcement in both plants and animals. Motivated by the current state of the art and the promise of shape morphing structures, this work seeks to investigate cellular structures in the form of hexagonal honeycombs as a means of increasing the stiffness of shape memory polymer infills. This is done by first improving the understanding of more general polymer-filled honeycomb, which exhibit effective stiffnesses greater than the honeycomb or polymer alone. With a working understanding of how the honeycomb stiffens the infill and how the cell geometry influences this behavior, variable modulus infills are next considered. First, sizing design variables (i.e. the lengths and thicknesses of the honeycomb geometry) are selected to describe cell geometries. Design optimization problems are considered and used to estimate the bounds of possible performance for these composites. Relationships between the design variables and the composite performance are investigated, and an improved understanding of these composites is developed. Next, shape design variables are selected to allow for the asymmetry and spatial variation found in natural cellular structures, and similar design optimizations are completed. The results of this work are experimentally validated, and demonstrate that these composites allow for combinations of stiffness and stiffness change that meet and exceed the current state of the art. Furthermore, tailoring the cell geometry allows for an easy means of changing the behavior of the composite. This work represents a great improvement and an important step in overcoming the challenges in developing shape morphing systems.

Sandwich Panels with cellular cores are widely used in the aerospace industry for their higher stiffness to mass, strength to mass ratio, and excellent energy absorption capability. Even though, sandwich panels are considered state of the art for lightweight aerospace structures, the requirement to further reduce the mass exists due to the direct impact of mass on mission costs. Traditional manufacturing techniques have limited the shape of the cores to be either hexagonal or rectangular, but, with rapid advancements in additive manufacturing, other core shapes can now be explored. This research aims to identify and evaluate the mechanical performance of two-dimensional cores having standard wall geometry, which provide higher specific stiffness than honeycomb cores. Triangular cores were identified to have higher specific in-plane moduli and equivalent specific out-of-plane and transverse shear moduli. To consider practical use of the triangular cores, elastic and elastic-plastic structural analysis was performed to evaluate the stiffness, strength, failure, and energy absorption characteristics of both the core and sandwich panels. The comparison made between triangular cores and hexagonal cores having the same cell size and relative density showed that triangular cores outperform hexagonal cores in elastic range and for applications where in-plane loading is dominant. Triangular cores also have excellent in-plane energy absorption capabilities at higher densities. / Master of Science

The mite ectoparasite Varroa destructor, poses a serious threat for the survival of the Apis mellifera colonies. The intensive use of acaricidal products is one of the most common methods for defending bees from Varroa that can cause the contamination of the wax foundation used in beekeeping. The natural honeycomb management could provide a solution for this problem, because it involves the use of frames without wax foundation which allows the bees to build a complete comb ex novo. On the other hand, colonies which are free to build cells of their choice, usually build a number of drone cells higher than colonies managed with the wax foundation. This could potentially lead to several negative consequences because the V. destructor reproductive success is greater on drone broods than on worker broods. The aim of the present study was to examine the colony development, to evaluate the honey production and to monitor the growth of V. destructor infestations and associated virus infections in Apis mellifera colonies managed by using natural honeycombs compared with the conventional management. Several colony parameters were measured in spring and summer. The strength of the colony was used to estimate the worker and drone populations. In order to measure the V. destructor infestations were used several methods, such as the natural mite fall, the powdered sugar roll, the soapy water and the brood cell uncapping. Molecular analysis was performed in order to measure the viral load of five Apis mellifera viruses. The honey produced was measured by collecting the honey stored in the supers, which are boxes placed on a beehive for bees to store. The results showed that the higher presence of drone brood in the colonies managed using the natural honeycomb did not negatively affect the colony development nor the mite V. destructor population compared to control colonies. The molecular analysis showed that the DWV was the most common virus found in bee samples, and its viral load was more influenced from the mite infestation rate than from the treatment. The analysis carried out in this study showed that the natural honeycomb management can represent a valid alternative to the wax foundation. This kind of colony management thus appears to contradict our primary hypothesis which was that letting the bees build their own honeycomb would have led to a significant increase in the V. destructor infestation. Productivity data did not provide reliable results about the difference between the natural honeycomb and the conventional colony management due to climatic adversities. Further studies will be performed to better investigate this aspect. Data about the natural mite fall and the estimation of the mite population in the phoretic/reproductive phases provided a useful starting point for further studies on the correct timing to carry out acaricide treatments both in conventional and natural honeycomb managed colonies.

<p> </p> <p>ndoor air quality (IAQ) due to the presence of airborne microorganisms or bioaerosols (0.01-10 μm) in indoor spaces has been a concern for many years; however, it gained significant attention during the COVID-19 pandemic. Photocatalytic oxidation (PCO) has shown promising potential to kill microorganisms (removal/disinfection) and has already been in use within HVAC systems to treat volatile organic compounds (VOCs) (treatment). The main motivation of this work is to understand whether PCO devices can be used for bioaerosol removal in indoor spaces by integrating them with HVAC systems. Among the various factors that influence the adoption of PCO for large-scale bioaerosol removal, this work specifically tries to investigate two factors 1) whether the commercially available PCO reactors for treatment can be used for removal/disinfection or not, and 2) how to setup a standardized experimental setup for evaluating the removal efficiency of these systems. Generally, most of the commercial PCO devices use UV- based photocatalysis, so the removal efficiency is a combination of inactivation by UV and the reactive oxygen species produced by photocatalytic reactions (pure photocatalytic effect).</p> <p>In this work, the bioaerosol transport and the photon transport in a reactor is hypothesized as central to using the photocatalytic effect to inactivate microorganisms. This study uses analytical models to estimate the collection efficiency of the bioaerosols inside the honeycomb channels as a function of non-dimensional aspect ratios and velocity typical of HVAC systems. Subsequently, the collection efficiency results are overlaid with the prior literature results on photon transport inside such channels to present a limiting case for the removal efficiency of these systems. Another crucial factor for the performance of PCO systems is to investigate about the bioaerosol remediation on a photocatalyst substrate. Since there are many challenges associated with the numerical modeling of this phenomenon, this work developed a standardized experimental setup at the Herrick Laboratories, Purdue to investigate these interactions and further validate the previous hypothesis .The setup is constructed to systematically characterize the bioaerosol flowing through the airstream and measure data crucial to the PCO reactor performance, such as fluence rate field, number concentration (#/cm3), and viable concentration (CFU or PFU/m3) of the microorganisms upstream and downstream of the treatment sections. </p> <p>The collection efficiency (CE) of bioaerosols in honeycomb channels with velocities typical to HVAC systems were estimated using analytical models, and the results were presented in dimensionless aspect ratios (AR= Lch/ Dch). Based on the CE modeling results, the highest CE for aspect ratio 25 was less than 20% for the entire bioaerosol size range. From the prior literature results on photon transport, it was found that the intensity of the light reduced significantly for aspect ratios less than or equal to 6. Based on these results, it was found that the existing honeycomb geometries weren’t effective for PCO disinfection in operating conditions typical of HVAC systems. Since there aren’t any existing well-established methods to experimentally investigate these kinds of systems, this work will present the details about the development of the proposed methods inspired from prior literature for general air cleaning devices and small-scale PCO experiments. Furthermore, a detailed discussion about the important subsystems such as aerosol generation subsystem, sampling subsystem, and reactor subsystem which is crucial to investigating the hypotheses is presented in this thesis. Finally, some preliminary results on each of these characterization experiments to test the hypotheses has been presented in this thesis.</p>

No description available.

A better understanding of the effect of impact damage on composite structures is necessary to give the engineer an ability to design safe, efficient structures. Current composite structures suffer severe strength reduction under compressive loading conditions, due to even light damage, such as from low velocity impact. A review is undertaken to access the current state-of-development in the areas of experimental testing, and analysis methods. A set of experiments on Nomex honeycomb core sandwich panels, with thin woven fiberglass cloth facesheets, is described, which includes detailed instrumentation and unique observation techniques. These techniques include high speed video photography of compression after impact (CAI) failure, as well as, digital image correlation (DIC) for full-field deformation measurements. The effect of nominal core density on the observed failure mode is described. A finite element model (FEM) is developed to simulate the experiments performed in the current study. The purpose of this simulation is to predict the experimental test results, and to conrm the experimental test conclusions. A newly-developed, commercial implementation of the Multicontinuum Failure Theory (MCT) for progressive failure analysis (PFA) in composite laminates, Helius:MCT, is included in this model. The inclusion of PFA in the present model gives it the new, unique ability to account for multiple failure modes. In addition, significant impact damage detail is included in the model as a result of a large amount of easily available experimental test data. A sensitivity study is used to assess the effect of each damage detail on overall analysis results. Mesh convergence of the new FEM is also discussed. Analysis results are compared to the experimental results for each of the 32 CAI sandwich panel specimens tested to failure. The failure of each specimen is accurately predicted in a high-fidelity, physics-based simulation and the results highlight key improvements in the understanding of honeycomb core sandwich panel CAI failure. Finally, a parametric study highlights the strength benefits compared to mass penalty for various core densities. / Ph. D.

Die vorliegende Arbeit befasst sich mit dem Dünnfilmwachstum der ternären Oxide Na2IrO3, Li2IrO3, Y2Ir2O7 und YBiO3. All diesen oxidischen Materialien ist gemein, dass sie Verwirklichungen sogenannter Topologischer Isolatoren oder Spin-Flüssigkeiten sein könnten. Diese neuartigen Materiezustände versprechen eine zukünftige Anwendung in der Quantencomputation, in magnetischen Speichern und in elektrischen Geräten mit geringer Leistungsaufnahme. Die Herstellung der hier gezeigten Dünnfilme ist daher ein erster Schritt zur Umsetzung dieser Anwendungen in der Zukunft. Alle Dünnfilme werden mittels gepulster Laserplasmaabscheidung auf verschiedenen einkristallinen Substraten hergestellt. Die strukturellen, optischen und elektrischen Eigenschaften der Filme werden mittels etablierter experimenteller Verfahren wie Röntgenbeugung, spektroskopischer Ellipsometrie und elektrischenWiderstandsmessungen untersucht. Die strukturellen Eigenschaften von erstmalig in der Masterarbeit des Authors verwirklichten Na2IrO3-Dünnfilmen können durch Abscheidung einer ZnO-Zwischenschicht deutlich verbessert werden. Einkristalline Li2IrO3-Dünnfilme mit einer definierten Kristallausrichtung werden erstmalig hergestellt. Die Messung der dielektrischen Funktion gibt Einblick in elektronische Anregungen, die gut vergleichbar mit Li2IrO3-Einkristallen und verwandten Iridaten sind. Des Weiteren wird aus den Daten eine optische Energielücke von ungefähr 300 meV bestimmt. In Y2Ir2O7-Dünnfilmen wird eine mögliche (111)-Vorzugsorientierung in Wachstumsrichtung gefunden. Im Vergleich mit der chemischen Lösungsabscheidung zeigen die hier mittels gepulster Laserplasmaabscheidung hergestellten YBiO3-Dünnfilme eine definierte, biaxiale Kristallausrichtung in der Wachstumsebene bei einer deutlich höheren Schichtdicke. Über die gemessene dielektrische Funktion können eine direkte und indirekte Bandlücke bestimmt werden. Deren Größe gibt eine notwendige experimentelle Rückmeldung an theoretische Berechnungen der elektronischen Bandstruktur von YBiO3, welche zur Vorhersage der oben erwähnten, neuartigen Materiezuständen verwendet werden. Nach einer Einleitung und Motivation dieser Arbeit gibt das zweite Kapitel einen Überblick über den gegenwärtigen Forschungsstand der hier untersuchten Materialien. Die folgenden zwei Kapitel beschreiben die Probenherstellung und die verwendeten experimentellen Untersuchungsmethoden. Anschließend werden für jedes Material einzeln die experimentellen Ergebnisse dieser Arbeit diskutiert. Die Arbeit schließt mit einer Zusammenfassung und einem Ausblick. / The present thesis reports on the thin film growth of ternary oxides Na2IrO3, Li2IrO3, Y2Ir2O7 and YBiO3. All of these oxides are candidate materials for the so-called topological insulator and spin liquid, respectively. These states of matter promise future application in quantum computation, and in magnetic memory and low-power electronic devices. The realization of the thin films presented here, thus represents a first step towards these future device applications. All thin films are prepared by means of pulsed laser deposition on various single-crystalline substrates. Their structural, optical and electronic properties are investigated with established experimental methods such as X-ray diffraction, spectroscopic ellipsometry and resistivity measurements. The structural properties of Na2IrO3 thin films, that were previously realized in the author’s M. Sc. thesis for the first time, are improved significantly by deposition of an intermediate ZnO layer. Single-crystalline Li2IrO3 thin films are grown for the first time and exhibit a defined crystal orientation. Measurement of the dielectric function gives insight into electronic excitations that compare well with single crystal samples and related iridates. From the data, an optical energy gap of about 300 meV is obtained. For Y2Ir2O7 thin films, a possible (111) out-of-plane preferential crystal orientation is obtained. Compared to chemical solution deposition, the pulsed laser-deposited YBiO3 thin films presented here exhibit a biaxial in-plane crystal orientation up to a significantly larger film thickness. From the measured dielectric function, a direct and indirect band gap energy is determined. Their magnitude provides necessary experimental feedback for theoretical calculations of the electronic structure of YBiO3, which are used in the prediction of the novel states of matter mentioned above. After the introduction and motivation of this thesis, the second chapter reviews the current state of the science of the studied thin film materials. The following two chapters introduce the sample preparation and the employed experimental methods, respectively. Subsequently, the experimental results of this thesis are discussed for each material individually. The thesis concludes with a summary and an outlook.

Failure modes for sandwich beams of GFRP laminate skins and Nomex honeycomb core are investigated. Theoretical models using honeycomb mechanics and classical beam theory are described. A failure mode map for loading under 3-point bending, is constructed, showing the dependence of failure mode and load on the ratio of skin thickness to span length and honeycomb relative density. Beam specimens are tested in 3-point bending. The effect of honeycomb direction is also examined. The experimental data agree satisfactorily with the theoretical predictions. The results reveal the important role of core shear in a sandwich beam's bending behaviour and the need for a better understanding of indentation failure mechanism. High order sandwich beam theory (HOSBT) is implemented to extract useful information about the way that sandwich beams respond to localised loads under 3-point bending. 'High-order' or localised effects relate to the non-linear patterns of the in-plane and vertical displacements fields of the core through its height resulting from the unequal deformations in the loaded and unloaded skins. The localised effects are examined experimentally by Surface Displacement Analysis of video images recorded during 3-point bending tests. A new parameter based on the intrinsic material and geometric properties of a sandwich beam is introduced to characterise its susceptibility to localised effects. Skin flexural rigidity is shown to play a key role in determining the way that the top skin allows the external load to pass over the core. Furthermore, the contact stress distribution in the interface between the central roller and the top skin, and its importance to an indentation stress analysis, are investigated. To better model the failure in the core under the vicinity of localised loads, an Arcan- type test rig is used to test honeycomb cores under simultaneous compression and shear loading. The experimental measurements show a linear relationship between the out-of-plane compression and shear in honeycomb cores. This is used to derive a failure criterion for applied shear and compression, which is combined with the high order sandwich beam theory to predict failure caused by localised loads in sandwich beams made of GFRP laminate skins and Nomex honeycomb under 3-point bending loading. Short beam tests with three different indenter's size are performed on appropriately prepared specimens. Experiments validate the theoretical approach and reveal the nature of pre- and post-failure behaviour of these sandwich beams. HOSBT is used as a compact computational tool to reconstruct failure mode maps for sandwich panels. Superposition of weight and stiffness contours on these failure maps provide carpet plots for design optimisation procedures.