Le contrôle actif a souvent été considéré pour la maîtrise du bruit basse fréquence rayonné par les panneaux d’habillage dans les cabines des avions et hélicoptères. Ces panneaux sont classiquement réalisés en matériaux sandwich nid d’abeille (nida), du fait de leur très bon rapport résistance/masse. La mise en œuvre des techniques de contrôle actif sur des panneaux de type nida n’a pas toujours donné des résultats à la hauteur des attentes. Le travail présenté dans cette thèse introduit un modèle coque/volume/coque (SVS) de panneau nida équipé de pastilles piézoélectriques, valide ce modèle expérimentalement et propose une analyse des limitations de performance du contrôle actif. Pour la modélisation des panneaux nida, la principale difficulté est d’estimer les propriétés effectives d’un matériau homogène équivalent au cœur. On introduit une procédure d’homogénéisation numérique à partir d’un modèle 3D très détaillé de la structure du nida. Cette procédure est basée sur la corrélation des modes périodiques du modèle 3D et du modèle SVS. L’utilisation de modes périodiques permet l’analyse détaillée de l’influence des constituants dans le comportement vibratoire du nida, en particulier de la couche de colle et des peaux du sandwich. Des essais vibratoires mettent en évidence les effets viscoélastiques présents pour les nida à base de papier Nomex. Ces effets sont pris en compte dans le modèle SVS en utilisant des paramètres élastiques dépendant de la fréquence. On intègre ensuite des actionneurs et capteurs piézoélectriques au modèle de panneau nida validé. Différentes stratégies pour l’intégration du modèle proposé dans un processus de conception sont discutées. On montre enfin que la réponse statique à une tension électrique correspond à une cloque, flexion très localisée des peaux plutôt que flexion globale du panneau. Il en résulte une mauvaise performance des actionneurs. Cet effet local est retrouvé sur un modèle de panneau d’habillage réaliste étudié à l’ONERA. / Active control has often been considered for low frequency control of noise radiated by trim panels inside aircraft or helicopter cabins. Trim panels are usually made of honeycomb core sandwich because of their high strength to mass ratio. Active control techniques applied to honeycomb panel have not always given results as good as expected and this thesis aims to understand these limitations based on validated mechanical models of the active panels. For the modeling of honeycomb panels, the main difficulty is to estimate equivalent properties for the core. A numerical homogenization procedure is introduced to estimate effective parameters of a shell/volume/shell model based on the correlation with periodic modes of a detailed 3D model. The use of periodic modes allows a detailed analysis of the influence of constituent properties, especially glue and skin. Tests show that the considered Nomex based honeycomb has significantly viscoelastic behavior. In the model, the viscoelastic behavior of the core is taken into account by a frequency dependence of material parameters. Piezoelectric actuators and sensors are included in the validated honeycomb model. Strategies for integration in a numerical design process are discussed. Finally, the static response to an applied voltage is shown to correspond to a blister shape with local bending of the skin rather than global bending of the panel. This behavior results in poor actuator performance, which is also found in a realistic panel configuration studied at ONERA.

The diploma thesis is focused on experimental reduction of nitrogen oxides on special catalysts. The latest and state-of-the-art flue gas cleaning technologies are used. Selective catalytic reduction results in the desired level of pollution. It is necessary to meet the prescribed emission limit. A ceramic honeycomb filter based on vanadium and titanium is used as the catalyst. The entire measurement is carried out on the experimental INTEQ II unit, which is installed in the flue gas cleaning laboratory at NETME Center. It is shown which operating parameters achieve better efficiency of flue gas cleaning. Comparison of the BASF and CERAM catalysts is also performed. Finally, a material balance of the system is performed and a new external electric heater is designed to accelerate the heating process.

The emergence of freeform architecture provides interesting geometric challenges with regards to the design and manufacturing of large-scale structures. To design these architectural structures, we have to consider two types of constraints. First, aesthetic constraints are important because the buildings have to be visually impressive. Sec- ond, functional constraints are important for the performance of a building and its e cient construction. This thesis contributes to the area of architectural geometry. Specifically, we are interested in the geometric rationalization of freeform architec- ture with the goal of combining aesthetic and functional constraints and construction requirements. Aesthetic requirements typically come from designers and architects. To obtain visually pleasing structures, they favor smoothness of the building shape, but also smoothness of the visible patterns on the surface. Functional requirements typically come from the engineers involved in the construction process. For exam- ple, covering freeform structures using planar panels is much cheaper than using non-planar ones. Further, constructed buildings have to be stable and should not collapse. In this thesis, we explore the geometric rationalization of freeform archi- tecture using four specific example problems inspired by real life applications. We achieve our results by developing optimization algorithms and a theoretical study of the underlying geometrical structure of the problems. The four example problems are the following: (1) The design of shading and lighting systems which are torsion-free structures with planar beams based on quad meshes. They satisfy the functionality requirements of preventing light from going inside a building as shad- ing systems or reflecting light into a building as lighting systems. (2) The Design of freeform honeycomb structures that are constructed based on hex-dominant meshes with a planar beam mounted along each edge. The beams intersect without torsion at each node and create identical angles between any two neighbors. (3) The design of polyhedral patterns on freeform surfaces, which are aesthetic designs created by planar panels. (4) The design of space frame structures that are statically-sound and material-e cient structures constructed by connected beams. Rationalization of cross sections of beams aims at minimizing production cost and ensuring force equilibrium as a functional constraint.

The diploma thesis deals with Formula Student Impact Attenuator design of TU Brno Racing team. The aim of the thesis is the design, the dynamic tests and the production of Impact Attenuator of racing formulas called Dragon 4 and Dragon 5, so to meet the Formula Student rules. The thesis deals further with FEM dynamic analysis of Impact Attenuator.

Introduction Solid targets for PET and SPECT radionuclides are getting popular. For radiohalogens the limiting factor, beside the high cost of enriched target material is beam current due to poor heat conductivity of the target material(s). We have designed a honeycomb solid target which has advantages over the traditional circular hole de-sign: 1) Even distribution of target material, 2) it takes higher beam current, 3) less target material loss during distillation (1) and 4) no “creeping” (surface tension phenomena) of the target material during distillation. Material and Methods The target (see FIG. 1.) consists of 19 hexagonal 0.3 mm deep openings (see FIG. 2.) thus having 84% transparency/transmission, in a 24×2 mm platinum disk. There is a 10mm circular cavity on the reverse side giving a 200µm thickness of the platinum. The irradiations were performed on an IBA twin 18/18 Cyclon equipped with a Costis sold target system. The target material thickness was ~300mg/cm2 124TeO2 (> 99.9% I.E., Isoflex) with 5% w/w Al2O3 (99.99%, Sigma-Aldrich). The target was irradiated with 14.8MeV protons (18 MeV degraded by 500µm aluminium). Results and Conclusion The target was able to take beam current up to ~35 µA (higher BCs have not yet been investigated); our “traditional” target (10mm circular hole) has a limit of ~ 20 µA. This means that the effective yield is ~ 50 % higher with the honeycomb as compared with the “traditional” target design.

Polymeric isoporous membranes have many interesting properties leading to various specific applications in different fields. However, such structures also have one main drawback, namely their poor solvent stability, which should be improved to extend the range of their possible applications. Therefore, this project will focus on the enhancement of solvent stability of polymeric isoporous membranes by UV cross-linking. Stable isoporous films were obtained by creating honeycomb membranes from star polystyrene (PS) and its derivatives. The star PS was synthesized by Atom Transfer Radical Polymerization (ATRP) method and was then functionalized with methacrylate groups. The isoporous films made from these materials maintained the honeycomb structures after curing by UV light and immersion in chloroform. The crosslinking of PS under UV light exposure rather than the cross-linking of the methacrylates groups was responsible for the solvent stability of these membranes. To further investigate the effect of specific end-groups on the film stability, PEG2k-G3-PCL30 linear-dendritic-linear hybrid polymers and its derivatives with allyl, acrylate, methacrylate end-groups were employed to cast films. Functionalized PEG2k-G3-PCL30 linear-dendritic-linear hybrid isoporous films were cross-linked by UV-induced thiol-ene reactions and allyl reactions. However, no significant increase in the solvent stability of these kinds of films was observed. When mixing PEG2k-G3-PCL30 linear-dendritic-linear hybrids with star PS, stable isoporous films could be obtained. The pores became smaller but the isoporous structures were still kept.

Drywall board-based structures, a competent and cost-effective method of providing flexible partitioning assemblies in commercial and residential houses, are now widely used as walls or ceilings. However, the gypsum-based drywall that has been used in construction is not water-resistant and can create problems such as mold growth and structural defects. The aim of this study is 1) to develop a new sandwich panel with better physical and mechanical properties using locally sourced materials 2) to investigate the long-term hygrothermal performance of the new sandwich panel through using a numerical simulation. The sandwich panel is composed of two different thicknesses of kraft-paper honeycomb core bonded to two cementitious panels with silicone-based adhesive. The experimental results show that the sandwich panel with a thicker core has lower thermal conductivity and higher flexural strength compared to the gypsum-based drywall. The heat and moisture performance of two wall structures were performed using the WUFI Pro simulation program. The results of the modeling analysis present that wall assembly with gypsum-based drywall has higher water content than multilayer sandwich panel. In addition, the multilayer sandwich panel shows a 4.6% lower annual heat flow compared to the reference wall.

In the industry, all passenger vehicles are treated with damping materials to reduce structure-borne sound. Though these damping materials are effective to attenuate structure-borne sound, they have little or no effect on the air-borne sound transmission.The lack of effective predictive methods for assessing the acoustic effects due to added damping on complex industrial structures leads to excessive use of damping materials.Examples are found in the railway industry where sometimes the damping material applied per carriage is more than one ton. The objective of this thesis is to provide a better understanding of the application of these damping materials in particular when applied to lightweight sandwich panels. As product development is carried out in a fast pace today, there is a strong need for validated prediction tools to assist in the design process. Sound transmission loss of sandwich plates with isotropic core materials can be accurately predicted by calculating the wave propagation in the structure. A modified wave propagation approach is used to predict the sound transmission loss of sandwich panels with honeycomb cores. The honeycomb panels are treated as being orthotropic and the wave numbers are calculated for the two principle directions. The orthotropic panel theory is used to predict the sound transmission loss of panels. Visco-elastic damping with a constraining layer is applied to these structures and the effect of these damping treatment on the sound transmission loss is studied. Measurements are performed to validate these predictions. Sound radiated from vibrating structures is of great practical importance.The radiation loss factor represents damping associated with the radiation of sound as a result of the vibrating structure and can be a significant contribution for structures around the critical frequency and for composite structures that are very lightly damped. The influence of the radiation loss factor on the sound reduction index of such structures is also studied. / QC 20100519 / ECO2-Multifunctional body Panels

This thesis presents a theory of electron-electron interaction effects and optical properties of nanostructures of two-dimensional (2D) honeycomb crystals - graphene and transition metal dichalcogenides (TMDC). Graphene, a semimetallic hexagonal lattice of carbon atoms can be described by a massless Dirac fermion model, with the conduction band (CB) and valence band (VB) touching in the corners of a hexagonal Brillouin zone, valleys K and -K. TMDC crystals sites host either a transition metal atom or a chalcogen dimer, which opens the energy gap and allows for describing their low-energy nature with massive Dirac fermion (mDf) model. The metal atom in TMDC crystals causes strong spin-orbit (SO) coupling, resulting in large SO splitting in bands at both valleys. For TMDCs it is possible to excite carriers in each valley with oppositely circularly polarised light, which offers promising prospects for devices based on electrons valley index, i.e. valleytronic devices. Additionally, the optical response of TMDCs is enhanced by the presence of secondary CB minima, at Q-points. The dimensionality of 2D crystals can be further reduced to form quantum dots (QDs) - nanostructures con ned in all dimensions. This thesis first discusses hexagonal graphene QDs, which exhibit energy gap oscillation as a function of size, due to the edge type: zigzag or armchair. These QDs are divided into concentric rings, analysed with tight-binding (TB) model. An armchair edged QD is built from a zigzag edged QD by adding a 1D Lieb lattice of carbon atoms on its edge. The energy gap is formed differently for both edges: from the outer ring states for zigzag edge and from the 1D Lieb lattice zero-energy states for armchair edge, which causes the energy gap. The remaining portion of the thesis focuses on TMDC materials. First a TB model is presented for a member of TMDC group, MoS2, using three d orbitals of Mo atom and three p orbitals of the S2 dimers. The tunneling matrix elements between nearest-neighbor and next-nearest-neighbour sites are explicitly derived at K and -K to form a six band TB Hamiltonian. Its solutions are fitted to the bands obtained from the density functional theory ab initio calculations to obtain the correct behaviour of bands around K and additional minima at Q-points, which explains the role of d orbitals in TMDCs. Close to K the TB model is reduced to mDf model, which is then studied in response to light, yielding the valley-dependent selection rules for absorption. The interaction of mDf with light is further studied in the presence of strong external magnetic eld, which leads to the formation of Landau levels (LLs), asymmetric between both valleys, and valley Zeeman splitting. These LLs are populated with electrons to form a Hartree-Fock ground state (GS), which can exhibit valley polarisation due to the LL asymmetry. Quasi-electron-hole excitations out of the GS are then formed and their self-energy, vertex corrections and scattering energy is calculated. The effect of electron-electron interactions on valley Zeeman splitting is demonstrated and the Bethe-Salpeter equation is numerically solved to give magnetoexciton spectrum for both valleys. The results include a valley-dependent absorption spectrum for mDf magnetoexcitons that vary with the valley polarisation. The final part of this thesis discusses the single particle and interacting effects in gated MoS2 QDs. First, I perform a single electron atomistic calculation for a million-atom computational box with periodic boundary conditions based on a TB model developed from ab initio methods for bulk MoS2. Electrons are then con ned with a parabolic electrostatic potential from top metallic gates. They exhibit twofold degenerate harmonic oscillator energy spectrum with shell spacing ω associated with valleys K as well as a sixfold degenerate energy spectrum derived from the Q-points. The degeneracy of electronic shells is broken due to valley contrasting Berry curvature,which acts as an effective magnetic eld splitting opposite angular momentum states in both valleys. I populate up to ve K-derived harmonic oscillator shells with up to six electrons and turn on the electron-electron interactions. The resulting GS phases form two regimes dependent on ω, which are dominated each by a broken-symmetry phase, i.e. valley and spin polarised GS for low ω and valley and spin unpolarised but spin intervalley antiferromagnetic GS for higher ω. This behaviour is explained as an effect of the strong SO splitting, weak intervalley exchange interaction and strong correlations. Means of detecting these effects in experiment based on the spin and valley blockade are proposed. These results advance the understanding of interaction-driven breaking of symmetry for valley systems, crucial for designing of valleytronic devices in the future.

京都大学 / 0048 / 新制・課程博士 / 博士(理学) / 甲第19479号 / 理博第4139号 / 新制||理||1595(附属図書館) / 32515 / 京都大学大学院理学研究科物理学・宇宙物理学専攻 / (主査)准教授 戸塚 圭介, 教授 川上 則雄, 教授 石田 憲二 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM