This thesis presents the results of a research project to develop methods to carry out fire safety design of welded steel tubular trusses at elevated temperatures due to fire exposure. It deals with three subjects: resistance of welded tubular joints at elevated temperatures, effects of large truss deflection in fire on member design and effects of localised heating. The objectives of the project are achieved through numerical finite element modelling at elevated temperatures using the commercial Finite Element software ABAQUS v6.10-1 (2011). Validation of the simulation model for joints is based on comparison against the test results of Nguyen et al. (2010) and Kurobane et al. (1986). Validation of the simulation model for trusses is through checking against the test results of Edwards (2004) and Liu et al. (2010).For welded tubular joints, extensive numerical simulations have been conducted on T-, Y-, X-, N- and non-overlapped K-joints subjected to brace axial compression or tension, considering a wide range of geometrical parameters. Uniform temperature distribution was assumed for both the chord and brace members. Results of the numerical simulations indicate for gap K- and N-joints (two brace members, one in tension and the other in compression) and for T-, Y- and X-joints with the brace member under axial tensile load (one brace member only, in tension), it is suitable to use the same ambient temperature calculation equation as in the CIDECT (2010) or EN 1993-1-8 (CEN, 2005a) design guides and simply replace the ambient temperature strength of steel with the elevated temperature value. However, for T-, Y- and X-joints under brace compression load (one brace member only, in compression), the effect of large chord deformation should be considered. Large chord deformation changes the chord geometry and invalidates the assumed yield line mechanism at ambient temperature. For approximation, the results of this research indicate that it is acceptable to modify the ambient temperature joint strength by a reduction factor for the elastic modulus of steel at elevated temperatures. In the current fire safety design method for steel truss, a member based approach is used. In this approach, the truss member forces are calculated at ambient temperature based on linear elastic analysis. These forces are then used to calculate the truss member limiting temperatures. An extensive parametric study has been carried out to investigate whether this method is appropriate. The parametric study encompasses different design parameters over a wide range of values, including truss type, joint type, truss span-to-depth ratio, critical member slenderness, applied load ratio, number of brace members, initial imperfection and thermal elongation. The results of this research show that due to a truss undergoing large displacements at elevated temperatures, some truss members (compression brace members near the truss centre) experience large increases in member forces. Therefore, using the ambient temperature member force, as in the current truss fire safety design method, may overestimate the truss member critical temperature by 100 °C. A method has been proposed to analytically calculate the increase in brace compressive force due to large truss deformation. In this method, the maximum truss displacement is assumed to be span/30. A comparison of the results calculated using the proposed method against the truss parametric study results has shown good agreement with the two sets of results, with the calculation results generally being slightly on the safe side. When different members of a truss are heated to different temperatures due to localised fire exposure, the brace members in compression experience increased compression due to restrained thermal expansion. To calculate the critical temperature of a brace member in a localised heated truss, it is necessary to consider this effect of restrained thermal expansion. It is also necessary to consider the beneficial effects of the adjacent members being heated, which tends to reduce the increase in compressive force in the critical member under consideration. Again, an extensive set of parametric studies have been conducted, for different load ratio, slenderness and axial restraint ratio. The results of this parametric study suggest that to calculate the critical temperature of a brace member, it is not necessary to consider the effects of the third or further adjacent members being heated. For the remainder of the heated members, this thesis has proposed a linear elastic, static analysis method at ambient temperature to calculate the additional compressive force (some negative, indicating tension) in the critical member caused by the heated members (including the critical member itself and the adjacent members). The additional compressive force is then used to calculate the limiting temperature of the critical member. For this purpose, the approximate analytical equation of Wang et al. (2010) has been demonstrated to be suitable.

A volume-averaged hollow cathode plasma model is presented that serves as a preliminary design tool for orificed hollow cathodes. The plasma discharge volume is subdivided into two computational domains with separate sub-models that are used to determine the emitter and orifice region plasma parameters. The plasma model is coupled with a lumped node thermal model that uses power inputs from the plasma model to estimate the temperature distribution of the hollow cathode. The model has been implemented for conventional cylindrical emitter geometries and for novel disc-shaped emitters. A lanthanum hexaboride (LaB6) hollow cathode has been used to validate the cylindrical model results and shows good agreement with well-known trends of hollow cathodes and published model data, while a calcium aluminate electride (C12A7:e-) hollow cathode developed at Technische Universität Dresden (TUD) served as the basis for the disc configuration. The model results of the disc configuration are presented and discussed to identify trends and optimization potential for hollow cathodes using C12A7:e- emitters. The model results in combination with thermal measurements of the TUD hollow cathode indicate a work function of C12A7:e- in a hollow cathode plasma below 2 eV.

There are many challenges in materializing the applications utilizing inorganic nanoparticles. The primary drawback is the degradation of properties due to aggregation and sintering either due to elevated temperatures or prevailing chemical/electrochemical conditions. In this thesis, various wet chemical synthesis methods are developed to obtain metal nanostructures with enhanced thermal stability. The thesis is organized as below: Chapter 1 presents the problems and challenges in materializing the application of nanomaterials associated with the thermal stability of nanomaterials. A review of the existing techniques to improve the thermal stability and the scope of the thesis are presented. Chapter 2 gives a summary of the various materials synthesized, the method adopted for the synthesis and the characterization techniques used in the material characterization. Chapter 3 presents a general template-less strategy for the synthesis of nanoporous alloy aggregates by controlled aggregation of nanoparticles in the solution phase with excellent control over morphology and composition as illustrated using PdPt and PtRu systems as examples. The Pt-based nanoporous clusters exhibit excellent activity for methanol oxidation with good long term stability and CO tolerance. Chapter 4 presents a detailed study on the thermal stability of spherical mesoporous aggregates consisting of nanoparticles. The thermal stability study leads to a general conclusion that nanoporous structures transform to hollow structures on heating to elevated temperatures before undergoing complete densification. Chapter 5 presents a simple and facile method for the synthesis of single crystalline intermetallic PtBi hollow nanoparticles. A mechanism is proposed for the formation of intermetallic PtBi hollow structures. The intermetallic PtBi hollow structures synthesised show excellent electrocatalytic activity for formic acid oxidation reaction. Chapter 6 presents a robust strategy for obtaining a high dispersion of ultrafine Pt and PtRu nanoparticles on graphene. The method involves the nucleation of a metal precursor phase on graphite oxide surfaces and subsequent reduction with a strong reducing agent. The electrocatalytic activity of the composites is investigated for methanol oxidation reaction. Chapter 7 presents a microwave-assisted synthesis method for selective heterogeneous nucleation of metal nanoparticles on oxide supports leading to the synthesis of high activity catalysts. The catalytic activity of the hybrids synthesized by this method for investigated for H2 combustion. Chapter 8 presents thermal stability studies carried out on nanostructures by in-situ heating in transmission electron microscope. The microstructural changes during the sintering process are observed in real time and the observations lead to the understanding of the mechanism of particle growth and sintering. At the end, the results of the investigations were summarized with conclusions drawn.

This thesis deals with the measurement of light tubes efficiency in laboratory conditions during lighting by almost direct light rays. It also deals with the measurement of the spectral reflectance of the reflective materials available on the Czech market. The comparison of the efficiency of different light routes and also the determination of the spectral qualities of different reflective materials are the aims of this thesis. The light tubes were measured by means of the cubic integrator. The light source was moved and manoeuvred by means of the automatic goniophotometer. The light source flow was determined by the method of the zonal flows. The data were calculated in the Matlab programme. The evaluation is both in the graphic and in the numeric forms. The result of the thesis is both the comparison of the reflective materials for light tubes qualities, and the evaluation of efficiency of the assigned light routes. The optimal variant can be then selected during designing of the light tubes route according to the results of the measurements.

Thesis (MScEng (Mechanical and Mechatronic Engineering))--University of Stellenbosch, 2009. / ENGLISH ABSTRACT: Polysulfone hollow-fibre membranes were fabricated via the dry-wet solution spinning technique. The objective was to demonstrate the influence of the various fabrication parameters on the diameter and mechanical properties of the hollow-fibre membranes and to optimize the spinning process by controlling these parameters with a computer control system. The effects of the operation parameters were investigated using an experimental design based on a fractional factorial method (Taguchi’s design of experiments). The parameters that were considered are the spinneret size, dope solution temperature, bore fluid temperature, coagulation bath temperature, dope extrusion rate, bore flow rate and the take-up speed. A new pilot solution spinning plant was installed and upgraded, and a computer control system, based on LabView, was developed to control, monitor and log the experimental data. The diameter of the hollow-fibres were determined using a scanning electron microscope (SEM) while the mechanical properties were measured using a tensile tester. The effects of diameter size and wall thickness of the hollow-fibres on the performance of the membranes were studied. The results showed the significance of the fabrication parameters that dominate the diameter and strength of the hollow-fibres. / AFRIKAANSE OPSOMMING: Polisulfoon holvesel membrane is met ‘n droë-nat oplossingspin proses vervaardig. Die doel hiermee was om die invloed van verskeie vervaardigingsparameters op die deursnee en meganiese eienskappe van die holvesel membrane te demonstreer asook om die spin proses te optimeer deur gerekenariseerde beheer van die aanleg. ‘n Eksperimentele ontwerp, gebaseer op ‘n gedeeltelike faktoriaal metode (Taguchi se eksperimentele ontwerp) is gebruik om die invloed van die vervaardigingsparameters te ondersoek. Die parameters wat oorweeg is, is spindop grootte, materiaal temperatuur, boorvloeistof temperatuur, stolbad temperatuur, materiaal ekstrusie tempo and opwen spoed. ‘n Nuwe oplossingspin loodsaanleg was geïnstalleer en opgegradeer en ‘n rekenaar beheerstelsel, gebaseer op LabView, is ontwikkel om die aanleg te beheer, moniteer en eksperimentele data te stoor. Die deursnee van die holvesel is gemeet met ‘n skanderingelektron mikroskoop (SEM) terwyl die meganiese eienskappe bepaal is met ‘n trektoets apparaat. Die effek van die deursnee en wanddikte van die holvesels op die werkverrigting van die membrane is ook bestudeer. Die resultate toon watter vervaardigingsparameters is beduidend vir die deursnee en sterkte van die holvesels.

Although branch plate connections with circular hollow section (CHS) members are simple to fabricate and cost-effective, they are generally very flexible under low load application resulting in the limit states design resistance being governed by an imposed deformation limit. Restricting the ultimate capacity of a branch plate connection by a deformation limit results in the inherent strength of the CHS member being under-utilized, highlighting the need to develop connection stiffening methods. Two methods to stiffen branch plate-to-CHS connections are examined: a through plate connection and a grout-filled CHS branch plate connection. Further, the current design guidelines of various plate-to-CHS connection types are reexamined including the effect of chord axial stress and chord length on connection behaviour. Finally, the behaviour of connections with non-orthogonal or skew plate orientation, which has not previously been examined, was studied in depth.The behaviour of these uniplanar connection types under quasi-static axial loading was studied through 16 large-scale laboratory experiments and 682 numerical finite element analyses, as well as an extensive review of all previous international experimental and numerical findings. The extensive study formed the basis for a complete set of proposed design guidelines and provided insight into plate-to-CHS connection behaviour. For all plate-to-CHS connection types, the plate thickness is shown to effect connection capacity, though previously this was thought not to have significant impact on connection behaviour. The existing ideology of using the same design recommendations for tension- and compression-loaded connections, which was developed from compression results, under-utilizes an inherent increase in capacity provided by a connection primarily loaded in tension. As such, the recommended design guidelines split the two load senses into separate expressions that reflect the difference in behaviour. Stiffened through plate connection behaviour was determined to be the summation of branch plate behaviour in compression and tension, leading to a significant increase in capacity and identical behaviour regardless of branch load sense. The skewed branch plate connection behaviour was found to relate directly to the established behaviour of longitudinal and transverse plate connections. A design function was developed that interpolates the capacities of intermediate angles by using the proposed design recommendations of the two extreme connection types. Finally, the examination of chord axial stress and chord length for plate-to-CHS connections yielded results similar to previous international studies on CHS-to-CHS connections. The effect of chord length, however, has wide-reaching implications as to how experimental and numerical FE research programs are developed.

Although branch plate connections with circular hollow section (CHS) members are simple to fabricate and cost-effective, they are generally very flexible under low load application resulting in the limit states design resistance being governed by an imposed deformation limit. Restricting the ultimate capacity of a branch plate connection by a deformation limit results in the inherent strength of the CHS member being under-utilized, highlighting the need to develop connection stiffening methods. Two methods to stiffen branch plate-to-CHS connections are examined: a through plate connection and a grout-filled CHS branch plate connection. Further, the current design guidelines of various plate-to-CHS connection types are reexamined including the effect of chord axial stress and chord length on connection behaviour. Finally, the behaviour of connections with non-orthogonal or skew plate orientation, which has not previously been examined, was studied in depth.The behaviour of these uniplanar connection types under quasi-static axial loading was studied through 16 large-scale laboratory experiments and 682 numerical finite element analyses, as well as an extensive review of all previous international experimental and numerical findings. The extensive study formed the basis for a complete set of proposed design guidelines and provided insight into plate-to-CHS connection behaviour. For all plate-to-CHS connection types, the plate thickness is shown to effect connection capacity, though previously this was thought not to have significant impact on connection behaviour. The existing ideology of using the same design recommendations for tension- and compression-loaded connections, which was developed from compression results, under-utilizes an inherent increase in capacity provided by a connection primarily loaded in tension. As such, the recommended design guidelines split the two load senses into separate expressions that reflect the difference in behaviour. Stiffened through plate connection behaviour was determined to be the summation of branch plate behaviour in compression and tension, leading to a significant increase in capacity and identical behaviour regardless of branch load sense. The skewed branch plate connection behaviour was found to relate directly to the established behaviour of longitudinal and transverse plate connections. A design function was developed that interpolates the capacities of intermediate angles by using the proposed design recommendations of the two extreme connection types. Finally, the examination of chord axial stress and chord length for plate-to-CHS connections yielded results similar to previous international studies on CHS-to-CHS connections. The effect of chord length, however, has wide-reaching implications as to how experimental and numerical FE research programs are developed.

Novel, tailored titanium dioxide pigments with controllable nanoscale morphological features were shown to significantly enhance the optical and strength properties of paper. The opacifying power of synthesized polycrystalline TiO2 particles in a cellulose matrix was found experimentally to be superior to that of a commercial rutile pigment, depending on the crystal structure of the synthesized particles. High aspect ratio polycrystalline rutile pigments composed of a linear linkage of several individual rutile crystals gave 6% more opacity than the commercial rutile pigment. Theoretical light scattering calculations using the T-Matrix Method showed the light scattering efficiency of linearly arranged polycrystalline rutile particles to depend on number and size of crystals composing the particle and confirmed the higher efficiency of the synthesized polycrystalline rutile pigments over commercial rutile. The opacifying power of hollow polycrystalline rutile particles was found experimentally to be superior to that of a commercial rutile pigment in a highly pressed bleached fiber matrix, depending on cavity size, while the opacifying power of silica-rutile titania core-shell particles was found comparable to commercial rutile at constant titania loading. The light scattering efficiency of titania core-shell particles was shown to be dependant on the light scattering efficiency of the core material. The overall particle shape and aspect ratio of titania core-shell and hollow nanoparticles were shown to be tunable by choosing an appropriate template and coating thickness in layer-by-layer or sol-gel templating synthesis. Inorganic-cellulose core-shell and hollow cellulose nanoparticles were prepared by self-encapsulation with regenerated cellulose via precipitation of cellulose in a polyacrylic acid hydrogel layer surrounding inorganic particle templates in 4-Methylmorpholine N-oxide (NMMO) monohydrate solution. This discrete encapsulation of inorganic pigments with a thin, uniform cellulose shell was found to increase the bondability improvement between the particles and a polysaccharide substrate. The crystallinity of several carbohydrate polymers was shown to significantly affect the bondability of encapsulated core-shell particles.

Until recently, the hot-rolled steel members have been recognized as the most popular and widely used steel group, but in recent times, the use of cold-formed high strength steel members has rapidly increased. However, the structural behavior of light gauge high strength cold-formed steel members characterized by various buckling modes is not yet fully understood. The current cold-formed steel sections such as C- and Z-sections are commonly used because of their simple forming procedures and easy connections, but they suffer from certain buckling modes. It is therefore important that these buckling modes are either delayed or eliminated to increase the ultimate capacity of these members. This research is therefore aimed at developing a new cold-formed steel beam with two torsionally rigid rectangular hollow flanges and a slender web formed using intermittent screw fastening to enhance the flexural capacity while maintaining a minimum fabrication cost. This thesis describes a detailed investigation into the structural behavior of this new Rectangular Hollow Flange Beam (RHFB), subjected to flexural action The first phase of this research included experimental investigations using thirty full scale lateral buckling tests and twenty two section moment capacity tests using specially designed test rigs to simulate the required loading and support conditions. A detailed description of the experimental methods, RHFB failure modes including local, lateral distortional and lateral torsional buckling modes, and moment capacity results is presented. A comparison of experimental results with the predictions from the current design rules and other design methods is also given. The second phase of this research involved a methodical and comprehensive investigation aimed at widening the scope of finite element analysis to investigate the buckling and ultimate failure behaviours of RHFBs subjected to flexural actions. Accurate finite element models simulating the physical conditions of both lateral buckling and section moment capacity tests were developed. Comparison of experimental and finite element analysis results showed that the buckling and ultimate failure behaviour of RHFBs can be simulated well using appropriate finite element models. Finite element models simulating ideal simply supported boundary conditions and a uniform moment loading were also developed in order to use in a detailed parametric study. The parametric study results were used to review the current design rules and to develop new design formulae for RHFBs subjected to local, lateral distortional and lateral torsional buckling effects. Finite element analysis results indicate that the discontinuity due to screw fastening has a noticeable influence only for members in the intermediate slenderness region. Investigations into different combinations of thicknesses in the flange and web indicate that increasing the flange thickness is more effective than web thickness in enhancing the flexural capacity of RHFBs. The current steel design standards, AS 4100 (1998) and AS/NZS 4600 (1996) are found sufficient to predict the section moment capacity of RHFBs. However, the results indicate that the AS/NZS 4600 is more accurate for slender sections whereas AS 4100 is more accurate for compact sections. The finite element analysis results further indicate that the current design rules given in AS/NZS 4600 is adequate in predicting the member moment capacity of RHFBs subject to lateral torsional buckling effects. However, they were inadequate in predicting the capacities of RHFBs subject to lateral distortional buckling effects. This thesis has therefore developed a new design formula to predict the lateral distortional buckling strength of RHFBs. Overall, this thesis has demonstrated that the innovative RHFB sections can perform well as economically and structurally efficient flexural members. Structural engineers and designers should make use of the new design rules and the validated existing design rules to design the most optimum RHFB sections depending on the type of applications. Intermittent screw fastening method has also been shown to be structurally adequate that also minimises the fabrication cost. Product manufacturers and builders should be able to make use of this in their applications.

Made available in DSpace on 2016-06-02T20:09:20Z (GMT). No. of bitstreams: 1 6039.pdf: 10273984 bytes, checksum: a13219d69346c1e1414f1a71e89cec17 (MD5) Previous issue date: 2014-04-28 / Financiadora de Estudos e Projetos / The use of precast elements has become crescent in Brazil, due to the need of haste during production as well as while assembling the structures. Bearing in mind a quick assembly and the competitive price for this kind of frame, precast elements have been growing and spreading in this field throughout the country. There is something special about demanding hollow core slabs, in virtue of their own low weight, in face of the empty spaces generated by the hollows and a better use of materials because of pretension technique, making it economically feasible. The National Technical Code ABNT NBR 9062, which deals with precast concrete structures, shows no more specific criteria as far as hollow core slabs are concerned, but on the other hand the 2011 review in force to ABNT NBR 14861 which covers precast hollow core slabs brings about relevant aspects such as the method used to check the capacity of shear strength on precast hollow core slabs, both with and without concrete structural cover, and furthermore with and without hollow fillings. Considering the reduced amount of national research on this topic, this study aims to develop and perform techniques in different ways of filling the hollows and the slabs and how they behave when exposed to shear strength tests. As a consequence to the manufacturing process of such type of slab and the hollow- filling method, failure in the idealized filling, in virtue of each material own behavior and inappropriate technique are commonly found. / O emprego de elementos pré-fabricados tem se tornado crescente no Brasil, dado a necessidade de velocidade de produção e montagem de estruturas. Tendo em vista a rápida montagem e o preço competitivo deste tipo de estrutura, elementos prémoldados tem ganhado campo no mercado nacional. Há um destaque pela procura de lajes alveolares, devido ao seu baixo peso próprio, decorrente de vazios proporcionados pelos alvéolos e maior otimização dos materiais em virtude da aplicação da técnica de pré-tração, tornando-a economicamente viável. A Norma Técnica Nacional ABNT NBR 9062 que trata de estruturas pré-moldadas de concreto não apresenta critérios mais específicos para lajes alveolares, por outro lado a revisão em vigor de 2011 da ABNT NBR 14861 que aborda lajes alveolares préfabricadas traz aspectos relevantes tais como o método de verificação da resistência à força cortante de lajes alveolares com ou sem capeamento estrutural e com ou sem preenchimento de alvéolos. Tendo em vista o reduzido volume de pesquisas nacionais sobre o tema, esta pesquisa tem como objetivo fazer um estudo teórico-experimental das diferentes técnicas de preenchimento de alvéolos de lajes alveolares e o seu comportamento quando submetidas a ensaios de força cortante. Como consequência do processo de fabricação deste tipo de laje e do método de preenchimento dos alvéolos, falhas no preenchimento idealizado devido ao comportamento distinto dos materiais e técnicas inadequadas são comumente constatadas.