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Geopolymers Incorporating Wastes and Composites Processing / Geopolymers Incorporating Wastes and Composites ProcessingTaveri, Gianmarco January 2019 (has links)
Buildings construction and realization of public infrastructures have always been a primary need in the human society, developing low cost and user-friendly materials which also encounter safety and durability requirements. Portland cement is the most used material in construction industry from the industrial revolution up to date, but the raising concerns related to the climate change are pushing the governments worldwide to replace it with more eco-friendly and greener materials. Geopolymers are considered to be best alternatives to Portland cement in construction industry, but issues related to cost and mechanical properties are still hindering the commercialization of this material. Geopolymer incorporating wastes is one of the solutions. Fly ash, a thermal power plant by-product, and borosilicate glass, a recycled glass from pharmaceutical vials, are suitable candidates in geopolymers activation. NMR and FTIR spectroscopies demonstrated that borates from borosilicate glass are active compounds in geopolymerization, substituting the alumina is its role, composing a B-Al-Si network never observed before. Various fly ash and borosilicate glass weight contents were studied in terms of mechanical properties (compression test, 3-point bending test). It was found that fly ash 55 wt.% and borosilicate 45 wt.% composition activated in 13 M NaOH solution holds the best compressive and flexural strength (45 and 4 MPa respectively), 25% stronger than similar counterparts found in literature. Cellulose fibres in different weight contents were dispersed into the geopolymeric paste to produce geopolymer composites, with the aim to render the material more suitable for structural applications. 3-point bending test showed an improvement of the flexural strength of about 165% (12 MPa), while the chevron notch method displayed a fracture toughness of 0.7 MPam1/2, in line with the results of geopolymer composites found in literature. In this thesis work, fly ash was also successfully densified in 3 M NaOH solution and distilled water through a new method based on hydraulic pressure, called hydro-pressure sintering. This innovative technology involves a drastic reduction of NaOH utilization in geopolymerization, rendering the material more eco-friendly. XRD spectroscopy conducted on produced samples revealed a higher formation of crystals, most likely induced by the application of hydraulic pressure (450 MPa).
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Coupled Modelling of Gas Migration in Host Rock and Application to a Potential Deep Geological Repository for Nuclear Wastes in OntarioWei, Xue 27 May 2022 (has links)
With the widening and increasing use of nuclear energy, it is very important to design and build long-term deep geological repositories (DGRs) to manage radioactive waste. The disposal of nuclear waste in deep rock formations is currently being investigated in several countries (e.g., Canada, China, France, Germany, India, Japan and Switzerland). In Canada, a repository for low and intermediate level radioactive waste is being proposed in Ontario’s sedimentary rock formations. During the post-closure phase of a repository, significant quantities of gas will be generated from several processes, such as corrosion of metal containers or microbial degradation of organic waste. The gas pressure could influence the engineered barrier system and host rock and might disturb the pressure-head gradients and groundwater flows near the repository. An increasing gas pressure could also cause damage to the host rock by inducing the development of micro-/macro-cracks. This will further cause perturbation to the hydrogeological properties of the host rock such as desiccation of the porous media, change in degree of saturation and hydraulic conductivity. In this regard, gas generation and migration may affect the stability or integrity of the integrate barriers and threaten the biosphere through the transmitting gaseous radionuclides as long-term contaminants. Thus, from the safety perspective of DGRs, gas generation and migration should be considered in their design and construction. The understanding and modelling of gas migration within the host rock (natural barrier) and the associated potential impacts on the integrity of the natural barrier are important for the safety assessment of a DGR. Therefore, the key objectives of this Ph.D. study include (i) the development of a simulator for coupled modelling of gas migration in the host rock of a DGR for nuclear waste; and (ii) the numerical investigation of gas migration in the host rock of a DGR for nuclear waste in Ontario by using the developed simulator. Firstly, a new thermo-hydro-mechanical-chemical (THMC) simulator (TOUGHREACT-COMSOL) has been developed to address these objectives. This simulator results from the coupling of the well-established numerical codes, TOUGHREACT and COMSOL. A series of mathematical models, which include an elastoplastic-damage model have been developed and then implemented into the simulator. Then, the predictive ability of the simulator is validated against laboratory and field tests on gas migration in host rocks. The validation results have shown that the developed simulator can predict well the gas migration in host rocks. This agreement between the predicted results and the experimental data indicates that the developed simulator can reasonably predict gas migration in DGR systems. The new simulator is used to predict gas migration and its effects in a potential DGR site in Ontario. Valuable results regarding gas migration in a potential DGR located in Ontario have been obtained. The research conducted in this Ph.D. study will provide a useful tool and information for the understanding and prediction of gas migration and its effect in a DGR, particularly in Ontario.
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Robust Optimization in Seasonal Planning of Hydro Power PlantsRisberg, Daniel January 2015 (has links)
Hydro power producers are faced with the task of releasing water from the reservoirs in the right time. To do this there are tools using stochastic optimization that aims at maximizing the income of that producer. The existing methods have a high computing time and grow exponentially with the size of the problem. A new approach that uses linear decision rules is investigated in this thesis to see if it is possible to maintain the same quality of the solutions and in the same time decrease run times. With this method the hydro power producer receives policies as an affine function of the realization of the uncertainty variables in inflow and price. This thesis presents a deterministic model and then converts it into an linear decision rules, LDR, model. It also presents a way to model the uncertainty in both inflow to the reservoir and the spot price. The result is that the LDR approach generates reasonable policies with low run times but loses a lot of optimality compared to solutions that are used today. Therefore it is concluded that this approach needs further development before commercial use. The work described in this thesis has been done in cooperation with three master students at NTNU. The approach of using linear decision rules are the same in the two projects but the differences are the models evaluated.
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MAXIMIZATION OF ENERGY GENERATION FROM SMALL HYDROPOWER PLANTIN SRI LANKA : - / MAXIMIZATION OF ENERGY GENERATION FROM SMALL HYDROPOWER PLANTIN SRI LANKA : -PATHIRANAGE, GUMINDA SANJEEWA PRIYADARSHANA January 2014 (has links)
Sri Lanka has a number of small waterfalls and channels. Related to this there is a significant potential to develop small hydropower plants, thus to generate much needed electricity for country’s development efforts. Small hydro power plants cause less environmental effects compared to large scale hydro power generation and power generation using fossil fuel. Therefore, it is a timely requirement to explore the possibilities of utilizing small water streams to generate electricity as much as possible as well as to optimize the energy generation with the available water in those water streams. The importance of small hydro power is highlighted in the Sri Lanka’s energy generation plan, and the Ceylon Electricity Board (CEB) annual report states that in year 2011 total installed capacity of small hydro plant was around 200MW and it is expected to expand energy generation to around 800GWh. This study focuses on finding out optimum operating parameters to maximize the energy generation of existing small hydro power plant in the country. By selecting a few small hydro power plants, preliminary studies were performed to identify optimum values of water flow rate to maximize the efficiency of the power generation. The study revealed that the selected plants had not operated at the maximum efficiency; hence they did not optimally utilize the available water.
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Three-Dimensional Finite Element Analysis of the Pile Foundation Behavior in Unsaturated Expansive SoilWu, Xingyi 22 April 2021 (has links)
Expansive soils, which are widely referred to as problematic soils are extensively found in many countries of the world, especially in semi-arid and arid regions. Several billions of dollars are spent annually for maintenance or for repairs to the structures constructed with and within expansive soils. The major problems of expansive soils can be attributed to the volume changes associated with the alternate wetting and drying conditions due to the influence of environmental factors. Pile foundations have been widely accepted by practicing engineers as a reasonably good solution to reduce the damages to the structures constructed on expansive soils. Typically, piles foundations are extended through the active layer of expansive soil to reach the bedrock or placed on a soil-bearing stratum of good quality. Such a design and construction approach typically facilitates pile foundations to safely carry the loads from the superstructures and reduce the settlement. However, in many scenarios, damages associated with the pile foundations are due to the expansion of the soil that is predominantly in the active zone that contributes to the pile uplift. Such a behavior can be attributed to the water infiltration into the expansive soil, which is a key factor that is associated with the soil swelling. Due to this phenomenon, expansive soil typically moves upward with respect to the pile. This generates extra positive friction on the pile because of the relative deformation. If the superstructure is light or the applied normal stress on the head of the piles is not significant, it is likely that there will be an uplift of the pile contributing to the damage of the superstructure.
In conventional engineering practice, the traditional design methods that include the rigid pile method and the elastic pile method are the most acceptable in pile foundation design. These methods are typically based on a computational technique that uses simplified assumptions with respect to soil and water content profile and the stiffness and shear strength properties. In other words, the traditional design method has limitations, as they do not take account of the complex hydromechanical behavior of the in-situ expansive soils. With the recent developments, it is possible to alleviate these limitations by using numerical modeling techniques such as finite element methods. In this thesis, a three-dimensional finite element method was used to study the hydro-mechanical behavior of a single pile in expansive soils during the infiltration process.
In this thesis, a coupled hydro-mechanical model for the unsaturated expansive soil is implemented into Abaqus software for analysis of the behavior of single piles in expansive soils during water infiltration. A rigorous continuum mechanics based approach in terms of two independent stress state variables; namely, net normal stress and suction are used to form two three-dimensional constitutive surfaces for describing the changes in the void ratio and water content of unsaturated expansive soils. The elasticity parameters for soil structure and water content in unsaturated soil were obtained by differentiating the mathematical equations of constitutive surfaces. The seepage and stress-deformation of expansive soil are described by the coupled hydro-mechanical model and the Darcy’s law. To develop the subroutines, the coupled hydro-mechanical model is transferred into the coupled thermal-mechanical model. Five user-material subroutines are used in this program. The user-defined field subroutine (USDFILD) in Abaqus is used to change and transfer parameters. Three subroutines including user-defined material subroutine (UMAT), user-defined thermal material subroutine (UMATHT), and user-defined thermal expansion subroutine (UEXPAN) are developed and used to calculate the stress-deformation, the hydraulic behavior, and the expansion strain, respectively. Except for the coupled hydro-mechanical model of unsaturated expansive soils, a soil-structure interface model is implemented into the user-defined friction behavior subroutine (FRIC) to calculate the friction between soil and pile. The program is verified by using an experimental study on a single pile in Regina clay. The results show that for the single pile in expansive soil under a vertical load, water infiltration can cause a reduction in the pile shaft friction. More pile head load is transferred to the pile at greater depth, which increases the pile head settlement and pile base resistance. In future, the proposed method can also be extended for verification of other case studies from the literature. In addition, complex scenarios can be investigated to understand the behavior of piles in expansive soils.
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Kinetic Analysis for Low Temperature Catalytic Hydro De-chlorination of PCBs (Poly-Chlorinated Biphenyls)Khopade, Akshay A. 04 November 2019 (has links)
No description available.
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Crack initiation in hydro power plant rotor rim sheets : A failure case study for Juktan hydro power plantAltzar, Oskar January 2014 (has links)
In 2013, cracks were found in the radius of the dovetail slots of the rotor rim sheets in generator 1 of Juktan hydro power plant in Västerbotten, Sweden. The cracks were estimated to be too deep to be able to repair and Alstom conducted an investigation on the cause of fracture. The investigation came to the conclusion that the radius was too small and that the new rotor rim sheets should have a six times greater fillet radius. However, it has not been investigated whether the material structure or the manufacturing process may have an impact on the crack initiation and following propagation that is the focus of this report.Parts of the dovetail slots were cut out and characterized with XRF, SEM and LOM. Further mechanical characterizations were done according to Vickers.From the SEM and LOM micrographs a high amount of large (10μm) and cubic particles were found in the microstructure. The micrographs also showed a deformation of the microstructure and the hardness test showed a deformation hardening near the edge where the sheet had been punched. The edge surface of the sheet also had notches.The large and hard particles in the microstructure impair the mechanical properties of the steel. Furthermore, the hardening effect combined with the notches will make a good crack initiation point. Therefore, there is a higher possibility that a crack will initiate in the radius of the dovetail slots where large stresses occur.
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Energilagring med pumpkraft i gruvor : En utredning av potentialen för långtidslagring i Sveriges energisystem / Underground pumped hydro energy storage in abandoned minesSederholm, Alexandra, Ågren, Sophie January 2022 (has links)
This thesis is divided in two sections. The first part consists of an interview study with 10 participants to investigate how the industry views the demand for energy storage and how it may develop in the future. Although some views differed, the study showed that a great responsibility lies on the existing hydropower. Batteries are believed to have the greatest potential as short-term storage. The participants agree that hydrogen could have great potential as a flexibility service. The future for Underground Pumped Hydro Energy Storage (UPHES) in Sweden have the participants divided but they seem to agree on the fact that the potential will depend on how price variations develop on the electricity market. Lastly, the industry agreed that a variety of energy storage technologies will be needed for the future energy system. The second part of the study is a deeper investigation into what energy deficit and demand for long-term energy storage (longer than 8 hours) might occur in the future and how UPHES may help shorten the longest deficits. To determine the need for energy storage, the scenario Electrification Renewable from a Svenska Kraftnät (Svk) report was chosen to represent the future energy system for year 2045. The result showed that depending on how the need for energy storage is defined, the amount of energy demand and therefore UPHES facilities, varied. If the need for energy storage was dimensioned regarding the average year it would result in 0,21 TWh of long-term energy deficits and 28 facilities would be enough to cover all of them. If the number of facilities was increased, the result showed a lower usage of all the facilities. However, if the need for energy storage was dimensioned regarding the ''worst case scenario'', the longest deficit out of 35 years, the energy demand in the long deficits was 14 TWh. If 28 facilities were used only 11 % of the energy demand in the long deficits would be covered. If the number of facilities increased, 172 facilities would cover 32 % of the energy demand in the long deficits and 1834 facilities would cover 60 %.
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A GIS-Based Strategy for Managing Levee Simulation DataHandy, Jeffrey R. 16 July 2008 (has links) (PDF)
Understanding and improving the state of the nation's levees has become a national priority following the devastating events surrounding Hurricanes Katrina and Rita. Federal legislation passed in 2007 created a new national Committee on Levee Safety and spurred the development of the National Levee Database, a central repository of information relating to the location and state of levees across the United States (Water Resources Development Act, 2007). One of the major goals in developing such a database is to improve the safety of America's levees. The National Levee Database, however, does not include features for storing seepage and slope stability data related to numerical analyses of levees. These data are critical in analyzing current levee conditions and predicting future failure scenarios, thus providing a path for further improving the safety of levees. The Levee Analyst is a new GIS data model and set of geoprocessing tools that make it possible to store and manipulate model data associated with seepage and slope stability analyses. The data model provides a concise structure for storing large amounts of levee seepage and slope stability data and also provides a structure that is expandable and compatible with the National Levee Database. The Levee Analyst combines the capabilities of various software systems in providing a data model and suite of tools that assists in further understanding and analyzing the state of America's levees.
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Hydro-dechlorination of Ortho-substituted PCB Congeners Widespread in the Environment: Effects of Triethylamine and Mild Reaction ConditionsXu, Juan January 2020 (has links)
No description available.
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