Butt fusion welding process is an extensively used method of joining for high density polyethylene (HDPE) pipe. With the increasing number of HDPE resin and pipe manufacturers and the diversity of industries utilising HDPE pipes, a wide range of different standards have evolved to specify the butt fusion welding parameters with inspection and testing methods, to maintain quality and structural integrity of welds. There is a lack of understanding and cohesion in these standards for the selection of welding parameters; effectiveness, accuracy, and selection of the test methods and; correlation of the mechanical properties to the micro and macro joint structure. The common standards (WIS 4-32-08, DVS 2207-1, ASTM F2620, and ISO 21307) for butt fusion welding were used to derive the six welding procedures. A total of 48 welds were produced using 180 mm outer diameter SDR 11 HDPE pipe manufactured from BorSafe™ HE3490-LS black bimodal PE100 resin. Three short term coupon mechanical tests were conducted. The waisted tensile test was able to differentiate the quality of welds using the energy to break parameter. The tensile impact test due to specimen geometry caused the failure to occur in the parent material. The guided side bend specimen geometry proved to be too ductile to be able to cause failures. A statistical t-test was used to analyse the results of the short term mechanical tests. The circumferential positon of the test specimen had no impact on their performance. Finite element analysis (FEA) study was conducted for the long term whole pipe tensile creep rupture (WPTCR) test to find the minimum length of pipe required for testing based on pipe geometry parameters of outer diameter and SDR. Macrographs of the weld beads supplemented with heat treatment were used to derive several weld bead parameters. The FEA modelling of the weld bead parameters identified the length to be a key parameter and provided insight into the relationship between the geometry of the weld beads and the stresses in the weld region. The realistic bead geometry digitised using the macrographs contributed a 30% increase in pipe wall stress due to the stress concentration effect of the notches formed between the weld beads and the pipe wall. The circumferential position of the weld bead had no impact on the pipe wall stresses in a similar manner to the results of the different mechanical tests. IV Nanoindentation (NI) and differential scanning calorimetry (DSC) techniques were used to study the weld microstructure and variation of mechanical properties across the weld at the resolutions of 100 and 50 microns, respectively. NI revealed signature 'twin-peaks and a valley' distribution of hardness and elastic modulus across the weld. The degrees of crystallinity obtained from DSC followed the NI pattern as crystallinity positively correlates with the material properties. Both techniques confirm annealing of the heat affected zone (HAZ) material towards the MZ from the parent material. The transmission light microscopy (TLM) was used to provide dimensions of the melt zone (MZ) which displays an hour glass figure widening to the size of the weld bead root length towards the pipe surfaces. Thermal FEA modelling was validated using both NI and TLM data to predict the HAZ size. The HAZ-parent boundary temperature was calculated to be 105 ⁰C. The 1st contribution of the study is to prove the existence of a positive correlation between the heat input calculated from FEA and the energy to break values obtained from the waisted tensile test. The 2nd contribution providing the minimum length of pipe for WPTCR based on the pipe dimensions. The 3rd contribution is the recommendation for the waisted tensile test with the test using the geometry designed to minimise deformation of the loading pin holes. The 4th contribution related the weld bead parameters to pipe wall stresses and the effect of notches as stress concentrators. The 5th contribution is a new method of visualising a welding procedure that can be used to not only compare the welding procedures but also predict the size of the MZ and the HAZ. The 6th contribution of the study is the proposal of new weld bead geometry that consist of the MZ bounded by the HAZ, for butt fusion welded joints of HDPE pipes.

Interruption to water services and low water pressure conditions are commonly observed problems in water distribution systems (WDSs). Of particular concern are the unplanned events, such as pipe bursts. The current regulation in the UK requires water utilities to provide reliable water service to consumers resulting in as little as possible interruptions and of as short possible duration. All this pushes water utilities toward developing and using smarter responses to these events, based on advanced tools and solutions. All with the aim to change network management style from reactive to a proactive, and reduce water losses, optimize energy use and provide better services for consumers. This thesis presents a novel methodology for efficient and effective operational, short time response to an unplanned failure event (such as pipe burst) in a WDS. The proposed automated, near real-time operational response methodology consists of isolating the failure event followed by the recovery of the affected system area by restoring the flows and pressures to normal conditions. The isolation is typically achieved by manipulating the relevant on/off valves that are located closely to the event location. The recovery involves selecting an optimal combination of suitable operational network interventions. These are selected from a number of possible options with the aim to reduce the negative impact of the failure over a pre-specified time horizon. The intervention options considered here include isolation valve manipulations, changing the pressure reducing valve’s (PRV) outlet pressure and installation and use of temporary overland bypasses from a nearby hydrant(s) in an adjacent, unaffected part of the network. The optimal mix of interventions is identified by using a multi-objective optimization approach driven by the minimization of the negative impact on the consumers and the minimization of the corresponding number of operational interventions (which acts as a surrogate for operational costs). The negative impact of a failure event was quantified here as a volume of water undelivered to consumers and was estimated by using a newly developed pressure-driven model (PDM) based hydraulic solver. The PDM based hydraulic solver was validated on a number of benchmark and real-life networks under different flow conditions. The results obtained clearly demonstrate its advantages when compared to a number of existing methods. The key advantages include the simplicity of its implementation and the ability to predict network pressures and flows in a consistently accurate, numerically stable and computationally efficient manner under both pressure-deficient and normal-flow conditions and in both steady-state and extended period simulations. The new real-time operational response methodology was applied to a real world water distribution network of D-Town. The results obtained demonstrate the effectiveness of the proposed methodology in identifying the Pareto optimal network type intervention strategies that could be ultimately presented to the control room operator for making a suitable decision in near real-time.

O presente trabalho tem como objetivo avaliar as tensões atuantes no conjunto conector e duto flexível de camadas não aderentes durante ensaios com carregamentos axiais de tração e fadiga. Estes ensaios são utilizados para a qualificação de dutos flexíveis. Foram desenvolvidos e patenteados alguns modelos de conectores contemplando apenas a parte estrutural. Ensaios preliminares de tração e fadiga, com dois conectores diferentes e um segmento de riser de dimensões reduzidas, foram realizados visando a seleção do modelo de melhor desempenho em um pórtico. O conector de melhor desempenho foi então ensaiado em uma bancada com dimensões que atendessem ao documento da Petrobras a I-ET 3500.00.6500-291-PAZ-001 - Non standartized Prototype qualification tests of flexible pipes (2007). Tanto os ensaios do pórtico como o de bancada, foram monitorados com strain gages colados nos tendões da armadura externa de tração próximos aos conectores. O foco deste trabalho está nas armaduras de tração na interface com a resina do conector. Questões quanto ao desempenho da mesma em fadiga são de grande importância prática. Complementando a parte experimental, foram construídos modelos sólidos tridimensionais, baseados no Método dos Elementos Finitos para análise das tensões. A comparação dos resultados das diferentes metodologias validou o modelo numérico possibilitando melhor entendimento das variações de tensões nas armaduras de tração na interface com os conectores. Isso possibilitou responder a importantes questões quanto ao desempenho em fadiga bem como possíveis melhorias no projeto de conectores para dutos flexíveis. Existem trabalhos referentes à análise de tensões dos tendões nos conectores considerando o estado plano de tensões. O presente estudo dos tendões usando modelos tridimensionais, abordagem não encontrada em literatura aberta, avalia melhor a concentração de tensões nos tendões na entrada do conector. A motivação deste estudo se deve tanto à falta de informações detalhadas das tensões e deformações nos tendões na interface com o conector, como pela importância das mesmas, em componentes vitais à explotação de petróleo Offshore. / This aim of this work is to evaluate stresses which actuate on a system made up of a unbonded flexible pipe and a end fitting during static and dynamic axial loading mechanical tests. These tests are used as a means of qualification of flexible pipes. The structural design of models of end fittings were developed and patented. Preliminary static and dynamic tests with two different end fittings and a smalldimensioned riser segment were performed in a frame in view of selecting the bestperforming type. After this evaluation, the end fitting with the best performance was tested in a rig with dimensions according to Petrobras document I-ET 3500.00.6500-291-PAZ- 001 - Non standartized Prototype qualification tests of flexible pipes (2007). Tests performed in the frame and on the rig were monitored with resistance strain gages attached to wires of the external armor, on the interface with the end fitting resin, since performance of this region under fatigue is of utmost practical importance. Three-dimensional solid models were built using the Finite Element Modelling (FEM) method, as a way of validating experimental results. Comparison of results obtained from the different methodologies validated the numerical model, allowing a better understanding of the variations of stresses in the interface of the riser with the end fitting. This led to the solution of many doubts regarding fatigue performance as well as possible improvements in the design of flexible riser end fittings. Existing work published in literature considers only plane stress; the present study, based on 3D models which are not found in literature, is thought to better describe the stress concentration on the wires at the end fitting interface. The motivation of this work relies on the lack of detailed information of the stress and strain to which wires are subjected at the interface with the end fitting, as well as the importance of these in vital components for offshore oil exploration.

A comparison of available fluid-to-fluid scaling laws for scaling convective heat transfer at supercritical pressures showed that the ones suggested by Zahlan, Groeneveld and Tavoularis (ZGT) have some advantages. The applicability of the ZGT laws was tested for pairs of fluids including carbon dioxide, water or Refrigerant R134a. The conditions of previous measurements taken in the Supercritical University of Ottawa Loop with CO2 flowing vertically upwards in an electrically heated tube with 8 mm ID were scaled to equivalent conditions in R134a and new measurements of the heat transfer coefficient (HTC) were taken in the same tube using the latter fluid. The inlet pressure was 1.13 times the critical pressure (4.06 MPa), the mass flux was in the range from 212 kg/m^2 s to 1609 kg/m^2 s, the heat flux was in the range from 2 kW/m^2 to 137 kW/m^2, and the inlet temperature was in the range from 62 ℃ to 105 ℃. The HTC at equivalent conditions in water was also determined with the use of transcritical look-up tables. Average and linearly varying corrections to the ZGT scaling laws were derived by statistical analysis for each pair of fluids under NHT or DHT conditions. Such corrections reduced the standard deviation of the scaling error but did not eliminate the presence of large errors under many sets of conditions. As expected, scaling errors were in general larger for DHT than NHT conditions. The present results did not reveal any systematic and correctable dependence of the scaling error upon the mass flux or heat flux but showed that scaling errors became particularly large as the bulk temperature T_b approached the pseudocritical temperature T_pc. In conclusion, the ZGT scaling laws appear to be fairly accurate for the three pairs of fluids considered in the liquid-like region with T_b/T_pc ≤ 0.94 and possibly in the gas-like region with T_b/T_pc ≥ 1.02, whereas outside this range scaling errors could be significant. It was also found that the ZGT scaling laws do not scale accurately the onset of DHT in different fluids.

CoordenaÃÃo de AperfeiÃoamento de Pessoal de NÃvel Superior / O presente trabalho buscou a determinaÃÃo de parÃmatros Ãtimos - como pressÃo e fraÃÃo de massa fria - para tubos de vÃrtice, visando o melhor desempnho termodinÃmico. As principais variÃveis de entrada estudadas fromas a pressÃo (1a 6 bar) e fraÃaà de massa fria, em torno de 40%, assim como o nÃmero de entradas da cÃmara de vÃrtice, com 4 e 6. As fraÃÃes de massa fria se apresentaram mais eficientes entre os valores de 40 e 50%. A anÃlise realizada usou um tube de vÃrtice que possibilitava um trabalho conjunto com um compressor de 7,5hp. Instrumentos de mediÃÃo foram utilizados para a obtenÃÃo dos dados experimentais. SÃo eles: um rotÃmatro com grande capacidade de mediÃÃo de fluxo de ar e uma sÃrie de termopares para mediÃÃes de temperaturas em diferentes pontos do circuito, como a entrada da cÃmara de vÃrtice e as saÃdas quente e fria do tubo. Os experimentos revelaram que o coeficiente de performance (definido como a razÃo entre o trabalho de compressÃo do ar e a variaÃÃo de entalpia deste entre a entrada do tubo e a saÃda fria) foi saifatÃrio, atingindo Ãndices de 0,12. A melhor configuraÃÃo apresentada foi com um tubo de vÃrtice trabalhando a pressÃo de 6 bar, com uma cÃmara de geraÃÃo de vÃrtice possuindo 4 entradas. A eficiÃncia em termos de energia - determinada como a razÃo entre a exergia das massas de ar na saÃda do tubo e a exergia da massa de ar na entrada deste - tambÃm foi estudadas e calculada, apresentando valores de 2% para os pontos mais eficientes. os valores desta eficiÃncia apresentaram pouca variaÃÃo em relaÃÃo à variaÃÃo de pressÃo. Nos trabalhos analÃticos, foram realizados o dimensionamento e a escolha de um arranjo fotovoltaico capaz de alimentar o sistema de geraÃÃo de energia, composto de 8 unidades de painÃis fotovoltaicos trabalhando em paralelo. / This work wanted to determine the optimum parameters - like pressure and cold mass fraction - to vortex pipes, in order to find out the best thermodynamic performance. The main inlet variables studied were the pressure - from 1 to 6 bar - and the cold mass fraction, around 40% as well as hte number of inlets on the vortex chamber, with 4 and 6 inlets. The cold mass fraction presented more efficient between 40 and 50%. This analysis used a vortex tube that enabled to work together with a 7,5hp compressor. Measurement instruments were used to obtain the experimental data. They are a rotameter capable of measure 400 standard cubic feet per hour and several termocouples, as in the inlet of the vortex chamber and the cold and hot outlet. The experiments revealed that the coefficient of performance (defined as the ratio between the air compression work and the enthalpy variation between the inlet of the chamber and the cold outlet) was satisfactory, reaching levels of 0,12. The best configuration presented used a vortex pipe working at 6 bar, with a vortex chamber with 4 inlets. The exergy efficiency - determined as the ratio between the exergy of tme mass in the both outlets and the exergy in the inlet - was also studied and calculated, resenting values of 2% in the most efficient points. The values of this efficiency presented little variation compared to the present variation. In the analytical works, it was done the dimensioning and the choice of a photovoltaic assemby, capable of feed the energy generation system, made of 8 units of photovoltaic panels working in parallel.

Neste trabalho são apresentados diversos métodos de localização de vazamentos, desde as técnicas e equipamentos mais elementares, como a inspeção visual e o geofone mecânico, até o uso dos sofisticados armazenadores de ruídos e de modelação computacional. Algumas dessas técnicas são amplamente difundidas e largamente utilizadas pelas empresas de saneamento, outras porém, constituem-se em ótimas promessas para o aperfeiçoamento do controle das perdas físicas nos sistemas de abastecimento. É dada ênfase na utilização do diagrama de resposta em freqüência para localizar e quantificar vazamentos, com especial aplicação às adutoras de água tratada. A técnica de utilização da resposta em freqüência desenvolvida por Lee et al. (2005) é esmiuçada, inclusive acerca do impacto que um vazamento impõe ao diagrama de resposta em freqüência. São abordadas as formas de obtenção do referido diagrama, tanto do ponto de vista do modelo matemático e computacional, quanto dos ensaios de campo necessários. / This work presents some methods for leak location, from de most elementary techniques and equipments, as visual inspection and mechanical geophone, until using sophisticated noise data-logger and computational modeling. Some of these techniques are very well issued and largely used by water companies, but others play excellent promises for the improvement of leak control in systems of water supply. The pattern of the frequency response diagram is used for leak location and quantification, with special application in drinking water pipelines. The frequency response technique developed by Lee et al. (2005) is studied in details, including the impact produced by the leak on the frequency response diagram. The ways to obtain the frequency response diagram, by using mathematical and computational models or necessary field data survey, are also discussed.

Os nervos periféricos são extensões do sistema nervoso central e responsáveis pela interação das atividades das extremidades, em suas funções sensitiva e motora. São vulneráveis aos mesmos tipos de traumas que afetam outros tecidos: contusão, compressão, esmagamento, estiramento, avulsão e laceração. Desta forma, a interrupção de continuidade da estrutura do nervo, por algum tipo de trauma, resulta na interrupção de transmissão dos impulsos nervosos e na desorganização de suas atividades funcionais. Para tanto, em vista da evolução tecnológica e o desenvolvimento de equipamentos mais sofisticados, a microcirurgia vem ganhando cada vez mais espaço no campo da investigação experimental referente a recuperação de nervos periféricos lesionados. Em uma secção simples, sem perda tecidual, a neurorrafia denominada término-terminal apresenta bons resultados, contudo, quando ocorre perda de tecido nervoso ou, não se têm mais os cotos distais do nervo, outras técnicas devem ser empregadas, até porque, não se pode de modo algum tencionar o nervo numa tentativa de coaptá-lo novamente. Várias técnicas de tubulização utilizando-se materiais biológicos e não biológicos, para criar um meio por onde ocorrerá a regeneração nervosa já foram ou ainda estão sendo testados com resultados insatisfatórios sob o aspecto funcional.É sabido que em um trauma sem perda tecidual, numa neuropraxia, por exemplo, o nervo recupera espontaneamente de forma satisfatória. É sabido também que em um feixe vásculo-nervoso, o nervo periférico encontra-se em íntimo contato com a adventícia de artérias e veias. A adventícia dos vasos é constituída por tecido conjuntivo frouxo, rico em adipócitos. Assim, em um trauma, os neuritos oriundos do coto proximal do nervo lesado, ficam diretamente em contato com esses adipócitos. Seguindo este raciocínio, e com base em trabalhos anteriores onde foi usada veia preenchida com músculo esquelético a fresco como enxerto, decidimos testar a possibilidade de crescimento axonal por meio de enxerto com tubo de polietileno preenchido por tecido adiposo autólogo. Para tanto será utilizado um tubo com 12 mm de comprimento por 0,25 mm de diâmetro, com poros de 80 µm de diâmetro, preenchido com tecido adiposo in natura retirado das adjacências do referido nervo, na tentativa de se recuperar o nervo isquiático. A certificação do sucesso da recuperação do nervo será feita por meio de técnicas de microcirurgia, microscopia e morfometria. O enxerto de polietileno mostrou ter resistência a pressões, uma vez que não foi observado colapso estrutural. A gordura mostrou ser bom material trófico já que no grupo onde a utilizou apresentou resultados mais próximos do controle final. / Peripheral nerves are extensions of the central nervous system and are responsible for the interaction of the activities of the extremities in their sensory and motor function. They are vulnerable to these types of injuries that affect other tissues: contusion, compression, crush, stretch, tear and avulsion. Thus, the interruption of continuity of the nerve structure, due to some sort of trauma, results in the interruption of transmission of nerve impulses and disruption of their functional activities. Therefore, in view of technological evolution and development of more sophisticated equipment, microsurgery is gaining more space in the field of experimental research concerning the recovery of injured peripheral nerves. In a single section, without loss of tissue, called the end-terminal neurorrhaphy was also good, however, when there is loss of nervous tissue or, if not longer have the distal nerve stumps, other techniques must be employed, because, in any circumstance the nerve should be tensioned as an attempt to coaptation again. Several techniques of tubing, using biological materials and non-biological means to create a place where nerve regeneration have been or are still being tested with unsatisfactory results in the functional aspect. It is known that in a trauma without loss of tissue, a neuropraxia, for example, the nerve recovers spontaneously and satisfactorily. It is also known that in a neurovascular bundle, the peripheral nerve is in close contact with the adventitia of arteries and veins. The adventitia of the vessels is composed of loose connective tissue rich in adipocytes. Thus, in trauma, the neurites from the proximal stump of injured nerve, are directly in contact with these adipocytes. Following this reasoning, and based on previous work where it was used vein filled with fresh skeletal muscle as a graft, decided to test the possibility of axonal growth by grafting polyethylene tube filled with autologous adipose tissue. For that will be used with a tube 12 mm long and 0.25 mm in diameter, with pores of 80 microns in diameter, filled with fresh adipose tissue removed from the vicinity of that nerve, in an attempt to recover the sciatic nerve. Certification of successful nerve recovery will be done through microsurgical techniques, microscopy and morphometry. The graft polyethylene proved to have pressure resistance, since no structural collapse was observed. The fat was found to be good material as trophic group which had used the results closer to the ultimate control.

Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 1980. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND ENGINEERING. / Includes bibliographical references. / by Mohamed Tayeb Benchaita. / Ph.D.

The development of an infrared instrument for the study of surface adsorption and high Tc superconductors is presented and its applicability is discussed. The use of and theoretical background for the metal light pipe multiple-reflection technique are discussed in comparison to other infrared devices. Measurements are carried out to determine its limitations with powdered substrates as well as its sensitivity limitation for thin films. The results of the two test measurements, adsorption of CO on MgO and investigation of the energy gap of high Tc superconductors, are presented. Comparisons of the spectra with the experimental and theoretical literature are presented where possible. The necessity for simultaneous infrared and vapor pressure isotherm measurements is discussed, and their instrumental realization is shown. Infrared measurements on the energy gap of high Tc superconductors are shown and compared with results form the literature.

This paper explores private investments in public equity (PIPE) deals as a means of alternative firm financing. Poorly performing companies often look towards PIPEs to quickly raise capital when traditional means of financing are limited. This study provides an analysis on both the discount and premia that PIPEs are issued at, as well as the performance of firms after the deal announcement. Overall, this study finds that successful PIPEs from the investor’s perspective are issued at a discount of close to 17%, and unsuccessful PIPEs are issued at an average of a 15% premium. I find substantial cumulative abnormal returns of 9% over a three-day period due to positive information shocks. Overall, this thesis corroborates past research in the field.