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Direct synthesis of carbide-derived carbon monoliths with hierarchical pore design by hard-templatingNickel, Winfried, Oschatz, Martin, von der Lehr, Martin, Leistner, Matthias, Hao, Guang-Ping, Adelhelm, Philipp, Müller, Philipp, Smarsly, Bernd M., Kaskel, Stefan 01 September 2014 (has links) (PDF)
Carbide-derived carbon Monoliths (CDC-Ms) containing a multimodal arrangement with high volumes of micro- meso- and macropores are prepared by direct nanocasting of silica monoliths with polycarbosilane precursors. CDC-Ms show well-defined pore structures along with specific surface areas of more than 2600 m2 g−1 and overall pore volumes as high as 3.14 cm3 g−1. They exhibit advanced gas filtration properties compared to purely microporous materials due to enhanced storage capacities and kinetics as demonstrated by thermal response measurements based on InfraSORP technology.
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Direct synthesis of carbide-derived carbon monoliths with hierarchical pore design by hard-templatingNickel, Winfried, Oschatz, Martin, von der Lehr, Martin, Leistner, Matthias, Hao, Guang-Ping, Adelhelm, Philipp, Müller, Philipp, Smarsly, Bernd M., Kaskel, Stefan 01 September 2014 (has links)
Carbide-derived carbon Monoliths (CDC-Ms) containing a multimodal arrangement with high volumes of micro- meso- and macropores are prepared by direct nanocasting of silica monoliths with polycarbosilane precursors. CDC-Ms show well-defined pore structures along with specific surface areas of more than 2600 m2 g−1 and overall pore volumes as high as 3.14 cm3 g−1. They exhibit advanced gas filtration properties compared to purely microporous materials due to enhanced storage capacities and kinetics as demonstrated by thermal response measurements based on InfraSORP technology.
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