Thesis (Ph.D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2002. / Includes bibliographical references (leaves 169-187). / The marine geochemistry of the North Atlantic Ocean varies on decadal to centennial time scales, a consequence of natural and anthropogenic forcing. Surface corals provide a useful geochemical archive to quantify past mixed layer variability, and this study presents elemental and isotopic records from the tropical and subtropical North Atlantic. A consistent method for stable lead isotope analysis via multiple collector ICP-MS is first presented. This method is then applied to western North Atlantic surface corals and seawater, constraining historical elemental and isotopic lead variability. Six stable lead isotope profiles are developed from the western and eastern North Atlantic, demonstrating consistent mixed layer, thermocline, and deep water variability. Finally, coralline trace element records, including cadmium, barium, and lead, are presented from the Cariaco Basin. First, a reliable method is developed for stable lead isotope analysis by multiple collector ICP-MS. This study presents new observations of the large (0.7% amu-l), time-dependent mass fractionation determined by thallium normalization, including preferential light ion transmission induced by the acceleration potential and nebulizer conditions. These experiments show equivalent results for three empirical correction laws, and the previously proposed [beta]Pb/[beta]TI correction does not improve isotope ratio accuracy under these conditions. External secondary normalization to SRM-981 provides one simple alternative, and a rationale is provided for this correction. With current intensities less than 1.5x10-12 A, external isotope ratio precision less than 200 ppm is observed (2[sigma]). Matrix effects are significant with concomitant calcium in SRM-981 (-280 ppm at 257 [mu]M [Ca]). / (cont.) With the appropriate corrections and minimal concomitants, MC-ICP-MS can reliably determine 206Pb/207Pb and 208Pb/207Pb ratios of marine carbonates and seawater. Anthropogenic lead represents a promising transient oceanographic tracer, and its historical isotopic and elemental North Atlantic variability have been documented by proxy reconstructions and seawater observations. Two high-resolution surface coral and seawater time series from the western North Atlantic are presented, demonstrating past variability consistent with upper ocean observations. The elemental reconstruction suggests the primary lead transient was advected to the western North Atlantic from 1955 to 1968, with an inferred maximum lead concentration of 205 pmol kg-1 in 1971. The mean 1999 North Atlantic seawater concentration (38 pmol kg-1) is equivalent to 1905, several decades prior to the initial consumption of leaded gasoline in the United States. A 206Pb/207Pb transient from 1968 to 1990 is also observed, lagging the elemental transient by ten years. The provenance of this isotopic record is distinct from Arctic and European ice core observations and supports a 40% ... / by Matthew K. Reuer. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), September 1998. / Includes bibliographical references (leaves 226-246). / The upper ocean crust contains a comprehensive record of the shallow geological processes active along the world's mid-ocean ridge system. This thesis examines the magnetic and seismic structure of the upper crust at two contrasting ridges-the fast spreading East Pacific Rise (EPR) and the slow spreading Mid-Atlantic Ridge (MAR)-to build a more complete understanding about the roles of volcanic emplacement, tectonic disruption and hydrothermal alteration in the near-ridge environment. A technique that inverts potential field measurements directly from an uneven observation track is developed and applied to near-bottom magnetic data from the spreading segments north of the Kane transform on the MAR. It is concluded that the central anomaly magnetization high marks the locus of focused volcanic emplacement. A cyclic faulting model is proposed to explain the oscillatory magnetization pattern associated with discrete blocks of crust being transported out of the rift valley between intensely altered fault zones. Seismic waveform and amplitude analyses of the magma sill along the EPR reveal it to be a thin (<100 m) body of partial melt. These characteristics have important implications for melt availability and transport within the cycle of eruption and replenishment. A genetic algorithm-based seismic waveform inversion technique is developed and applied to on- and near-axis multichannel data from 17'20'S on the EPR and the spreading segment south of the Oceanographer transform (MAR) to map and compare for the first time the detailed velocity structure of the upper crust at two different spreading rates. Combined with conventionally processed seismic profiles, our results show that, while final extrusive thickness is comparable at all spreading ridges (300-500 m), the style of thickening may vary. While a thin (<100 m) extrusive carapace quadruples in thickness within 1-4 km of the EPR crest, the extrusive section at the MAR achieves its final thickness within the inner valley. Both show evidence for a narrow zone of volcanic emplacement. Vigorous hydrothermalism at the EPR may produce a more rapid increase in basement velocities relative to the MAR. Rapid modification of the extrusive/dike transition at both ridges indicates that hydrothermalism is enhanced in this interval. Along-axis transport of lavas may thicken the extrusive pile at slow spreading segment ends, strengthening the magnetic highs generated by lava chemistry. / by Stefan Anthony Hussenoeder. / Ph.D.

Thesis: Ph. D., Massachusetts Institute of Technology, Department of Biology, 2017. / Thesis: Ph. D., Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Biology; and the Woods Hole Oceanographic Institution), 2017. / Cataloged from PDF version of thesis. / Includes bibliographical references. / Blooms of the dinoflagellate Alexandrium catenella cause paralytic shellfish poisoning syndrome and present an expanding public health threat. They are inoculated through the germination of benthic cysts, a process regulated by internal and environmental factors, most importantly temperature. Less understood is the effect of temperature conditioning on cyst dormancy cycling, which inhibits germination for long periods. This thesis characterizes the temperature-dependence of both dormancy and germination in natural A. catenella cyst populations from Nauset Marsh (Cape Cod, MA, USA), a small estuarine embayment, and relates these processes to the phenology of blooms there. Through laboratory germination assays, it is shown that dormant A. catenella cysts require a quantifiable amount of chilling to exit dormancy and attain quiescence (i.e. become germinable). A series of experiments compares germination rates of quiescent cysts across a range of temperatures through laboratory experiments and field incubations of raw sediment using plankton emergence traps (PETs). Emergence rates of A. catenella germlings measured by PETs increased linearly with temperature and were comparable to germination under constant laboratory conditions. Total emergence fluxes were much lower than expected, suggesting that germination occurs in a much shallower layer of sediments than typically assumed. The results are synthesized to develop a temperature-dependent model to examine the sensitivity of A. catenella bloom phenology to dormancy-breaking by winter chilling. Notably, the chilling-alleviated dormancy model accurately predicted the timing of quiescence (January) and the variable bloom phenology from multiple blooms in Nauset. Once cysts became quiescent and began to germinate, however, temperatures were typically too cold for growth to exceed losses so there was a several-week lag until bloom development. Years with warmer winters and springs had shorter lag periods and thus significantly earlier blooms. Ecologically, dormancy-breaking by a chilling threshold is advantageous because it prevents the mismatch between conditions that are favorable for germination but not for the formation of large blooms. Synchronized germination after winter chilling also promotes promotes efficient conversion from the cyst seedbed to the spring bloom inoculum. The dormancy mechanism characterized here may be present in other cyst-forming dinoflagellates, but there is likely plasticity that reflects the temperature regime of each habitat. / by Alexis Dal Fischer. / Ph. D.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Biology; and the Woods Hole Oceanographic Institution), 2007. / Includes bibliographical references (p. 188-204). / Geochemical signatures in the otoliths of diadromous fishes may allow for retrospective analyses of natal origins. In an assessment of river-specific signatures in American shad (Alosa sapidissima), an anadromous clupeid native to the Atlantic coast of North America, stable isotope and elemental ratios in otoliths of juvenile American shad produced accurate natal tags from 12 rivers. Significant inter-annual variability in geochemical signatures from several rivers was detected, due largely to differences in 8180 values among years. The database was further expanded to include 20 rivers from Florida to Quebec, encompassing all major spawning populations. This task was accomplished by collecting juvenile otoliths along with water samples from rivers where juveniles were not sampled. Regressions between otolith and water chemistry for those rivers where both were collected showed significant relationships for Sr:Ca, Ba:Ca, 86180, and 87Sr:86Sr ratios but not for Mg:Ca or Mn:Ca. Despite reducing the combined signature to only four chemical ratios, cross-validated classification accuracies of known-origin juveniles averaged 93%. Ground-truthed signatures were used to classify migrants of unknown origins. Adults returning to spawn in the York River were classified according to their otolith composition. / (cont.) Only 6% of spawners originated from rivers other than the York, supporting the hypothesis that most American shad spawn in their natal river. Of remaining spawners, 79% originated from the Mattaponi River and 21% from the Pamunkey River. The results suggested that while most American shad home to their natal river there is less fidelity to individual tributaries, allowing subsidies to subpopulations with persistent recruitment failure. Otolith signatures were also used in mixed-stock analyses of immature migrants along the coast of Maine in the spring and Minas Basin in the summer. Mixed-stock compositions showed remarkably low diversity and were dominated by fish from the Shubenacadie and Hudson rivers, with an increasing proportion of Potomac River fish over time. In contrast to results from adult tagging studies, southern stocks were virtually absent. These data suggest ontogenetic shifts in migratory behavior. The thesis concludes with a report that water contributed 83% of Sr and 98% of Ba in the otoliths of a marine fish. / by Benjamin Walther. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2012. / Cataloged from PDF version of thesis. / Includes bibliographical references. / Radioactive isotopes can be used in paleoceanography both for dating samples and as tracers of ocean processes. Here I use radiocarbon and uranium series isotopes to investigate the ocean's role in climate change over the last deglaciation. I present a new method for rapid radiocarbon analyses as a means of age-screening deep-sea corals for further study. Based on age survey results, I selected forty corals from the Drake Passage and thirteen from the Reykjanes Ridge off Iceland and dated them with uranium series isotopes. The uranium series dates give independent ages that allow radiocarbon to be used as a tracer of circulation and carbon cycle changes. The radiocarbon records generated from the Drake Passage corals show increased stratification in the Southern Ocean during the last glacial maximum (LGM) that disappeared during the start of the deglaciation as atmospheric CO2 began to rise during Heinrich Stadial 1 (HI). Considering these data and using a simple mass budget calculation, I show that the drop in atmospheric radiocarbon activity during H1 can be explained given direct carbon exchange between the radiocarbon-depleted deep ocean and atmosphere, e.g. through the Southern Ocean. The Drake Passage radiocarbon records also show evidence for decreased air-sea gas exchange in the Southern Ocean during the Antarctic Cold Reversal/Belling-Allered coincident with the hiatus in the deglacial CO2 rise. During this time period in the North Atlantic, radiocarbon reconstructions from deep-sea corals collected from off Iceland show a similar ventilation rate to that observed today and during the Holocene. To further investigate changes in North Atlantic ventilation over the last deglaciation, I used an inverse model to assess the consistency of sedimentary 2m1 Pa/ 230Th ratios from the Holocene, Hl, and the LGM with the modern circulation. Although sedimentary 231Pa/230Th has been used to infer changes in the strength of the meridional overturning circulation in the past, I find that published data are consistent with the modern circulation during the LGM and Hi. These findings highlight the importance of giving due regard to the uncertainties in the behavior and spatial distribution of paleoceanographic tracers. / by Andrea Burke. / Ph.D.

Includes bibliographical references (p. 211-216). / Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2008. / Inspired by the swimming abilities of marine animals, this thesis presents "Finnegan the RoboTurtle", an autonomous underwater vehicle (AUV) powered entirely by four flapping foils. Biomimetic actuation is shown to produce dramatic improvements in AUV maneuvering at cruising speeds, while simultaneously allowing for agility at low speeds. Using control algorithms linear in the modified Rodrigues parameters to support large angle maneuvers, the vehicle is successfully controlled in banked and twisting turns, exceeding the best reported AUV turning performance by more than a factor of two; a minimum turning radius of 0.7BL, and the ability to avoid walls detected > 1.8BL ahead, are found for cruising speeds of 0.75BL/s, with a maximum heading rate of 400/s recorded. Observations of "Myrtle", a 250kg Green sea turtle (Chelonia mydas) at the New England Aquarium, are detailed; along with steady swimming, Myrtle is observed performing 1800 level turns and rapidly actuating pitch to control depth and speed. Limb kinematics for the level turning maneuver are replicated by Finnegan, and turning rates comparable to those of the turtle are achieved. Foil kinematics which produce approximately sinusoidal nominal angle of attack trace are shown to improve turning performance by as much as 25%; the effect is achieved despite limited knowledge of the flow field. Finally, tests with a single foil are used to demonstrate that biomimetically inspired inline motion can allow oscillating foils utilizing a power/recovery style stroke to generate as much as 90% of the thrust from a power/power stroke style motion. / by Stephen Carl Licht. / Ph.D.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2003. / In title on t.p., "[Beta]" appears as the Greek letter. / Includes bibliographical references (p. 81-84). / by Shinichiro Kida. / S.M.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2013. / Cataloged from PDF version of thesis. / Includes bibliographical references. / Predicting the response of net community calcification (NCC) to ocean acidification OA and declining aragonite saturation state [Omega]a requires a thorough understanding of controls on NCC. The diurnal control of light and net community production (NCP) on NCC confounds the underlying control of [Omega]a on NCC and must be averaged out in order to predict the general response of NCC to OA. I did this by generating a general NCC-[Omega]a correlation based on data from 15 field and mesocosm studies around the globe. The general relationship agrees well with results from mesocosm experiments. This general relationship implies that NCC will transition from net calcification to net dissolution at a [Omega]a of 1.0 ± 0.6 and predicts that NCC will decline by 50% from 1880 to 2100, for a reef of any percent calcifier cover and short reef water residence time. NCC will also decline if percent calcifier cover declines, as evidenced by estimates of NCC in two Caribbean reefs having declined by an estimated 50-90% since 1880. The general NCC-([Omega]a relationship determined here, along with changes in percent calcifier cover, will be useful in predicting changes in NCC in response to OA and for refining models of reef water [Omega]a. / by Whitney Nicole Bernstein. / Ph.D.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), September 2011. / "September 2011." "©2011"--P. 2. Cataloged from PDF version of thesis. / Includes bibliographical references (p. 97-101). / The ocean depths provide an ever changing and complex imaging environment. As scientists and researches strive to document and study more remote and optically challenging areas, specifically scatter-limited environments. There is a requirement for new illumination systems that improve both image quality and increase imaging distance. One of the most constraining optical properties to underwater image quality are scattering caused by ocean chemistry and entrained organic material. By reducing the size of the scatter interaction volume, one can immediately improve both the focus (forward scatter limited) and contrast (backscatter limited) of underwater images. This thesis describes a relatively simple, cost-effective and field-deployable low-power dynamic lighting system that minimizes the scatter interaction volume with both subjective and quantifiable improvements in imaging performance. / by Geoffrey Allen Gorman. / S.M.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Electrical Engineering and Computer Science; and the Woods Hole Oceanographic Institution), 2002. / Includes bibliographical references (p. 151-154). / by Rajesh Rao Naduditi. / S.M.