Architecture et mécanismes de bout en bout pour les communications mobiles et sans fil dans l'Internet. La gestion performante de la mobilité et l'amélioration des performances des couches basses sont deux enjeux fondamentaux dans le contexte des réseaux sans fil. Cette thèse apporte des solutions originales et innovantes qui visent à répondre à ces deux problématiques empêchant à ce jour d'offrir des possibilités de communication performantes et sans couture aux usagers mobiles accédant à l'Internet via des réseaux d'accès locaux sans fil (WLAN). Ces solutions se distinguent en particulier par l'impact minimum qu'elles ont sur les protocoles standards de l'Internet (niveaux transport et réseau) ou de l'IEEE (niveaux physique et liaison de données). S'inscrivant dans les paradigmes de "bout en bout" et "cross-layer", notre architecture permet d'offrir des solutions efficaces pour la gestion de la mobilité : gestion de la localisation et des handover en particulier. En outre, nous montrons que notre approche permet également d'améliorer l'efficacité des transmissions ainsi que de résoudre efficacement plusieurs syndromes identifiés au sein de 802.11 tels que les anomalies de performance, l'iniquité entre les flux et l'absence de contrôle de débit entre la couche MAC et les couches supérieures. Cette thèse résout ces problèmes en combinant des modèles analytiques, des simulations et de réelles expérimentations. Ces mécanismes adaptatifs ont été développés et intégrés dans une architecture de communication qui fournit des services de communication à haute performance pour réseaux sans fils tels que WIFI et WIMAX. / Wireless networks, because of the potential pervasive and mobile communication services they offer, are becoming the dominant Internet access networks. However, the legacy Internet protocols, still dominant at that time, have not been designed with mobility and wireless in mind. Therefore, numerous maladjustments and “defaults of impedance” can be observed when combining wireless physical and MAC layers with the traditional upper layers. This thesis proposes several solutions for a pacific coexistence between these communication layers that have been defined and designed independently. Reliable mobility management and Low layer performance enhancements are two main challenging issues in the context of wireless networks. Mobility management (which is mostly based on mobile IP architecture nowadays) aims to continuously assign and control the wireless connections of mobile nodes amongst a space of wireless access networks. Low layer performance enhancements mainly focus on the transmission efficiency such as higher rate, lower loss, interference avoidance. This thesis addresses these two important issues from an original and innovative approach that, conversely to the traditional contributions, entails a minimum impact on the legacy protocols and internet infrastructure. Following the “end to end” and “cross layer” paradigms, we address and offer efficient and light solutions to fast handover, location management and continuous connection support through a space of wireless networks. Moreover, we show that such an approach makes it possible to enhance transmission efficiency and solve efficiently several syndromes that plague the performances of current wireless networks such as performance anomaly, unfairness issues and maladjustment between MAC layer and upper layers. This thesis tackles these issues by combining analytical models, simulations and real experiments. The resulting mechanisms have been developed and integrated into adaptive mobility management communication architecture that delivers high performing communication services to mobile wireless systems, with a focus on WIFI and WIMAX access networks.

Cette thèse s’insère dans un projet d’élaboration et de caractérisation des cellules photovoltaïques organiques classiques et inverses, plus précisément il s’agit d’améliorer les performances des cellules via des couches tampons anodiques et cathodiques originales. Nous avons commencé d’améliorer les couches tampons cathodiques avec différents donneurs d’électrons: phtalocyanine de cuivre CuPc, subphtalocyanine SubPc et dérivés de thiophène organiques. Dans le premier cas de donneur d’électrons (CuPc), nous avons mis en évidence l’effet d’une fine couche d’un composé de césium, utilisée comme couche tampon cathodique dans des cellules inverses, sur la collecte des électrons après un traitement thermique. Nous avons montré aussi que la couche tampon cathodique hybride, Alq3 (9nm) / Ca (3nm) améliore les performances des cellules quelque soit le donneur d’électrons et sans nécessité de recuit. Dans le cas de drivés de thiophène, nous avons montré comment la morphologie de surface des couches organiques peut influencer les performances des cellules photovoltaïques organiques. Et dans le cas de SubPc utilisé dans des cellules inverses, nous avons étudié l’effet de la vitesse de dépôt de la couche SubPc sur sa morphologie. Concernant l’amélioration de la couche tampon anodique, nous avons étudié des cellules classiques à base SubPc et du pentathiophene (5T). Après l’optimisation de l’épaisseur des donneurs d’électrons, nous avons montré que la bicouche MoO3 (3 nm) / Cul (1,5 nm) utilisée comme couche tampon anodique, permet d'améliorer les performances des cellules, quelque soit le donneur d’électrons. Dans le cas du SubPc, nous avons obtenu un rendement qui approche de 5%. / This thesis concerns elaboration and characterization of classical and inverse organic photovoltaic cells, specifically improving the anodic and cathodic buffer layers. We started by improving the cathode buffer layers with different electron donors: copper phthalocyanine CuPc, subphtalocyanine SubPc and thiophene derivatives (BSTV and BOTV). In the first case of electron donor (CuPc), we highlighted the effect of the thin layer of cesium compound, used as a cathodic buffer layer in inverse cells, on the collection of electrons after heat treatment.We have also shown that the hybrid cathodic buffer layer, Alq3 (9 nm) / Ca (3nm) improves the cell performance whatever the electron donor without annealing. In the case of thiophene derivatives, we have shown how the morphology of the organic layers surface can influence the performance of organic photovoltaic cells. In the case of SubPc used in inverse cells, we studied the effect of the deposition rate of the layer on the morphology of SubPc surface.Regarding the improvement of the anodic buffer layers, we investigated those based on the SubPc and pentathiophene (5T) in classical cells. After optimization of the electron donors thickness, we have shown that the bilayer MoO3 (3 nm) / CuI (1.5 nm) used as an anodic buffer layer, improves cell performances, whatever the electron donor. In the case of SubPc, we obtained a efficiency approaching 5%.

The initial slow viscous growth of the Tollmein-Schlichting wave in a canonical boundary layer transition is absent in bypass and wake-induced transitions. Although there have been a great deal of studies pertaining to bypass transition in boundary layers, the underlying breakdown mechanism is not clearly understood and it continues to be a subject of interest. Similarly, a wake-induced transition caused by Karman wake in the freestream remains poorly understood. The breakdown in this case is caused by anisotropic disturbances containing large scale unsteadiness in the freestream. Differing view points among workers on the transition process have also added to the complexities. In this thesis, bypass and wake-induced boundary layer transitions studied experimentally towards understanding various flow breakdown features are reported. The measurements were made on a flat plate boundary layer in a low-speed wind tunnel. The particle image velocimetry (PIV) technique was extensively used. Various grids were used to generate nearly isotropic freestream turbulence. A circular cylinder was placed at different heights from the plate leading edge to generate Karman wake in the freestream. Two cylinders of different diameters were used to vary the Reynolds number(based on the cylinder diameter). The PIV measurements being simultaneous over a large spatial domain enabled to assess various spatial transitional flow structures. In the case of bypass transition, the streamwise velocity fluctuation, u, is found to exhibit some organized negative and positive fluctuations that dominate the flow during transition, and confirm the simulation results reported in the literature. These positive and negative u fluctuations are found to be associated with the streak unsteadiness. By conditional sampling of these positive and negative u fluctuations, we find that urms (root-mean-squaredof u)can be expressed as a linear combination of urms,f and urms,b,i.e. urms = a(urms,f + urms,b); ais constant, and the subscripts fand bdenote the positive and nega-tive ufluctuations, respectively. Both urms,f and urms,b arefoundto follow the non-modal growth distribution. The wall-normal results clearly show that an inclined shear layer is often associated with an organized structure of negative ufluctuations and an inflectional in-stantaneous velocity profile. These inclined shear layers appear to be similar to those in ribbon-induced transition. The turbulent spot precursor appears to be the vortex shedding from an oscillating in-clined shear layer. Interestingly, the normalized vortex shedding fre-quency is found to be Reynolds number invariant, as in the case of ribbon-induced transition. The present study also confirms the sim-ulated turbulent spot features, including a thin log-law at the break-down stage. The spanwise plane PIV results reveal the signature of streak secondary instability in the flow in terms of symmetric and anti-symmetric streaks oscillations. The initial growth of streak amplitude is followed by a slow decay. The maximum streak amplitude is well above30% of the freestream velocity. These two aspects provide support to the streak instability analysis reported in the literature. While the present wake-induced transition study provides some sup-port to the available numerical simulation and experimental results, some new results have also emerged. The measured sharp rise in the disturbance energy during transition is found to be closer to the simulated result, compared to the difference reported in the literature. The spanwise vortices in the early stage, as also seen in other experimental studies, deform leading to the formation of lambda structures, the signature of which is found by the linear stochastic analysis. With increased Reynolds number and decreased cylinder height from the plate, the physical size of the lambda structure is found to decrease. These lambda structures are often found to appear in a staggered manner in the spanwise plane, as in the case of sub-harmonic boundary layer transition. Although a sub-harmonic peak in the frequency spectra is reported in the literature, as also in the present study, the clear staggered pattern went unnoticed. Streamwise streaks are subsequently generated due to the mean shear stretching of these lambda vortices. The spanwise spacing of these streamwise streaks is found to be comparable with the recent simulation results. Also, these streaks are found to undergo somewhat sinuous-like oscillations, compared to the only varicose type oscillations reported in the literature. The streak amplitude is found to saturate at about 35% of the freestream speed. Here again an inclined shear layer in the wall-normal plane is associated with organized negative u fluctuations and an inflectional instantaneous velocity profile. The movement of the peak urms towards the wall is found to be due to the positive u fluctuation, which follows a hairpin-like structure. The inclined shear layers herein are associated with the lambda or a hairpin-like structure. As in a by-pass transition, an inclined shear layer, vortex shedding from it, the imprint of which is also found in the linear stochastic analysis are present. The normalized high frequency shed vortices is found to be Reynolds number invariant in the present wake-induced transition, as in ribbon-induced and bypass transitions. Compared to the re-cent suggestion that the parent-offspring mechanism is the governing self-sustaining mechanism in the boundary layer, the present study suggests that streak-instability mechanism is also present. The proper orthogonal decomposition(POD) analysis of the experimental data was carried out with an emphasis on the bypass transition case studied. The first few energetic POD modes are found to capture the dominant flow structures, i.e. the organized positive and negative u fluctuations. In the case of bypass transition, the first two energetic POD modes are self-similar, i.e. independent of the freestream turbulent intensity and the Reynolds number. An attempt is also made to construct a low-dimensional model with the POD eigenfunction modes to predict the qualitative dynamics of bypass transition. This has revealed the existence of a traveling disturbance in the bypass transition. On the whole, the present study shows some similar breakdown features in bypass and wake-induced transitions, although more studies in this regard are essential.

No description available.

The aim of Master thesis "Control and monitoring unit for optical link station" is a web server, enabling communication microcontroller with the user. The communication is based on TCP/IP model. Work an overview of the various parts of the TCP/IP model. The main part of this work is devoted to the software created. The core of unit are microcontroller C8051F120 and ethernet controller CP2200 made by Silicon Laboratories.

This research focuses on measurements of a convective shear-layer instability seen naturally in quiet hypersonic flow. Experiments were carried out in the Boeing/AFOSR Mach 6 Quiet Tunnel (BAM6QT) at Purdue University. The BAM6QT provides low-disturbance hypersonic flow with freestream noise levels similar to what would be experienced by a flight vehicle. To obtain high-speed, off-the-surface measurements of the instability, a modified focused laser differential interferometer (FLDI) was first designed to work with the contoured Plexiglas windows available in the tunnel.<div><br>A cone-cylinder-flare geometry was then selected to study the instabilities related to an axisymmetric separation bubble at Mach 6. The sharp cone had a 5-degree half-angle, while flare angles of 10 degrees and 3.5 degrees were tested to compare axisymmetric compression with and without separation, respectively. Under quiet flow, laminar separation and reattachment was confirmed by schlieren and surface pressure-fluctuation measurements. Coherent traveling waves were observed. These were attributed to both the second-mode instability, as well as a shear-generated instability from the separation bubble. The symmetry of the bubble was found to be highly sensitive to angle of attack. Additionally, by introducing controlled disturbances on the cone upstream of the separation, larger-amplitude shear-generated waves were measured while the second-mode amplitudes remained unchanged. Therefore, the shear-generated waves were amplified moving through the shear layer, while the second mode remained neutrally stable. These appear to be the first measurements of traveling waves that are generated in the shear layer of a separation bubble in hypersonic flow. <br></div>

Die hier vorliegende Arbeit beschäftigt sich mit Eignung bakterieller Hüllproteine als Bindungsmatrix für die Kopplung funktionaler Moleküle mit dem Ziel, sensorische Schichten zu erzeugen. Bakterielle Hüllproteine sind biologische SAMs, anderen Oberfläche sich modifizierbare COOH-, NH2- und OH-Gruppen befinden. Die Ausbildung polymerer Strukturen erfolgt dabei in wässrigen Systemen und auf Oberflächen. Im Zuge der boomenden Entwicklung von Biosensoren werden insbesondere Biotemplate gesucht, die zwischen biologischer Komponente und Sensoroberfläche vermitteln. Bakterielle Hüllproteine stellen eine solche Zwischenschicht dar. Als Anwendungsbeispiel wurden die Proteine daher mit einem FRET-Paar und Thrombin und Kanamycin-Aptameren modifiziert. Hierbei wurden das FRET-Paar H488 und H555 an die bakteriellen Hüllproteine der beiden Haldenisolate A12 und B53 mittels EDC mit einer Modifizierungsrate von 0,54 molFarbstoff/molProtein kovalent gebunden. Bei der vorhandenen p4-Symmetrie bedeutet dies, dass ein FRET-Paar pro Einheitszelle vorhanden war. Der Nachweis eines Energietransfers zwischen den beiden am Protein gebundenen Fluoreszenzfarbstoffen H488 und H555 erfolgte mittels statischer und zeitaufgelöster Fluoreszenzmessung. Die Ergebnisse zeigten, dass ein Energietransfer nur möglich war, wenn die Proteine in polymerer Form vorlagen, unabhängig davon, ob sich die Proteine immobilisiert an einer Oberfläche oder in wässriger Lösung befanden. Mittels Variieren des Donor-Akzeptor-Verhältnisses konnte ein maximaler Energietransfer von 40 % generiert werden, wenn das Verhältnis der Fluoreszenzfarbstoffe von Donor und Akzeptor 4 betrug. Die Fluoreszenzintensität der Fluorophore wurde durch die Bindung an die Proteine nicht verringert oder gelöscht. Dies legt nahe, dass die Farbstoffe in den hydrophoben Poren immobilisiert wurden und die Poren die Fluoreszenzfarbstoffe schützen. Um weitere Aussagen über die Lage der gebundenen Fluoreszenzfarbstoffe zu erhalten, wurden die bakteriellen Hüllproteine der Stämme A12 und B53 enzymatisch verdaut und die Fragmente mittels SEC und SDS-PAGE untersucht. Dabei zeigten sich je nach Enzym und Protein unterschiedliche Bandenmuster bezüglich modifizierter und nativer Hüllproteine. Dies belegt, dass die Fluoreszenzfarbstoffe an NH2-und COOH-Gruppen der Proteine gebunden wurden und so teilweise den enzymatischen Verdau hinderten. Die SEC deutet an, dass die Fluoreszenzfarbstoffe an verschiedenen Stellen am Protein gebunden wurden. In einem zweiten Beispiel wurde das bakterielle Hüllprotein von A12 mit einem Aptamer modifiziert. Aptamere sind kurze einzelsträngige Oligonukleotide, die u.a. mittels ihrer ausgebildeten 3D-Struktur spezifisch Zielstrukturen reversibel binden können. Die hier verwendeten Aptamere binden spezifisch Thrombin und Kanamycin. Die Aptamere wurden mit Hilfe einer der beiden Vernetzer PMPI oder Sulfo-SMCC an die bakteriellen Hüllproteine kovalent gebunden. Nach dem Modifizieren der Proteine wurden diese auf entsprechenden Sensorchips immobilisiert und die Aktivität des gekoppelten Aptamers mittels Affinitätsmessungen, SPR-Spektroskopie und QCM-D-Messungen analysiert. Die Funktion des gebundenen Thrombinaptamers konnte mittels Affinitätsmessungen und QCM-D nachgewiesen werden und entspricht in beiden Fällen einer Bindung von 2 nmol Thrombin pro Quadratzentimeter. Die Funktionalität des Kanamycinaptamers sollte mittels SPR bestimmt werden, jedoch konnte keine Funktionalität des gekoppelten Kanamycinaptamers nachgewiesen werden. Alle Messungen bestätigten jedoch, dass die Bindungsmatrix aus bakteriellen Hüllproteinen keinerlei oder nur ein sehr geringes Hintergrundsignal liefert. Werden nun beide Komponenten, FRET-Paar und Aptamere, an das Protein gebunden, ist es möglich, eine sensorische Schicht zu erzeugen. Die Zielstruktur, welche detektiert werden soll, wird an das Aptamer gebunden und so in räumliche Nähe zur Sensorfläche gebracht. Stell die Zielstruktur einen Fluoreszenzlöscher dar, so wird der Energietransfer durch die räumliche Nähe des Fluoreszenzlöscher gestört. Die Detektion des Zielmoleküls erfolgt nun über die Änderung von Fluoreszenzintensitäten. Die hier vorgelegte Arbeit soll einen Grundstein legen für die Entwicklung eines solchen Sensors und insbesondere die Detektion eines Energietransfers optimieren und Schwachstellen in der Detektion nachweisen. Die systematische Untersuchung der Fluoreszenzfarbstoffe auf dem Protein ermöglichen es, in zukünftigen Arbeiten einen FRET zweifelsfrei zu detektieren. Die Modifizierung von bakteriellen Hüllproteinen von A12 mit Aptameren und die Detektion der Funktionalität der Aptamere mittels verschiedener Methoden zeigte auf, dass die bakteriellen Hüllproteine als universelle Bindungsmatrix für sensorische Moleküle dienen können, bei denen Affinitätsmessungen, SPR- oder QCM-D-Messungen genutzt werden. Besonders hervorzuheben ist, dass bakterielle Hüllproteine nahezu kein Hintergrundsignal liefern und aufgrund ihrer dünnen Monolage von etwa 6 - 9 nm die Sensitivität der Messungen nur gering beeinträchtigen.

Published Article / Rapid tooling (RT) in the context of this research presents the possibility of improving the traditional investment casting process by shortening lead times while still maintaining affordable costs and required quality. Various rapid prototyping processes are available that can be used to create direct metal, polymer or wooden dies for this casting technology. This paper presents results gained in an AMTS project, focusing on RT development for investment casting of light metals. One of the most widely used layer manufacturing processes available in South Africa is selective laser sintering. A machine produced by the German manufacturer EOS (process known as laser sintering) utilising this technology was selected for the study. Two of the materials that are suitable for rapid die making are used, which in tum reflects different mechanical properties and process economics. A standard benchmark part was used as a study base. Two dies were built, one in alumide and one in polyamide. A comprehensive measurement programme was conducted, followed by an appropriate statistical analysis and evaluation regarding accuracy and surface finish. A number of wax patterns were produced. The best wax patterns from each die were selected and evaluated. The subsequently produced castings in AI, Mg and TI were further examined and evaluated. Various issues concerning the reinforcement, wax injection, pattern removal, accuracy and surface finish of the dies are discussed in the paper. The research concludes that rapid tooling techniques can be successfully used for creating accurate dies in order to shorten lead times in the investment casting process chain.

The cognitive radio network (CRN) concept has been proposed as a solution to the growing demand and underutilization of the radio spectrum. To improve the radio spectrum utilization, CRN technology allows the coexistence of licensed and unlicensed systems over the same spectrum. In an underlay spectrum sharing system, secondary users (SUs) transmit simultaneously with the primary users (PUs) in the same frequency band given that the interference caused by the SU to the PU remains below a tolerable interference limit. Besides the transmission power limitation, a secondary network is subject to distinct channel impairments such as fading and interference from the primary transmissions. Also, CRNs face new security threats and challenges due to their unique cognitive characteristics.This thesis analyzes the performance of underlay CRNs and underlay cognitive relay networks under spectrum sharing constraints and security constraints. Distinct SU transmit power policies are obtained considering various interference constraints such as PU outage constraint or PU peak interference power constraint. The thesis is divided into an introduction and two research parts based on peer-reviewed publications. The introduction provides an overview of radio spectrum management, basic concepts of CRNs, and physical layer security. In the first research part, we study the performance of underlay CRNs with emphasis on a multiuser environment.In Part I-A, we consider a secondary network with delay-tolerant applications and analyze the ergodic capacity. Part I-B analyzes the secondary outage capacity which characterises the maximum data rate that can be achieved over a channel for a given outage probability. In Part I-C, we consider a secondary network with delay constrained applications, and derive expressions of the outage probability and delay-limited throughput. Part I-D presents a queueing model that provides an analytical tool to evaluate the secondary packet-level performance with multiple classes of traffic considering general interarrival and service time distributions. Analytical expressions of the SU average packet transmission time, waiting time in the queue, andtime spent in the system are provided.In the second research part, we analyze the physical layer security for underlay CRNs and underlay cognitive relay networks. Analytical expressions of the probability of non-zero secrecy capacity and secrecy outage probability are derived.Part II-A considers a single hop underlay CRN in the presence of multiple eavesdroppers (EAVs) and multiple SU-Rxs. In Part II-B, an underlay cognitive relay network in the presence of multiple secondary relays and multiple EAVs is studied.Numerical examples illustrate that it is possible to exploit the physical layer characteristics to achieve both security and quality of service in CRNs while satisfying spectrum sharing constraints.

The large scale and smaller production scale motions contain over the half of turbulent kinetic energy in the flow. These motions are responsible for sediment transport and deposition processes, contaminant mixing and stream bio-diversity. These motions are corresponded to the left and right bounds of -1 power region of the spectral energy. The most well recognized and highly studied power law has been upon Kolmogorov’s -5/3 power law region of the streamwise spectral energy density and this research focused on investigating the -1 power region bounds and energy. Energy budget and time-average turbulence calculations along with spectral analysis are performed to investigate the characteristics of large scale and smaller production scale motions in the flow. Spectral analyses of turbulent flows offers the utility of investigating the distribution of turbulent energy across wavenumber scales as well as identifying prominent wavenumbers at which the periodicity of coherent processes are centered. In turn, the results of spectral analyses can be coupled with visualization of coherent vortices and time-average turbulence results to advance our understanding of turbulent energy distribution and dominant processes that drive environmental phenomena such as sediment transport and solute transfer. A new method for identifying the wavenumbers associated to the macroturbulence and bursting is introduced. Also this study offers a new scaling method of energy spectral that derived from the turbulence energy model for an equilibrium boundary layer. Results of this study show an equilibrium boundary layer for the outer region of the flow in which the flow is uniform and fully-developed. Also for a given roughness, the results of this study provide an approach to calculate the streamwise turbulence kinetic energy of bursting and macroturbulence which show a linkage of this work to applications such as bedload and suspended load sediment transport.