The development of improved water management strategies for the polymer electrolyte membrane fuel cell (PEMFC) could stand to benefit from an improved understanding of the surface and internal structure of the gas diffusion layer (GDL). The GDL is a fibrous porous material enabling mass transport between the PEMFC catalyst layer and flow fields. Fluorescence-based visualizations of liquid water droplet evaporation on GDL surfaces were performed to investigate water droplet pinning behaviours. The heterogeneous in-plane and through-plane porosity distributions of untreated GDLs were studied using computed tomography visualizations. The through-plane porosity distributions were utilized to calculate heterogeneous local tortuosity, relative diffusivity, and permeability distributions. Finally, the heterogeneous through-plane porosity distributions of GDLs treated for increased hydrophobicity were investigated. This work provides new insight into GDL material properties to better inform future PEMFC models.

The purpose is to isolate a natural compound, which shows a high activity against Candida albicans, from plant, Vincetoxicum stocksii. Bio-Assay, Thin layer Chromatography, Column Chromatography, TLC bio Assay, and other extraction techniques are used in order to isolate the active compound. First, bio assay technique is carried out on the crude gum. Next, several flash chromatography columns are carried out in order to isolate the target compound, which has a Rf value of ~0.53 in 10:1 DCM/methanol solvent mixture. The TLC bioassay technique is also carried out in order to confirm the hypothesis that the target compound is indeed active.

Beef jerky is a dried meat snack which is rich in protein but of low calorific value. This ready-to- eat meat snack is in high demand among hikers, bikers and travelers due to its compact nature and nutritional value. The current processing methods such as smoke house and home dehydrators take 6-10 h. Increasing market for this shelf-stable meat product increases the need for alternate efficient processing method. Also, this meat snack market depends on its textural characteristics which denote the consumer acceptability. In this research, three different methods of drying beef jerky were examined. Influences of pH and salt on different characteristics of beef jerky were investigated using combined microwave-convection drying. Also, the effects of relative humidity and airflow rates in forced air thin layer drying on jerky processing were studied. Samples of beef jerky dried using a combined microwave-convection drier and thin layer drying unit were compared with samples dried in a smoke house. The results obtained showed that pH and salt content had a significant influence on drying, physical and textural characteristics of jerky. It was found that samples with low pH (5.15) and high salt content (3.28% (w/w)) dried faster than samples with high pH and low salt content due to their high drying rates. These samples had shown high shrinkage and weight loss compared to samples with pH 5.65 and 1.28% (w/w) salt content. Analysis of the textural characteristics such as tensile force, puncture force and texture profile showed that the samples with high pH and low salt content were comparably softer than the rest of the samples. Results of the effect of relative humidity and airflow rate in forced air thin layer drying on jerky processing showed that relative humidity and airflow rate influenced the drying, physical, chemical and textural characteristics of beef jerky. Combination of low relative humidity and high airflow rate showed desirable drying characteristics. However, samples dried at this combination showed high shrinkage and weight loss. The hardness of the beef jerky increased with increase in airflow rate and reduction in relative humidity. A comparison of the drying methods revealed that different drying methods produced different desirable properties. Combined microwave-convection drying was found to be efficient and very rapid (8.25 min). The low shrinkage and weight losses along with high drying rate obtained using this method would pave a way to fast and efficient processing. The color and textural characteristics were different from those of samples dried in a smoke house. Surprisingly, combined microwave-convection drying method produced softer beef jerky than thin layer and smokehouse methods. However, the commercially available jerky is tougher than the one dried using combined microwave-convection drying. The samples dried in a thin layer drier had comparable color and textural characteristics with samples dried in a smoke-house. Also, forced-air thin layer drying method reduced drying time of beef jerky from 7 to 3 h. The forced air thin layer drier has the potential to produce beef jerky with similar color and textural characteristics to commercially available smoke house dried samples.

This thesis considers the problem of cross layer scheduling and radio resource allocation of multiple users in the downlink of time-slotted and frequency-slotted cellular data networks. For these networks, opportunistic scheduling algorithms improve system performance by exploiting time variations of the radio channel. Within the broader framework of opportunistic scheduling, this thesis solves three distinct problems and proposes efficient and scalable solutions for them. First, we present novel optimal and approximate opportunistic scheduling algorithms that combine channel fluctuation and user mobility information in their decision rules. The algorithms propose the use of dynamic fairness constraints. These fairness constraints adapt according to the user mobility. The optimal algorithm is an off-line algorithm that precomputes constraint values according to a known mobility model. The approximate algorithm is an on-line algorithm that relies on the future prediction of the user mobility locations in time. We show that the use of mobility information increases channel capacity. We also provide analytical bounds on the performance of the approximate algorithm. Second, this thesis presents a new opportunistic scheduling solution that maximizes the aggregate user performance subject to certain minimum and maximum performance constraints. By constraining the performance experienced by individual users, who share a common radio downlink, to some upper bounds, it is possible to provide the system operator with a better control of radio resource allocations and service differentiation among different classes of users. The proposed solution offers better performance than existing solution under practical channel conditions. Finally, we present a dynamic subcarrier allocation solution for fractional frequency reuse in multicell orthogonal frequency division multiple access systems. We formulate the subcarrier allocation as an equivalent set partitioning problem and then propose an efficient hierarchical solution which first partitions subcarriers into groups and next schedules subcarriers opportunistically to users. Simulation results for three solutions illustrate the usefulness of the proposed schemes.

Cognitive radio (CR) is a novel wireless communication approach that may alleviate the looming spectrum-shortage crisis. Orthogonal frequency division multiplexing (OFDM) is an attractive modulation candidate for CR systems. In this thesis, we study resource allocation (RA) for OFDM-based CR systems using both aggressive and protective sharing. In aggressive sharing, cognitive radio users (CRUs) can share both non-active and active primary user (PU) bands. We develop a model that describes aggressive sharing, and formulate a corresponding multidimensional knapsack problem (MDKP). Low-complexity suboptimal RA algorithms are proposed for both single and multiple CRU systems. A simplified model is proposed which provides a faster suboptimal solution. Simulation results show that the proposed suboptimal solutions are close to optimal, and that aggressive sharing of the whole band can provide a substantial performance improvement over protective sharing, which makes use of only the non-active PU bands. Although aggressive sharing generally yields a higher spectrum-utilization efficiency than protective sharing, aggressive sharing may not be feasible in some situations. In such cases, sharing only non-active PU bands is more appropriate. When there are no fairness or quality of service (QoS) considerations among CRUs, both theoretical analysis and simulation results show that plain equal power allocation (PEPA) yields similar performance as optimal power allocation in a multiuser OFDM-based CR system. We propose a low-complexity discrete bit PEPA algorithm. To improve spectrum-utilization efficiency, while considering the time-varying nature of the available spectrum as well as the fading characteristics of wireless communication channels and providing QoS provisioning and fairness among users, this thesis introduces the following novel algorithms: (1) a distributed RA algorithm that provides both fairness and efficient spectrum usage for ad hoc systems; (2) a RA algorithm for non-real-time (NRT) services that maintains average user rates proportionally on the downlink of multiuser OFDM-based CR systems; and (3) cross-layer RA algorithms for the downlink of multiuser OFDM-based CR systems for both real-time (RT) services and mixed (RT and NRT) services. Simulation results show that the proposed algorithms provide satisfactory QoS to all supported services and perform better than existing algorithms designed for multiuser OFDM systems.

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IEEE 802.15.4 is a standard defined for wireless sensor network applications with limited power and relaxed throughput needs. The devices transmit data during two periods: Contention Access Period (CAP) by accessing the channel using CSMA/CA and Contention Free Period (CFP), which consists of Guaranteed Time Slots (GTS) allocated to individual devices by the network coordinator. The GTS is used by devices for cyclic data transmission and the coordinator can allocate GTS to a maximum of only seven devices. In this work, we have proposed two algorithms for an efficient GTS allocation. The first algorithm is focused on improving the bandwidth utilization of devices, while the second algorithm uses traffic arrival information of devices to allow sharing of GTS slots between more than seven devices. The proposed schemes were tested through simulations and the results show that the new GTS allocation schemes perform better than the original IEEE 802.15.4 standard.

This is a Master Thesis done at the Swedish Defence Research Agency with the purpose to design and investigate how different geometries of a compression surface integrated with an intake affects the performance such as distortion, boundary layer diversion, pressure recovery and deceleration of speed. The work was divided in two parts. In the first part, CFD calculations using the FOI developed Edge 4.1 code were made for the compression surfaces alone. In the second part the most promising design was integrated with an intake. Two more bumps with the intake were modelled and the three geometries were compared to the intake without bump. Surface flow, deceleration of Mach number, pressure recovery, mass flow, boundary layer diversion, lift and drag were the factors chosen to be examined, boundary layer diversion and pressure recovery being the two most vital.