This diploma thesis was focused on the preparation of mesoporous titanium dioxide layers. Mesoporous layers were prepared from titanium tetraisopropoxide as a precursor with addition diethanolamine and polyethylene glycol. These layers were deposited by material printing. This work was also focused on the characterisation of prepared layers. Hydrophilicity of titanium dioxide layers were studied. The photocatalytic activity of the printed titanium layers was tested by the photocatalytic degradation of stearic acid. Bang-gap studies were performed. Quality of prepared layers was inspected by optical microscopy, scanning electron microscopy and atomic force microscopy.

This diploma thesis is focused on the preparation of hybrid titania-silica layers. Titanium tetraisopropoxide and tetraethyl orthosilicate with Levasil were used as the precursors for TiO2 and SiO2 synthesis, respectively. The layers were deposited on substrates by material printing. Furthermore, this work is focused on the study of the rheological properties of TiO2-SiO2 sol and characterization of prepared films by XRD, SEM, ellipsometry, AFM, pencil hardnes test, optical microscopy. Optical properties were also characterized by transmitance and reflectance measurement and the functionality of these layers was demonstrated by a stearic acid degradation experiment.

The focus of the present licentiate thesis is on the effect of suction and pressure gradients on turbulent boundary-layer flows, which are investigated separately through performing numerical simulations.The first part aims at assessing history and development effects on adverse pressure-gradient (APG) turbulent boundary layers (TBL). A suitable set-up was developed to study near-equilibrium conditions for a boundary layer developingon a flat plate by setting the free-stream velocity at the top of the domain following a power law. The computational box size and the correct definition of the top-boundary condition were systematically tested. Well-resolved large-eddy simulations were performed to keep computational costs low. By varying the free-stream velocity distribution parameters, e.g. power-law exponent and virtual origin, pressure gradients of different strength and development were obtained. The magnitude of the pressure gradient is quantified in terms of the Clauser pressure-gradient parameter β. The effect of the APG is closely related to its streamwise development, hence, TBLs with non-constant and constant β were investigated. The effect was manifested in the mean flow through a much more pronounced wake region and in the Reynolds stresses through the existence of an outer peak. The terms of the turbulent kinetic energy budgets indicate the influence of the APG on the distribution of the transfer mechanism across the boundary layer. Stronger and more energetic structures were identified in boundary layers with relatively stronger pressure gradients in their development history. Due to the difficulty of determining the boundary-layer thickness in flows with strong pressure gradients or over a curvedsurface, a new method based on the diagnostic-plot concept was introduced to obtain a robust estimation of the edge of a turbulent boundary layer. In the second part, large-eddy simulations were performed on temporally developing turbulent asymptotic suction boundary layers (TASBLs). Findings from previous studies about the effect of suction could be confirmed, e.g. the reduction of the fluctuation levels and Reynolds shear stresses. Furthermore, the importance of the size of the computational domain and the time development were investigated. Both parameters were found to have a large impact on the results even on low-order statistics. While the mean velocity profile collapses in the inner layer irrespective of box size and development time, a wake region occurs for too small box sizes or early development time and vanishes once sufficiently large domains and/or integration times are chosen. The asymptotic state is charactersized by surprisingly thick boundary layers even for moderateReynolds numbers Re (based on free-stream velocity and laminar displacement thickness); for instance, Re = 333 gives rise to a friction Reynolds number Reτ = 2000. Similarly, the flow gives rise to very large structures in the outer region. These findings have important ramifications for experiments, since very large facilities are required to reach the asymptotic state even for low Reynolds numbers. / <p>QC 20160418</p>

The present study deals with the effects of sparsely distributed three-dimensional elements on two-dimensional (2-D) and three-dimensional (3-D) turbulent boundary layers (TBL) such as those that occur on submarines, ship hulls, etc. This study was achieved in three parts: Part 1 dealt with the cylinders when placed individually in the turbulent boundary layers, thereby considering the effect of a single perturbation on the TBL; Part 2 considered the effects when the same individual elements were placed in a sparse and regular distribution, thus studying the response of the flow to a sequence of perturbations; and in Part 3, the distributions were subjected to 3-D turbulent boundary layers, thus examining the effects of streamwise and spanwise pressure gradients on the same perturbed flows as considered in Part 2. The 3-D turbulent boundary layers were generated by an idealized wing-body junction flow. Detailed 3-velocity-component Laser-Doppler Velocimetry (LDV) and other measurements were carried out to understand and describe the rough-wall flow structure. The measurements include mean velocities, turbulence quantities (Reynolds stresses and triple products), skin friction, surface pressure and oil flow visualizations in 2-D and 3-D rough-wall flows for Reynolds numbers, based on momentum thickness, greater than 7000. Very uniform circular cylindrical roughness elements of 0.38mm, 0.76mm and 1.52mm height (k) were used in square and diagonal patterns, yielding six different roughness geometries of rough-wall surface. For the 2-D rough-wall flows, the roughness Reynolds numbers, based on the element height (k) and the friction velocity, range from 26 to 131. Results for the 2-D rough-wall flows reveal that the velocity-defect law is similar for both smooth and rough surfaces, and the semi-logarithmic velocity-distribution curve is shifted by an amount depending on the height of the roughness element, showing that this amount is a function of roughness Reynolds number and the wall geometry. For the 3-D flows, the data show that the surface pressure gradient is not strongly influenced by the roughness elements. In general, for both 2-D and 3-D rough-wall TBL, the differences between the two roughness patterns (straight and diagonal), as regards the mean velocities and the Reynolds stresses, are limited to about 3 roughness element heights from the wall. The study on single elements revealed that the separated shear layers emanating from the top of the elements form a pair of counter rotating vortices that dominate the downstream flow structure. These vortices, termed as the roughness top vortex structure (RTVS), in conjunction with mean flow, forced over and around the elements, are responsible for the production of large Reynolds stresses in the neighborhood of the element height aft of the elements. When these elements are placed in a distribution, the effects of RTVS are not apparent. The roughness elements create a large region of back flow behind them which is continuously replenished by faster moving fluid flowing through the gaps in the rough-wall. The fluid in the back flow region moves upward as low speed ejections where it collides with the inrushing high speed flow, thus, leading to a strong mixing of shear layers. This is responsible for the generation of large levels of turbulent kinetic energy (TKE) in the vicinity of the element height which is transported, primarily, by turbulent diffusion. As regards the 3-D rough-wall TBL, the effect of flow three-dimensionality is seen in the large skewing of the distributions of mean velocities, Reynolds stresses and TKE, aft of the elements. In general, the regions of large TKE production-rates seem to propagate in the direction of the local velocity vector at the element height. The data-sets also enable the extraction of the turbulent flow structure to better describe the flow physics of these rough-wall turbulent boundary layers. / Ph. D.

We develop a physics-based reduced-order model of the aero-acoustic sound sources in reacting mixing layers as a method for fast and accurate predictions of the radiated sound. Instabilities in low-speed mixing layers are known to be dominated by the traditional Kelvin–Helmholtz (K–H)-type “central” mode, which is expected to be superseded by the “outer” modes as the chemical-reaction-based heat-release modifies the mean density, yielding new peaks in the density-weighted vorticity profiles. Although, these outer modes are known to be of lesser importance in the near-field mixing, how these radiate to the far-field is uncertain, on which we focus primarily, when the mixing layer is supersonic, but also report subsonic cases. On keeping the flow compressibility fixed, the outer modes are realized via biasing the respective mean density of the fast (oxidizer) or slow (fuel) side. In the linearized model that we use, the mean flow are laminar solutions of two-dimensional compressible boundary layers with an imposed composite turbulent spread rate, which we show to correctly predict the growth of instability waves by saturating them earlier, similar to in non-linear calculations, but obtained here via solving the linear parabolized stability equations (PSE). The chemical reaction is modeled via a single-step, single-product overall process which introduces a heat release term in the mean temperature equation. As the flow parameters are varied, modes that are unstable on the slow side are shown to be more sensitive to heat release, potentially exceeding equivalent central modes, as these modes yield relatively compact sound sources with lesser spreading of the mixing layer, when compared to the corresponding fast modes. In contrast, the radiated sound, obtained directly from the PSE solutions, seems to be relatively unaffected by a variation of mixture equivalence ratio, except for a lean mixture which is shown to yield a pronounced effect on the slow mode radiation by reducing its modal growth. For subsonic mixing layers, the sensitivity of central mode is explored, which in addition requires an acoustic analogy based method (e.g. the Lilley–Goldstein equations) to predict the sound from the linearized PSE sources, as used here, unlike in supersonic cases.

The focus of this study was analytical investigations of Egyptian paintings, mainly Coptic icons and Islamic wooden ceilings, dating from 1300-1900 using multi-instrumental techniques. Twenty three Coptic icons and three wooden ceilings dated from different periods and painted by different painters in case of icons were examined. The materials used including pigments, media, varnishes, ground layers and gold layers. The surface stratigraphy of paint samples, their layered structured and the composition of materials used in each layer were analysed. Variations in painting techniques, pigments palettes, paint media and varnishes applied in Egyptian paintings according to painters, time and type of paintings were revealed. A total of twenty-eight organic and inorganic pigments were identified in this study, of which nine have never been previously included as a part of the Egyptian pigment palettes, namely; smalt, lapis lazuli, indigo, pararealgar, Prussian blue, chrome yellow, barium yellow, barium white and hydromagnesite. The identification of hydromagnesite, which has never been to date considered as a pigment either in Egypt or elsewhere and the identification of smalt from the mid-14th century, whose reported earliest large scale use was in the 16th century. Two types of resins were identified as a constituent of the oil/resin varnish applied on Coptic icons of which Venice turpentine has been identified for the first time as an ingredient of Egyptian varnishes. The identification of mosaic gold in an 18th C. icon, a novel usage of dammar resin and the multilayered structure of the white ground layers were revealed.

This study aimed to evaluate the effect of age and lineage of layers breeders light and semi heavy on the quality of the egg, the pinto newly eclodido and performance of incubation. 3,456 eggs were used for breeding light (Dekalb White) and semi heavy (Bovans Goldline) in three different ages (young, old and middle age). The experiment was divided into two stages, at first we evaluate the characteristics of the eggs of a sample of 360 eggs (60 per treatment). In the second stage evaluated the performance of chicks hatching and quality of a sample of 3,096 eggs (516 per treatment). It was observed that the quality of the shell fell and the weight of the egg increased with the increase of age of the birds. The layers breeders Dekalb White eggs produced heavier in the middle ages and with better quality of bark at all ages. With the increasing age of the bird has increased the percentage of yolk and albumen decreases. This decrease was more pronounced in a manner eggs line Dekalb White. Eggs of the same lineage, layers breeders young and old had a higher percentage of egg yolk. The pH of the yolk and albumen increased with the ageing of layers breeding, which in old age, the egg line Dekalb White shows higher values for these variables that line Bovans Goldline. As for the assessment of incubation found that birds' eggs old line Bovans Goldline had greater percentage of weight loss during the incubation than those from Dekalb White layers breeders of the same age. The weight of pinto increased with increasing age of the leyer breeding and Dekalb White chicks born heavier that the Bovans Goldline. However, the relationship of chicks weight / weight of the egg was higher for chicks Bovans Goldline poultry young and middle age. The progeny Dekalb White was not influenced by the age of reproductive on this parameter. The percentage of females born in respect of fertile eggs was greater in the lineage Dekalb White. Since young matrices obtained lower values for this variable, regardless of their lineage. The female chicks Dekalb White, and had weights more uniform, had a higher percentage of bag viteline than the Bovans Goldline. The age of the matrix no effect on these variables. The percentage of the heart and lungs in the weight of the female chicks were not influenced by age or the lineage of breeding. / O presente trabalho teve como objetivo avaliar o efeito da idade e da linhagem de galinhas matrizes leves e semi pesadas sobre a qualidade do ovo, do pinto recém-eclodido e do rendimento da incubação. Foram utilizados 3.456 ovos de reprodutoras leves (Dekalb White) e semi pesadas (Bovans Goldline) em três diferentes idades (jovens, velhas e de média idade). O experimento foi dividido em duas etapas; na primeira se avaliou as características dos ovos de uma amostra de 360 ovos (60 por tratamento). Na segunda etapa avaliou-se o desempenho da incubação e a qualidade dos pintinhos numa amostra de 3.096 ovos (516 por tratamento). Observou-se que a qualidade da casca diminuiu e o peso do ovo aumentou com a elevação da idade das aves. As matrizes Dekalb White produziram ovos mais pesados na idade média e com melhor qualidade de casca em todas as idades. Com o aumento da idade da ave o percentual da gema aumentou e do albúmen diminui. Essa diminuição ocorreu de maneira mais acentuada em ovos da linhagem Dekalb White. Ovos dessa mesma linhagem, de matrizes jovens e velhas apresentaram maior percentual de gema. O ph da gema e do albúmen aumentou com o envelhecimento das matrizes, sendo que na idade ve lha, o ovo da linhagem Dekalb White apresenta valores maiores para essas variáveis que os da linhagem Bovans Goldline. Quanto à avaliação da incubação verificou-se que ovos de aves velhas da linhagem Bovans Goldline apresentaram maior percentual de perda de peso durante a incubação do que aqueles provenientes de matrizes Dekalb White de mesma idade. O peso do pinto aumentou com o aumento da idade da matriz e pintinhos Dekalb White nasceram mais pesados que os Bovans Goldline. Porém, a relação peso do pinto / peso do ovo foi maior para pintos Bovans Goldline de aves jovens e de média idade. A progênie Dekalb White não foi influenciada pela idade da reprodutora quanto a esse parâmetro. O percentual de fêmeas nascidas em relação aos ovos férteis foi maior na linhagem Dekalb White. Sendo que matrizes jovens obtiveram valores menores para essa variável, independente de sua linhagem. As pintinhas Dekalb White, além de apresentaram pesos mais uniformes, obtiveram maior percentual de saco vitelino do que as Bovans Goldline. A idade da matriz não exerceu influência sobre essas variáveis. O percentual do coração e dos pulmões em relação ao peso da pintinha não foi influenciado pela idade nem pela linhagem das reprodutoras. / Mestre em Ciências Veterinárias

This thesis is concerned with studies on spatially developing high speed mixing layers with twin objectives: (a) to provide enhanced and detailed understanding of spatial development of two-dimensional mixing layer emanating from splitter plate through large eddy simulation (LES, from now on) technique and (b) to evolve a consistent strategy for Unsteady Reynolds Averaged Navier-Stokes (URANS) approach to mixing layer calculations. The inspiration for this work arose out of the explanations that were being developed for the reduction in the mixing layer thickness with compressibility (measured by a parameter called convective Mach number, Mc). The reasons centered around increased stability, increase in compressible dissipation that was later discounted in favor of reduction in production and pressure-strain terms (with Mc, of course). These were obtained with direct numerical simulations (DNS) or LES techniques with homogeneous shear flow or temporal mixing layer. As apart, there was also a wide held view that using RANS (steady) techniques did not capture the compressibility effects when used in a way described above and so classical industrial codes for computing mixing- layer-embedded flows are unsuitable for such applications. Other important aspects that come out of the examination of literature are: the mixing layer growth is controlled in the initial stages by the double- boundary layer profile over the splitter plate and results in the mixing layer growth that is somewhat irregular due to doubling and merging of vertical structures. The view point of a smooth growth of the mixing layer is a theo- retical approximation arising out of the use of a smooth tan-hyperbolic profile that results at larger distances from the splitter plate. For all practical applications, it is inferred that the initial development is what is important because the processes of ignition and stable combustion occur close to the splitter plate. For these reasons, it was thought that understanding the development of the mixing layer is best dealt with using accurate spatial simulation with the appropriate initial profile. The LES technique used here is drawn from an OpenFOAM approach for dissimilar gases and uses one-equation Eddy Model for SGS stresses. The temporal discretization is second order accurate backward Euler and spatial discretization is fourth order least squares; the algorithm used for solving the equations is PISO and the parallelized code uses domain decomposition approach to cover large spatial domain. The calculations are performed with boundary layer profiles over the splitter plate and an initial velocity field with white noise-like fluctuations to simulate the turbulence as in the experiments. Grid independence studies are performed and several experimental cases are considered for comparison with measured data on the velocity and temperature fields as well as turbulent statistics. These comparisons are excellent for the mean field behavior and moderately acceptable for turbulent kinetic energy and shear stress. To further benefit from the LES approach, the details of the mixing layer are calculated as a function of four independent parameters on which the growth depends: convective Mach number (Mc = (U1 -U2)/ (a1 +a2)), stream speed ratio (r = U2=U1), stream density ratio (s = p2/p1) and the average velocity of the two streams ((U1+U2)=2) and examine the various terms in the equations to enable answering the questions discussed earlier. It is uncovered that r has significant influence on the attainment of self similarity (which also implies on the rate of removal of velocity defect in the double-boundary layer profile) and other parameters have a very weak influence. The minimum velocity variation with distance from the splitter plate has the 1/paxial distance behavior like in wakes; however, after a distance, departure to linear rise occurs and the distance it takes for this to appear is delayed with Mc. Other features such as the coherent structures, their merger or break up, the area of the structures, convective velocity information extraction from the coherent structures, the behavior of the pressure field in the mixing layer through the field are elucidated in detail; the behavior of the correlations between parameters (like pressure, velocity etc) at different points is used to elucidate the coherence of their fluctuating field. The effects of the parameters on the energy spectra have expected trends. An examination of the kinetic energy budget terms reveals that • the production term is the main source of the xx turbulence stress, whereas it is not significant in the yy component. • A substantial portion of this is carried by the pressure-velocity coupling from the xx direction to the yy direction, which becomes the main source term in the yy component. • Both, the production term as well as the pressure-velocity term show a clear decrease with increase in Mc. The high point of the thesis is related to using the understanding derived from an analysis of various source terms in the kinetic energy balance to evolve an unsteady Reynolds Averaged Navier Stokes (URANS) model for calculating high speed mixing layers, a subject that has eluded international research till now. It recognizes that the key feature affected by ompressibility is related to the anisotropy of the stress tensor. The relationship between stress component (_Txy) and the velocity gradient (Sxy) as obtained from LES is set out in the form of a simple relationship accounting for the effects of other parameters obtained earlier in this thesis. A minor influence due to _Tyy is extracted by describing its dependence on Sxy again as gleaned from LES studies. The needed variation of Prandtl and Schmidt numbers through the field is extracted. While the detailed variations can in fact be taken into account in URANS simulations, a simple assumption of these values being around 0.3 is chosen for the present simulations of URANS. Introduction of these features into the momentum equation gives the much expected variation of the reduction in the growth rate of the mixing layer with convective Mach number as in experiments. The relationships that can be used in high speed mixing layers are Introduction of these features into the momentum equation gives the much expected variation of the reduction in the growth rate of the mixing layer with convective Mach number as in experiments. This is then a suggested new approach to solve high speed mixing layers. While it can be thought that the principal contributions of the thesis are complete here, an additional segment is presented related to entropy view of the mixing layer. This study that considers the mixing layer with two different species expresses various terms involved in the entropy conservation equation and obtains the contribution of various terms on the entropy change for various Mc. It is first verified that the entropy derived from the conservation equation matches with those calculated from fluid properties, entropy being a state variable. It is shown that irreversible diffusion comes down the most with convective Mach number. Left: This image shows pictorially the flow of source of turbulent stress from the axial to the cross wise turbulent stress. Production (Σ) of turbulence happens mainly in the xx direction, a part of it is carried by the pressure-velocity correlation to the yy direction, which itself has a low production. With increasing Mc, both the production as well as the pressure-velocity correlation decrease. Right: This image shows the growth rate obtained from simulations scaled with the incompressible growth rate, of LES and RANS in the background of experiments (others). As is clear, the growth rate obtained is well within the band of experimental results.

There are a large number of research vessels and fishing vessels equipped with echosounders plying the world ocean, making continual observations of the ocean interior. Developing data collation programmes (e.g. Integrated Marine Observing System) and automated, repeatable analyses techniques enable the upper c. 1,200 meters of the world ocean to be sampled routinely, and for their characteristic deep scattering layers (DSLs) to be compared. Deep scattering layers are comprised of zooplankton (e.g. euphausiids) and fish, particularly myctophids or lantern fish, and comprise the majority of sub-surface biomass. Here we present, by the analysis of a global acoustic dataset, a mesopelagic biogeography of the sea. This was accomplished by (i) the collation and processing of a global active acoustic dataset, (ii) the development of a standardised and automated method of sound scattering layer (SSL) extraction and description, (iii) the derivation of the environmental drivers of DSL depth and biomass, (iv) the definition of a mesopelagic biogeography based on the drivers of DSL metrics and (v) the prediction, using output from the NEMO-MEDUSA-2.0 coupled model, of how the metrics and biogeography may change by 2100. Key findings include, the development of the Sound Scattering Layer Extraction Method (SSLEM) the inference that primary production, water temperature and wind stress are key drivers in DSL depth and biomass and that mesopelagic fish biomass may increase by 2100. Such an increase is a result of increased trophic efficiency from the shallowing of DSLs and rising water temperatures, suggesting, that as the climate warms the ocean is becoming more efficient. The biophysical relationships and biogeography derived here, serve to improve our understanding of mesopelagic mid-trophic level dynamics in open-ocean ecosystems. This will aid both fisheries and conservation management, which now adopt more holistic approaches when monitoring and evaluating ecosystem health and stability.

This diploma thesis deals with methodology of thin film thickness determination using X-ray radiation of silver anode which provides radiation with energy of 2984,3 eV. This energy is twice as high as the standard aluminium radiation which allows a measurement of new photoelectron lines with higher bonding energy and it also provides thanks to the higher photoelectron energy greater information depth. In order to get the right results it was necessary to calibrate the spectrometer Kratos Axis Supra in the silver anode mode first and found out the form of the transmission function. The determination of the thickness of the thin layer was demonstrated by the comparation of the ratio of different photoelectron lines intensities with the theoretical model. For that purpose was specifically used the Si 1s and Si 2p peak bound in the substrate in the Si-Si bonding or in the thin oxid layer in the Si-O bonding. The results show that for thin SiO2/Si film thickness determination is the best to use the intensity ratio of only one photoelectron line. A silver anode however provides greater information depth.