In broad terms, this thesis is concerned with the measurement and interpretation of carrier lifetimes in multicrystalline silicon. An understanding of these lifetimes in turn leads to a clearer picture of the limiting mechanisms in solar cells made with this promising material, and points to possible paths for improvement. The work falls into three broad categories: gettering, trapping and recombination. A further section discusses a powerful new technique for characterising impurities in semiconductors in general, and provides an example of its application. Gettering of recombination centres in multicrystalline silicon wafers improves the bulk lifetime, often considerably. Although not employed deliberately in most commercial cell processes, gettering nevertheless occurs to some extent during emitter formation, and so may have an important impact on cell performance. However, the response of different wafers to gettering is quite variable, and in some cases is non-existent. Work in this thesis shows that the response to gettering is best when the dislocation density is low and the density of mobile impurities is high. For Eurosolare material these conditions prevail at the bottom and to a lesser extent in the middle of an ingot. However, these conclusions can not always be applied to multicrystalline silicon produced by other manufacturers. Low resistivity multicrystalline silicon suffers from a concurrent thermally induced degradation of the lifetime. This had previously been attributed to the dissolution of precipitated metals, although we note that the crystallographic quality also appears to deteriorate. The thermal degradation effect results in an optimum gettering time for low resistivity material. Edge-defined Film-fed Growth (EFG) ribbon silicon was also found to respond to gettering, and even more so to bulk hydrogenation. Evidence for Cu contamination in the as-grown EFG wafers is presented. Multicrystalline silicon is often plagued by trapping effects, which can make lifetime measurement in the injection-level range of interest very difficult, and sometimes impossible. An old model based on centres that trap and release minority carriers, but do not interact with majority carriers, was found to provide a good explanation for these effects. These trapping states were linked with the presence of dislocations and also with boron-impurity complexes. Their annealing behaviour and lack of impact on device parameters can be explained in terms of the models developed. The trapping model allowed a recently proposed method for correcting trap-affected data to be tested using typical values of the trapping parameters. The correction method was found to extend the range of useable data to approximately an order of magnitude lower in terms of carrier density than would be available otherwise, an improvement that could prove useful in many practical cases. High efficiency PERL and PERC cells made on gettered multicrystalline silicon resulted in devices with open circuit voltages in the 640mV range that were almost entirely limited by bulk recombination. Furthermore, the injection-level dependence of the bulk lifetime resulted in decreased fill factors. Modelling showed that these effects are even more pronounced for cells dominated by interstitial iron recombination centres. Analysis of a commercial multicrystalline cell fabrication process revealed that recombination in the emitter created the most stringent limit on the open circuit voltage, followed by the bulk and the rear surface. The fill factors of these commercial cells were mostly affected by series resistance, although some reduction due to injection-level dependent lifetimes seems likely also. Secondary Ion Mass Spectroscopy on gettered layers of multicrystalline silicon revealed the presence of Cr and Fe in considerable quantities. Further evidence strongly implied that they resided almost exclusively as precipitates. More generally, injection-level dependent lifetime measurements offer the prospect of powerful contamination-monitoring tools, provided that the impurities are well characterised in terms of their energy levels and capture cross-sections. Conversely, lifetime measurements can assist with this process of characterising impurities, since they are extremely sensitive to their presence. This possibility is explored in this thesis, and a new technique, dubbed Injection-level Dependent Lifetime Spectroscopy (IDLS) is developed. To test its potential, the method was applied to the well-known case of FeB pairs in boron-doped silicon. The results indicate that the technique can offer much greater accuracy than more conventional DLTS methods, and may find applications in microelectronics as well as photovoltaics.

In this thesis, we propose mechanisms to extend the lifetime of wireless sensor networks. In-network data aggregation is considered on both tree-based and flow-based routing protocols during the process of data collection to reduce redundant transmissions. In the flow-based data collection design, we introduce the concept of flow loss multiplier to express the impact of data aggregation over correlated data. The application has the freedom to set the flow loss multiplier to reflect its specific knowledge of correlation. We also introduce traffic balancing as a complementary technique to data aggregation. It helps avoid exhausting the energy of any sensor node while leaving large amounts of energy at other nodes. In tree-based data collection schemes, we adjust the tree structure judiciously to balance energy consumption before any node's failure due to total residual energy depletion. In flow-based schemes, after aggregation, data flows are split and the fragments are spread to increase network lifetime. We investigate the impact of performing greedily data aggregation at the "best" aggregation site regardless of its location, the results of our analysis show that only applying 2-way data aggregation may limit the ability to explore more complex aggregation possibilities. To address this problem, we propose an aggressive data aggregation for a specified application, contour map reconstruction. Based on the simulation results, our aggregation scheme is shown to be able to eliminate large volume of contour data and retain satisfying data accuracy.

The generation and propagation of fluorescence light within biological tissue offers the potential for biomedical diagnostics and analyte sensing. Arising from an exogenous fluorescent dye injected as a contrast agent or immobilized in a polymer implant, the fluorescent decay kinetics can be sensitive to the tissue??s biochemical environment, providing quantitative in vivo information of the confined tissue site. The impact of light propagation and decay kinetics upon the measured signals is important for consideration, simply because tissue scatters light, giving rise to nanosecond photon time-of-flights that are comparable to fluorescence relaxation kinetics. The goal of this study is to develop a time-dependent model describing (i) the generation of fluorescence from dyes exhibiting multi-exponential or more complex kinetics and (ii) its propagation in scattering media. In the preliminary study, fluorescence lifetime spectroscopy is investigated in tissue-like scattering solution. Two fluorescent dyes, 3,3-diethylthiatricarbocyanine iodide (DTTCI) and Indocynanine Green (ICG), which exhibit distinctly different lifetimes and each exhibits single-exponential decay kinetics, were employed. Measurements of phase-modulation as a function of modulation frequency were made at varying concentration ratios of the two dyes to experimentally simulate fluorescence multi-exponential decay kinetics in non-scattering and scattering solutions. The results suggest that frequency-domain measurements of fluorescent decay kinetics along with models of light propagation may be enhanced by scatter in order to probe kinetics more sensitively than in non-scattering solutions. The next study involved fluorescence lifetime sensing in scattering and non-scattering solutions with a pH sensitive dye, Carboxy Seminaphthofluorescein-1 (C-SNAFL-1), which is known to exhibit multi-exponential decay kinetics. The results demonstrate accurate pH sensing in scattering solution via fluorescence kinetics using a simplified propagation model incorporating an average lifetime. Finally, fluorescence lifetime sensing in immobilized systems were investigated. C-SNAFL-1 was immobilized in poly(ethylene glycol) (PEG) microparticles that were immersed in buffered polystyrene solutions. The results demonstrate the ability to perform pH sensing with fluorescence lifetime without the confounding effect of fluorophore loading or the use of 'reference' measurement within multiply scattering systems. In addition, the stability of the immobilized fluorescence sensor and the reliability of fluorescence lifetime measurement verify the prospect of this technology for implantable purposes.

Wireless Sensor Networking is envisioned as an economically viable paradigm and a promising technology because of its ability to provide a variety of services, such as intrusion detection, weather monitoring, security, tactical surveillance, and disaster management. The services provided by wireless senor networks (WSNs) are based on collaboration among small energy-constrained sensor nodes. The large deployment of WSNs and the need for energy efficient strategy necessitate efficient organization of the network topology for the purpose of balancing the load and prolonging the network lifetime. Clustering has been proven to provide the required scalability and prolong the network lifetime. Due to the bottle neck phenomena in WSNs, a sensor network loses its connectivity with the base station and the remaining energy resources of the functioning nodes are wasted. This thesis highlights some of the research done to prolong the network lifetime of wireless sensor networks and proposes a solution to overcome the bottle neck phenomena in cluster-based sensor networks. Transmission tuning algorithm for a cluster-based WSNs is proposed based on our modeling of the extra burden of the sensor nodes that have direct communication with the base station. Under this solution, a wireless sensor network continues to operate with minimum live nodes, hence increase the longevity of the system. An information theoretic metric is proposed as a cluster head selection criteria for breaking ties among competing clusters, hence as means to decrease node reaffiliation and hence increasing the stability of the clusters, and prolonging the network lifetime. This proposed metric attempts to predict undesired mobility caused by erosion.

Wireless Sensor Networking is envisioned as an economically viable paradigm and a promising technology because of its ability to provide a variety of services, such as intrusion detection, weather monitoring, security, tactical surveillance, and disaster management. The services provided by wireless senor networks (WSNs) are based on collaboration among small energy-constrained sensor nodes. The large deployment of WSNs and the need for energy efficient strategy necessitate efficient organization of the network topology for the purpose of balancing the load and prolonging the network lifetime. Clustering has been proven to provide the required scalability and prolong the network lifetime. Due to the bottle neck phenomena in WSNs, a sensor network loses its connectivity with the base station and the remaining energy resources of the functioning nodes are wasted. This thesis highlights some of the research done to prolong the network lifetime of wireless sensor networks and proposes a solution to overcome the bottle neck phenomena in cluster-based sensor networks. Transmission tuning algorithm for a cluster-based WSNs is proposed based on our modeling of the extra burden of the sensor nodes that have direct communication with the base station. Under this solution, a wireless sensor network continues to operate with minimum live nodes, hence increase the longevity of the system. An information theoretic metric is proposed as a cluster head selection criteria for breaking ties among competing clusters, hence as means to decrease node reaffiliation and hence increasing the stability of the clusters, and prolonging the network lifetime. This proposed metric attempts to predict undesired mobility caused by erosion.

<p>The lifetime of $^{19}$Ne is an important parameter in precision tests of the Standard Model. Improvement in the uncertainty of experimental observables of this and other $T=\frac{1}{2}$ mirror isotopes would allow for an extraction of</p><p>V$_{ud}$ at a similar precision to that obtained by superallowed $0^+\rightarrow0^+$ Fermi decays. We report on a new high precision measurement of the lifetime of $^{19}$Ne, performed at the Kernfysich Versneller Instituut (KVI) in Groningen, the Netherlands. A 10.5 $\frac{MeV}{A}$ $^{19}$F beam was used to produce $^{19}$Ne using inverse reaction kinematics in a H$_2$ gas target. Contaminant productions were eliminated using the TRI$\mu$P magnetic isotope separator. The $^{19}$Ne beam was implanted into a thick aluminum tape, which was translated to a shielded detection region by a custom tape drive system. Collinear annihilation radiation from the emitted decay positrons were detected by two high purity germanium (HPGe) detectors. Event pulse waveforms were digitized and stored using a CAEN V1724 Digitizer. Systematic studies were performed to characterize rate-dependent data acquisition effects, diffusion, backgrounds, and contamination from the separator. We have obtained the result for the lifetime of $\tau = 24.9344 \pm 0.0073(stat) \pm 0.0083(sys)$ seconds.</p> / Dissertation

This thesis used TCSPC (Time-Correlated Single Photon Counting) apparatus to study the time-resolve photoluminescence (TRPL) of InGaN multi-quantum-well light emission diode and the photoluminescence of Zn1-xMgxSe properties at different Mg concentration. We obtained the activation energy form Arrhenius Plot, internal quantum efficiency (IQE), the radiative lifetime, and the radiative recombination critical at 180K of In0.25Ga0.75N multi-quantum well LED. Furthermore, the variation of PL peak location and FWHM with Mg concentration of Zn1-xMgxSe thin film with x=0.1¡B0.25¡B0.34¡B0.37¡B0.4¡B0.42 are observed.

Vulnerable plaque is a clinically silent condition of atherosclerotic plaque that leaves a large number of patients at risk of a coronary event. A method to detect vulnerable atherosclerotic plaque would greatly enhance the ability of clinicians to diagnose and treat patients at risk. Fluorescence lifetime imaging microscopy (FLIM) offers a way to extract both spatial and biochemical information from plaque by taking several wide-field images over time. The goal of this study was to determine the potential of a FLIM angioscopy system to detect and differentiate coronary atherosclerotic plaques ex-vivo into several groups including thin, fibrotic, lipid-laden, thick-cap fibroatheroma (FA), and fibrocalcified. Samples were extracted post-mortem weekly and sliced open to have their lumens imaged. For each sample, 51 time resolved wide-field images were taken over 10 nanoseconds at 390 (±40) nm, 450 (±40) nm, and 550 (±88) nm wavelengths. To analyze the samples, the intensity map and lifetime map were created at each wavelength. The intensity map was simply the wide-field images summed in time and normalized. In order to calculate lifetime at each point, a fast, model-free Laguerre deconvolution algorithm was recently developed for FLIM data analysis and was used. This allowed for fast, efficient estimations of the fluorescence decay curves at each pixel of the FLIM images and facilitated the computation of quantitative parameters describing the fluorescence emission of the tissue, specifically, the relative fluorescence intensity and lifetime at defined emission bands. Statistical analysis on these FLIM derived parameters indicated that the autofluorescence emission of the plaques allows for distinguishing relative plaque thickness: thin plaque, whose signal is dominated by elastin fluorophores, shows a marked difference between thicker plaques, such as fibrotic, fibrocalcified and thick-cap FA (who are dominated primarily by collagen). However, the ability of the current FLIM system to differentiate vulnerable plaque remains in question due to the absence of thin-cap FA samples. Further work has also been proposed; of primary concern is gathering thin-cap FA plaque samples needed to validate the system’s ability to differentiate vulnerable plaques from other common groupings.

The generation and propagation of fluorescence light within biological tissue offers the potential for biomedical diagnostics and analyte sensing. Arising from an exogenous fluorescent dye injected as a contrast agent or immobilized in a polymer implant, the fluorescent decay kinetics can be sensitive to the tissue??s biochemical environment, providing quantitative in vivo information of the confined tissue site. The impact of light propagation and decay kinetics upon the measured signals is important for consideration, simply because tissue scatters light, giving rise to nanosecond photon time-of-flights that are comparable to fluorescence relaxation kinetics. The goal of this study is to develop a time-dependent model describing (i) the generation of fluorescence from dyes exhibiting multi-exponential or more complex kinetics and (ii) its propagation in scattering media. In the preliminary study, fluorescence lifetime spectroscopy is investigated in tissue-like scattering solution. Two fluorescent dyes, 3,3-diethylthiatricarbocyanine iodide (DTTCI) and Indocynanine Green (ICG), which exhibit distinctly different lifetimes and each exhibits single-exponential decay kinetics, were employed. Measurements of phase-modulation as a function of modulation frequency were made at varying concentration ratios of the two dyes to experimentally simulate fluorescence multi-exponential decay kinetics in non-scattering and scattering solutions. The results suggest that frequency-domain measurements of fluorescent decay kinetics along with models of light propagation may be enhanced by scatter in order to probe kinetics more sensitively than in non-scattering solutions. The next study involved fluorescence lifetime sensing in scattering and non-scattering solutions with a pH sensitive dye, Carboxy Seminaphthofluorescein-1 (C-SNAFL-1), which is known to exhibit multi-exponential decay kinetics. The results demonstrate accurate pH sensing in scattering solution via fluorescence kinetics using a simplified propagation model incorporating an average lifetime. Finally, fluorescence lifetime sensing in immobilized systems were investigated. C-SNAFL-1 was immobilized in poly(ethylene glycol) (PEG) microparticles that were immersed in buffered polystyrene solutions. The results demonstrate the ability to perform pH sensing with fluorescence lifetime without the confounding effect of fluorophore loading or the use of 'reference' measurement within multiply scattering systems. In addition, the stability of the immobilized fluorescence sensor and the reliability of fluorescence lifetime measurement verify the prospect of this technology for implantable purposes.

Due to hierarchical sensor networks is capable to elimination extra sensing information and reduce extra communication load, it is remarkably important to increase scalability of network and prolong lifetime of network. In the paper, we focus on relay nodes of two-layered heterogeneous sensor networks. When relay nodes transmit data without scheduling, the collision probability must increase. It will cost too much for energy to re-transmission data and listening channel. To avoid extra energy consumption, we build a grid network according to RSS, and naming IP for every relay node on the grid network. Then, all leaf nodes join a certain cluster and naming IP according to RSS. Through the exclusive IP it schedule mission for TDMA. Only when relay node comes in specific slot, it wakes up to transmit or receive data, the remaining time to sleep and save power consumption. Besides, in order to balance energy consumption of backbone or non-backbone relay nodes and prolong lifetime of network, we proposal three routing protocol (DTS¡BREARBS¡BVIPOS). According to simulation results, VIPOS is the longest lifetime above them.