In der theoretischen Auseinandersetzung mit mobilen Internet-Diensten sind Quality of Service (QoS) und Quality of Experience (QoE) als hochkomplexe und verbundene Konzepte zu erkennen. QoS umfasst dabei die technische Sicht auf das Telekommunikationsnetz, charakterisiert durch leistungsrelevante Parameterwerte (z. B. Durchsatz und Latenz). QoE hingegen bezieht sich auf die Bewertung des Nutzererlebnisses (z. B. Zufriedenheit und Akzeptanz). Zur gemeinsamen Erklärung bedarf es einer multi- bzw. interdisziplinären Betrachtung zwischen Ingenieurs- und Humanwissenschaften, da neben der Technik auch der Mensch als Nutzer in den QoS-QoE-Zusammenhang involviert ist. Ein mehrschichtiges Modell erfasst die relevanten Einflussfaktoren und internen Zusammenhänge zwischen QoS und QoE sowohl aus Netz- als auch Nutzersicht. Zur Quantifizierung des Zusammenhangs konkreter Werte in einer empirischen QoE-Evaluation wurde ein umfangreiches psychophysikalisches Laborexperiment konzipiert. Das dafür entwickelte Netzemulations-Testbed erlaubt mobiltypische Netz- und Nutzungssituationen gezielt in einem Testparcours zusammenzubringen. Die formulierten Prinzipien zur Testrelevanz, -eignung und -effizienz berücksichtigen hierbei die Besonderheiten des Testaufbaus und -designs mit echten Endgeräten und Diensten. Die Ergebnisse von über 200 Probanden bestätigen die vorhergesagten QoS-QoE-Charakteristiken der sechs untersuchten Dienste als kontinuierlich-elastisch bzw. sprunghaft-fest. Dienstspezifisch lässt sich jeweils von einem angestrebten Grad der Nutzerzufriedenheit auf die notwendigen Werte der QoS-Netzparameter schließen, woraus sich ein QoS-QoE-Zufriedenheitskorridor zwischen einem unteren und oberen Schwellwert ergibt. Teilweise sind dabei QoS-unabhängige Faktoren, z. B. die Art der Präsentation der Stimuli in der App auf dem Endgerät, als ebenso relevant zu erkennen wie die QoS-Netzparameter selbst. / The thesis is centered on the relationship of Quality of Service (QoS) and Quality of Experience (QoE) for mobile Internet services. While QoS covers the technical view on the telecommunications network characterized by performance-related parameter values (e.g. throughput and latency), QoE refers to the assessment of the user experience (e.g. satisfaction and acceptability) in the use of the services. In the thesis QoS and QoE are revealed as highly complex and related concepts in theoretical contemplation. Integrating both concepts requires a multidisciplinary or interdisciplinary approach between engineering and human sciences to consider both - technological aspects of the network as well the human user. The designed multilayered model appropriately integrates the technical network view as well as the user's perspective by considering all relevant factors of influence and all internal relationships between QoS and QoE. The conducted extensive psychophysical laboratory experiment with real users, devices and services quantifies the relationship between specific QoS values and specific QoE values. A testbed developed for network emulation allows combining typical mobile network situations with typical usage situations in a controlled and focused manner. The three elaborated principles to test for relevance, suitability and efficiency take into account the special features of the test setup and test design. Test results gained from more than 200 volunteers confirm the predicted QoS-QoE-characteristics of the six tested mobile services to be either elastic or non-elastic. It is possible to conclude from the desired degree of user satisfaction on the necessary values of the QoS network parameters, which results in a QoS-QoE-corridor between lower and upper threshold values. Findings prove that QoS-independent factors, e.g. the type of presentation of the stimuli in the app on the user’s device, can be as relevant for QoE as the evaluated QoS network parameters themselves.

In der theoretischen Auseinandersetzung mit mobilen Internet-Diensten sind Quality of Service (QoS) und Quality of Experience (QoE) als hochkomplexe und verbundene Konzepte zu erkennen. QoS umfasst dabei die technische Sicht auf das Telekommunikationsnetz, charakterisiert durch leistungsrelevante Parameterwerte (z. B. Durchsatz und Latenz). QoE hingegen bezieht sich auf die Bewertung des Nutzererlebnisses (z. B. Zufriedenheit und Akzeptanz). Zur gemeinsamen Erklärung bedarf es einer multi- bzw. interdisziplinären Betrachtung zwischen Ingenieurs- und Humanwissenschaften, da neben der Technik auch der Mensch als Nutzer in den QoS-QoE-Zusammenhang involviert ist. Ein mehrschichtiges Modell erfasst die relevanten Einflussfaktoren und internen Zusammenhänge zwischen QoS und QoE sowohl aus Netz- als auch Nutzersicht. Zur Quantifizierung des Zusammenhangs konkreter Werte in einer empirischen QoE-Evaluation wurde ein umfangreiches psychophysikalisches Laborexperiment konzipiert. Das dafür entwickelte Netzemulations-Testbed erlaubt mobiltypische Netz- und Nutzungssituationen gezielt in einem Testparcours zusammenzubringen. Die formulierten Prinzipien zur Testrelevanz, -eignung und -effizienz berücksichtigen hierbei die Besonderheiten des Testaufbaus und -designs mit echten Endgeräten und Diensten. Die Ergebnisse von über 200 Probanden bestätigen die vorhergesagten QoS-QoE-Charakteristiken der sechs untersuchten Dienste als kontinuierlich-elastisch bzw. sprunghaft-fest. Dienstspezifisch lässt sich jeweils von einem angestrebten Grad der Nutzerzufriedenheit auf die notwendigen Werte der QoS-Netzparameter schließen, woraus sich ein QoS-QoE-Zufriedenheitskorridor zwischen einem unteren und oberen Schwellwert ergibt. Teilweise sind dabei QoS-unabhängige Faktoren, z. B. die Art der Präsentation der Stimuli in der App auf dem Endgerät, als ebenso relevant zu erkennen wie die QoS-Netzparameter selbst. / The thesis is centered on the relationship of Quality of Service (QoS) and Quality of Experience (QoE) for mobile Internet services. While QoS covers the technical view on the telecommunications network characterized by performance-related parameter values (e.g. throughput and latency), QoE refers to the assessment of the user experience (e.g. satisfaction and acceptability) in the use of the services. In the thesis QoS and QoE are revealed as highly complex and related concepts in theoretical contemplation. Integrating both concepts requires a multidisciplinary or interdisciplinary approach between engineering and human sciences to consider both - technological aspects of the network as well the human user. The designed multilayered model appropriately integrates the technical network view as well as the user's perspective by considering all relevant factors of influence and all internal relationships between QoS and QoE. The conducted extensive psychophysical laboratory experiment with real users, devices and services quantifies the relationship between specific QoS values and specific QoE values. A testbed developed for network emulation allows combining typical mobile network situations with typical usage situations in a controlled and focused manner. The three elaborated principles to test for relevance, suitability and efficiency take into account the special features of the test setup and test design. Test results gained from more than 200 volunteers confirm the predicted QoS-QoE-characteristics of the six tested mobile services to be either elastic or non-elastic. It is possible to conclude from the desired degree of user satisfaction on the necessary values of the QoS network parameters, which results in a QoS-QoE-corridor between lower and upper threshold values. Findings prove that QoS-independent factors, e.g. the type of presentation of the stimuli in the app on the user’s device, can be as relevant for QoE as the evaluated QoS network parameters themselves.

Geophysical methods are essential for exploration and monitoring of subsurface formations, e.g. in carbon dioxide sequestration or enhanced geothermal energy. One of the keys to their successful application is the knowledge of how the measured physical quantities are related to the desired reservoir parameters. The work presented in this thesis shows that the presence of carbon dioxide (CO2) in pore space gives rise to multiple processes all of which contribute to the electrical rock conductivity variation. Basically, three mechanisms take place: (1) CO2 partially replaces the pore water, which is equivalent to a decrease in water saturation. (2) CO2 chemically interacts with the pore water by dissolution and dissociation. These processes change both the chemical composition and the pH of the pore filling fluid. (3) The low-pH environment can give rise to mineral dissolution and/or precipitation processes and changes the properties of the grain-water interface. Investigations on the pore water phase show that the reactive nature of CO2 in all physical states significantly acts on the electrical conductivity of saline pore waters. The physico-chemical interaction appears in different manifestations depending mainly on the pore water composition (salinity, ion types) but also on both temperature and pressure. The complex behaviour includes a low- and a high-salinity regime originating from the conductivity increasing effect of CO2 dissociation, which is opposed by the conductivity decreasing effect of reduced ion activity caused by the enhanced mutual impediment of all solutes. These results are fundamental since the properties of the water phase significantly act on all conduction mechanisms in porous media. In order to predict the variation of pore water conductivity, both a semi-analytical formulation and an empirical relationship for correcting the pore water conductivity, which depends on salinity, pressure and temperature, are derived. The central part of the laboratory experiments covers the spectral complex conductivity of water-bearing sand during exposure to and flow-through by CO2 at pressures up to 30MPa and temperatures up to 80°C. It is shown that the impact of CO2 on the real part of conductivity of a clean quartz sand is dominated by the low- and high-salinity regime of the pore water. The obtained data further show that chemical interaction causes a reduction of interface conductivity, which could be related to the low pH in the acidic environment. This effect is described by a correction term, which is a constant value as a first approximation. When the impact of CO2 is taken into account, a correct reconstruction of fluid saturation from electrical measurements is possible. In addition, changes of the inner surface area, which are related to mineral dissolution or precipitation processes, can be quantified. Both the knowledge gained from the laboratory experiments and a new workflow for the description and incorporation of geological geometry models enable realistic finite element simulations. Those were conducted for three different electromagnetic methods applied in the geological scenario of a fictitious carbon dioxide sequestration site. The results show that electromagnetic methods can play an important role in monitoring CO2 sequestration. Compared to other geophysical methods, electromagnetic techniques are generally very sensitive to pore fluids. The proper configuration of sources and receivers for a suitable electromagnetic method that generates the appropriate current systems is essential. Its reactive nature causes CO2 to interact with a water-bearing porous rock in a much more complex manner than non-reactive gases. Without knowledge of the specific interactions between CO2 and rock, a determination of saturation and, consequently, a successful monitoring are possible only to a limited extend. The presented work provides fundamental laboratory investigations for the understanding of the electrical properties of rocks when the reactive gas CO2 enters the rock-water system. All laboratory results are put in the context of potential monitoring applications. The transfer from petrophysical investigations to the planning of an operational monitoring design by means of close-to-reality 3D FE simulations is accomplished.

Geophysical methods are essential for exploration and monitoring of subsurface formations, e.g. in carbon dioxide sequestration or enhanced geothermal energy. One of the keys to their successful application is the knowledge of how the measured physical quantities are related to the desired reservoir parameters. The work presented in this thesis shows that the presence of carbon dioxide (CO2) in pore space gives rise to multiple processes all of which contribute to the electrical rock conductivity variation. Basically, three mechanisms take place: (1) CO2 partially replaces the pore water, which is equivalent to a decrease in water saturation. (2) CO2 chemically interacts with the pore water by dissolution and dissociation. These processes change both the chemical composition and the pH of the pore filling fluid. (3) The low-pH environment can give rise to mineral dissolution and/or precipitation processes and changes the properties of the grain-water interface. Investigations on the pore water phase show that the reactive nature of CO2 in all physical states significantly acts on the electrical conductivity of saline pore waters. The physico-chemical interaction appears in different manifestations depending mainly on the pore water composition (salinity, ion types) but also on both temperature and pressure. The complex behaviour includes a low- and a high-salinity regime originating from the conductivity increasing effect of CO2 dissociation, which is opposed by the conductivity decreasing effect of reduced ion activity caused by the enhanced mutual impediment of all solutes. These results are fundamental since the properties of the water phase significantly act on all conduction mechanisms in porous media. In order to predict the variation of pore water conductivity, both a semi-analytical formulation and an empirical relationship for correcting the pore water conductivity, which depends on salinity, pressure and temperature, are derived. The central part of the laboratory experiments covers the spectral complex conductivity of water-bearing sand during exposure to and flow-through by CO2 at pressures up to 30MPa and temperatures up to 80°C. It is shown that the impact of CO2 on the real part of conductivity of a clean quartz sand is dominated by the low- and high-salinity regime of the pore water. The obtained data further show that chemical interaction causes a reduction of interface conductivity, which could be related to the low pH in the acidic environment. This effect is described by a correction term, which is a constant value as a first approximation. When the impact of CO2 is taken into account, a correct reconstruction of fluid saturation from electrical measurements is possible. In addition, changes of the inner surface area, which are related to mineral dissolution or precipitation processes, can be quantified. Both the knowledge gained from the laboratory experiments and a new workflow for the description and incorporation of geological geometry models enable realistic finite element simulations. Those were conducted for three different electromagnetic methods applied in the geological scenario of a fictitious carbon dioxide sequestration site. The results show that electromagnetic methods can play an important role in monitoring CO2 sequestration. Compared to other geophysical methods, electromagnetic techniques are generally very sensitive to pore fluids. The proper configuration of sources and receivers for a suitable electromagnetic method that generates the appropriate current systems is essential. Its reactive nature causes CO2 to interact with a water-bearing porous rock in a much more complex manner than non-reactive gases. Without knowledge of the specific interactions between CO2 and rock, a determination of saturation and, consequently, a successful monitoring are possible only to a limited extend. The presented work provides fundamental laboratory investigations for the understanding of the electrical properties of rocks when the reactive gas CO2 enters the rock-water system. All laboratory results are put in the context of potential monitoring applications. The transfer from petrophysical investigations to the planning of an operational monitoring design by means of close-to-reality 3D FE simulations is accomplished.