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POLYMER ELECTROLYTES FOR HIGH CURRENT DENSITY LITHIUM STRIPPING/PLATING TESTZhang, Yuhan 24 June 2019 (has links)
No description available.
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Highly electrochemical stable quaternary solid polymer electrolyte for all-solid-state lithium metal batteriesShao, Yunfan 08 June 2018 (has links)
No description available.
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Constructing Poly(Ionic Liquid)s-Based Composite Solid State Electrolytes and Application in Lithium Metal BatteriesLi, Jiajia January 1900 (has links)
The pursuit of reliable and high-performance batteries has fueled extensive research into new battery chemistries and materials, aiming to enhance the current lithium-ion battery technologies in terms of energy density and safety. Among the potential advancements, solid-state batteries (SSBs) have captured significant attention as the next-generation energy storage technology. One key factor contributing to their appeal is the utilization of solid-state electrolytes (SSEs) with a wide electrochemical stability window (ESW), making SSBs compatible with high-voltage cathodes. The energy density of SSBs can be further improved by employing the “holy-grail” anode, Li-metal, which boasts the lowest working voltage (-3.04 V vs. Li+/Li) and an ultrahigh theoretical capacity (3860 mAh g−1). Consequently, these batteries are referred to as lithium metal batteries (LMBs). However, realizing the full potential of LMBs presents formidable challenge, including the low ionic conductivity of current SSEs, large interfacial resistance between SSE and electrodes, uncontrollable interfacial reactions, and the growth of Li dendrites. Typically, SSEs can be categorized into three types. Among these, solid composite electrolytes (SCEs) are considered the most promising choice for solid-state LMBs due to their combination of high ionic conductivity and excellent mechanical strength from inorganic solid electrolytes (ISEs) and the flexibility and good interface compatibility provided by solid polymer electrolytes (SPEs). Polymeric ionic liquids (PolyILs), which contain both ionic liquid-like moieties and polymer frameworks, have emerged as highly attractive alternatives to traditional polymers in SCEs. The overall objective of this thesis was to develop PolyIL-based SCEs with enhanced ionic conductivity, wide ESW, high Li+ transference number, and reduced electrodes/electrolyte interface resistance. The main progress achieved in this thesis is as follows: 1. We selected three F-based Li-salts to prepare SPEs using poly(ethylene oxide) and polyimide. The investigation focused on assessing the impact of molecular size, F content, and chemical structures (F-connecting bonds) of these Li-salts. Additionally, we aimed to uncover the formation process of LiF in the solid electrolyte interphase (SEI). The result revealed that the F-connecting bond plays a more significant role than the molecular size and F element content, resulting in slightly better cell performance using LiPFSI compared to LiTFSI and substantially better performance compared to LiFSI. The preferential breakage of bonds in LiPFSI was found to be related to its position to Li anode. Consequently, we proposed the LiPFSI reduction mechanism based on these findings. 2. Using the template method, we synthesized a monolayer SCE with enhanced Li+ transference number and high ionic conductivity. In this study, boron nitride (BN) nanosheets with a high specific surface area and richly porous structure were employed as inert inorganic filler. These BN nanosheets played a crucial role in homogenizing the Li+ flux and facilitating the Li+ transmission to suppress Li dendrite growth. When integrated into a LiFePO4//Li cell with the optimized SCE, the assembled battery demonstrated remarkable cycling performance. 3. A monolayer GSCE with multifunctionality was synthesized via a natural sedimentation and subsequent UV-curing polymerization technique. This innovative method capitalizes on intrinsic gravity, allowing for the integration of multiple functions within a single layer, thereby eliminating the additional interlayer resistance. The developed GSCE provides an optimum Li+ transportation path and enhanced Li+ transference number, leading to an enhanced ionic conductivity and a long cycle life of Li//Li cells and SSLMBs. Compared with the monolayer uniform SCEs, the gradient structure also alleviates the uncoordinated thermal expansion between fillers and PolyIL, avoiding increased stress during the cycle and battery capacity fade.
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Caractérisation et optimisation de copolymères à blocs comme électrolytes de batteries lithium métal / Characterization and optimization of block copolymers as electrolytes for lithium metal batteriesDevaux, Didier 12 March 2012 (has links)
Le facteur clé limitant le déploiement des accumulateurs au lithium métal est dû à la formation de dendrites de lithium métallique à l'anode au cours de la recharge. Une solution consiste à employer un électrolyte solide polymère. Un copolymère à blocs est composé d'un ou plusieurs blocs conducteurs à base de POE (poly(oxyde d'éthylène)), linéaire ou branchée, dopés en sel de lithium (LiTFSI) et de blocs de renforts mécaniques qui idéalement mitigent la croissance dendritique. Ces matériaux ont la particularité de s'auto-assembler en domaines nanométriques. Les interfaces entre les domaines génèrent de bonnes propriétés mécaniques à l'échelle macroscopique tandis que localement la dynamique des chaînes POE demeure élevée, assurant la conduction ionique.Ce travail de thèse porte sur les caractérisations physico-chimiques d'électrolytes copolymères, selon différentes architectures (diblocs, triblocs et étoilées) et de l'optimisation de leurs compositions. Une étude fondamentale des polymères dopés en sel a mis en évidence les principaux mécanismes de transport ionique, ainsi que l'impact des groupes terminaux à faible masse molaire sur la conductivité et la viscosité. Cette étape a permis de sélectionner les meilleurs candidats. L'étude de la stabilité des électrolytes vis-à-vis du lithium a été menée. Après avoir formulé des cathodes, des batteries plastiques ont été assemblées et testées avec succès par cyclages galvanostatiques, en température [40°C-100°C] et à des régimes élevés. Enfin, un prototype de 6 mAh a réalisé plus de 400 cycles à des régimes C/4 et D/2 à 100°C. / The key limiting factor for the deployment of Lithium metal batteries is the formation of lithium dendrites at the anode during recharge. One solution consists in the use of a solid polymer electrolyte. A bloc copolymer is composed of one or several conductive blocks based on PEO (poly(ethylene oxide)), linear or branched, doped with a lithium salt (LiTFSI) and reinforced blocks that ideally mitigate the dendritic growth. These materials can self-organize in nanometric domains. The interfaces between the domains generate sufficient mechanical properties at the macroscopic level whilst, locally, the PEO chain dynamics remain high, ensuring ionic conduction.This thesis deals with physico-chemical characterizations of these copolymer electrolytes, with different architectures (diblock, triblock and star shaped), and the optimization of their composition. A fundamental study of doped polymers highlighted the main mechanisms of ionic transport and the impact of the end groups at low molar mass on conductivity and viscosity. This step enabled a selection of the best candidates to be made. A study of the electrolyte stability with respect to lithium was carried out. After the formulation of cathodes, plastic batteries were assembled and successfully tested by galvanostatic cycling under temperature [40°C-100°C] and high regime. Finally, a 6 mAh prototype realised more than 400 cycles under the regime C/4 and D/2 at 100°C.
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