Natural composites, in particular nacre, often combine high strength and toughness thanks to highly ordered architectures and controlled geometries of the reinforcement components. However, combining strength, toughness and resorbability in synthetic materials remains a challenge in particular in the field of bone graft substitutes. In the present study, calcium phosphate-(CaP-)based materials with designed architectures inspired from natural composite materials were achieved. CaP platelets obtained by precipitation in organic medium were first aligned in chitosan matrices by solvent casting in ambient conditions. Efficient strengthening was obtained with 15 vol-% ceramic, reaching cortical bone strength (150 MPa) and preserving good ductility (5 % deformation). In a weak magnetic field, high spatial arrangement without percolation was maintained up to 20 vol-%. With directional freezing, good alignment of the platelets could be pushed up to 50 vol-%. In parallel, in situ recrystallization of CaP blocks in hydrothermal conditions led to hierarchical structures. The strength and the work-of-fracture were enhanced (300%) thanks to a change of failure mode.

Baigiamajame magistro darbe nagrinėjami galimi prekybos ir pramogų centro perdangos ir ledo arenos denginio pagrindinių laikančiųjų konstrukcijų variantai, įvertinami jų techniniai– ekonominiai rodikliai, parenkamas racionalus konstrukcijų variantas tolesniam pastato projektavimui. Nagrinėjamas gelžbetoninės ledo arenos denginio arkos patikimumas, išskiriami rodikliai, darantys didžiausią įtaką konstrukcijos patikimumui, atliekama konstrukcijos parametrinė analizė. Pateikiamos baigiamojo darbo išvados. Projektuojama briaunotoji TT tipo denginio plokštė, gelžbetoninė dviejų lankstų denginio arka su iš anksto įtempta styga, kolona ir polinis pamatas, parengiami šių konstrukcijų darbo brėžiniai. Darbą sudaro 11 dalių: įvadas, aiškinamasis raštas, techninė-ekonominė, konstrukcijų projektavimo ir patikimumo analizės dalys, išvados, literatūros sąrašas. Darbo apimtis – 149 p. teksto be priedų, 43 iliustr., 27 lent., 34 bibliografiniai šaltiniai, 9 A1 lapai brėžinių. Atskirai pridedami darbo priedai. / This MA thesis focuses on the possible versions of floors in a Shopping and Entertainment Centre as well as the roof load-bearing constructions of an Ice Arena. Their technical and economic parameters are evaluated and a rational construction option for the further building design is selected. This thesis analyses the reliability of the reinforced concrete arch in the Ice Arena, and the parameters that have the biggest influence on the reliability of the construction are singled out. The parameter analysis of the construction is presented. The thesis ends with concluding remarks. The design features a double tee-type roof slab, a reinforced concrete two-hinged arch with a pre-stressed tie, a column and a pile foundation. The working drawings of the above-mentioned constructions are drafted. The thesis consists of 11 parts: the introduction, the expository letter, the technological-economic part, the parts dealing with the construction design and reliability analysis, the conclusions, the bibliography, etc. The scope of the thesis is as follows: 149 pages of text without annexes, 43 figures, 27 tables, 34 bibliographical sources and 9 A1-size pages of drawings. There are annexes attached to the thesis.

Atualmente, muitas empresas de construção civil não acompanham o avanço tecnológico, preferindo utilizar sistemas convencionais em vez de investir em novas soluções. Além disso, há sérios problemas com mão de obra, que estão cada vez mais presentes na sociedade. Este trabalho apresenta o projeto de um edifício com elementos pré-moldados de Concreto Leve com pérolas de EPS, considerando lajes prontas maciças e paredes portantes, executadas com esse tipo de material. A princípio, foram considerados os estados limites últimos e de serviço para os elementos da estrutura, utilizando os modelos clássicos de análise estrutural. Para modelagem do edifício, foi utilizado o programa comercial SAP2000. Quanto aos procedimentos para dimensionamento das peças, foram preparadas planilhas do Excel, enquanto o detalhamento foi realizado por meio do AutoCAD. Definido o projeto estrutural, foram considerados aspectos construtivos na fábrica e na obra, levando em conta os custos de produção e de transporte, além de apresentar as vantagens que esse sistema construtivo pode proporcionar. Esses custos foram considerados para as lajes prontas maciças e para as paredes pré-moldadas. Mesmo levando em conta apenas os custos de produção e de transporte, o Concreto Leve com EPS foi comparado com o Concreto Autoadensável, o que permitiu visualizar as vantagens do primeiro, quando for considerado o custo global do empreendimento. / Currently, many construction companies do not follow the technological advances, preferring to use conventional systems rather than investing in new solutions. Moreover, there are serious problems with manpower, which are increasingly present in society. This work presents the design of a building with precast elements of lightweight concrete with EPS beads, considering solid slabs ready to use and load bearing walls, made with this type of material. As a rule, the ultimate limit states and serviceability were considered for the elements of the structure, using classical models of structural analysis. For modelling the building, the commercial software SAP2000 was used. Regarding the procedures for dimensioning of the pieces, Excel spreadsheets were prepared, while the detailing was carried out by means of the AutoCAD. Defined structural design, construction aspects were considered in the factory and in the work, taking into account costs of production and transportation, besides presenting the advantages that this constructive system can provide. These costs were considered for the solid slabs ready to use and for the precast walls. Even taking into account only the cost of production and transportation, the Lightweight Concrete with EPS was compared with Self-compacting Concrete, allowing visualize the advantages of the former when considering the overall cost of the project.

Glasträger sind in einer auf Transparenz ausgerichteten Bauweise zunehmend gefragt. Üblicherweise bestehen diese lastabtragenden Elemente aus mehreren Glasscheiben, verbunden mit Polyvinylbutyral-Folie (PVB-Folie), und gleichen in ihrem Aufbau somit Verbund-Sicherheitsglas (VSG). VSG-Träger besitzen bei vollständigem Glasbruch keine Resttragfähigkeit und werden daher in Dicke und Aufbau mit dem Ziel ausgelegt, vollständigen Glasbruch zu vermeiden. Hybride Glasträger kombinieren in der Regel Glas mit einem duktilen Material und besitzen im Falle des vollständigen Glasbruchs ein duktiles Versagensverhalten. Sie stellen damit eine vielversprechende Option zur Erfüllung des geforderten Sicherheitsniveaus bei Glasträgern dar. Die in der vorliegenden Arbeit betrachteten hybriden Träger entstehen durch die flächige Verklebung von Glas- und transparenten Kunststoffscheiben mit einem ebenfalls transparenten Klebstoff. Bei vollständigem Glasbruch stellt sich ein Tragverhalten ein, bei dem infolge des Klebstoffverbunds der Kunststoff die Zugspannungen und das gebrochene Glas weiterhin Druckspannungen aufnimmt. Die erste Auswahl von Klebstoff und Kunststoff basiert auf Voruntersuchungen an kleinformatigen Prüfkörpern. Die erforderliche Kantenqualität von Floatglas wurde anhand von Vierpunkt-Biegeuntersuchungen bestimmt. Zur weiteren Beurteilung der Eignung des Klebstoffs dienen Klimawechseltests an kleinformatigen Hybridbauteilen, da zwischen Glas und Kunststoff deutliche Unterschiede in der Temperaturausdehnung vorliegen. Aufbauend auf den durchgeführten Untersuchungen wurden das Kunststoffmaterial Polycarbonat und ein niedrigviskoser UV- und strahlungshärtender Acrylatklebstoff, der im ausgehärteten Zustand über hohe Nachgiebigkeit verfügt, für die weiteren mechanischen Untersuchungen an Prüfkörpern im Bauteilformat ausgewählt. Kurzzeitversuche mit kraftgesteuerter Belastungsaufbringung und unter Variation von Polycarbonatdicke, Trägerhöhe und Glasart geben Aufschluss über das Trag- und Resttragfähigkeitsverhalten. Sie stellen die prinzipielle Wirkweise der Hybridträger vor und nach Bruch dar. Vergleichende Versuche an VSG-Trägern demonstrieren die fehlende Resttragfähigkeit dieser Elemente. Belastungsversuche an reinen Polycarbonatscheiben verdeutlichen die Notwendigkeit der Stabilisierung der Hybridträger durch das gebrochene Glas. Langzeitversuche fanden bei statischer Belastung der intakten und gebrochenen Hybridträger statt. Lasthöhe und Belastungsdauer der gebrochenen Träger orientieren sich an realistischen Einsatzbedingungen. Die Versuche zeigen die Unterschiede bei der Entwicklung des Bruchbilds aufgrund der geringeren Last und ermöglichen die Untersuchung des Resttragfähigkeitsverhaltens unter Dauerlast sowie des Ablaufs und der Hintergründe des Trägerversagens. Aufbauend auf den durchgeführten Versuchen erfolgt eine Einteilung der unterschiedlichen Trägerzustände in drei Stadien mit Angaben zu einer einfachen analytischen Betrachtung. Die Diskussion der erhaltenen Ergebnisse sowie ein Ausblick auf weiteren Untersuchungsbedarf schließen die Arbeit ab. / In transparency-oriented architecture, glass beams are increasingly in demand. These load-bearing elements usually consist of multiple glass panes, bonded with polyvinyl butyral foil (PVB foil), and are comparable to laminated safety glass. These glass beams do not assure any level of post-breakage performance after complete glass breakage. Therefore glass thickness and assembly of the beams are chosen with the objective of avoiding complete glass breakage at all costs. Hybrid glass beams typically combine glass with a ductile material and offer a ductile failure mode in case of complete glass breakage. For this reason they represent a promising solution to meet the required safety levels for glass beams. This study deals with hybrid glass beams which are made by bonding panes of glass and transparent plastics using a transparent adhesive. In case of complete glass breakage the plastic material, which is connected to the glass by the adhesive bond, bears the tensile stress whereas the glass is still able to carry the compressive stress. The pre-selection of plastic and adhesive is based on preliminary tests on small specimens. The required quality of the edges of annealed glass was determined by specific four-point bending tests. Because of the considerable difference in thermal expansion between glass and plastics, alternating climate tests were executed on small hybrid components to further evaluate the suitability of the adhesive. Based on the research conducted, the plastic material polycarbonate and a UV- and light-curing acrylate adhesive, which shows a very flexible behavior when hardened, were chosen for further mechanical tests on larger specimens. Short-term tests with constantly increasing load and varying polycarbonate thickness, beam height and glass type provide information on the load-bearing capacity before and the residual load-bearing capacity after glass breakage of the hybrid beams. Comparative tests on laminated glass beams demonstrate the missing residual load-bearing capacity of these components. Loading tests on polycarbonate panes illustrate the need for stabilization of the hybrid beams by the broken glass. Long-term tests were executed by static loading of the intact and broken hybrid beams. The load level and the load duration of the broken beams are based on realistic working conditions. The tests show the difference in the development of the fracture pattern resulting of the lower load and allow the examination of the residual load-bearing capacity at continuous load as well as the process and the reasons behind the beam failure. Based on the tests conducted, three different states of the hybrid beams are categorized and detailed for their easy analytical approach. A discussion of the obtained results and an outlook on further needed research complete the study.

This thesis describe methods to improve the interfacial stability of an interpenetrating phase composite (IPC) polyvinylurethanecarbonate), and to increase the hydrophobicity of the polymer phase. The current IPCs introduce covalent bonding between the phases via silanizing agents to enhance the interfacial stability. Incorporation of the silanizing agents was also intended to reduce the IPC’s sensitivity to interfacial hydration, thereby enhancing the IPC’s resistance to degradation during aging. Lysine diisocyanate was used to increase the hydrophobic character in the polyvinylurethanecarbonate resin. The polymer resins were infiltrated into porous CPP blocks with 25 volume% interconnected porosity and polymerized to produce the IPCs. After mechanical testing following a aging study it was found that the silanizing agents contributed to stability of the mechanical properties under aqueous conditions. It was concluded that the mechanical properties and stability were comparable to available biodegradable composites, as well as being biocompatible to a preosteoblast model cell line.

This thesis describe methods to improve the interfacial stability of an interpenetrating phase composite (IPC) polyvinylurethanecarbonate), and to increase the hydrophobicity of the polymer phase. The current IPCs introduce covalent bonding between the phases via silanizing agents to enhance the interfacial stability. Incorporation of the silanizing agents was also intended to reduce the IPC’s sensitivity to interfacial hydration, thereby enhancing the IPC’s resistance to degradation during aging. Lysine diisocyanate was used to increase the hydrophobic character in the polyvinylurethanecarbonate resin. The polymer resins were infiltrated into porous CPP blocks with 25 volume% interconnected porosity and polymerized to produce the IPCs. After mechanical testing following a aging study it was found that the silanizing agents contributed to stability of the mechanical properties under aqueous conditions. It was concluded that the mechanical properties and stability were comparable to available biodegradable composites, as well as being biocompatible to a preosteoblast model cell line.

Doppelt gekrümmte Schalen und Gitterschalen sind Tragsysteme, die, obwohl in Ihrer Wirkungsweise grundsätzlich verschieden, besonders für den Einsatz von Textilbeton geeignet sind. Aufgrund ihrer doppelten Krümmung weisen derartige Tragsysteme zahlreiche Besonderheiten hinsichtlich Formfindung, Lastabtrag und Herstellung auf. Anhand eines Ausführungsbeispiels von monolithischen Schirmschalen und Konstruktionsstudien zu Gitterschalen werden die Strukturkonzepte und ihre Auswirkungen auf das Tragverhalten, das Bewehrungskonzept und die Auswirkungen auf die Herstellung sowie die Bauteilfügung erläutert. / Structural systems based on double curved monolithic shells or gridshells are both characterised by their good load bearing behaviour depending on the chosen geometry. Although both systems are different regarding their functionality they are suitable applications for TRC while taking advantage of the main constructive and design characteristics of the material. In describing an execution example of an umbrella-shaped shell-structure and design studies on gridshells the relation between structural concept and load bearing behaviour and the relation between the reinforcement concept and production as well as joining are discussed.

Sandwichkonstruktionen mit Deckschichten aus dünnen Metallblechen und Stahlbeton stellen seit Jahrzehnten bewährte und wirtschaftliche Verbundkonstruktionen für Gebäudehüllen dar. Der Einsatz von dünnen Deckschichten aus textilbewehrtem Beton verbindet deren Vorteile und ermöglicht auch bei steigenden Anforderungen an den Wärmeschutz geringe Konstruktionsdicken. Der Beitrag berichtet über die Entwicklung von Ingenieurmodellen zur wirklichkeitsnahen Beschreibung des Tragverhaltens von Sandwichquerschnitten aus textilbewehrtem Beton, Hartschaumdämmkern und geeigneten Verbundmitteln. / Sandwich constructions made of thin metal sheets and structural concrete have been reliable and economic composite structures in the past decades. The application of thin-walled facings made of Textile Reinforced Concrete (TRC) combines the advantages of this construction and allows for slender construction thicknesses despite the progressing demands on thermal insulation. This contribution reports on the development of models, which enable the realistic mechanical description of the load-bearing behavior of the sandwich panels made of two TRC-facings and a core of polymeric rigid foam together with suitable connecting devices.

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / The preconsolidation pressure (σp) is obtained from the curve of the soil compression visual graphical form, mathematical or associating both and is an estimate of its load-bearing capacity. In order to remove the subjectivity of the visual graphical method is need for mathematical description (models using) of the compression curve. However, research results do not provide subsidies for the choice of a model whose σp represents well the resulting load-bearing capacity of soil, but if some model to represent, the σp should be a function of density and water content soil, other properties remain constant. The objective of this study was to understand the variability in the preconsolidation pressure caused by different models and options to adjust these models to the compression curve and evaluate the relationship of preconsolidation pressure with bulk density (Ds), volumetric water content (θ) and macroporisity (Ma) . For this, we performed the uniaxial compression test of 300 samples from a Hapludox, clayey, with wide variation Ds and θ. The preconsolidation pressure was determined by strictly mathematical, from the set of ten models, where seven of them consisted of variations of the model van Genuchten (1980) and others have been proposed by Friton (2001), Assouline (2002) and Gregory et al. (2006). The model proposed by Gregory and Friton possible to obtain the σp for only 62 and 56% of the curves, respectively, the variations of the model van Genuchten were enable the calculation of σp at least 90% of the curves. In three of the variations of the van Genuchten model, it was possible to get σp in 100% of the curves. The range of σp produced by the various options described in compression curve affects the physical significant of σp to represent the load bearing capacity of the soil. Likewise, Ds, θ and Ma, which influence the same load bearing capacity of the soil, not explained more than 58% of the variation of σp produced using different models. With the criteria used, it is not possible to choose one model over the other which allows to estimate more adequately by σp, the load bearing capacity of the soil, which limits the use of this parameter as an indicator for soil management agricultural. Given this result, it was investigated whether the percentage of deformation of the sample as a function of the applied loads would be more closely related to Ds, θ, and Ma was considered a safe limit of deformation of the physical viewpoint, that Ma deformation where the remains higher than 10%. The use of maintenance limit of 80% of voids index (Mεi) displaces the deformation to the plastic region of the curves of all the density ranges and therefore cannot be used for soil with structure more affected by compaction. The load to achieve a certain percentage (Mεi) is best explained by the variation of Ds and θ. The pedotransfer functions to load in Mεi between 85 and 87.5% resulted in higher coefficients of determination (0.74), having potential use of such values as critical limits to maintenance of porosity without degradation of soil physical quality. / A pressão de preconsolidação (σp) é obtida da curva de compressão do solo de forma gráfica visual, matemática ou associando ambas e é uma estimativa de sua capacidade de suporte de carga. A fim de se retirar a subjetividade do método gráfico visual, há necessidade de descrição matemática (uso de modelos) da curva de compressão. Porém, os resultados de pesquisa não fornecem subsídios para a escolha de um modelo cuja σp resultante represente, de maneira confiável, a capacidade de suporte de carga do solo. Entretanto, se algum modelo a representar, a σp deverá ser uma função da densidade e conteúdo de água do solo, mantidas constantes outras propriedades. O objetivo deste trabalho foi conhecer a variabilidade na pressão de preconsolidação provocada por diferentes modelos e opções de ajuste desses modelos à curva de compressão e avaliar a relação da pressão de preconsolidação com a densidade do solo (Ds), conteúdo volumétrico de água (θ) e macroporosidade do solo (Ma). Para isso, foi realizado o ensaio de compressão uniaxial para 300 amostras provenientes de um Latossolo Vermelho Distroférrico típico, com textura argilosa, com ampla variação Ds e θ. A pressão de preconsolidação foi determinada por meio estritamente matemático, a partir do ajuste de dez modelos, onde sete deles consistiram em variações do modelo de van Genuchten (1980) e os demais foram propostos por Friton (2001), Assouline (2002) e Gregory et al. (2006). Os modelos propostos por Gregory e Friton possibilitaram a obtenção da σp para apenas 62 e 56 % das curvas, respectivamente, já as variações do modelo de van Genuchten viabilizam o cálculo da σp para no mínimo 90 % das curvas. Em três das variações do modelo de van Genuchten, foi possível obter a σp em 100% das curvas. A variação da σp produzida pelas diferentes opções de descrição da curva de compressão compromete o significado físico da σp para representar a capacidade de suporte de carga do solo. Da mesma forma, Ds, θ e Ma, mesmo que influenciem a capacidade de suporte de carga do solo, não explicaram mais que 58% da variação da σp produzida com o uso de diferentes modelos. Com os critérios utilizados, não é possível eleger um modelo em relação aos demais que possibilite estimar de maneira mais adequada, através da σp, a capacidade de suporte de carga do solo, o que limita o uso desse parâmetro como um indicador para o manejo dos solos agrícolas. Diante desse resultado, foi investigado se a porcentagem de deformação da amostra em função das cargas aplicadas estaria melhor relacionada com Ds, θ e Ma. Considerou-se um limite de deformação prudente do ponto vista físico, aquela deformação onde a Ma permaneça maior que 10%. O uso do limite de manutenção de 80 % do índice de vazios inicial (Mεi) desloca as deformações para a região plástica das curvas de todas as faixas de densidade e, por isso, não pode ser utilizado para solos com estrutura mais comprometida pela compactação. A carga para atingir determinada porcentagem de Mεi é melhor explicada pela variação da Ds e θ. As funções de pedotransferência da carga para a Mεi entre 85 e 87,5% resultaram em maiores coeficientes de determinação (0,74), havendo potencial da utilização destes valores como limites críticos de manutenção da porosidade sem haver degradação da qualidade física do solo.

Atualmente, muitas empresas de construção civil não acompanham o avanço tecnológico, preferindo utilizar sistemas convencionais em vez de investir em novas soluções. Além disso, há sérios problemas com mão de obra, que estão cada vez mais presentes na sociedade. Este trabalho apresenta o projeto de um edifício com elementos pré-moldados de Concreto Leve com pérolas de EPS, considerando lajes prontas maciças e paredes portantes, executadas com esse tipo de material. A princípio, foram considerados os estados limites últimos e de serviço para os elementos da estrutura, utilizando os modelos clássicos de análise estrutural. Para modelagem do edifício, foi utilizado o programa comercial SAP2000. Quanto aos procedimentos para dimensionamento das peças, foram preparadas planilhas do Excel, enquanto o detalhamento foi realizado por meio do AutoCAD. Definido o projeto estrutural, foram considerados aspectos construtivos na fábrica e na obra, levando em conta os custos de produção e de transporte, além de apresentar as vantagens que esse sistema construtivo pode proporcionar. Esses custos foram considerados para as lajes prontas maciças e para as paredes pré-moldadas. Mesmo levando em conta apenas os custos de produção e de transporte, o Concreto Leve com EPS foi comparado com o Concreto Autoadensável, o que permitiu visualizar as vantagens do primeiro, quando for considerado o custo global do empreendimento. / Currently, many construction companies do not follow the technological advances, preferring to use conventional systems rather than investing in new solutions. Moreover, there are serious problems with manpower, which are increasingly present in society. This work presents the design of a building with precast elements of lightweight concrete with EPS beads, considering solid slabs ready to use and load bearing walls, made with this type of material. As a rule, the ultimate limit states and serviceability were considered for the elements of the structure, using classical models of structural analysis. For modelling the building, the commercial software SAP2000 was used. Regarding the procedures for dimensioning of the pieces, Excel spreadsheets were prepared, while the detailing was carried out by means of the AutoCAD. Defined structural design, construction aspects were considered in the factory and in the work, taking into account costs of production and transportation, besides presenting the advantages that this constructive system can provide. These costs were considered for the solid slabs ready to use and for the precast walls. Even taking into account only the cost of production and transportation, the Lightweight Concrete with EPS was compared with Self-compacting Concrete, allowing visualize the advantages of the former when considering the overall cost of the project.