Atualmente, nanopartículas (NPs) são utilizadas em todos os ramos da tecnologia. Suas promissoras aplicações envolvem entre outros, o campo dos sensores e transdutores, mídia de gravação magnética, carreadores magnéticos de drogas medicinais. Com o objetivo de produzir NPs pelo método físico, um gerador de nanopartículas foi adaptado usando um dos canhões do sistema de magnetron sputtering, baseando-se no método de agregação gasosa. Com o gerador somos capazes de produzir NPs de diversos materiais e codepositá-las em matrizes dielétricas ou metálicas. Neste trabalho apresentamos o desenvolvimento da metodologia para a produção de nanopartículas de materiais magnéticos duros, usando alvos de SmCo5, Sm2Co17, Nd2Fe17B, FePt e CoPt. Investigamos a influência dos parâmetros de deposição (pressão, fluxo de gás e potência de sputtering), tipo de substrato e a existência de buffer e/ou codeposição, na obtenção das propriedades estruturais e magnéticas desejadas para esses materiais. As NPs produzidas são analisadas magneticamente pelo VSM e SQUID, sua morfologia e tamanho por TEM e SEM, a sua estequiometria pelo RBS, e a sua estrutura cristalina por XRD, a fim de obter nano-ímãs de alta anisotropia magnética. Da caracterização morfológica, através de microscopia eletrônica, encontramos para as NPs produzidas e estudadas diâmetros entre 5 e 17 nm. Através de análises de RBS obtemos para composição das NPs que as mesmas possuem estequiometria diferente dos alvos usados. Estudos estruturais e magnéticos mostram que para Sm-Co, Fe-Pt e Co-Pt é possível obter NPs cristalinas e com coercividade da ordem de 1 kOe. / In the recent years, nanoparticles (NPs) are being in all fields of technology. Their promising applications involve among others, the field of sensors and transducers, magnetic recording media, magnetic carriers of medicinal drugs. Aiming to produce NPs by physical method, a generator of nanoparticles was adapted using a system of guns \"magnetron sputtering\", based on the aggregation gas method. With the generator we are able to produce NPs with different types of material. In this work, we present the development of the methodology for the production of nanoparticles of hard magnetic materials, using targets of SmCo5, Sm2Co17, Nd2Fe17B, FePt and CoPt. We investigated the influence of the deposition parameters (pressure, gas flux and sputtering power), substrate type and the existence of the buffer and/or codeposition layers, to obtain the desired structural and magnetic properties for the nanoparticles. The produced NPs were magnetically analyzed by VSM and SQUID, the morphology and size by TEM and SEM, the stoichiometry by RBS and the crystal structure by XRD. The main objective of this work is to obtain nano-magnet with high magnetic anisotropy. Through the morphological characterization by electron microscopy, we found for NPs produced and studied have diameters between 5 and 17 nm. Through RBS analysis we have obtained the composition of the NPs, and also that they have different stoichiometry in relation to the used targets. Structural and magnetic studies have show that for Sm-Co, Fe-Pt and Co-Pt it is possible to obtain crystalline NPs with coercive field around 1 kOe.

No description available.

This thesis describes the synthesis, characterization and magnetic investigation of homometallic lanthanide complexes based on two different o-vanillin-derived Schiff base ligands: H2ovph and H2ovgrd. The studies were performed using single crystal X-ray diffractometry, Powder XRD and SQUID magnetometry. Chapter 2 focuses on dinuclear systems 1-8 coordinated to the ligand H2ovph and presents their structural and magnetic properties, mainly with respect to their intramolecular interactions. Chapter 3 describes two hexanuclear systems, 9 (DyIII) and 10 (GdIII), with trigonal prism-assembled core structures. A structural comparison to other similar complexes in the literature is performed. A series of dinuclear complexes, 11-15, based on the ligand H2ovgrd are described in Chapter 4, focusing on the synthetic strategy, crystal structures and magnetism. The presence of the lanthanide contraction is evident in this system of complexes and is consistent with the intrinsic lanthanide contraction property.

In this study I explore the perception of the influence of several school choice initiatives on secondary music programs in Milwaukee Public Schools (MPS). In 1990, MPS had fewer than 20 high schools. In 2010, it had close to 60. This increase, coupled with a rapidly expanding voucher program, the influx of charter schools, and a decrease in the number of secondary music programs made MPS an ideal setting for a study of this type. I conducted a two-stage qualitative study, coupling survey data and 19 interviews with MPS students, teachers, and administrators. The survey revealed data regarding the number of secondary music programs in MPS. In addition, the survey data revealed information regarding the type of programs in existence and what music courses were offered at MPS high schools. The interview data helped me to recognize the perceived influence of these government initiatives. Students, teachers, and administrators discussed course offerings, staffing, funding, the Milwaukee Parental Choice Program (MPCP), Milwaukee High School Redesign Initiative (MHSRI), and charter schools. Many teacher and student participants had trouble differentiating between the various initiatives but were of the opinion that secondary music education in MPS was declining. Administrators had more informed opinions regarding the initiatives but—even when they were directly responsible for their implementation—showed very little accountability or willingness to acknowledge that some of these programs were not producing desired results. What was not clear was what individual role, if any, these various governmental policies played. There was a great deal of overlap between these initiatives. There was speculation from some that with MPS facing so many other difficulties, music education may have been placed in a role of secondary importance. Because there is little research coupling school choice with secondary music education, these findings have important implications. This study could aid policy makers, administrators, and governmental officials in making informed decisions regarding secondary music programs and school choice. Too many decisions regarding school music programs are made without the aid of research driven data.

Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Nuclear Engineering, 1981. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND SCIENCE. / Includes bibliographies. / by Stanley R. Shanfield. / Ph.D.

No description available.

The objective of this research work is to investigate the practicality of magnetic workholding of non-magnetic synthetic quartz during high-speed grinding. This research work is sponsored by Quartzdyne and will be used as the starting point to applying single-piece rounding of its quartz. Hypotheses were created that would permit the authors to conclude that magnets are in fact worthwhile workholders for non-magnetic materials. Designs of Experiments were used to reject or fail to reject the null hypotheses. Experiments were carried out using a custom HAAS lathe, modified into a grinding center with an NSK live spindle, and neodymium-iron-boron magnets used to obtain both the holding and shear forces. Lastly, purchased polyolefin foam bumpers were used to increase the shear force, values were obtained with the Starrett force measurement machine. Input variables for the Design of Experiments (DOE) comprised of the holding force, feed-rate, part rotation, and in-feed size of cuts. Sample rotation relative to the magnets was the singular output variable. Experimental results were fitted with the correct distribution and modeled. Once a statistically significant model was attained input settings that minimized quartz sample rotation were determined and used to create an optimized program. Two sets of experiments were needed before the data could be properly fitted with a model. Thirteen out of fifteen samples remained stationary during the optimized program, which was adequate in failing to reject the second null hypothesis; a static sample at 350 RPM will remain static when undergoing high-speed rounding of its outside perimeter. Comparison of cycle times was crucial in reaching this conclusion; in fact, the cycle time of 7 minutes and 58 seconds for the optimized program was substantially less than Quartzdyne's estimated batch flow per piece cycle time of around 15 minutes. Obtaining a model was not possible or needed for the first hypothesis due to all experiments having zero rotation, therefore the authors also failed to reject the first null hypothesis; a static sample sandwiched between two permanent magnets with adequate holding force will remain stationary during rotation (min 250 RPM) Larger in-feed size cuts are possible when the quartz is square in shape –interrupted cuts. As it becomes cylindrical, cuts were reduced to experimental levels. Also, due to the amount of material being removed, the resin bonded wheel required dressing, without it rotation is expected. Variation was noticed while quantifying the shear force; it is attributed to the polyolefin foam bumper with its inconsistent coefficient of friction. A more uniform material, which can provide repeatable shear force values, would lessen the variation. All optimized program samples turned out perfectly round- even the two that had slight rotation.

In this thesis I present a complete and detailed guide for the development process and fabrication of efficient single-electron transistors (SETs) and a better single-molecule magnets (SMMs) deposition yield. Starting from a commercial Si/SiO2 wafer I show the steps for the deposition of different layers to fabricate a SET as well as the improvements achieved in those for a completely functional SET device. The development process is based on a combination of optical lithography and e-beam lithography with metal deposition in ultra-high vacuum. The improvements involve a better conductance in the Al gate component, with a controlled formation of the superficial oxide layer and a faster feedback electromigration-induced breaking of Au nanowires for the creation of nanogaps at room temperature. The gate component is improved by increasing its thickness and exposing it to plasma oxidation for the complete oxidation of its surface. The nanowire breaking is realized at room temperature to make use of the surface tension of Au, which, after a previous feedback procedure, eventually opens the final gap in the nanowire. Finally, I demonstrate a new technique that allows increasing the yield of having a SMM connected in the nanowire gap. This new technique is based on monitoring the resistance of the broken nanowires during the SMM deposition from a controlled liquid solution at room temperature. When the resistance ( > GΩ for open gaps) drops to values below Mega-ohms (characteristic resistance of a molecule bridging the gap) for a number of nanowires in the chip, the device is then ready for low temperature measurements.

A Superconducting Magnetic Energy Storage (SMES) system is a very efficient storage device capable of storing large amounts of energy. The primary applications it has been considered till now are load-leveling and system stabilization.This thesis explores new applications/benefits of SMES in power systems. Three areas have been identified. • Using SMES in conjunction with PV systems.SMES because of their excellent dynamic response and PV being an intermittent source complement one another.A scheme for this hybrid system is developed and simulation done accordingly. • Using SMES in an Asynchronous link between Power Systems. SMES when used in a series configuration between two or more systems combines the benefits of asynchronous connection, interconnection and energy storage. A model of such a scheme has been developed and the control of such a scheme is demonstrated using the EMTP. The economic benefits of this scheme over pure power interchange, SMES operation alone and a battery/dc link is shown. Improvement of transmission through the use of SMES. SMES when used for diurnal load leveling provides additional benefits like reduced transmission losses, reduced peak loading and more effective utilization of transmission facility, the impact of size and location on these benefits were studied, and if used as an asynchronous link provides power flow control. / Master of Science

Light-framed wood structures generally have satisfied the life safety objective of the current seismic design approach. The main source of energy dissipation in such structures is the inelastic behavior of the connectors connecting framing and sheathing elements. Wood framed structures when subjected to strong ground excitations experience structural and non-structural damage which may incur large repair/replacement costs or may even render the structure out of service. Thus, it is very important to apply techniques to mitigate the seismic response of the light-framed structures and avoid large monetary losses. It is proposed to use commercially available permanent magnets, incorporated in the form of passive friction dampers, to dissipate a part of input energy induced due to strong ground motions, thereby reducing the inelastic energy dissipation demand of the lateral load resisting system. The force of attraction between the permanent magnet and ferromagnetic material like steel was utilized to produce the required friction resistance. A sliding wall configuration consisting of flexible permanent magnets and steel plates sandwiched between the plywood sheets was analyzed for its effectiveness in mitigating the response of a two story wood shear wall structure. The structural analysis program SAP2000 was used to perform nonlinear dynamic analysis of the finite element models generated using the meshing algorithms incorporated into 'WoodFrameMesh'. Nonlinear link elements available in SAP2000 were used to model the friction between the flexible magnet sheet and the steel plate. The effects of various modeling parameters on the solution of the nonlinear analysis were studied so as to arrive at appropriate values to represent the friction problem. Also the friction damped structure was analyzed to study its forced and free vibration characteristics. Further, the responses of the friction damped structure and the undamped structure were compared when subjected to different ground accelerations. The response of the friction damped structure was also compared to that of the structure in which the proposed friction dampers were replaced by normal shear walls. A huge reduction in the response of the friction damped structure was observed when compared to the response of the undamped structure. The friction damped structure was also analyzed for different values of modal damping ratios. Over all about 60-80% of the input energy was dissipated by friction damping in all the cases. The slip resistance of a flexible permanent magnet sheet was also verified in the laboratory. Above all the magnetic properties of commercially available permanent magnets and the effects of strong permanent magnets on human health were also studied. / Master of Science