The present work reports a study of the effects of the compositions, and various catalytic additives and nanostructuring by high-energy ball milling, on the hydrogen storage properties of LiBH4, NaBH4, LiNH2 and LiAlH4 complex hydrides and their composites. The composites of (NaBH4+2Mg(OH)2) and (LiBH4+2Mg(OH)2) without and with nanometric nickel (n-Ni) added as a potential catalyst were synthesized by ball milling. The effect of the addition of 5 wt.% nanometric Ni on the dehydrogenation behavior of both the NaBH4-and LiBH4-based composites is rather negligible. In the (LiNH2+nMgH2) system, the phase transformations occurring as a function of the ball milling energy injected into the hydride system (LiNH2+nMgH2), having molar ratios n=0.5 to 2.0, have been thoroughly studied. The milling energy is estimated by a semi-empirical method. The results show that for the molar ratios n<1.0 three new phases such as LiH, amorphous Mg(NH2)2 (a-Mg(NH2)2) and Li2Mg(NH)2 are formed during ball milling depending on the injected energy. For the molar ratios n≥1.0 the new phase of MgNH forms whose formation is accompanied by a profound release of hydrogen. Addition of 5 %wt. KH can improve desorption rate of the LiNH2+0.5 MgH2 system. Furthermore this hydride system can be nearly fully rehydrogenated at 200°C and 50 bar H2 pressure. LiAlH4 containing 5 wt.% of nanometric Fe and Ni shows a profound mechanical dehydrogenation by continuously desorbing hydrogen (H2) during ball milling. X-ray diffraction studies show that Fe and Ni ions dissolve in the lattice, replacing the Al ions and forming a substitutional solid solution. Both Fe and Ni decrease the activation energies of stage I and II , but stage I is more sensitive to the particle size . The addition of 5 wt.% nano-size “interstitial compound” (n-TiC, n-TiN and n-ZrC) shows a continuous desorption of H2 is observed during high energy milling. Mechanical dehydrogenation rate of the doped samples increases noticeably during high-energy ball milling in the order of TiN > TiC > ZrC. The interstitial compound additives are able to strongly reduce the activation energy of Stage II dehydrogenation but do not substantially affect the apparent activation energy of Stage I .

A simple model that includes energy and carbon dioxide (CO2) emissions in the economics of machining is proposed, which has been published in the highly respected and cited journal, Annals of CIRP (International Academy for Production Engineering). This is a timely analysis in current government discussions on a proposed carbon tax or a carbon cap and trade regime and greater energy efficiency. The new cost model is based on life cycle analysis methodology for the initial part production. An illustrative example is given showing that the cheapest electrical grid should not be chosen, if it also has the highest CO2 emissions. Accurate pricing is important, because the more expensive product was highly dependent on the carbon price. A comprehensive review of machining economic models is covered. However, there is a dearth of actual machining data in the literature. This work includes studies in milling and single point incremental forming (SPIF) which can be used by other manufacturing engineers in their machining economic model development. The first milling study involved simple straight cuts. In general, as feed rate (FD) increased (increasing the material removal rate, MRR), the energy consumed decreased as process time decreased. In contrast, as spindle speed (N) increased, energy consumed increased, since more power is drawn by the motor, without a process time reduction. Given the inverse power relationship observed for the time, energy, process CO2 and cost against MRR, the recommended parameters were the same at the highest FD and lowest N permissible. In the second milling study with constant N for a more complex part (sprocket), similar relationships were observed. However, for sprockets made at constant chip load (allowing FD and N to change together), there were varying prescribed MRRs for time, energy, process CO2 and cost minimization. The SPIF studies showed a similar relationship to the constant N milling, and, that results for a simple part can be extrapolated to improve efficiency in more complex parts. Finally, although the energy and carbon costs represented a small contribution to the final cost, their significance increased for higher efficiency parameters or user conditions, e.g. low labour rate. / Thesis (Master, Mechanical and Materials Engineering) -- Queen's University, 2011-12-03 19:58:07.76

No description available.

A 20 litre experimental batch and continuous test rig and 5 litre batch and 50 litre continuous test rigs for stirred ball milling were built at the University of Natal and Mintek respectively. All the mills featured a grinding vessel with a central shaft equipped with pins and a torque measurement system. A washed chrome sand from the Bushveld Igneous Complex was used for the grinding experiments. Particle size analysis of products was performed using standard sieves and a Malvern Particle Sizer. Batch tests were run in the 20 litre stirred ball mill to achieve efficient grinding conditions. The effects of grinding conditions such as pulp density, media size, media density and shaft rotation speed and mill design parameters such as ball load, pin spacing and pin diameter on product size, power consumption and media wear were studied. It has been shown that the median size of the product can be calculated by the Charles' Energy-Size Equation. The stirred ball mill has been found to be more energy efficient than the tumbling ball mill. An energy reduction of 50% was possible for a product size of 6 microns when the stirred ball mill was employed instead of the tumbling ball mill. The energy input per ton of grinding media in the stirred ball mill could be 10 times higher than for the tumbling ball mill. Although during coarse grinds the media wear was higher in the stirred ball mill than in the tumbling mill, it became less so as grinding proceeded and for a product median size of 4.8 microns it was the same. Using a 5 litre batch mill, an experimental programme was designed to study the comminution characteristics of the stirred mill. A factorial design was prepared with the following parameters, which influence grinding in the stirred ball mill: pulp density, pin tip velocity and ball density and size. The energy required for grinding the chromite sand in the stirred ball mill was determined by the use of Charles' Equation. The findings were in agreement with the results predicted by this equation. It was shown that the Rosin-Rammler size distribution equation was a suitable procedure for presenting and comparing grinding data obtained from the stirred ball mill. The factors that had the greatest effect on grindability were, in order of importance: ball size, pin tip velocity and ball density. Interactions between grinding parameters were negligible. results implied that accurate predictions can be made to determine the grinding conditions required to achieve a desired product specification. An attempt was made to study the grinding kinetics the chromite are using the mass population·balance model. Grinding tests were performed with two mono size fractions ·53+38 and -38+25 microns and natural feed ·100 microns using various pin tip velocities, ball densities and within the normal stirred ball milling operating range. relationship between the ball diameter and the particle was explained by the "angle of nip" theory which applied for roller crushers. It was shown that the particle giving the maximum breakage rate was directly proportional to the ball diameter. Estimated grinding kinetic parameters from monosize provided a good basis for predictions of natural feed. However, the breakage rate obtained from monosize tests appeared to be lower than those from the natural feed It was found that if the selection and breakage functions were determined by monosize tests, it was possible to modify selection function parameters by back-calculation which gave the best fit to the natural feed size. A good correlation was obtained between the experimental and product distributions using a population-balance model. The links between the empirical model combining Charles' and Rosin-Rammler equations and the first-order batch grinding equation were also shown. The stirred ball mills were operated in batch and continuous mode. The median size of the products from the batch stirred ball mill experiments closely matched those of the continuous grinding experiments under similar grinding conditions. Using a salt solution as a tracer material, an attempt was made to estimate the residence time distribution based on a simplified analysis of the motion of the water in tile mill. The current scale-up methods for the stirred ball mill are discussed. A torque model was developed for given shaft geometry and ball relating the power rements of the stirred ball mill to the following prime design and operating parameters : mill diameter, mill height, pin tip velocity and effective density of the mill load. The basic assumptions underlying the model were that the mill content behaved as a fluidised bed, consequently a P effg h type model for the pressure was applied throughout the grinding media bed the effective charge velocity was proportional to the pin tip velocity. It was found that pin spacing, pin diameter and ball diameter significantly affected the mill torque. A semi-empirical torque model was derived to include these parameters. The relationships formulated from these models were shown to be in excellent agreement with experimental results. / Thesis (Ph.D.)-University of Natal, Durban, 1993.

The credit card industry is huge with over two and a half billion cards shipped annually. A local card manufacturer, with a production volume in excess of forty million cards annually, approached the University of Canterbury to design and develop advanced card manufacturing technology. The motivation behind this development was the desire of the sponsoring company to keep abreast of new technologies and to have the ability to manufacture and supply cards with this new and emerging technology into a highly competitive world market. This thesis reports the research surrounding the development of a dedicated new machine tool explicitly designed to implement the emerging technologies found in the international credit card industry. The machine tool, a dedicated milling machine, was not developed in its entirety within these pages; however, three major constituents of the machine were researched and developed to a point where they could be implemented or become the subject of further research. The three areas of interest were; • A machine table system that avoided the increased zonal wear to which linear bearings are subject, typically due to short high frequency traversals, and also the high friction and mass generally found in dovetail slides. • Design requirements demanded the use of a single commercially available carbide cutter to produce 1500 components per hour. Therefore, a purpose built high (revs per minute) rpm spindle and drive system specifically for use with polymeric materials, (R-PVC in particular) was deemed necessary. • Tracking the cutter depth in relation to an RFID aerial track embedded within the credit card core. The aerial tracking was to be dynamic and occur during the machining process with the machine “remembering” the depth of cut at contact with the aerial. Each of the three areas was researched via an in-depth literature review to determine what and if any material had been published in these fields. For the development of the machine table a novel flexure hinge idea was considered. Considerable material was discovered about flexures, but very little was found to be relevant to the application of high displacement metal flexures necessary to meet the required levels of table movement. In effect the proposed machine table system and research in this field would be novel. The high performance spindle investigation became directed into a much narrower focus as it progressed; that of determining the power consumption required to machine the integrated circuit pockets in an R-PVC work piece. This was due to the lack of information pertaining to the physical properties of polymeric materials, in particular the specific cutting pressure. The depth following sensor array was configured using capacitance detection methods to determine the distance between the cutter?s end and the aerial tracks. Capacitance sensing methods, whilst not new, were developed into a novel arrangement to meet the specific cutter tracking requirements of the proposed new machine tool. Each of the respective development areas had concept designs completed and were prototyped before being tested to determine the effectiveness of the respective designs. The outcomes from the testing are reported herein, and show each constituent part to be basically feasible, in the application. The results were sufficient to indicate that each development showed distinct potential but further development and integration into the machine tool should ensue.

The production and storage of uranium mine mill tailings have the potential to contaminate local groundwater and surface waters with metals and metalloids. As such, an understanding of the solids reservoirs for potential contaminants in uranium ore blends and leach residues (solid wastes generated by the milling of ore) is required to predict long-term controls on these contaminants in tailings porewaters. This study characterized the distribution of the elements of concern (EOCs; As, Mo, Ni, and Se) in uranium ores and waste rock used to blend the mill feeds in the milling process and leach residues from the Key Lake mining operation, Saskatchewan. This study also evaluated the alteration of the clay minerals in these uranium ores, waste rocks and leach residues. X-ray diffraction, electron micro-probe, and mineral liberation analyses showed that the reservoirs for As, Mo, Ni, and Se (in ores and ore blends) were dominated by sulphides including cobaltite, gersdorffite, molybdenite, pyrite, galena and chalcopyrite, secondary Ni-arsenates (annabergite?), Fe-arsenate (scorodite?) and Ni-Co/Ni-sulfates. The secondary arsenates and sulfates present in special waste were identified as major As, Mo, Ni, and Se bearing minerals and most likely the product of oxidation of arsenide-bearing sulphide minerals within the special waste rock. Analyses also showed that sulphides and arsenates occurred in trace amounts in the ores and special waste rock (0.5 to 1.0 wt %). Data showed that 55 to 90% pyrite, 36 to 51% chalcopyrite, 23 to 37% molybdenite, and 52 to 70% galena remained unleached in the leach residues after milling of the ore blends. The percentages of unleached minerals varied between mill feeds and were dependent on the grain-size distribution and the degree of mineral liberation. Cation exchange capacity (CEC) analysis indicated an increase of the CEC values in the leach residues suggesting possible evolution of 2:1 layers into high-charge layers during the milling.

In manufacturing, cutting fluids promote machining performance by removing heat, lubricating the cutting zone, flushing away chips, and preventing in process corrosion. To synthetize conventional metalworking fluids (MWFs), aside from choosing from a selection of base oils, an array of additives are also typically added. In traditional cutting fluid applications, the cost of waste fluid treatment is enormous. Moreover, the treatment is not always effective and disposal may lead to unexpected environmental contamination. The bacteria and chemical elements in the waste liquids may also introduce health and safety concerns. For the milling process at the micro-scale, i.e., micro-milling, traditional flood cooling may not be suitable. Since the cutting zone between the tool flank and workpiece is in the order of micrometers, the liquid surface tension of flood coolant would impede effective cooling and lubrication of the cutting fluid especially at a high spindle speed for tools. So for micro-milling, some researchers have tried to use minimum quantity lubrication method to apply cutting fluids. Other semi-dry methods like atomization method based on an ultrasonic atomizer have also been tested. However, even though these systems are able to decrease the amount of cutting fluids, the atomization of conventional cutting fluids with harmful surfactants (especially water miscible MWFs) and additives inside would still pose problems related to health hazard and contamination. Thus, new systems and/or green cutting fluids that eliminate the use of undesired surfactants or additives need to be developed. In this thesis, efforts to solve these problems for micro-milling operations are presented. Firstly, canola oil is selected and used to be emulsified in distilled water through ultrasonic atomization without any surfactant. Then, the emulsified water and oil solution is applied as cutting fluid in micro-milling, and the cutting performance results are compared to those with dry machining and traditional cutting fluid – 5% TRIM aqueous solution. The experimental results show that smaller chip thickness, and burr amount are observed with canola oil-in-water emulsion compared to conventional MWF. Reduction of almost 30% in cutting forces has also been achieved. Secondly, development of a new atomization-based cutting fluid system is introduced. Both cooling and lubricating capabilities of the cutting fluids are achieved using air-mixed water and oil mists, requiring no surfactants. Experiments are then conducted to evaluate the new system and the air-mixed jet of independently atomized water and oil sprays and compared to results with water only, oil only, and conventional cutting fluid (5% TRIM) conditions. The results reveal the mixture of water and oil leads to best performance in cooling and lubrication during micro-milling. The new system is proved to be effective in cooling and lubricating the cutting zone for both Al6061 and steel 1018. This atomization system is considered as a novel application method to apply totally green cutting fluids. Finally, a novel environmentally friendly additive was added to conventional cutting fluids. In this thesis, lignin powder obtained from wood is considered as one kind of these “green” additives. It is firstly tried to be dissolved in 5% TRIM aqueous solutions in 8 different concentrations through injection and atomization methods. Then, those lignin containing cutting fluids are used to run micro-milling experiments and compared with 5% TRIM. Nine MWFs are all nebulized by a nebulizer to cool and lubricate the workpiece. The results show that the concentration of 0.015% lignin leads to the least cutting forces, tool wear and burrs. The obtained solution (f) with 0.15% lignin inside causes cutting forces that are just 50% in value of those with 5% TRIM. Considering lignin’s anti-oxidative characteristic and its performance in improving machining processes, it is a promising additive in MWFs. / Graduate / 0346 / 0548 / yanqiaoz@uvic.ca

Due to increasing trends of miniaturization, components with microscale features are in high demand. Accordingly, manufacturing and measurement of small components as small as a few microns became new challenges. Micro milling and femtosecond laser machining are the most common in use cutting operations providing high accuracy and productivity. Micro milling has unique features different from traditional milling including high ratio of tool size to feature size, and constant ratio of tool edge radius to tool size [1]. Due to the mentioned differences, low stiffness of the micro mill and the complexity of the cutting mechanism at the macroscale, selection of cutting parameters are difficult [2]. Therefore, process performance in micro milling, which affects surface quality and tool life, depends on the selected cutting parameters. Also, for measuring micro components, the available dimensional control systems in the market are atomic force microscopes (AFMs) and a combination of coordinate measuring machines (CMMs) and vision systems. These are confined to the scopes of nanoscale and macroscale parts, respectively. It is difficult to justify the high cost and large size of these systems for measurement of mesoscale/microscale features and components and dimensional verification of miniature parts with 3D features. Therefore, a new cost-effective way is needed for measuring components and features in these scales. Additionally, lack of advanced CAD/CAM software for micro laser machining providing constant velocity along the tool path, is the main problem in femtosecond laser machining. In this thesis, to address the mentioned challenges, different software packages are presented to improve micro machining productivity, to provide an accurate and cost effective way of micro scanning and to bring CAD/CAM capability for micro laser machining. / Graduate / 0548 / abdolreza.bayesteh@gmail.com

Although a considerable amount of research exists on geometrical aspects of 5-axis flank milling, the dynamics of this efficient milling operation have not yet been given proper attention. In particular, investigating machining chatter in 5-axis flank milling remains as an open problem in the literature. The axial depth of cut in this operation is typically quite large, which makes it prone to machining chatter. In this thesis, chatter in 5-axis flank milling is studied by developing analytical methods of examining vibration stability, generating numerical simulations of the process, and conducting experimental investigations. The typical application of 5-axis milling includes the machining of thermal resistant steel alloys at low cutting speeds, where the process damping dominates the machining vibration. The results of experimental study in this thesis showed that the effect of process damping is even stronger in flank milling due to the long axial engagement. Accordingly, the first part of the thesis is devoted to studying process damping, and in the second part, the modeling of chatter in flank milling is presented. Linear and nonlinear models have been reported in the literature that account for process damping. Although linear models are easier to implement in predicting stability limits, they could lead to misinterpretation of the actual status of the cut. On the other hand, nonlinear damping models are difficult to implement for stability estimation analytically, yet they allow the prediction of “finite amplitude stability” from time domain simulations. This phenomenon of “finite amplitude stability” has been demonstrated in the literature using numerical simulations. In this thesis, that phenomenon is investigated experimentally. The experimental work focuses on uninterrupted cutting, in particular plunge turning, to avoid unduly complications associated with transient vibration. The experiments confirm that, because of the nonlinearity of the process damping, the transition from fully stable to fully unstable cutting occurs gradually over a range of width of cut. The experimental investigation is followed by developing a new formulation for process damping based on the indentation force model. Then, the presented formulation is used to compute the stability lobes in plunge turning, taking into account the effect of nonlinear process damping. The developed lobes could be established for different amplitudes of vibration. This is a departure from the traditional notion that the stability lobes represent a single boundary between fully stable and fully unstable cutting conditions. Moreover, the process damping model is integrated into the Multi-Frequency Solution and the Semi Discretization Method to establish the stability lobes in milling. The basic formulations are presented along with comparisons between the two approaches, using examples from the literature. A non-shallow cut is employed in the comparisons. Assessing the performance of the two methods is conducted using time domain simulations. It is shown that the Semi Discretization Method provides accurate results over the whole tested range of cutting speed, whereas higher harmonics are required to achieve the same accuracy when applying the Multi Frequency Solution at low speeds. Semi Discretization method is modified further to calculate the stability lobes in flank milling with tools with helical teeth. In addition to the tool helix angle and long axial immersion, the effect of instantaneous chip thickness on the cutting force coefficients is considered in the modified formulation of Semi Discretization as well. Considering the effect of chip thickness variation on the cutting force coefficients is even more important in the modeling of 5-axis flank milling, where the feedrate, and consequently the chip thickness, varies at each cutter location. It also varies along the tool axis due to the additional rotary and tilt axis. In addition to the feedrate, the tool and workpiece engagement geometry varies at each cutter location as well. The actual feedrate at each cutter location is calculated by the dynamic processing of the toolpath. The tool and workpiece engagement geometry is calculated analytically using the parametric formulation of grazing surface at the previous and current passes. After calculating the instantaneous chip thickness and tool/workpiece engagement geometry, they are integrated into the Semi Discretization Method in 5-axis flank milling to examine the stability of vibration at each cutter location. While the presented chatter analysis results in establishing stability lobes in 3-axis flank milling, it results in developing a novel approach in presenting the stability of the cut in 5-axis flank milling. The new approach, namely “stability maps”, determines the unstable cutter locations of the toolpath at each spindle speed. The accuracy of established 3-axis flank milling stability lobes and 5-axis stability maps is verified by conducting a set of cutting experiments and numerical simulations.

The main focus of this thesis is the characterization of defects and microstructure in high-energy ball milled magnesium hydride powder and magnesium-based multilayered composites. Enhancement in kinetics of hydrogen cycling in magnesium can be achieved by applying severe plastic deformation. A literature survey reveals that, due to extreme instability of -MgH2 in transmission electron microscope (TEM), the physical parameters that researchers have studied are limited to particle size and grain size. By utilizing a cryogenic TEM sample holder, we extended the stability time of the hydride phase during TEM characterization. Milling for only 30 minutes resulted in a significant enhancement in desorption kinetics. A subsequent annealing cycle under pressurized hydrogen reverted the kinetics to its initial sluggish state. Cryo-TEM analysis of the milled hydride revealed that mechanical milling induces deformation twinning in the hydride microstructure. Milling did not alter the thermodynamics of desorption. Twins can enhance the kinetics by acting as preferential locations for the heterogeneous nucleation of metallic magnesium. We also looked at the phase transformation characteristics of desorption in MgH2. By using energy-filtered TEM, we investigated the morphology of the phases in a partially desorbed state. Our observations prove that desorption phase transformation in MgH2 is of nucleation and growth type, with a substantial energy barrier for nucleation. This is contrary to the generally assumed core-shell structure in most of the simulation models for this system. We also tested the hydrogen storage cycling behavior of bulk centimeter-scale Mg-Ti and Mg-SS multilayer composites synthesized by accumulative roll-bonding. Addition of either phase (Ti or SS) allows the reversible hydrogen sorption at 350C, whereas identically roll-bonded pure magnesium cannot be absorbed. In the composites the first cycle of absorption (also called activation) kinetics improve with increased number of fold and roll (FR) operations. With increasing FR operations the distribution of the Ti phase is progressively refined, and the shape of the absorption curve no longer remains sigmoidal. Up to a point, increasing the loading amount of the second phase also accelerates the kinetics. Microscopy analysis performed on 1-2 wt.% hydrogen absorbed composites demonstrates that MgH2 formed exclusively on various heterogeneous nucleation sites. During activation, MgH2 nucleation occurred at the Mg-hard phase interfaces. On the subsequent absorption cycles, heterogeneous nucleation primarily occurred in the vicinity of internal free surfaces such as cracks. / Materials Engineering