[Truncated abstract] Magnetic gradiometers are powerful tools for mineral exploration. The magnetic field contains valuable information about the mineral content of the surveyed terrain. The magnetic gradient specifies the amount of spatial variation in the direction and magnitude of the magnetic field. Surveys that measure the magnetic gradient provide vastly more information about geological targets than the magnetic field alone. This technology could have enormous benefits in terms of new discoveries and lower exploration costs. The magnetic gradient is normally calculated by subtracting the outputs of two total field magnetometers which are separated by a baseline. In 1997, a direct string magnetic gradiometer (DSMG) was developed that directly measures magnetic gradients using only a single string as its sensing element. This thesis describes research conducted to improve the sensitivity and performance of the DSMG. The main advantage of the DSMG is that only gradients can induce second harmonic vibrations in the string. Thus, the DSMG is insensitive to uniform magnetic fields that we are not interested in, such as the global magnetic field of the Earth. By using inductive electronics to measure second harmonic string vibrations, we can select to measure the magnetic gradient of nearby targets. Recent work has shown that a magnetic gradiometer with a noise floor of 0.01 nT/m/ v Hz should be sufficiently sensitive for geophysical exploration. In order to reach this goal, this thesis presents an investigation of all noise sources affecting the DSMG. ... Gas damping is negligible in high vacuum and no vibration isolation is required. This means that longer strings with low resonant frequencies can be used. Using theoretical modelling, I show that a space borne DSMG should be able to match the white noise level of SQuID based magnetic gradiometers and have a lower 1/f noise corner. Deployment in space could be the most viable application of the DSMG because of the ease of operation and enhancement of sensitivity. If the thermal noise level is reduced then other sources of noise will start to become more important. When rotated in the Earth's magnetic field, the DSMG detects a pseudo magnetic gradient despite the field being almost uniform. A possible cause is magnetically susceptible parts which are magnetically aligning with the Earth's field. I have conducted a thorough investigation of magnetic susceptible parts in the DSMG and reported the results in this thesis. In the DSMG, a pair of inductive pickup coils are used to measure the string's displacement with a root mean square accuracy of 1011 m/ v Hz. This is adequate at present but the inductive electronics may not be sensitive enough after other improvements in the DSMG are implemented. Here, I present a new capacitive displacement readout with a high sensitivity of 1013 m/ v Hz. The thesis also presents some magnetic gradient measurements in the lab and the results of a ground survey in the field. These trial measurements are used to characterise the DSMG and demonstrate its effectiveness for airborne surveying.

<p>The modern coastline provides few clues as to the ancient harbour configuration since Kalamianos has been partially submerged by > 6 m of relative sea-level rise since the Early Helladic. In 2009, a detailed marine geophysical survey and underwater diver search was conducted in the inshore waters to identify potential anchorage sites and to examine evidence for coastal subsidence. Single-beam bathymetry and magnetic gradiometer data were acquired and integrated within a detailed digital bathymetric model (DBM).</p> <p>The DBM revealed two submerged beachrock platforms (BR-1, BR-2) paralleling the modern shoreline and a submerged isthmus connecting the mainland with small island 200 m offshore. The BR-1 platform (3.5-3.7 m depth) contained abundant Late Helladic (LH; 1300-1190 BC) pottery sherds (30-50%) and wood charcoal fragments.¹⁴C dating of the extracted charcoal yielded an AMS ¹⁴C uncalibrated age of 3250±40 BP, consistent with the LH ceramics. The BR-2 platform (5.8-5.9 m depth) contained less pottery (<20%) and included well-preserved fragments of Early Helladic (EH) jars.</p> <p>The beachrock elevations and ¹⁴C and pottery ages were used to reconstruct a sea level curve and a series of paleogeographic maps of the EH to LH shorelines. The presence of abundant pottery and wood charcoal in the BR-1 beachrock indicates that shipping activity during the LH was focused at the south end of the site in a western harbour basin. This is supported by magnetic gradiometer results, which identified several magnetic anomalies in the western harbour basin. These were investigated by diver search and found to be concentrations of ship ballast stones (mainly andesite) and clay pottery.</p> / Master of Science (MSc)

Konische Mikro- und Nanostrukturen besitzen spezifische magnetische, superhydrophobe und elektrokatalytische Eigenschaften und sind deshalb von hohem Interesse für eine Vielzahl von Anwendungen. Eine einfache und kostengünstige Methode zur Synthese dieser strukturierten Schichten ist die elektrochemische Abscheidung. Neben dem Einsatz von Capping-Reagenzien (engl. Capping agents) könnten Magnetfelder das lokale Konuswachstum auf einer planaren Elektrode unterstützen. In der vorliegenden Dissertation wird die Elektroabscheidung an konisch strukturierten Metallschichten in Magnetfeldern untersucht. Je nach Ausrichtung und Stärke des Magnetfeldes können die Lorentzkraft und die magnetische Gradientenkraft die Strömung des mit Metallionen angereicherten Elektrolyts in Richtung der Konusspitze gezielt antreiben. Folglich erhöht das Magnetfeld die lokale Abscheidungsrate und fördert das Konuswachstum. Für ein grundlegendes Verständnis des Effektes werden systematische numerische und theoretische Untersuchungen für die Elektroabscheidung an mm-großen Konen unterschiedlicher Materialien, Formen und Anordnungen unter verschiedenen elektrochemischen und magnetischen Bedingungen durchgeführt. Ein parallel zur Konusachse ausgerichtetes homogenes externes Magnetfeld erzeugt durch die Magnetisierung der ferromagnetischen Konen eine magnetische Gradientenkraft, die zu einer starken Unterstützung für das Konuswachstum führt. Dabei überwiegt sie oft gegenüber der Lorentzkraft und der Auftriebskraft, die durch Elektrodenreaktionen entsteht. Diese unterstützende Wirkung wird nur geringfügig abgeschwächt, wenn sich benachbarte Konusse einander annähern. Die numerischen Ergebnisse werden durch experimentelle Daten für verschiedene Konfigurationen und Abscheidungsparameter validiert. Um den Effekt der Magnetfelder zur Unterstützung des Wachstums kleinerer konischer Strukturen im Mikro- und Nanometerbereich zu ermitteln, werden die Skalengesetze für die Geschwindigkeiten der magnetisch angetriebenen lokalen Strömungen beim Verkleinern der Konusgröße aus numerischen Simulationen abgeleitet und durch eine analytische Lösung bestätigt. Obwohl die magnetische Gradientenkraft eine günstige Strömung bei ferromagnetischen Konussen erzeugt, limitieren die kleine Größe der Strömungsregion und die nahezu konstant verbleibende Dicke der Konzentrationsgrenzschicht die Unterstützung der Magnetfelder. Diese kann jedoch durch die Anwendung gepulster Ströme sowie moderat auch durch den Einsatz stärkerer Magnetfelder weiter erhöht werden. Weiterhin wird eine einfache Modellierung entwickelt, um den Einfluss von Capping-Reagenzien bei der Abscheidung von Nano-Strukturen numerisch zu simulieren. Experimentelle Resultate der von Partnern in Krakau durchgeführten Elektroabscheidung von nanostrukturierten Ni-Schichten in magnetischen Feldern werden mittels Simulationen sowohl globalen Zellströmung als auch der lokalen Strömung analysiert. Die Betrachtung beider Aspekte liefert eine Interpretation der experimentellen Ergebnisse und ermöglicht ein besseres Verständnis der Wirkung des capping agents. Zum Schluss wird der Einfluss der Wasserstoff-Nebenreaktion einbezogen. Die numerischen Ergebnisse zeigen, dass an der Konusspitze sitzende Wasserstoffblasen das Konuswachstum verringern können. Gleichzeig wird die durch die magnetischen Kräfte getriebene Strömung die Ablösung der Wasserstoffblase geringfügig verzögern. / Micro- and nano-sized conical structures possess specific magnetic, superhydrophobic and electrocatalytic properties and are therefore attractive for numerous applications. Among the various methods of manufacturing such structured layers, electrodeposition appears a simple and inexpensive method. Beside the use of capping agents, the application of magnetic fields could support the local growth of cones on a non-templated planar electrode. This dissertation investigates electrodeposition at conically structured metal layers in external magnetic fields. Depending on the direction and the intensity of the magnetic field, the Lorentz force and the magnetic gradient force can generate electrolyte flow and bring electrolyte enriched with metal ions towards the cone tips. As a result, the local deposition rate is increased and conical growth is promoted. In order to obtain a basic understanding of the magnetic field effects, systematic numerical and theoretical investigations are performed for electrodeposition at mm-sized cones of different materials, shapes and arrangements under different electrochemical and magnetic conditions. If a uniform external magnetic field is oriented parallel to the cone axis, the magnetic gradient force enabled by the magnetization of ferromagnetic cones provides a strong support for conical growth, thereby often dominating over the Lorentz force and the buoyancy force arising from electrode reactions. This supporting effect is only slightly mitigated when neighboring cones are getting closer. The numerical results shown are validated by experimental data for different configurations and deposition parameters. In order to explore the prospects of magnetic fields to enhance the growth of smaller, micro- and nanometer sized conical structures, scaling laws of the local flows driven by the magnetic forces are derived numerically and confirmed analytically for shrinking cone sizes. Although the magnetic gradient force can generate a beneficial flow at ferromagnetic cones, the small flow region and the nearly constant thickness of the concentration boundary layer limit the support of the magnetic field. Enhancements of the structuring effect are observed for pulsed deposition and, despite only moderately, at higher magnetic field intensities. Furthermore, a simplified modeling approach is developed to simulate the growth mechanism of nano-cones with respect to the influence of capping agents. Experimental results of the electrodeposition of Ni cones in magnetic fields obtained by partners in Krakow are analyzed by performing simulations of both the global cell flow and the local flows generated by magnetic fields of different orientations. This two-step approach provides an interpretation of the experimental results, and gives a deeper insight on how the capping agent influences the local growth. Finally, the impact of the hydrogen side reaction on the electrodeposition in magnetic fields is considered. The numerical results indicate that hydrogen bubbles sitting at the cone tips may damp conical growth, while the magnetic-field-driven flow imposes a weak stabilizing force on the bubble.

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