Dois modelos descrevendo sistemas magnéticos modulados são estudados na presença de um campo magnético. Na primeira parte consideramos um modelo de Ising com interações competitivas numa única direção espacial (modelo ANNNI). A superfície crítica, a linha tricrítica, a estrutura das fases moduladas, e os diagramas de fases são determinados na aproximação de campo médio. O comportamento crítico e tricrítico é analisado através do método de Grupo de Renormalização. Na segunda parte estudamos um modelo adequado à descrição do composto MnP. Cálculos realizados na aproximação de campo médio e através do método de Grupo de Renormalização contribuem para esclarecer os resultados experimentais acerca do ponto de Lifshitz observado neste composto. / Two models describing modulated magnetic systems are studied in the presence of a magnetic field. The first part is dedicated to the study of an Ising model with competing interactions along one of the spatial directions (ANNNI model). The critical surface, the tricritical line, the structure of the modulated phases, and the phase diagrams are determined in the mean field approximation. The critical and the tricritical behaviour is analised by the Renormalization Group method. The second part is concerned with a model suitable for the description of the compound MnP. Calculations carried out in the mean field approximation and through the Renormalization Group method provide a better understanding of the experimental results on the Lifshitz point observed in this compound.

Atualmente, a intensidade de campo elétrico, campo magnético e campo eletromagnético é um fator determinante não só para a implantação de novas instalações, mas também, para as instalações existentes no sistema elétrico. Apesar de não existir nenhum estudo conclusivo que comprove a evidência direta entre a exposição a estes campos e os efeitos nocivos na saúde das pessoas, muitos países, inclusive o Brasil, definiram em suas legislações limites básicos à exposição de campos elétrico e magnético provenientes dos sistemas elétricos. Este trabalho tem como objetivo contribuir para análise de campo magnético de linhas subterrâneas de alta tensão existentes ou linhas em fase inicial de projeto, visando atender os limites de exposição vigentes na legislação local. Nele é apresentada a metodologia de cálculo de campo magnético baseada na Lei de Biot-Savart e no princípio da superposição. Estudos analíticos para verificação da influência dos parâmetros de instalação e elétricos de linhas sobre o campo magnético são apresentados para linhas subterrâneas de alta tensão compostas por um e dois circuitos com diferentes tipos de instalação e aterramentos. Comparações entre valores analíticos e valores de medições de campo magnético de linhas subterrâneas de alta tensão existentes em operação também são abordadas neste trabalho. As principais técnicas de mitigação de campo magnético utilizadas em linhas subterrâneas de alta tensão, tais como técnicas de compensação envolvendo laços de cabos e técnicas de blindagens com materiais metálicos externos aos cabos, também são apresentadas. Devido ao campo elétrico externo ao cabo isolado ser praticamente zero, assuntos referentes a este campo não são abordados neste trabalho. Por simplicidade, campo magnético refere-se à densidade de fluxo magnético neste documento. / Nowadays, the intensity of electric field, magnetic field and electromagnetic field is a determining factor, not only for implantation of new installations, but also for existing installations in the power system. Although no exist conclusive study that proves the direct evidence between exposure to these fields and adverse effects on human health, many countries, including Brazil, have defined in their laws basic limits for exposure to electric and magnetic fields produced by the electric system. This work aims to contribute to analysis of magnetic field for both existing high voltage underground lines and lines in initial stage of project, aiming the actual exposure limits of the local legislation. In it, is shown the magnetic field calculation methodology based on the Biot-Savart\'s law and the superposition principle. Analytical studies to verify the influence of installation and electrical parameters of lines on the magnetic field are presented for high voltage underground lines consist of one and two circuits with different types of installation and earthing. Comparisons between analytical and measurement values of magnetic field of existing high voltage underground lines in operation are also addressed in this work. The main mitigation techniques of magnetic field used in high voltage underground lines, such as compensation techniques by loop of cables and shielding by metallic materials, are also presented. Due the electric field outside the insulated cable be practically zero, issues related to the electric field are not addressed in this work. For simplicity, the magnetic field refers to the magnetic flux density in this document.

This thesis consists of three main studies: magnetic field effects in thermally activated delayed fluorescent (TADF) organic light emitting diodes (OLEDs), magnetic field effects in bipolar and unipolar polythiophene (P3HT) devices and a study of hybrid organic/inorganic perovskite devices. Spin-dependent transport and recombination processes of spin-pair species have been detected by magnetic field effect (MFE) technique in carbon-based semi- conductor devices. Magneto-electroluminescence (MEL) and magneto-conductivity have been measured as a function of the applied magnetic field, B, in light emitting diodes. TADF materials have been used instead of simple fluorescent materials in OLEDs. We have observed very large magnetic response with TADF materials. The second study is magnetic field effects of regio-regular P3HT based OLED devices. P3HT is a well known semiconducting polymer, and its electrical properties such as magneto-conductance can be affected by an applied magnetic field. P3HT was chosen because it exhibits a sign change in magnetoresistance (MR) as the bias is increased. Unipolar and bipolar devices have been fabricated with different electrode materials to understand which model can be best to explain organic magnetoresistance effect, possibly depending on the operating regime of the device. Transport and luminescence spectroscopies were studied to isolate the different mechanisms and identify their fingerprints. The third study is on hybrid organic-inorganic perovskite devices. With the potential of achieving very high efficiencies and the very low production costs, perovskite solar cells have become commercially attractive. Scanning electron microscopy (SEM) images and absorption spectrum of the films were compared in single-step solution, two-step solution and solution-assisted vapor deposition techniques. Grain size, morphology and thickness parameters of perovskite films were studied within these techniques. Perovskite solar cells were fabricated and their efficiencies were measured.

Organic semiconductors (OSCs) have already been shown to have great potential to play an important role in the future of clean energy generation (organic solar cells) and provide energy efficient lighting (organic light-emitting diodes, OLED). Prior research has found that the light-emission efficiency of OLED is severely limited by the magnetic state (technically the spin-configuration) of the light-emission process. In this thesis, we work on the processes using external magnetic fields that can overcome these magnetic limitations. A major focus of this research is to enhance the performance of OLED, while at the same time to unravel the scientific mechanisms by which magnetic fields act on OSCs devices. Thermally activated delayed fluorescence (TADF) is a next-generation OLED emission technology which enables nearly 100% light-emission efficiency without using heavy precious metals. TADF characteristics depend on the probability of reverse intersystem crossing (RISC) from the triplet excited states (T1) to singlet excited states (S1). The conversion (T1 to S1) process depends strongly on spin dynamics, thus we predict a dramatic magnetic field effects (MFEs) in such TADF OLED devices. In subsequent experiments we observed that changes in TADF devices due to various forms of electrical stress can lead to enormous increases in magnetic field effects (MFEs) on the current (> 1400%) and electroluminescence (> 4000%). Our work provides a flexible and inexpensive pathway towards magnetic functionality and field sensitivity in current organic devices. Such OLED pave the way for novel magnetic sensitive OSCs devices with integrated optical, electronic and magnetic characteristics. Organic magnetoresistance (OMAR) has been observed to alter the current and efficiency of OLED without any ferromagnetic components. Here we utilizes slight alterations to the device properties, the addition of a radical-doped functional layer, in which the spin-relaxing effects of localized nuclear spins and electronic spins interfere, to address the assumption about the importance of the hyperfine interaction and to attempt to differentiate between the different models for OMAR. A feature where the magnitude of OMAR exhibits a plateau over a wide range of doping fraction was observed at all temperatures investigated. This phenomenon is well explained by a theory in which a single dopant spin strongly interacts, by exchange, with one of the bottleneck sites. A similar can be used to explain the efficiency increases observed in organic solar cells for certain doping fractions.

It has been found that non-magnetic organic semiconductors can show some magnetic responses in low magnetic field (<100 >mT). When applying magnetic field, the electroluminescence, electrical current, photocurrent, and photoluminescence could change with magnetic field, which are called magnetic field effects. Magnetic field effects are generated through spin-dependent process affected by the internal magnetic interaction. In nonmagnetic materials, hyperfine interaction has been supposed to dominantly affect the spin-dependent process recently. But the conclusion was made in weak spin-orbital coupling organic semiconductor. The hyperfine interaction might not be the main reason responsible for magnetic field effects in strong spin-orbital coupling materials. Therefore, the study of magnetic field effects in strong spin-orbital coupling organic semiconductor is important to get a whole view of the origin of the magnetic field effects in nonmagnetic organic semiconductors. This dissertation will clarify the generation mechanism of magnetic field effect in nonmagnetic organic semiconductors and further explore how the strong spin-orbital coupling affecting the magnetic field effect. It has been found the intermolecular excited states are important inter-median for magnetic field effects. The change of intersystem crossing at intermolecular excited states will change the singlet/triplet ratio and further generate magnetic field effects through different recombination and dissociation properties of singlet and triplet intermolecular excited states. Both the energy transfer effect coupled spin orbital coupling and energy transfer effect free spin orbital-coupling are discussed in the dissertation. The tuning of the magnetic field effect by adjusting the spin-orbital coupling is also established through distance effect and interface effect. It has been found that changing inter-molecular spin-orbital coupling is a critical factor to generate magnetic field effects in organic semiconductors. And the sensitivity of different magnetic field effects to strong spin-orbital coupling strength is depending on the final product. The internal magnetic interaction can be hyperfine interaction, spin orbital coupling and spin-spin interaction between electrons. The hyperfine interaction and spin orbital coupling are important in nonmagnetic organic semiconductors. But the electron spin-spin interaction is important in magnetic organic semiconductors. The magnetocurrent for magnetic and nonmagnetic organic semiconductors at different temperature has been compared.

Recently, technological advancement and the promise of next-generation devices have created an overwhelming push for the continued miniaturization of active systems to the micro- and nanometer scale. In this regime, traditional mechanical systems are largely inaccessible and as a result new active or stimuli-responsive materials are required. The work presented in this dissertation provides an understanding of the responsive nature of polymer and biopolymer interfaces especially in contact with metal nanoparticles. This understanding was utilized in conjunction with top-down template-based and self-assembly fabrication strategies to create hybrid protein based films and active polymer-metal hybrids that exhibit large and well-defined modulation of mechanical and optical properties. These materials processing developments represent advancement in the current state of the art specifically in three major areas: 1. template-based top-down control of protein chain conformation, 2. high-throughput synthesis and assembly of strongly coupled plasmonic nanoparticles with modulated optical properties (both near- and far-field), 3. field-assisted assembly of highly mobile and non-close packed magnetic nanorods with capabilities for rapid actuation.

La tesi s’inicia fent una presentació del comportament dels llits estabilitzats magnèticament i de les seves aplicacions, així com de les limitacions que tenen degut a les pèrdues de les propietats magnètiques en certes condicions.A continuació, es proposa un model matemàtic dels llits fluïditzats estabilitzats magnèticament, basat en la distribució que segueixen les partícules amb les línies del camp. L’estabilització magnètica també s’ha aplicat a llits fluïditzats amb barreges de partícules magnètiques i no magnètiques. S’ha estudiat el comportament d’aquests sistemes, així com la influència de la fracció màssica de material magnètic en el retard en l’aparició del bombolleig. Els resultats obtinguts mostren que l’estabilització magnètica pot aplicar-se no solament a la fluïdització de partícules magnetitzables sinó també a partícules no magnetitzables, si una certa fracció de material magnètic és present en el llit. Es proposen diferents correlacions per al càlcul de la velocitat de transició en funció de les propietats del sistema gas-sòlid i les condicions d’operació.També s’estudia l’efecte del camp magnètic sobre el comportament tèrmic dels llits fluïditzats de partícules magnètiques escalfats amb una superfície calefactora introduïda dins el llit. S’ha determinat la distribució axial i radial de temperatures en el llit. A partir dels resultats experimentals, s’ha desenvolupat un model que permet el càlcul de la conductivitat tèrmica efectiva del llit. A més, mitjançant l’aplicació de l’analogia de Chilton i Colburn a les dades experimentals obtingudes, s’han proposat diferents correlacions per a l’estimació del coeficient de transferència de calor en llits estabilitzats i semi estabilitzats.Finalment, s’ha estudiat experimentalment, mitjançant l’assecament d’aire humit en llits formats per barreges d’alúmina-acer, la transferència de matèria en llits estabilitzats i semi estabilitzats. S’han emprat dos paràmetres, eficiència del llit i factor de eficiència, per comparar el comportament dels diferents tipus de llits. La precisió del model teòric desenvolupat s’ha provat amb els resultats experimentals obtinguts. Els models corresponents als llits fluïditzats clàssics no presenten un bon ajust amb les dades experimentals; ara bé, quan aquests models són modificats tenint en compte l’efecte del camp magnètic, l’ajust amb les dades és molt millor. / First, in this thesis, the behaviour of the magnetically stabilized fluidized bed is presented, as well as its applications; the limitations due to the loss of magnetic properties in certain conditions are also considered.Later, a mathematical model of the magnetically stabilized fluidized bed, based on the arrangement of particles following field lines is proposed. Magnetic stabilization has also been applied to fluidized beds with mixture of magnetisable and non-magnetisable particles. The behaviour of these systems is studied, as well as the influence of the magnetic material mass fraction on the delay of bubbling. The results obtained show that the magnetic stabilization can be applied not only to the fluidization of magnetisable materials but also to non-magnetisable particles, if a certain fraction of magnetisable material is present. Correlations are proposed to calculate the transition velocity as a function of gas-solid properties and operating conditions.Also, the effect of the magnetic field on the thermal behaviour of a fluidized bed of magnetisable particles with an immersed heating surface has been studied. The temperature distribution inside the bed has been determined, both in the radial and axial directions. A model has been developed which allows calculation of the effective thermal conductivity of the bed from experimental data. In addition, by means of the application of the Chilton and Colburn analogy to the experimental data obtained, different correlations for the estimation of the heat transfer coefficient in stabilized and semi-stabilized beds have been proposed.Finally, the mass transfer in magnetically stabilized and semi-stabilized beds has been studied experimentally using the drying of moist air in beds of alumina-steel mixtures. Two parameters, bed efficiency and efficiency factor have been used to compare the behaviour of the different beds. The accuracy of the theoretical model developed has been tested using the results obtained. The models corresponding to the classical fluidized bed do not agree with experimental data; however, when these models are modified to take into account the effect of magnetic stabilization, the accuracy is much better.

Optical spin injection in InAs/GaAs quantum dots (QDs) structures under cryogenic temperature has been investigated in this work using continuous-wave optical orientation spectroscopy. Circularly polarized luminescence from trions in the QDs was used as a measure for the degree of spin polarization of the carriers in the QD ground states. The efficiency of spin conservation of the carriers during the injection process into the QDs and also the influence of the nuclear spins in the QDs were studied both under zero and external magnetic field. It was shown in zero magnetic field that the spin states were less conserved during the injection process for correlated excitons and hot free carriers. While under the external magnetic field, measurements were done in Faraday configuration. Confined electron motion yielding the quantized Landau levels in the InGaAs wetting layer (WL) and lifting of the Landau level spin degeneracy was observed. Also possible spin thermalization in the InGaAs WL during spin injection process was found. Finally, the quench of hyperfine induced spin relaxation by dynamic nuclear polarization (DNP) in the QDs was discovered and believed to be a stronger effect under weak/zero magnetic field.

Effects of a magnetic field on the double-probe technique are studied experimentally by means of symmetric floating computer controlled fast double probes in low and intermediate pressure plasmas. In addition, the effects of the magnetic field on the electron temperature, electron density, and electric field have been investigated. As it is expected, when there is no magnetic field, properties of the discharge plasma are best described by Langmuir theory. Whereas, when there&rsquo / s a magnetic field of sufficient strength Schottky&rsquo / s theory of ambipolar diffusion applies.

The Interplanetary Magnetic Field (IMF) has a controlling effect on the Magnetosphere and Ionosphere. The objective in this work is to investigate the probable effects of IMF on Ionospheric and Geomagnetic response. To fulfill the objective the concept of an event has been created based on the polarity reversals and rate of change of the interplanetary magnetic field components, Bz and By. Superposed Epoch Method (SPE) was employed with the three event definitions, which are based on IMF Bz southward turnings ranging from 6 to 11 nT in order to quantify the effects of IMF By and Bz. For the first event only IMF Bz turnings were taken into account while for the remaining, positive and negative polarity for IMF By were added. Results showed that the increase in the magnitude of IMF Bz turnings increased the drop of F layer critical frequency, f0F2. The drop was almost linear with the increase in magnitude of polarity reversals. Reversals with a positive IMF By has resulted in the continuation of geomagnetic activity more than 4 days, that is to say, the energy, that has penetrated as a consequence of reversal with a positive By polarity, was stored in outer Magnetosphere,whereas, with a negative IMF By the energy was consumed in a small time scale. At the second step of the work, although conclusions about geomagnetic activity could be done, as a consequence of data gaps for f0F2 in addition to having low numbers of events, characterization of f0F2 due to constant IMF By polarity could not be accomplished. Thus, a modeling attempt for the characterization of the response due to polarity reversals of IMF components with the Genetic Programming was carried out. Four models were constructed for different polarity reversal cases and they were used as the components of one general unique model. The model is designed in such a way that given 3 consecutive value of f0F2, IMF By and IMF Bz, the model can forecast one hour ahead value of f0F2. The overall model, GETY-IYON was successful at a normalized error of 7.3%.