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M.Tech. (Mechanical Engineering Technology) / Please refer to full text to view abstract

Submitted in fulfilment of the requirements for the Degree of Master of Technology: Organic Chemistry, Durban University of Technology, 2011. / ortho-Deoxygrisan (38), a spirodienone was synthesised from bisphenol (42) using both conventional and microwave assisted methods. The bisphenol (42) was synthesised from phenol (52) by conventional and microwave assisted methods. Benzophenone (43) was synthesised from compound (49) which in turn was synthesised from compound (53) by chromic acid oxidation in acetic anhydride or acetic acid. Compound (53) was synthesised from bisphenol (42) by mono-acetylation method.Acid-catalysed rearrangement of ortho-deoxygrisan (38) in the absence of light was investigated. Chromatography of the reaction mixture afforded compound (D) as a major component. Attempts to synthesise ortho-grisan (50) from benzophenone (43) were unsuccessful. Microwave assisted selenium dioxide oxidation of compound (53) gave a yellow compound C. The spectra of this compound were very similar to the spectra of ortho-deoxygrisan (38). However, selenium dioxide was reacted with compound (53) in the absence of microwave to give a yellow solid B. The 1H NMR spectral data of this compound led to the proposed structure B for it. / National Research Foundation.

We present Bessel function and Gaussian beam models for a study of microwave power deposition in bounded and inhomogeneous lossy media. The aim is to develop methods that can accurately simulate practical results commonly found in electromagnetic hyperthermic treatment, which is a noninvasive method. The Bessel function method has a closed form solution and can be used to compute accurate results of electromagnetic fields emanating from applicators with cosinusoidal aperture fields. On the other hand, the Gaussian beam method is approximate but has the capability to simplify boundary value problems and to compute fields in three-dimensions with extremely low CPU time (less than 30 sec). Although the Gaussian beam method is derived from geometrical optics theory, it performs very well in domains outside the realm of geometrical optics which stipulates that aperture dimension/λ ≥ 5 in the design of microwave systems. This condition has no relevance to the Gaussian beam method since the method shows that a limit of aperture dimension/ λ ≥ 0.9 is possible, which is a very important achievement in the design and application of microwave systems. Experimental verifications of the two theoretical models are integral parts of the presentation and show the viability of the methods.

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Thesis (Ph. D.)--Washington State University. / Includes bibliographical references.

M. Tech. Chemical Engineering. / Aims of this study is to determine the relationship between the temperature of the coal coke (and other mixtures) and the measured microwave impedance in the waveguide feeding the applicator.

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This study was designed to develop some predictive models for the dielectric properties of the chemicals and chemical reactions and make use of dielectric properties and microwave irradiation in the chemical reactions. Specifically, the dielectric properties of the following systems were investigated at microwave frequencies of 2450 and 915 MHz: (1) C1--C5 alcohols, (2) glucose aqueous solutions, (3) lysine aqueous solutions, (4) mimicked esterification reaction model systems of parahydroxybenzoic acid with methanol, 1-propanol and 1-butanol in the presence of para-toluene sulfonic acid as a catalyst, (5) Maillard reaction model system consisting of glucose, lysine and water. / The dielectric properties of the model systems showed that they depended on the frequency applied, concentration of the material, and temperature. Most of the predictive models showed that there exists a linear or quadratic relationship between dielectric constant and concentration or temperature. However, the quadratic equation is better than the linear one to describe the variation of the loss factor with temperature or concentration. / Esterification showed great advantages for the use of microwave irradiation in chemical reaction. It included reduction in reaction time, and provided distinct temperature profiles due to microwave environment during chemical reactions. The reason for rate enhancement of this type of reaction was also demonstrated from the temperature profile. / Microwave-assisted solvent free Maillard reaction model system, consisting of glucose and lysine, demonstrated that the heating method applied was not one of the crucial factors, but the temperature level was important during the chemical reaction. / The relationship of loss factor with yield of reaction showed that it is possible to use dielectric data to analyze, and monitor the chemical reaction. It provided a new methodology to analyze the reaction. / The relationship between the loss factor, loss tangent and the reaction time, and concentration of the material showed that it is also possible to use dielectric data at microwave frequencies of 2450 and 915 MHz to study chemical reactions, especially the kinetics.