Orientador: Saul Barisnik Suslick / Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecanica e Instituto de Geociencias / Made available in DSpace on 2018-08-12T11:55:27Z (GMT). No. of bitstreams: 1 Gaspar_AnaTeresaFerreiradaSilva_D.pdf: 2070944 bytes, checksum: abd840647c52a6c6cf1fc318f0e0a772 (MD5) Previous issue date: 2007 / Resumo: Esta tese apresenta um estudo da viabilidade técnica e econômica da Recuperação Avançada de Óleo (EOR) em um pequeno projeto localizado em um campo maduro no Brasil. O estudo considera duas motivações importantes e complementares: (1) a recuperação avançada de óleo por meio da injeção de CO2 - o gás desloca o óleo residual deixado no local após a produção primária e injeção secundária de água (waterflooding); (2) o armazenamento deste gás no reservatório de óleo e, conseqüente contribuição para a mitigação de emissões de CO2. Os aspectos físicos deste projeto são descritos e um modelo de simulação dinâmica foi desenvolvido para modelar o comportamento do sistema seqüestro de CO2 - EOR ao longo do tempo. Este modelo leva em conta os requisitos de energia para todo o processo de seqüestro de CO2 e suas respectivas emissões inerentes ao processo. Adicionalmente, uma metodologia é proposta para estimar os principais determinantes financeiros do projeto de seqüestro de CO2 (custos de compra do CO2, compressão, transporte e armazenamento) por meio de EOR. A avaliação do projeto é derivada de um modelo de fluxo de caixa, levando-se em conta o perfil de produção do reservatório, preço, custos de capital (CAPEX), custos operacionais (OPEX), créditos de CO2, depreciação, premissas fiscais etc. Um estudo de análise de sensibilidade é realizado para identificar as variáveis mais críticas. A viabilidade econômica do projeto, como esperado, é muito sensível ao preço do óleo, produção de óleo e CAPEX. Além disso, há a contribuição para a mitigação do gás de efeito estufa (GEE), armazenando uma quantidade significativa de CO2 no reservatório onde pode permanecer por milhares de anos. / Abstract: This thesis presents a technical and economic feasibility study for CO2 EOR in a small project located in a mature oilfield in Brazil. The present study considers two important and complementary motivations: (1) EOR - CO2 displaces residual oil left in place after primary production and secondary water flooding; (2) storage of this gas in the oil reservoir and hence, contributing to mitigate CO2 emissions. The physical aspects of this project are described and a dynamic simulation model has been developed in order to model the behavior of the CO2 Sequestration - EOR system and its emissions due to the process over time. This model takes into account the energy requirements for the whole CO2 sequestration process. Additionally, a breakdown cost methodology is proposed in order to estimate the main financial determinants of the integrated EOR with CO2 sequestration (costs of CO2 purchase, compression, transportation and storage). Project evaluation is derived from a cash flow model, regarding reservoir production profile, price and costs, capital expenditures (CAPEX), operating expenditures (OPEX), carbon credits, depreciation time, fiscal assumptions etc. A sensitivity analysis study is carried out in order to identify the most critical variables. Project feasibility, as expected, is found to be very sensitive to oil price, oil production, and CAPEX. Moreover, there is the contribution from the mitigation of the Green House Gas (GHG) by storing a significant amount of CO2 in the reservoir where it can remain for thousands of years. / Doutorado / Reservatórios e Gestão / Doutor em Ciências e Engenharia de Petróleo

There is an urgent need to mitigate carbon emissions to the atmosphere to reduce the negative effects of climate change. Countries have pledged national strategies to reach their climate change mitigation goals in their Nationally Determined Contributions (NDC). In the case of Colombia, the country envisions becoming carbon neutral by 2050.  A pathway to reach this goal is emission reduction through nature-based solutions (NBS). Biochar is an NBS with the potential to be used as a land-based emission mitigation technology. Records indicate that it was first used by indigenous communities in the Amazon about a thousand years ago. Biochar can be obtained through thermochemical conversion by slow pyrolysis of residual biomass. The original organic carbon present in the biomass is sequestered in the biochar as it is pyrolyzed and thus, CO2 emissions are prevented. Biochar is not yet considered in Colombia´s carbon neutrality strategy. The aim of this thesis project is to investigate the potential of biochar production in Colombia as a land-based mitigation technology (LMT). Therefore, a comprehensive assessment is performed with the purpose of identifying the status of biochar in the country. The motivation behind the assessment is to gain an understanding of the variables involved in biochar production. Factors such as the production sectors involved, feedstocks, production technologies, project costs and emission mitigation are of interest. The study explores these factors by following five methodological steps. First, the current research on the technology is mapped to understand biochar’s status at a national level. Second, experts are interviewed to collect their views regarding biochar and a PESTEL (Political, Economic, Social, Technological, Environmental & Legal) analysis is employed based on their point of view on the technology. Third, the potential sources of residual biomass which could be used to produce biochar in the agricultural sector are quantified. The approach to biochar’s potential is enriched with a focused in-person case study of biochar production from oil palm residues. Fourth, these residual biomass sources are subsequently employed to estimate the emissions sequestered in their biochar production. Lastly, project feasibility implementation is evaluated through a techno-economic to identify the project’s main cost drivers. The results are then discussed using a SWOT (Strength, Weaknesses, and Opportunities & Threats) analysis. The existing studies and the local experts’ opinion indicate that biochar potential is in the agricultural sector and that it can be thought of for soil adaptation. Biochar’s emission mitigation is considered an added value. In 2021, the agricultural sector produced near 73 million tonnes of agricultural products. The residues from agriculture could be used for biochar production. If the residues from the most produced agricultural products are transformed into biochar, about 1 to 2,2 tonne of CO2 per tonne of biochar could be avoided. The published literature and the in-person study visit confirmed that the largest advance in biochar production and use in Colombia is in the oil palm sector. Palm kernel shell, fibre and empty fruit bunches are the oil palm residues that could be used to produce biochar. From 1 tonne of these three oil palm residues, about 60 kg of biochar can be obtained. The results show that currently there is no market for trading with biochar in Colombia. High investments, transport and feedstock costs are identified obstacles. An Advanced Technology pyrolizer cost can cost around 330.000 USD while a Basic Technology one can be around 100 USD. Taxes associated with revenue from the biochar trade can negatively impact a biochar project’s feasibility. In this study, a price for biochar is estimated using break-even analysis. Under the assumptions used, the biochar price per tonne is around 200 to 1.000 USD. Price variability is explained in the technologies used for production, feedstock biomass availability and variable revenues from biochar sales. / Koldioxidutsläppen till atmosfären behöver minskas för att undvika de negativa effekterna av klimatförändringar. Olika länder har presenterat på sina nationellt fastställda bidrag (NDC) hur sina mål för begränsning av klimatförändringarna skulle kunna uppnås. I Colombia är planen att uppnå koldioxidneutralitet år 2050. Ett sätt att uppnå detta mål är att minska utsläpp genom naturbaserade lösningar (NBS). Biokol är en NBS som kan användas som landbaserade åtgärder för att minska växthusgasutsläpp eller öka koldioxidupptag. Forskning har bevisat att biokol användes i Amazonas för ungefär tusen år sedan. Biokol framställs genom långsam pyrolys av restprodukter av biomass. Kolet i biomassan binds i biokolet genom pyrolysis, vilket förhindrar koldioxidens utsläppning till atmosfären. Biokol inkluderas ännu inte i Colombias strategi för koldioxidneutralitet. Syftet med detta projekt är att undersöka biokolets produktionspotential i Colombia son ett landbaserade åtgärder (LMT). En analys gjordes för att identifiera statusen av biokol runt om i landet. Faktorer såsom berörda produktionssektorer, råvaror, produktionstekniker, projektkostnader och koldioxidutsläppen var av intresse. Studien undersöker faktorerna ovan genom att tillämpa en femstegsmetod. Först identifierades den aktuella forskningen om biokol i Colombia. Sedan intervjuades experter för att samla in deras åsikter om biokol och en PESTEL analys (Political, Economic, Social, Technological, Environmental & Legal) användes. Nästa steg i metoden var att kvantifiera potentialen av restprodukter inom jordbrukssektorn. Detta steg kompletterades med en fallstudie som fokuserade på biokolproduktion från rester från oljepalmer och sedan beräknades utsläppen som binds i biokol. Till sist utvärderades projektets genomförbarhet genom en teknoekonomisk analys som identifierade viktigaste drivkrafterna bakom kostnaderna. Resultaten diskuterades med hjälp av en SWOT analys (Strength, Weaknesses, and Opportunities & Threats). Experter och forskningsresultat om biokol i Colombia anger att det finns stor potential nom jordbrukssektor där biokol skulle kunna användas för jordförbättring, medan utsläppsminskningar endast anses vara en ytterligare fördel. År 2021 Colombias jordbrukssektor producerade nästan 73 millioner tonne av jordbruksprodukter och restprodukter från jordbruket kan användas för produktion av biokol. För varje ton biokol som produceras undviks ungefär 1 till 2,2 tonne koldioxid. Litteraturen och studiebesöket bekräftade att största framsteget inom produktion och användning av biokol i Colombia händer inom oljepalmssektorn. Palmkärnor, fibrer och tomma fruktknippar är restprodukterna som kan användas för att producera biokol. En ton av dessa tre typer av oljepalmsrester ger cirka 60 kg biokol. Resultaten visar att det inte finns en marknad för biokol i Colombia. Höga investeringskostnader, transport-och råvarukostnader är främsta hindarna som identifierades. En pyrolysanläggning med avancerad teknik kostar cirka 330 000 US-dollar, medan en pyrolysanläggning med grundläggande teknik kostar cirka 100 US -dollar. Skatter på inkomster från biokolsförsäljning kan ha en negativ effekt på genomförbarhet. Studien uppskattas ett pris för biokol med hjälp av en break-even-analys och visar att cirka 200 till 1.000 USD per tonne biokol vore ett möjligt prisintervall. Prisvariationerna förklaras av tekniken som används för produktion, tillgång på biomassa som råvara och varierande intäkter från biokolförsäljning.