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Electrodeposition of platinum-based catalysts for polymer electrolyte membrane fuel cellsThompson, Scott Damon, 1976- January 2003 (has links)
Abstract not available
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The development of a biofuels engine testing facilityPalmer, Duncan 12 1900 (has links)
Thesis (MScEng (Process Engineering))--Stellenbosch University, 2008. / This report covers the development of a biofuels engine testing facility at Stellenbosch
University. The motivation for the project was three fold: a) a desire to establish biofuels
and engine testing know-how; b) to test the performance characteristics of biodiesel; and
c) make a facility available for future research. The two main conclusions drawn from the
initial test results are: 1) the test cell is fully operational and 2) biodiesel can be
substituted for mineral diesel. To the author’s knowledge this is the first biofuel specific
engine testing facility in South Africa.
After a literature study the test cell was realised in three phases.
• Firstly, the hardware layout was designed and the necessary equipment was
sourced from respectable suppliers including the judicious use of good qaulity
second hand components to minimize capital cost.
• The test cell was then instrumented with new sensors. Key components among
these are the K-type thermocouples, barometric pressure, humidity, oil pressure
and an Allen-Bradley programmable controller to serve as a data acquisition
card. Two software programs were chosen, ETA for the control of the test cell
and RSLogix to program the programmable logic controller (PLC).
• The complete system was then integrated, debugged and validated.
The design methods and procedures have been documented throughout the project
along with user manuals to facilitate further research.
To determine the difference in combustion parameters between biodiesel and mineral
diesel an autonomous power curve test was conducted. This revealed little difference in
terms of performance between the two fuels, although biodiesel had on average a
marginal 0.4% decrease in power over mineral diesel. The fuel consumption for pure
biodiesel was found to be higher, which is as expected as it is has a lower calorific value
than mineral diesel.
As a final validation, an energy balance was conducted. Here the calculated calorific
value of biodiesel was compared to the results from a calorie bomb test, and the two
results were found to be within 2% of each of other. / Centre for Renewable and Sustainable Energy Studies
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Reducing emissions of older vehicles through fuel system conversion to natural gasUdell, Thomas Gregory 05 1900 (has links)
No description available.
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A comparative study on the performance of biodiesel in a modern 1.9L turbo diesel engineKotze, Johan 03 1900 (has links)
Thesis (MScEng (Mechanical and Mechatronic Engineering))--University of Stellenbosch, 2010. / ENGLISH ABSTRACT: This thesis comprises of the testing and evaluation of a modern diesel engine running on both biodiesel and mineral diesel on the upgraded Bio-fuels Testing Facility (BTF) at Stellenbosch University. The project was motivated by the need to install a modern diesel engine onto the existing BTF test rig for biodiesel testing. In this project, the BTF was re-designed to support a new Volkswagen 1.9L TDI engine. The capabilities of the BTF were then expanded further by the implementation of a low-cost pressure indicating system, utilising an optical pressure transducer. During the testing of biodiesel, it was found that the calorific value of the biodiesel was 14% lower than that of the tested mineral diesel. The ignition quality (cetane index) of the biodiesel was also lower than that of the mineral diesel. Even so, the engine only experienced a maximum power loss of 4.2%. During heat-release analysis, it was determined that there was no significant difference in the combustion process of biodiesel and that of mineral diesel. The conclusion could be made that biodiesel is suitable for use in modern TDI engines. Testing validated the operation of the upgraded test cell, and in trials it was determined that the test results are highly repeatable. The pressure indicating set proved to have some limitations. Only simplified heat-release analyses and reasonable indicated power calculations could be performed with the indicating set. Recommendations were made for improvement in future research. / Centre for Renewable and Sustainable Energy Studies
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Refueling and evaporative emissions of volatile organic compounds from gasoline powered motor vehiclesQuigley, Christopher John, 1962- 29 August 2008 (has links)
The United States Environmental Protection Agency has estimated that over 111 million people reside in areas that exceed the National Ambient Air Quality Standards for ozone. One major source of the chemical precursors (nitrogen dioxides and volatile organic compounds (VOCs)) for ozone are motor vehicles. The overall goal of this research is to improve the knowledge base related to VOC refueling and evaporative emissions from motor vehicles. Refueling, running loss, hot soak, and diurnal loss total and speciated VOC emissions were investigated. A total of 12 uncontrolled refueling events were completed and involved the determination of volumetric flow rates of gasoline vapor during refueling, as well as total and speciated VOC concentrations. Total VOC emissions were compared with two commonly used algorithms. Speciated VOC vapor profiles were compared with two published gasoline vapor profiles and theoretical predictions based on knowledge of liquid composition and environmental conditions. An evaluation of refueling emissions impacts on ozone formation potentials using MIR was completed and results were compared against speciated emissions and MOBILE-based total VOC emissions estimates coupled with a default speciation profile. Refueling VOC emissions and resultant ozone formation potential may be underestimated in existing emission inventories, particularly during the summer ozone season, A model was developed to predict the speciation of VOCs associated with evaporative emissions from motor vehicles. Model-predicted speciation profiles were evaluated using SHED studies. Running loss, hot soak and diurnal emissions were included in each test. Total VOC emissions measured during each test were compared against MOBILE6 predicted emissions. An evaluation of evaporative emissions impacts on ozone formation potentials using MIR was completed, comparing measured and predicted emissions. The measured:predicted speciation results ranged between 0.93 and 1.11 and had an average value of 1.02. For the conditions tested, MOBILE6 underestimated evaporative emissions in 20 of 24 comparisons. MOBILE6-based ozone formation potentials may be underestimated.
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