No description available.

No description available.

No description available.

No description available.

No description available.

No / A crystalline solid called a gas hydrate has gas molecules surrounded by water molecules. There are several gases with suitable structures for the production of hydrates, but methane-rich gas hydrates are more common and form in seas and on the ocean. The place of hydrates formation is usually the sediment of the ocean floor and the polar regions, which largely covered with ice. It is also found in large quantities in combination with ambient ice in the ever-frozen polar regions. The importance of gas hydrates is due to the great ability of gas hydrates in natural gas storage, which makes it attractive to use them for the purposes of storing and transporting natural gas and other gases as a competitor to liquefaction and condensing methods. Due to the significance potential of these reserves as the world's future energy supplier and their direct impact on changes in climate conditions due to the greenhouse effect of methane, as well as their geological risks during water hydrocarbon discoveries, marine science researchers have been studying them over the past few years. Acoustic and seismic methods are helpful instruments for measuring subterranean hydrated reserves because there is not the technology to measure hydrated reserves directly.

The effects of a DC voltage on the catalytic combustion rate of natural gas in air over a platinum wire in various configurations is examined. In most cases a high applied voltage reduces and quenches the catalytic reaction. These effects are dependent on the catalyst surface charge density but not on the direction of the field. Greater effects were also observed when the field was applied on the upstream rather than the downstream side of the catalyst. Although the mechanism of this quenching effect is unknown, it is suggested that it involves the generation and diffusion of charged gas-phase species and their interaction with the catalyst surface. Possible quantum effects are also discussed. Further work to verify or refute the mechanisms presented here is suggested. / Master of Science

This study attempts to show that judicial review of administrative decisions has provided the greatest degree of protection for consumers during the time that natural gas has been subject to regulation by the Federal Power Commission. The first part of the investigation deals with the activities of the regulatory agency since controls were established in 1938. It continues with a discussion of the influence of consumer and producer interests on the legislative process. The contributions of the courts to policy-making is discussed in the following section. The report concludes that more protection from the political environment could be realized by placing the major responsibility for the regulatory program in the hands of the Executive branch.

The present dissertation covers three research topics on catalytic environmental emissions control, including (1) aging and regeneration mechanisms of Rh- and Pd- model three-way catalysts (TWC) for gasoline automotive emission control, (2) catalytic methane emissions abatement from natural gas vehicles, and (3) scale-up of CO₂ capture and methanation using dual functional catalytic materials. The study resulted in two peer-reviewed publications, two future papers and one patent application which is currently under review. Modern TWC use supported two separate catalyst layers on a monolith containing one Pd and the other Rh for the emissions control of CO, HC and NOₓ. The rhodium (Rh) metallic component (active for NOₓ reduction) experiences the most severe oxidative thermal deactivation (forming inactive Rh³⁺) during fuel cutoff, an engine mode (e.g., at downhill coasting) used for enhancing fuel economy. In a subsequent switch to a slightly fuel rich condition, in situ catalyst regeneration is accomplished by the reduction of the Rh³⁺ with H₂ generated through steam reforming catalyzed by residual Rh⁰ sites. The present thesis reports the effects of the deactivation and regeneration processes on the activity, stability and structural properties of 0.5% Rh/Al₂O₃ and 0.5% Rh/Ce_xO_y-ZrO₂ (CZO) as model catalysts. Both materials are used to varying extents in modern TWC. A very brief introduction of three-way catalysis and system considerations will be presented. During simulated fuel cutoff, catalyst deactivation is accelerated with increasing aging temperature from 800 °C to 1050 °C. Rh on a CZO support experiences less deactivation and faster regeneration than Rh on Al₂O₃. Catalyst characterization techniques including BET surface area, CO chemisorption, temperature programmed reduction, and x-ray photoelectron spectroscopy, transmission electron microscopy, scanning-electron microscopy, and x-ray diffraction measurements were applied to examine the role of metal-support interactions in each catalyst system. For Rh/Al₂O₃, strong metal-support interactions leading to the formation of a stable rhodium aluminate (Rh(AlO₂)_y) complex dominates during fuel cutoff, resulting in more difficult catalyst regeneration (reduction). For Rh/CZO, Rh sites were partially oxidized to Rh₂O₃ and were relatively easy to be reduced to active Rh⁰ during regeneration. Moderate Pd and support sintering of Pd-Ce_xO_y is experienced upon aging, but with a minimal effect on the catalyst activity. Cooling in air, following aging, was not able to reverse the metallic Pd sintering by re-dispersing to PdO. Unlike the aged Rh-TWCs, reduction via in situ steam reforming (SR) of exhaust HCs was not effective in reversing the deactivation of aged Pd/Al₂O₃, but did show a slight recovery of the Pd activity when CZO was the carrier. The Pd⁺/Pd⁰ and Ce³⁺/Ce⁴⁺ couples in Pd/CZO are reported to promote the catalytic SR by improving the redox efficiency during the regeneration, while no such promoting effect was observed for Pd/Al₂O₃. A suggestion is made for improving the catalyst performance. The use of natural gas for vehicle applications is growing in popularity due to advanced fracking technology. Exhaust methane has been excluded from regulations since it does not participate in photochemical reactions. New vehicle environmental regulations are expected for controlling methane emissions given their contribution to the greenhouse gas effects. Methane is extremely resistant to oxidation when the natural gas-fueled engine operates in the stoichiometric mode with a supported Rh-Pd three-way catalyst (TWC). Furthermore, vehicles will still operate with fuel cutoff (for enhanced fuel economy), resulting in thermal oxidative deactivation (1050 °C) of the Rh metal in TWC to inactive Rh³⁺, resulting in a loss of both NOₓ and methane abatement activity. When the engine returns to the slightly rich mode, H₂ generated by methane steam reforming does not readily occur to reduce and regenerate the Rh. We report a solution to methane emissions abatement by catalytic reforming of an injected aqueous solution of ethanol into the simulated exhaust stream in TWC mode, which generates sufficient H₂ to regenerate especially Rh by reducing Rh³⁺ to its metallic active state. Conventional CO₂ capture and sequestration (CCS) in aqueous alkaline solutions is a very energy-intensive process with relative unstable performance and low efficiency especially for power plant effluents, and therefore there is a need for new approaches to control green house gas emissions of CO₂. Here we report on progress with an advanced technology involving CO₂ adsorption from flue gas and synthetic natural gas production, via methanation, both performed at the same temperature with the addition of renewable H₂ and by using a dual functional material (DFM). The stored H₂ used is produced by water electrolysis during those times when solar, wind, and other alternative energies generate excess power out of phase with the direct use of the electricity. The DFM is composed of nano-dispersed CaO (or Na₂CO₃) and Ru metal supported on γAl₂O₃ carrier, respectively functioning as the CO₂ adsorbent and methanation catalyst. The present paper focuses on a laboratory scale-up study by using a simulated flue gas and 5%Ru,10%CaO/Al₂O₃ and 5% Ru,10%Na₂CO₃/Al₂O₃ DFM samples. The effects of DFM preparation methods, Al₂O₃ carrier materials (with different shapes and properties), and adsorption and methanation conditions (feed compositions, flow rates, reaction temperatures) on the DFM performance were examined. Samples were prepared using chloride precursor salts and showed stable performance under pseudo scale-up conditions, with SASOL TH100 Al₂O₃ (with the highest BET surface area and pore volume/radius among the support materials) exhibiting the best performance. Compared to Ru-CaO, Ru-Na₂CO₃ based DFM materials showed improved CO₂ utilization and methanation production. Reaction conditions were explored to find optimized CO₂ adsorption and methanation.

The cryogenic carbon capture™ (CCC) process provides energy- and cost-efficient carbon capture and can be configured to provide an energy storage system using an open-loop natural gas (NG) refrigeration system, which is called energy storing cryogenic carbon capture (CCC-ES™). This investigation focuses on the transient operation and especially on the dynamic response of this energy storage system and explores its efficiency, effectiveness, design, and operation. This investigation included four tasks.The first task explores the steady-state design of four different natural gas liquefaction processes simulated by Aspen HYSYS. These processes differ from traditional LNG process in that the CCC process vaporizes the LNG and the cold vapors return through the LNG heat exchangers, exchanging sensible heat with the incoming flows. The comparisons include costs and energy performance with individually optimized processes, each operating at three operating conditions: energy storage, energy recovery, and balanced operation. The second task examines steady-state and transient models and optimization of natural gas liquefaction using Aspen HYSYS. Steady-state exergy and heat exchanger efficiency analyses characterize the performance of several potential systems. Transient analyses of the optimal steady-state model produced most of the results discussed here. The third task explores transient Aspen HYSYS modeling and optimization of two natural gas liquefaction processes and identifies the rate-limiting process components during load variations. Novel flowrate variations included in this investigation drive transient responses of all units, especially compressors and heat exchangers. Model-predictive controls (MPC) effectively manages such heat exchangers and compares favorably with results using traditional controls. The last task shows how an unprocessed natural gas (NG) pretreatment system can remove more than 90% of the CO2 from NG with CCC technology using Aspen Plus simulations and experimental data. This task shows how CCC-based technology can treat NG streams to prepare them for LNG use. Data from an experimental bench-scale apparatus verify simulation results. Simulated results on carbon (CO2) capture qualitatively and quantitatively agree with experimental results as a function of feedstock properties.