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Avaliação do efeito de tratamentos superficiais na resistência à corrosão de magnetos de Nd-Fe-B / Assessment of the effect of surface treatments on the corrosion resistance of Nd-Fe-B Magnets.Martins, Emerson Alves 13 May 2009 (has links)
Magnetos de Nd-Fe-B produzidos por metalurgia do pó são altamente susceptíveis à corrosão devido à porosidade intrínseca e à sua microestrutura complexa. Por outro lado, tais ímãs apresentam excelentes propriedades magnéticas tendo por isso várias aplicações. Na área nuclear, os ímãs permanentes à base de terras raras-metais de transição-boro (Nd-Fe-B) são utilizados na fabricação de suportes magnéticos (levitação magnética) para ultra-centrífugas utilizadas no enriquecimento isotópico do urânio natural de utilização em reatores nucleares. Em Odontologia são utilizados para fixar próteses totais e parciais sobre implantes, em Ortodontia, para corrigir maloclusões e fazer movimentações dentárias e em Cirurgia buco-maxilo-facial para fixar próteses de grandes defeitos da face. Em equipamentos eletrônicos, os magnetos são utilizados em balanças, cadeados, motores elétricos e principalmente na confecção de discos rígidos de computadores.Diante disso, o objetivo deste trabalho foi avaliar o comportamento de corrosão do magneto e testar tratamentos superficiais a fim de substituir principalmente os tratamentos com cromato que hoje em dia não estão sendo mais utilizados principalmente devido à sua toxicidade e altos custos dos tratamentos dos resíduos. A avaliação da resistência à corrosão foi feita através da análise de curvas de polarização potenciodinâmica, espectroscopia de impedância eletroquímica, medidas de potencial de corrosão versus tempo e microscopia eletrônica de varredura a fim de associar a microestrutura ao comportamento de corrosão apresentado pelas amostras. Os resultados obtidos mostram que estes magnetos são altamente susceptíveis à corrosão e esta ocorre preferencialmente na fase rica em Nd, localizada nos contornos da fase matriz e magnética (). Tratamentos para proteção da superfície com revestimento de silano, revestimento de conversão de cério, moléculas auto-organizáveis (SAM), Cr hexavalente, fosfato tricatiônico seguido por passivação em solução de trióxido de cromo, e revestimento de fosfato obtido por imersão por 24 h em solução de NaH2PO4 (pH= 3,8) seguido de imersão em solução de sulfato de zinco não melhoraram a resistência à corrosão do magneto. Dentre os tratamentos utilizados, o de fosfatização por 24h em solução de NaH2PO4 (pH= 3,8) foi muito superior, conferindo maior proteção contra corrosão quando comparado com os outros tipos de tratamentos testados. ABSTRACT Nd-Fe-B magnets produced by powder metallurgy are highly susceptible to corrosion due to their complex microstructure and intrinsic porosity due to their fabrication process. Moreover, these magnets have excellent magnetic properties and find many applications. In the nuclear area, permanent magnets based on rare earth transition-iron-boron (Ne-Fe-B) are used in the manufacture of magnetic media (magnetic levitation) for ultra-centrifuges used for isotopic enrichment of uranium employed in nuclear reactors. In dentistry these types of magnets are used to fix total and partial prostheses on implants; in orthodontics to correct dental malocclusion and make moves; in buco-maxillo-facial surgery for setting facial prostheses of large defects of the face. In electronic equipment, they are used in scales, locks, electric motors and particularly in the manufacturing of hard drives of computers. The objective of this study is to evaluate the corrosion resistance of the magnet tested and surface treatments that could replace chromating that generates toxic residues and present high cost of processing waste with treatments that are environmentally friendly. The evaluation / Nd-Fe-B magnets produced by powder metallurgy are highly susceptible to corrosion due to their complex microstructure and intrinsic porosity due to their fabrication process. Moreover, these magnets have excellent magnetic properties and find many applications. In the nuclear area, permanent magnets based on rare earth transition-iron-boron (Ne-Fe-B) are used in the manufacture of magnetic media (magnetic levitation) for ultra-centrifuges used for isotopic enrichment of uranium employed in nuclear reactors. In dentistry these types of magnets are used to fix total and partial prostheses on implants; in orthodontics to correct dental malocclusion and make moves; in buco-maxillo-facial surgery for setting facial prostheses of large defects of the face. In electronic equipment, they are used in scales, locks, electric motors and particularly in the manufacturing of hard drives of computers. The objective of this study is to evaluate the corrosion resistance of the magnet tested and surface treatments that could replace chromating that generates toxic residues and present high cost of processing waste with treatments that are environmentally friendly. The evaluation of the corrosion resistance was carried out through the analysis potentiodynamic polarization curves, electrochemical impedance spectroscopy, monitoring of corrosion potential as a function of test time and scanning electron microscopy to try to correlate the magnet microstructure with its corrosion resistance. The results show that these magnets are highly susceptible to corrosion that occurs preferentially in the Nd-rich phase, located in the boundaries of the magnetic matrix phase (). Treatment with silane, cerium, sam, Cr 6+, tricationic phosphate followed by bath of chromium trioxide and in NaH2PO4 solution for 24 hours followed by bath of zinc sulphate did not improve the corrosion resistance of the magnet. Among the treatments used, immersion in NaH2PO4 solution for 24 hours pH=3.8 was the one that provided the best corrosion protection against corrosion, when compared with the other types of tested treatments.
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Avaliação do efeito de tratamentos superficiais na resistência à corrosão de magnetos de Nd-Fe-B / Assessment of the effect of surface treatments on the corrosion resistance of Nd-Fe-B Magnets.Emerson Alves Martins 13 May 2009 (has links)
Magnetos de Nd-Fe-B produzidos por metalurgia do pó são altamente susceptíveis à corrosão devido à porosidade intrínseca e à sua microestrutura complexa. Por outro lado, tais ímãs apresentam excelentes propriedades magnéticas tendo por isso várias aplicações. Na área nuclear, os ímãs permanentes à base de terras raras-metais de transição-boro (Nd-Fe-B) são utilizados na fabricação de suportes magnéticos (levitação magnética) para ultra-centrífugas utilizadas no enriquecimento isotópico do urânio natural de utilização em reatores nucleares. Em Odontologia são utilizados para fixar próteses totais e parciais sobre implantes, em Ortodontia, para corrigir maloclusões e fazer movimentações dentárias e em Cirurgia buco-maxilo-facial para fixar próteses de grandes defeitos da face. Em equipamentos eletrônicos, os magnetos são utilizados em balanças, cadeados, motores elétricos e principalmente na confecção de discos rígidos de computadores.Diante disso, o objetivo deste trabalho foi avaliar o comportamento de corrosão do magneto e testar tratamentos superficiais a fim de substituir principalmente os tratamentos com cromato que hoje em dia não estão sendo mais utilizados principalmente devido à sua toxicidade e altos custos dos tratamentos dos resíduos. A avaliação da resistência à corrosão foi feita através da análise de curvas de polarização potenciodinâmica, espectroscopia de impedância eletroquímica, medidas de potencial de corrosão versus tempo e microscopia eletrônica de varredura a fim de associar a microestrutura ao comportamento de corrosão apresentado pelas amostras. Os resultados obtidos mostram que estes magnetos são altamente susceptíveis à corrosão e esta ocorre preferencialmente na fase rica em Nd, localizada nos contornos da fase matriz e magnética (). Tratamentos para proteção da superfície com revestimento de silano, revestimento de conversão de cério, moléculas auto-organizáveis (SAM), Cr hexavalente, fosfato tricatiônico seguido por passivação em solução de trióxido de cromo, e revestimento de fosfato obtido por imersão por 24 h em solução de NaH2PO4 (pH= 3,8) seguido de imersão em solução de sulfato de zinco não melhoraram a resistência à corrosão do magneto. Dentre os tratamentos utilizados, o de fosfatização por 24h em solução de NaH2PO4 (pH= 3,8) foi muito superior, conferindo maior proteção contra corrosão quando comparado com os outros tipos de tratamentos testados. ABSTRACT Nd-Fe-B magnets produced by powder metallurgy are highly susceptible to corrosion due to their complex microstructure and intrinsic porosity due to their fabrication process. Moreover, these magnets have excellent magnetic properties and find many applications. In the nuclear area, permanent magnets based on rare earth transition-iron-boron (Ne-Fe-B) are used in the manufacture of magnetic media (magnetic levitation) for ultra-centrifuges used for isotopic enrichment of uranium employed in nuclear reactors. In dentistry these types of magnets are used to fix total and partial prostheses on implants; in orthodontics to correct dental malocclusion and make moves; in buco-maxillo-facial surgery for setting facial prostheses of large defects of the face. In electronic equipment, they are used in scales, locks, electric motors and particularly in the manufacturing of hard drives of computers. The objective of this study is to evaluate the corrosion resistance of the magnet tested and surface treatments that could replace chromating that generates toxic residues and present high cost of processing waste with treatments that are environmentally friendly. The evaluation / Nd-Fe-B magnets produced by powder metallurgy are highly susceptible to corrosion due to their complex microstructure and intrinsic porosity due to their fabrication process. Moreover, these magnets have excellent magnetic properties and find many applications. In the nuclear area, permanent magnets based on rare earth transition-iron-boron (Ne-Fe-B) are used in the manufacture of magnetic media (magnetic levitation) for ultra-centrifuges used for isotopic enrichment of uranium employed in nuclear reactors. In dentistry these types of magnets are used to fix total and partial prostheses on implants; in orthodontics to correct dental malocclusion and make moves; in buco-maxillo-facial surgery for setting facial prostheses of large defects of the face. In electronic equipment, they are used in scales, locks, electric motors and particularly in the manufacturing of hard drives of computers. The objective of this study is to evaluate the corrosion resistance of the magnet tested and surface treatments that could replace chromating that generates toxic residues and present high cost of processing waste with treatments that are environmentally friendly. The evaluation of the corrosion resistance was carried out through the analysis potentiodynamic polarization curves, electrochemical impedance spectroscopy, monitoring of corrosion potential as a function of test time and scanning electron microscopy to try to correlate the magnet microstructure with its corrosion resistance. The results show that these magnets are highly susceptible to corrosion that occurs preferentially in the Nd-rich phase, located in the boundaries of the magnetic matrix phase (). Treatment with silane, cerium, sam, Cr 6+, tricationic phosphate followed by bath of chromium trioxide and in NaH2PO4 solution for 24 hours followed by bath of zinc sulphate did not improve the corrosion resistance of the magnet. Among the treatments used, immersion in NaH2PO4 solution for 24 hours pH=3.8 was the one that provided the best corrosion protection against corrosion, when compared with the other types of tested treatments.
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Design and fabrication of in-plane micro-generator using low temperature co-fire ceramicsChen, Yong-Jheng 05 September 2012 (has links)
This study focuses on the design, fabrication, test and application of in-plane rotary electromagnetic micro-generator to obtain a high power output. The micro-generator comprises multilayer planar low temperature co-fired ceramics (LTCC) Ag micro-coil and multipole hard magnet of Nd/Fe/B. Finite element simulations have been carried out to observe electromagnetic information. The study also establishes analytical solutions for the micro-generator to predict the induced voltage. Three different configurations of planar micro-coils investigated, which are sector-shaped, circle-shaped, and square-shaped micro-coils. A prototype of the micro-generator is as small as 9¡Ñ9¡Ñ1 mm3 in volume size. The experimental results show that the micro-generator with sector-shaped micro-coil has the highest power output of 1.89 mW, and the effective value of the induced voltage of 205.7 mV at 13,325 rpm is achieved. In application, this study designed and fabricated a planar rotary electromagnetic energy harvester with a low rotary speed for use in bicycle dynamos. Finite element analysis and the Taguchi method were used to design this dynamo system. LTCC technology was applied to fabricate Ag planar multilayer coils with 20 layers. A 28-pole magnet Nd/Fe/B with an outer diameter of 50 mm and a thickness of 2 mm was also sintered and magnetized. This harvester system was approximately 50¡Ñ50¡Ñ3 mm3 in volume. The experimentally induced voltages for 20-layer coils were 1.539 V at the rotary speeds of 300 rpm. The power output was 0.788 mW with an external resistance load of 740 £[, and the efficiency was 26.62%. This harvester is capable of powering a minimum of 200 light emitted diodes (LEDs) (forward voltage (VF) <2.2 V and 20 mA) using a rotary speed of 250 rpm, and can be used for bicycle dynamo lighting.
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The Effect Of Strain Rate And Temperature On The Development Of Magnetic Properties In Nano Crystalline Nd-Fe-B AlloyNarayan, Shashi Prakash 07 1900 (has links) (PDF)
No description available.
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Epitaxial Nd-Fe-B films: Growth, texture, magnetism and the influence of mechanical elongationKwon, Ah-Ram 19 January 2010 (has links) (PDF)
The work in this thesis focuses on the preparation of epitaxial Nd-Fe-B thin films using pulsed laser deposition for good hard magnetic properties. They are suitable for a basic understanding of the intrinsic magnetic properties. Compositional control was necessary to achieve phase formation with improved magnetic properties. Nd-Fe-B samples were prepared on single crystal MgO (001) substrates with different buffer layers in order to obtain good textures with different surface morphology. The smooth and continuous epitaxial films were suitable for performing magnetization measurements under stress. Although the magnetostriction is easily neglected in the Nd2Fe14B compound, distinguishable inverse magnetostriction was observed by conventional tensile elongation with a flexible substrate. As a result, anisotropic strain in the film, which breaks the in-plane symmetry, affected the opening angle during the spin reorientation. Therefore an elliptical distortion of the in-plane anisotropy below the spin reorientation temperature of Nd2Fe14B was obtained, whereas the transition temperature itself was not influenced significantly. / Diese Arbeit behandelt die Herstellung dünner epitaktischer Nd-Fe-B-Schichten mit gepulster Laserdeposition mit dem Ziel, gute hartmagnetische Eigenschaften zu erreichen. Diese Schichten sind außerdem für das Verständnis grundlegender magnetischer Eigenschaften geeignet. Die Kontrolle der Zusammensetzung ist notwendig, um die Phasenbildung und optimale hartmagnetische Eigenschaften zu erreichen. Nd-Fe-B-Schichten wurden auf einkristallinen MgO (001)-Substraten mit verschiedenen Buffern deponiert, um unterschiedliche Texturen und Oberflächenmorphologien einzustellen. Die glatten kontinuierlichen epitaktischen Schichten ermöglichen die Messung der Magnetisierung bei gleichzeitig angelegter mechanischer Spannung. Obwohl die Magnetostriktion bei Nd-Fe-B im Allgemeinen vernachlässigt werden kann, konnte an Nd-Fe-B-Schichten nach dem Aufbringen einer Dehnung auf ein flexibles Substrat eine deutliche inverse Magnetostriktion induziert werden. Die anisotrope Dehnung in der Schicht, die die Symmetrie in der Schichtebene bricht, beeinflusst die Öffnungswinkel bei der Spinreorientierung. Damit wurde unterhalb der Spinreorientierungstemperatur eine elliptische Verzerrung der Anisotropie in der Schichtebene erreicht, die Übergangstemperatur selbst änderte sich dagegen nicht signifikant.
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Epitaxial Nd-Fe-B films: Growth, texture, magnetism and the influence of mechanical elongationKwon, Ah-Ram 17 April 2009 (has links)
The work in this thesis focuses on the preparation of epitaxial Nd-Fe-B thin films using pulsed laser deposition for good hard magnetic properties. They are suitable for a basic understanding of the intrinsic magnetic properties. Compositional control was necessary to achieve phase formation with improved magnetic properties. Nd-Fe-B samples were prepared on single crystal MgO (001) substrates with different buffer layers in order to obtain good textures with different surface morphology. The smooth and continuous epitaxial films were suitable for performing magnetization measurements under stress. Although the magnetostriction is easily neglected in the Nd2Fe14B compound, distinguishable inverse magnetostriction was observed by conventional tensile elongation with a flexible substrate. As a result, anisotropic strain in the film, which breaks the in-plane symmetry, affected the opening angle during the spin reorientation. Therefore an elliptical distortion of the in-plane anisotropy below the spin reorientation temperature of Nd2Fe14B was obtained, whereas the transition temperature itself was not influenced significantly. / Diese Arbeit behandelt die Herstellung dünner epitaktischer Nd-Fe-B-Schichten mit gepulster Laserdeposition mit dem Ziel, gute hartmagnetische Eigenschaften zu erreichen. Diese Schichten sind außerdem für das Verständnis grundlegender magnetischer Eigenschaften geeignet. Die Kontrolle der Zusammensetzung ist notwendig, um die Phasenbildung und optimale hartmagnetische Eigenschaften zu erreichen. Nd-Fe-B-Schichten wurden auf einkristallinen MgO (001)-Substraten mit verschiedenen Buffern deponiert, um unterschiedliche Texturen und Oberflächenmorphologien einzustellen. Die glatten kontinuierlichen epitaktischen Schichten ermöglichen die Messung der Magnetisierung bei gleichzeitig angelegter mechanischer Spannung. Obwohl die Magnetostriktion bei Nd-Fe-B im Allgemeinen vernachlässigt werden kann, konnte an Nd-Fe-B-Schichten nach dem Aufbringen einer Dehnung auf ein flexibles Substrat eine deutliche inverse Magnetostriktion induziert werden. Die anisotrope Dehnung in der Schicht, die die Symmetrie in der Schichtebene bricht, beeinflusst die Öffnungswinkel bei der Spinreorientierung. Damit wurde unterhalb der Spinreorientierungstemperatur eine elliptische Verzerrung der Anisotropie in der Schichtebene erreicht, die Übergangstemperatur selbst änderte sich dagegen nicht signifikant.
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Développement de poudres anisotropes Nd-Fe-B à partir d'aimants frittés par procédé de décrépitation à l'hydrogène et désorptionLuo, Jianjun 20 November 2009 (has links) (PDF)
L'objectif de la thèse était d'étudier le procédé de Décrepitation à l'Hydrogène (HD) en tant que moyen de recycler les rebus d'aimants frittés Nd-Fe-B en poudres fortement coercitives et anisotropes, pour l'industrie d'aimants liés. Le procédé consiste à appliquer une première hydruration, afin de réduire le matériau massif en poudre, grâce à l'expansion du volume de la maille. Des traitements de désorption de l'hydrogène et de recuit sont ensuite nécessaires pour rétablir les caractéristiques initiales du précurseur (coercivité et anisotropie). Les différentes étapes du procédé HD ont été étudiées à partir d'aimants frittés (NdDy)2(FeCoNbCu)14B utilisés comme précurseurs. Les caractéristiques d'absorption et de désorption de l'hydrogène ont été étudiées par Calorimétrie Différentielles (DSC) et par des mesures de cinétique d'hydruration. Des mesures magnétothermiques ont permis d'analyser l'effet de la présence d'hydrogène résiduel sur les propriétés magnétiques des poudres (NdDy)-(FeCoNbCu)-B. La thèse se focalise sur l'impact des conditions expérimentales appliquées, telles que la température de décrepitation, l'application d'un double cycle de décrépitation, la température de désorption, l'application d'un champ magnétique pendant la désorption de l'hydrogène, la température de recuit, etc... sur les propriétés magnétiques des poudres (NdDy)-(FeCoNbCu)-B. Parmi ces facteurs, les températures d'absorption et de désorption, et la température de recuit jouent un rôle prépondérant sur les propriétés magnétiques. La double décrépitation améliore la distribution de taille des poudres. La désorption de l'hydrogène sous le champ magnétique réduit le contenu d'hydrogène résiduel des poudres anisotropes, et conduit ainsi à une augmentation de la rémanence (Br). Après l'optimisation des étapes successives du procédé, des poudres anisotropes présentant des propriétés satisfaisantes ont été obtenues : Br = 10.29 kGs (1.029 T), Hcj = 14.3 kOe (1138 kA/m), (BH)Max = 21.67 MGOe (172.5 kJ/m3). Les propriétés magnétiques initiales des aimants frittés (NdDy)-(FeCoNbCu)-B ont été restaurées respectivement à 93 %, 46 % et 74 %.
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Desenvolvimento de ímãs de Nd-Fe-B pelo processo MPI- aplicados em máquinas elétricas (motores)Luna, Wilberth Harold Deza January 2012 (has links)
O processo tradicional de fabricação de ímãs de terras raras – TR – é a metalurgia do pó convencional. Este processo inclui etapas de preparação da liga, moagem, compactação sob campo e sinterização. Atualmente, ímãs obtidos pelo processo de injeção tem como resultado os ímãs conhecidos como bonded, que são compósitos de resina e ligas magnéticas. O processo de obtenção proposto neste trabalho é a moldagem de pós por injeção – MPI, o que implica novos desafios uma vez que ligas de terras raras são altamente reativas. A obtenção de ímãs de Nd-Fe-B por esse processo fornece a oportunidade de diversificar ainda mais os setores, potencialmente lucrativos, que trabalham com materiais magnéticos. As dificuldades desse processo foram encontradas em cada etapa, desde a mistura da liga com os polímeros à eliminação destes polímeros depois de as peças serem injetadas, essa etapa se tornou crítica dado que está diretamente relacionada às propriedades finais do material. Assim, propuseram-se novos ciclos de extração dos polímeros com solventes orgânicos e degradação térmica. Além disso, modelou-se ferramental para o processo de injeção, uma vez que o material deve ser orientado magneticamente durante a injeção. Finalmente usou-se o MAXWELL 14® (software para análises por elementos finitos para resolução em 3D) para incluir propriedades no banco de dados do software e assim predizer o comportamento do material quando aplicado nas máquinas elétricas de núcleos com de formato complexo. / The typical magnets production process of Rare Earths – RE is the conventional powder metallurgy. This process includes preparation stages of alloys, grind, pressing under field and sintering. Nowadays, magnet obtained by the injection process has as result the magnets known as bonded, that is a resin composite and magnetic alloys. The proposed process to obtainment, in this work, is the Metal Injection Molding- MIM, what involve new challenges once alloys of RE are highly reactive. The magnets obtainment of ND-Fe-B for this process supplies even opportunity of diversifying the sectors, potentially lucrative, that work with magnetic materials. The difficulties of this process were found in each stage, since the alloy mixture with the polymers to the elimination of these polymers after the pieces are injected, this stage became criticizes given it is directly related to final properties of the material. This way if it propose to polymers extraction new cycles with organic solvents and thermal degradation. Moreover, it modeled die for the injection process, once the material should be guided magnetically during the injection. It finally used MAXWELL 14 ® (Software for analyses by finite elements for resolution in 3D) to include properties on the bench of data of the software and thus predict the material behavior when applied in cores of electrical machines with complex shape.
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Desenvolvimento de ímãs de Nd-Fe-B pelo processo MPI- aplicados em máquinas elétricas (motores)Luna, Wilberth Harold Deza January 2012 (has links)
O processo tradicional de fabricação de ímãs de terras raras – TR – é a metalurgia do pó convencional. Este processo inclui etapas de preparação da liga, moagem, compactação sob campo e sinterização. Atualmente, ímãs obtidos pelo processo de injeção tem como resultado os ímãs conhecidos como bonded, que são compósitos de resina e ligas magnéticas. O processo de obtenção proposto neste trabalho é a moldagem de pós por injeção – MPI, o que implica novos desafios uma vez que ligas de terras raras são altamente reativas. A obtenção de ímãs de Nd-Fe-B por esse processo fornece a oportunidade de diversificar ainda mais os setores, potencialmente lucrativos, que trabalham com materiais magnéticos. As dificuldades desse processo foram encontradas em cada etapa, desde a mistura da liga com os polímeros à eliminação destes polímeros depois de as peças serem injetadas, essa etapa se tornou crítica dado que está diretamente relacionada às propriedades finais do material. Assim, propuseram-se novos ciclos de extração dos polímeros com solventes orgânicos e degradação térmica. Além disso, modelou-se ferramental para o processo de injeção, uma vez que o material deve ser orientado magneticamente durante a injeção. Finalmente usou-se o MAXWELL 14® (software para análises por elementos finitos para resolução em 3D) para incluir propriedades no banco de dados do software e assim predizer o comportamento do material quando aplicado nas máquinas elétricas de núcleos com de formato complexo. / The typical magnets production process of Rare Earths – RE is the conventional powder metallurgy. This process includes preparation stages of alloys, grind, pressing under field and sintering. Nowadays, magnet obtained by the injection process has as result the magnets known as bonded, that is a resin composite and magnetic alloys. The proposed process to obtainment, in this work, is the Metal Injection Molding- MIM, what involve new challenges once alloys of RE are highly reactive. The magnets obtainment of ND-Fe-B for this process supplies even opportunity of diversifying the sectors, potentially lucrative, that work with magnetic materials. The difficulties of this process were found in each stage, since the alloy mixture with the polymers to the elimination of these polymers after the pieces are injected, this stage became criticizes given it is directly related to final properties of the material. This way if it propose to polymers extraction new cycles with organic solvents and thermal degradation. Moreover, it modeled die for the injection process, once the material should be guided magnetically during the injection. It finally used MAXWELL 14 ® (Software for analyses by finite elements for resolution in 3D) to include properties on the bench of data of the software and thus predict the material behavior when applied in cores of electrical machines with complex shape.
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Desenvolvimento de ímãs de Nd-Fe-B pelo processo MPI- aplicados em máquinas elétricas (motores)Luna, Wilberth Harold Deza January 2012 (has links)
O processo tradicional de fabricação de ímãs de terras raras – TR – é a metalurgia do pó convencional. Este processo inclui etapas de preparação da liga, moagem, compactação sob campo e sinterização. Atualmente, ímãs obtidos pelo processo de injeção tem como resultado os ímãs conhecidos como bonded, que são compósitos de resina e ligas magnéticas. O processo de obtenção proposto neste trabalho é a moldagem de pós por injeção – MPI, o que implica novos desafios uma vez que ligas de terras raras são altamente reativas. A obtenção de ímãs de Nd-Fe-B por esse processo fornece a oportunidade de diversificar ainda mais os setores, potencialmente lucrativos, que trabalham com materiais magnéticos. As dificuldades desse processo foram encontradas em cada etapa, desde a mistura da liga com os polímeros à eliminação destes polímeros depois de as peças serem injetadas, essa etapa se tornou crítica dado que está diretamente relacionada às propriedades finais do material. Assim, propuseram-se novos ciclos de extração dos polímeros com solventes orgânicos e degradação térmica. Além disso, modelou-se ferramental para o processo de injeção, uma vez que o material deve ser orientado magneticamente durante a injeção. Finalmente usou-se o MAXWELL 14® (software para análises por elementos finitos para resolução em 3D) para incluir propriedades no banco de dados do software e assim predizer o comportamento do material quando aplicado nas máquinas elétricas de núcleos com de formato complexo. / The typical magnets production process of Rare Earths – RE is the conventional powder metallurgy. This process includes preparation stages of alloys, grind, pressing under field and sintering. Nowadays, magnet obtained by the injection process has as result the magnets known as bonded, that is a resin composite and magnetic alloys. The proposed process to obtainment, in this work, is the Metal Injection Molding- MIM, what involve new challenges once alloys of RE are highly reactive. The magnets obtainment of ND-Fe-B for this process supplies even opportunity of diversifying the sectors, potentially lucrative, that work with magnetic materials. The difficulties of this process were found in each stage, since the alloy mixture with the polymers to the elimination of these polymers after the pieces are injected, this stage became criticizes given it is directly related to final properties of the material. This way if it propose to polymers extraction new cycles with organic solvents and thermal degradation. Moreover, it modeled die for the injection process, once the material should be guided magnetically during the injection. It finally used MAXWELL 14 ® (Software for analyses by finite elements for resolution in 3D) to include properties on the bench of data of the software and thus predict the material behavior when applied in cores of electrical machines with complex shape.
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