Hot Mix Asphalt (HMA) has been used over the years for laying roads. It required the aggregate and the binder to be heated to temperatures above 160°C (320°F). Heating the aggregate and binder in large quantities consumed a lot of fuel. This called for alternative solutions in the technology of laying roads. This brought about a new technology called Warm Mix Asphalt (WMA). WMA is an emerging technology that can allow asphalt to be produced and compacted at a significantly lower temperature. In the past, a number of researchers evaluated various WMA mixtures using selected testing procedures in the laboratory. However, none of them evaluated all the major WMA products and compared them with WMA mixtures without an additive using a comprehensive set of testing protocols. This paper presents a comprehensive evaluation result of three major WMA additives (Sasobit®, Evotherm J1 and RedisetTM) regarding their viscosity, tensile strength, moisture sensitivity, dynamic modulus and flow number. These three additives were chosen since all of them are prepared from a base wax product. The asphalt showed a decreasing trend in viscosity with increase in the concentration of the additives. The WMA specimen with additives exhibits similar air voids as control WMA specimens which indicate these WMA additives are effective in compacting asphalt mixtures at low temperatures. The Indirect Tensile Strengths (ITS) and Tensile Strength Ratio (TSR) values of the WMA specimen with admixtures were found to be higher than the control WMA specimens. This result indicates that the admixtures play a significant role in enhancing the properties of WMA. WMA mixtures with additives exhibited higher dynamic modulus than the control WMA at all temperatures. All the specimens passed the requirement of 10,000 cycles of repeated loading. The WMA specimen with Sasobit® additive exhibited the lowest permanent deformation. Based on overall test results it can be concluded that Sasobit®, Evotherm J1 and RedisetTM WMA additives are effective in producing WMA mixtures in the laboratory which have high strengths.

Subsoil compaction is a major yield limiting factor for most agricultural crops. Tillage is the most efficient method to quickly treat compacted subsoil, but it is also expensive, increases erosion, and accelerates nutrient cycling. The use of real-time electrical conductivity (EC) and near-infrared (NIR) reflectance values to differentiate compacted areas from uncompacted areas was studied. This method has potential to reduce monetary and time investments inherent in traditional grid sampling and the resultant deep tillage of an entire field. EC and NIR reflectance are both very sensitive to spatial variability of soil attributes. The objective of this research was to determine whether the amount of soil moisture affects the efficacy of EC and NIR spectroscopy (at 2151.9 nm) in identifying subsoil compaction through correlation analysis, and also to determine whether a minimum level of compaction was necessary for these same methods to detect compaction in three different soil textures across a variable water gradient. Bulk density measurements were taken in late 2007 from plots traversing an induced soil moisture gradient, and low, medium, and high levels of compaction at three locations with different soil textures. A Veris Technologies (Salina, KS) Near-Infrared Spectrophotometer equipped with an Electrical Conductivity Surveyor 3150 was used to measure and geo-reference EC and NIR reflectance data over the same plots. Analysis of the data for a correlation between compaction (bulk density values) and EC, as well as compaction and NIR reflectance, produced clear results. It was found that electrical conductivity is not significantly different between compacted or uncompacted soils even when tested at all moisture extremes and in different soil textures in Utah. Also, NIR spectroscopy was unsuccessful at identifying subsoil compaction because all tested procedures to induce a spectrometer into the soil resulted in changes the physical properties of the soil.

The retention of water in soils is a very interesting subject. Soil-water research presents a great challenge to research workers. The challenge is broad in scope and extends from the field problems of large irrigation projects to the atomic scale of the solid-liquid interface. If scientists are going to describe scientifically soil-water relations, they must ultimately utilize the instruments of science and the language of mathematics. To the end of the latter the mathematics of thermodynamics has been applied in these studies of water retention in soils.

Bibliography: leaves 146-170. / xix, 170 leaves : ill. ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--Dept. of Soil and Water, Waite Agricultural Research Institute, University of Adelaide, 1994

No description available.

<p>In this thesis, the strength-enhancing mechanisms of dry binders in direct compression were studied. The systems investigated were binary mixtures containing various compounds and binders. Among the binders used were a series of different molecular weights of polyethylene glycol. The proposed simplified tablet model describing the fracture path in a tablet during strength testing offers an explanation for the increase in tablet strength caused by the binder. The model and results in this thesis indicate that fractures will usually propagate around the tablet particles and through the interparticulate voids during tablet strength testing.</p><p>One important characteristic of the binder is its ability to be effectively and evenly distributed through the interparticulate voids in a compound tablet. Characteristics such as high plasticity, low elasticity and a small particle size were associated with a more even distribution and a consequent pronounced effect on pore structure and marked improvement in tablet strength. The strength of tablets containing less plastic binders was governed more by the compactibility of the binder. The tablet porosity, bonding mechanisms and volume reduction mechanisms of the compound also influenced the effect of the binder. For example, the plasticity and particle size of the binder had the most significant effects on tablet strength when the tablet porosity of the com-pound was relatively low. A combination of the plasticity and the compactibility of the binder determined the strength of tablets when the tablet of a compound was more porous. The positive effect of a binder on pore structure and tablet strength resulted in an increase in the disintegration time. Although addition of a superdisintegrant generally improved the disintegration time, the effect was decreased when the formulation included more deformable binders.</p><p>The choice of a suitable binder for a tablet formulation requires extensive knowledge of the relative importance of binder properties for enhancing the strength of the tablet and also of the interactions between the various materials constituting a tablet. Thus, the increased knowledge of the functionality of a binder obtained in this thesis enables a more rational approach to tablet formulation.</p>

Compaction of soil is essential in the construction of highways, airports, buildings, and bridges. Typically compaction is controlled by measuring the dry density and the water content of the compacted soil and checking that target values have been achieved. There is a current trend towards measuring the soil modulus instead or in addition to density. The reasons are that the density measurements are made using nuclear density meter, an undesirable tool in today??s political environment and that pavement design uses moduli as an input parameter. Although there are many apparatus available to measure soil modulus in the field such as Falling Weight Deflectometer, Dynamic Cone Penetrometer and Seismic Pavement Analyzer, a light weight and easy to use device which can measure the soil modulus fast and accurately is in great need. Briaud Compaction Device (BCD) is a portable device which can measure a soil modulus in several seconds. The principle of the BCD is to use the bending of a plate resting on the ground surface as an indicator of the modulus of the soil below. Numerical simulations show that within a certain range, the soil modulus is simply related to the plate bending. Strain gauges are glued on the top of the plate of BCD and a double half Wheatstone bridge is used to measure the strain. BCD tests were done in parallel with plate tests of the same size. A good correlation was found between the ratio of the plate pressure over the bending strain measured with a BCD and the reload soil modulus obtained from the plate test. This correlation can be incorporated into the BCD processor to display the soil modulus directly. To transit from dry density based compaction control to modulus based compaction control, BCD tests were also performed in the laboratory on top of a soil sample compacted inside the Proctor mold followed by plate tests. That way, a soil modulus versus water content curve is developed which parallels the approach for the dry density versus water content. The soil modulus versus water content curve can be used to provide the target values for compaction control in the field.

The internal dynamics of powder systems under compression are as of yet not fully understood, and thus there is a necessity for approaches that can help in further clarifying and enhancing the level of understanding on this subject. To this end, the internal dynamics of powder systems under compression were probed by means of force distributions and a novel compaction equation. The determination of force distributions hinged on the use of carbon paper as a force sensor, where the imprints transferred from it onto white paper where converted through calibration into forces. Through analysis of these imprints, it was found that the absence of friction and bonding capacity between the particles composing the powder bed had no effect on how the applied load was transferred through the system. Additionally, it was found that pellet strength had a role to play in the homogeneity of force distributions, where, upon the occurrence of fracture, force distributions became less homogenous. A novel compaction equation was derived and tested on a series of systems composed of pellets with differing mechanical properties. The main value of the equation lay in its ability to predict compression behavior from single particle properties, and the agreement was especially good when a compact of zero porosity was formed. The utility of the equation was tested in two further studies, using a series of pharmaceutically relevant powder materials. It was established that the A parameter of the equation was a measure of the deformability of the powder material, much like the Heckel 1/K parameter, and can be used as a means to rank powders according to deformability, i.e. to establish plasticity scale. The equation also provided insights into the dominating compression mechanisms through an invariance that could be exploited to determine the point, at which the powder system became constrained, i.e. the end of rearrangement. Additionally, the robustness of the equation was demonstrated through fruitful analysis of a set of diverse materials. In summary, this thesis has provided insights and tools that can be translated into more efficient development and manufacturing of medicines in the form of tablets.

In this thesis, the strength-enhancing mechanisms of dry binders in direct compression were studied. The systems investigated were binary mixtures containing various compounds and binders. Among the binders used were a series of different molecular weights of polyethylene glycol. The proposed simplified tablet model describing the fracture path in a tablet during strength testing offers an explanation for the increase in tablet strength caused by the binder. The model and results in this thesis indicate that fractures will usually propagate around the tablet particles and through the interparticulate voids during tablet strength testing. One important characteristic of the binder is its ability to be effectively and evenly distributed through the interparticulate voids in a compound tablet. Characteristics such as high plasticity, low elasticity and a small particle size were associated with a more even distribution and a consequent pronounced effect on pore structure and marked improvement in tablet strength. The strength of tablets containing less plastic binders was governed more by the compactibility of the binder. The tablet porosity, bonding mechanisms and volume reduction mechanisms of the compound also influenced the effect of the binder. For example, the plasticity and particle size of the binder had the most significant effects on tablet strength when the tablet porosity of the com-pound was relatively low. A combination of the plasticity and the compactibility of the binder determined the strength of tablets when the tablet of a compound was more porous. The positive effect of a binder on pore structure and tablet strength resulted in an increase in the disintegration time. Although addition of a superdisintegrant generally improved the disintegration time, the effect was decreased when the formulation included more deformable binders. The choice of a suitable binder for a tablet formulation requires extensive knowledge of the relative importance of binder properties for enhancing the strength of the tablet and also of the interactions between the various materials constituting a tablet. Thus, the increased knowledge of the functionality of a binder obtained in this thesis enables a more rational approach to tablet formulation.

<p>Soil compaction is an inevitable result of agricultural practices. It alters physical properties of soil and tends to be undesirable as it adversely affects water and nutrient penetration. Furthermore, additional energy is spent to till the soil. Although a tremendous amount of research has been conducted in the area of soil compaction, the focus has been primarily on surface soil displacement.</p> <p>Realizing that the observed soil displacement is the cumulative effect from the compaction of subsurface layers, this research discusses the displacement and distributed pressure through the soil from a surface load. A given volume of soil of known density and moisture content was loaded at the surface with a slowly applied force using an Instron® testing machine. The distribution of the pressure and displacement profile from the surface to depth was measured to provide insight into the formation of the subsurface soil structures. The nonlinear exponential decay of the soil displacement (compaction) from the surface to a given depth converges to zero at the location of a hard, compact layer or a point where no soil movement occurs, regardless of the initial soil compaction. By increasing soil moisture content and decreasing soil bulk density, the vertical soil displacement increased at the surface and within the soil profile, and the pressure distribution decreased with depth. Changing the shape of loading surface had minimal effect on soil displacement.</p>