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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
311

Near-trapping effect of wave-cylinders interaction on pore water pressure and liquefaction around a cylinder array

Lin, Z., Pokrajac, D., Guo, Yakun, Liao, C., Tang, T. 10 October 2021 (has links)
Yes / The near-trapping effects on wave-induced dynamic seabed response and liquefaction close to a multi-cylinder foundation in storm wave conditions are examined. Momentary liquefaction near multi-cylinder structures is simulated using an integrated wave-structure-seabed interaction model. The proposed model is firstly validated for the case of interaction of wave and a four-cylinder structure, with a good agreement with available experimental measurements. The validated model is then applied to investigate the seabed response around a four-cylinder structure at 0° and 45° incident angles. The comparison of liquefaction potential around individual cylinders in an array shows that downstream cylinder is well protected from liquefaction by upstream cylinders. For a range of incident wave parameters, the comparison with the results for a single pile shows the amplification of pressure within the seabed induced by progressive wave. This phenomenon is similar to the near-trapping phenomenon of free surface elevation within a cylinder array. / Energy Technology Partnership (ETP), Wood Group / Full-text of this article will be released for public view at the end of the publisher embargo on 10 Oct 2021.
312

Coupling model for waves propagating over a porous seabed

Liao, C.C., Lin, Z., Guo, Yakun, Jeng, D-S. 11 March 2015 (has links)
Yes / The wave–seabed interaction issue is of great importance for the design of foundation around marine infrastructures. Most previous investigations for such a problem have been limited to uncoupled or one-way coupled methods connecting two separated wave and seabed sub models with the continuity of pressures at the seabed surface. In this study, a strongly coupled model was proposed to realize both wave and seabed processes in a same program and to calculate the wave fields and seabed response simultaneously. The information between wave fields and seabed fields were strongly shared and thus results in a more profound investigation of the mechanism of the wave–seabed interaction. In this letter, the wave and seabed models were validated with previous experimental tests. Then, a set of application of present model were discussed in prediction of the wave-induced seabed response. Numerical results show the wave-induced liquefaction area of coupled model is smaller than that of uncoupled model. / Yes
313

Investigation of nonlinear wave-induced seabed response around mono-pile foundation

Lin, Z., Pokrajac, D., Guo, Yakun, Jeng, D-S., Tang, T., Rey, N., Zheng, J., Zhang, J. 14 January 2017 (has links)
Yes / Stability and safety of offshore wind turbines with mono-pile foundations, affected by nonlinear wave effect and dynamic seabed response, are the primary concerns in offshore foundation design. In order to address these problems, the nonlinear wave effect on dynamic seabed response in the vicinity of mono-pile foundation is investigated using an integrated model, developed using OpenFOAM, which incorporates both wave model (waves2Foam) and Biot’s poro-elastic model. The present model was validated against several laboratory experiments and promising agreements were obtained. Special attention was paid to the systematic analysis of pore water pressure as well as the momentary liquefaction in the proximity of mono-pile induced by nonlinear wave effects. Various embedment depths of mono-pile relevant for practical engineering design were studied in order to attain the insights into nonlinear wave effect around and underneath the mono-pile foundation. By comparing time-series of water surface elevation, inline force, and wave-induced pore water pressure at the front, lateral, and lee side of mono-pile, the distinct nonlinear wave effect on pore water pressure was shown. Simulated results confirmed that the presence of mono-pile foundation in a porous seabed had evident blocking effect on the vertical and horizontal development of pore water pressure. Increasing embedment depth enhances the blockage of vertical pore pressure development and hence results in somewhat reduced momentary liquefaction depth of the soil around the mono-pile foundation. / Energy Technology Partnership (ETP), Wood Group Kenny, and University of Aberdeen; the National Science Fund for Distinguished Young Scholars (51425901) and the 111 project (B12032).
314

[en] LIQUEFACTION ASPECTS ON THE STABILITY OF A COPPER ORE HEAP LEACH UNDER SEISMIC LOADING / [pt] ASPECTOS DE LIQUEFAÇÃO NA ESTABILIDADE DE PILHA DE LIXIVIAÇÃO DE MINÉRIO DE COBRE SOB CARREGAMENTO SÍSMICO

GLADYS CELIA HURTADO AQUINO 27 October 2017 (has links)
[pt] O fenômeno de liquefação continua sendo um dos temas mais importantes, complexos e controversos da engenharia geotécnica, sendo a liquefação dinâmica, causada por terremotos, o maior contribuinte de risco sísmico urbano em vários países andinos. O movimento causa incrementos da poropressão que reduz a tensão efetiva e conseqüentemente a resistência ao cisalhamento de solos arenosos. O presente trabalho de pesquisa apresenta e compara algumas das metodologias existentes para a avaliação do fenômeno de liquefação dinâmica, variando desde o método semi-empírico de Seed-Idriss para estimativas do potencial de liquefação até a execução de algumas análises numéricas, no contexto dinâmico, através do programa computacional FLAC 2D v.5. Um estudo de caso, para uma comparação dos diversos procedimentos, consiste na análise dinâmica de uma pilha de lixiviação de minério de cobre, situada em região de atividade sísmica no Peru que, devido a problemas no sistema de drenagem interna, resultou com um alto nível de saturação que poderia colocar sua estabilidade em risco devido à possibilidade de liquefação sob carregamento sísmico. Dos resultados obtidos nessas análises, pode-se afirmar que o método semi-empírico de Seed-Idriss, para determinação do potencial de liquefação, compara-se bastante bem com modelos mais sofisticados baseados em análises dinâmicas empregando tanto o modelo constitutivo de Finn quanto o modelo constitutivo elastoplástico UBCSAND. / [en] The phenomenon of liquefaction is still one of the most important, complex and controversial subjects of the geotechnical engineering, being the dynamic liquefaction, caused by earthquakes, the major contributor to urban seismic risks in several Andesian countries. The shaking increases the pore water pressure which reduces the soil effective stress and, therefore, the shear strength of sandy soils. This dissertation presents and compares some of the proposed methodologies to evaluate the phenomenon of dynamic liquefaction, ranging from the semi-empirical method of Seed-Idriss to estimate the liquefaction potential to the execution of some numerical analyses, within the dynamic context, through the computational program FLAC 2D v.5. The case study, for the comparison among the several procedures, consists of a copper ore heap leach, situated in a high seismic activity zone in Peru, that experimented high levels of saturation, due to problems in the internal drainage system, that could put in risk the stability of the leach pad to the possibility of liquefaction under seismic loading. From the results of such analyses, one can say that the semi-empirical method proposed by Seed- Idriss for the determination of the liquefaction potential compares quite well with outputs from more sophisticated numerical analyses based on dynamic studies that incorporate either the Finn s or the elasto-plastic UBCSAND constitutive models.
315

Seismic Hazard Assessment of Tripura and Mizoram States along with Microzonation of Agartala and Aizawl Cities

Sil, Arjun January 2013 (has links) (PDF)
Tee present research focuses on seismic hazard studies for the states of Tripura and Mizoram in the North-East India with taking into account the complex sesismotectonic characteristics of the region. This area is more prone to earthquake hazard due to complex subsurface geology, peculiar topographical distribution, continuous crustal deformation due to the under thrusting of Indian and the Eurasian plates, a possible seismic gap, and many active intraplate sources identified within this region. The study area encompasses major seismic source zones such as Indo Burmese Range (IBR), Shillong Plateau (SP), Eastern Himalayan arc (EH), Bengal Basin (BB), Mishmi Thrust (MT) and Naga Thrust (NT). Five historical earthquakes of magnitude Mw>8 have been listed in the study area and 15 events of magnitude Mw>7 have occurred in last 100 years. Indian seismic code BIS-1893-2002 places the study area with a high level of seismic hazard in the country (i.e. seismic zone V). More than 60% of the area is hilly steep-terrain in nature and the altitude varies from 0 to 3000 meters. Recent works have located a seismic gap, known as the Assam gap since 1950 between the EH, SP, and IBR with the Eurasian plate. Various researchers have estimated the return period, and a large size earthquake is expected in this region any time in future. The area is also highly prone to liquefaction, since rivers in Tripura (Gomati, Howrah, Dhalai, Manu, Bijay, Jeri, Feni) and the rivers in Mizoram (Chhimtuipui, Tlawng, Tut, Tuirial and Tuivawl etc.) are scattered throughout the study area where soil deposits are of sedimentary type. In 2011, both the states together have experienced 37 earthquakes (including foreshocks and aftershocks) with magnitudes ranging from 2.9 to 6.9. Of these events, there were 23 earthquakes (M>4) of magnitudes M6.4 (Feb 4th 2011), M6.7 (March 24th 2011), M6.9 (Sept.18th 2011), M6.4 (October 30th 2011), M6.9 (Dec 13th 2011), M5.8 (Nov 21st 2011), M5 (Aug 18th 2011), M4.9 (July 28th 2011), M4.6 (Dec 15th 2011), M4.6 (Jan 21st 2011), M4.5 (Dec 9th 2011), M4.5 (Oct 21th 2011), M4.5 (Oct 17th 2011), M4.5 (Sept 18th 2011), M4.3 (Oct 10th 2011), M4.3 (Sept 22nd 2011), M4.3 (April 4th 2011), M4.2 (Sept 9th 2011), M4.2 (Sept 18th 2011), M4.1 (April 29th 2011), M4.1 (Feb 22nd 2011), M4 (June 9th 2011), and M4 (Dec 2nd 2011) which occurred within this region [source: IMD (Indian Metrological Department), India]. The earthquake (M6.9) that occurred on Sept. 18th 2011 is known as the Sikkim earthquake, and it caused immense destruction including building collapse, landslides, causalities, disrupted connectivity by road damages and other infrastructural damages in Sikkim state as well as the entire North-East India. In the cities of Agartala and Aizawl of Tripura and Mizoram, construction of high rise building is highly restricted by the Government. Being the capital city, many modern infrastructures are still pending for growth of the city planning. Although many researchers have studied and reported about the status of seismicity in North-East Region of India, very few detailed studies have been carried out in this region except Guwahati, Sikkim and Manipur where almost the whole of the study area is highly vulnerable to severe shaking, amplification, liquefaction, and landslide. From the available literature, no specific study exists for Tripura and Mizoram till date. In the present research, seismic hazard assessment has been performed based on spatial-temporal distribution of seismicity and fault rupture characteristics of the region. The seismic events were collected from regions covering about 500 km from the political boundary of the study area. The earthquake data were collected from various national and international seismological agencies such as the IMD, Geological Survey of India (GSI), United State Geological Survey (USGS), and International Seismological Centre (ISC) etc. As the collected events were in different magnitude scales, all the events were homogenized to a unified moment magnitude scale using recent magnitude conversion relations (region specific) developed by the authors for North-East Region of India. The dependent events (foreshocks and aftershocks) were removed using declustering algorithm and in total 3251 declustered events (main shocks) were identified in the study area since 1731 to 2011. The data set contains 825 events of MW < 4, 1279 events of MW from 4 to 4.9, 996 events MW from 5 to 5.9, 131 events MW from 6 to 6.9, 15 events MW from 7 to 7.9 and 5 events MW ≥8. The statistical analysis was carried out for data completeness (Stepp, 1972). The whole region was divided into six seismic source zones based on the updated seismicity characteristics, fault rupture mechanism, size of earthquake magnitude and the epicentral depth. Separate catalogs were used for each zone, and seismicity parameters a and b were estimated for each source zone and other necessary parameters such as mean magnitude (Mmean), Mmax, Mmin, Mc and recurrence periods were also estimated. Toposheets/vector maps of the study area were collected and seismic sources were identified and characterized as line, point, and areal sources. Linear seismic sources were identified from the Seismotectonic atlas (SEISAT, 2000) published by the GSI, in addition to the source details collected from available literature and remote sensing images. The SEISAT map contains 43 maps presented in 42 sheets covering entire India and adjacent countries with 1:1million scale. Sheets representing the features of the study area were scanned, digitized and georeferenced using MapInfo 10.0 version. After this, tectonic features and seismicity events were superimposed on the map of the study area to prepare a Seismotectonic Map with a scale of 1:1million. In seismic hazard assessment, a state of art well known methodologies (deterministic and probabilistic) was used. In deterministic seismic hazard analysis (DSHA) procedure, hazard assessment is based on the minimum distance between sources to site considering the maximum magnitude occurred at each source. In hazard estimation procedure a lot of uncertainties are involved, which can be explained by probabilistic seismic hazard analysis (PSHA) procedure related to the source, magnitude, distance, and local site conditions. The attenuation relations proposed by Atkinson and Boore (2003), and Gupta (2010) are used in this analysis. Because in this region two type activities are mostly observed, regions such as SP, and EH are under plate boundary zone whereas IBR is under subduction process. These equations (GMPEs) were validated with the observed PGA (Peak ground acceleration) values before use in the hazard evaluation. The hazard curves for all six major sources were prepared and compiled to get the total hazard curve which represents the cumulative hazard of all sources. Evaluation of PGA, Sa (0.2s and 1.0s) parameters at bedrock level were estimated considering a grid size of 5 km x 5 km, and spectral acceleration values corresponding to a certain level of probability (2% and 10%) were done to develop uniform hazard spectrum (UHS) for both the cities (Agartala and Aizawl). To carry out the seismic microzonation of Agartala and Aizawl cities, a detailed study using geotechnical and geophysical data has been carried out for site characterization and evaluation of site response according to NEHRP (National Earthquake Hazard Response Program) soil classifications (A, B, C, D, and E-type). Seismic site characterization, which is the basic requirement for seismic microzonation and site response studies of an area. Site characterization helps to have the idea about the average dynamic behavior of soil deposits, and thus helps to evaluate the surface level response. A series of geophysical tests at selected locations have been conducted using multichannel analysis of surface waves (MASW) technique, which is an advanced method to obtain direct shear wave velocity profiles from in situ measurements for both the cities. Based on the present study a major part of Agartala city falls under site class D, very few portions come under site class E. On the other hand, Aizawl city comes under site class C. Next, a detailed site response analysis has been carried out for both the cities. This study addresses the influence of local geology and soil conditions on incoming ground motion. Subsurface geotechnical (SPT) and geophysical (MASW) data have been obtained and used to estimate surface level response. The vulnerable seismic source has been identified based on DSHA. Due to the lack of strong motion time history of the study area, synthetic ground motion time histories have been generated using point source seismological model (Boore 2003) at bedrock level based on fault rupture parameters such as stress drop, quality factor, frequency range, magnitude, hypocentral distance etc. Dynamic properties such as the shear modulus (G) and damping ratios (ζ) have been evaluated from the soil properties obtained from SPT bore log data collected from different agencies such as PWD (Public works Department), and Urban Development Dept. of the State Government, in situ shear wave velocity has been obtained from MASW survey in different locations, and following this, a site response analysis has been carried out using SHAKE-2000 to calculate the responses at the ground surface in combination of different magnitudes, distances and epicentral depth for a particular site class. An amplification factor was estimated as the ratio of the PGA at the ground surface to the PGA at bedrock level, a regression analysis was carried out to evaluate period dependant site coefficients, and hence, the period dependant hazard impact on the ground surface could be calculated to obtain the spatial variation of PGA over the study area. Further, liquefaction potential of the site (Agartala) was also evaluated using available SPT bore log data collected and using presently estimated surface level PGA. The results are presented in the form of liquefaction hazard map representing as a Factor of safety (FS) against liquefaction with various depths such as 1.5m, 10m, and 15m respectively. It has been seen that Agartala city shows highly prone to liquefaction even up to 15 m depth. Hence, site specific study is highly recommended for implementing any important project. The liquefaction hazard assessment could not be conducted for the Aizawl city because of non availability of the SPT-N data, however, the city stands on hills/mountains, and therefore, such a study is not applicable in this area. Further, seismic microzonation maps for both the cities have been prepared considering Analytical Hierarchy Process (AHP) which support to the Eigen value properties of the system. Two types of hazard maps have been developed, one using deterministic and another using the probabilistic seismic microzonation maps. These maps can be directly used as inputs for earthquake resistant design, and disaster mitigation planning of the study area. However, an investigation has also been made in forecasting a major earthquake (Mw>6) in North-East India using several probabilistic models such as Gamma, Weibull and lognormal models. IBR and EH show a high probability of occurrences in the next 5 years (i.e. 2013-2018) with >90% probability.
316

Effect of prefabricated vertical drains on pore water pressure generation and dissipation in liquefiable sand

Marinucci, Antonio 21 September 2010 (has links)
Soil improvement methods are used to minimize the consequences of liquefaction by changing the characteristics and/or response of a liquefiable soil deposit. When considering sites with previous development, the options for soil improvement are limited. Traditional methods, such as compaction and vibratory techniques, are difficult to employ because of adverse effects on adjacent structures. One potential method for soil improvement against soil liquefaction in developed sites is accelerated drainage through in situ vertical drains. Vertical drains expedite the dissipation of excess pore water pressures by reducing the length of the pore water drainage path. For more than thirty years, vertical gravel drains or stone columns have been employed to ensure the excess pore water pressure ratio remains below a prescribed maximum value. In recent years, the use of prefabricated vertical drains (PVDs) has increased because the drains can be installed with less site disruption than with traditional soil improvement methods. To date, little-to-no field or experimental verification is available regarding the seismic performance of sites treated with PVDs. The effectiveness of PVDs for liquefaction remediation was evaluated via small-scale centrifuge testing and full-scale field testing. A small-scale centrifuge test was performed on an untreated soil deposit and on a soil deposit treated with small-scale vertical drains. Compared to the untreated condition, the presence of the small-scale vertical drains provided numerous benefits including smaller magnitudes of excess pore water pressure generation and buildup, smaller induced cyclic shear strains, reduced times for pore pressure dissipation, and smaller permanent horizontal and vertical displacements. In addition, full-scale in situ field experiments were performed in an untreated soil deposit and in a soil deposit treated with full-scale PVDs using a vibrating mandrel as the dynamic source. In the untreated test area, the maximum induced excess pore pressure ratio reached about 0.95. In the treated test area, the vibratory installation of the first few drains generated significant excess pore pressures; however, significant excess pore pressures were not generated during the vibratory installation of additional drains because of the presence of the adjacent drains. Additionally, the vibratory installation of the drains caused significant settlement and significantly altered the shear wave velocity of the sand. Dynamic shaking after installation of all of the drains induced small accelerations, small cyclic shear strains, and negligible excess pore water pressures in the soil. The results of the field experiment indicate that the prefabricated vertical drains were effective at dissipating excess pore water pressures during shaking and densifying the site. / text
317

PREDICTING THE DYNAMIC BEHAVIOR OF COAL MINE TAILINGS USING STATE-OF-PRACTICE GEOTECHNICAL FIELD METHODS

Salehian, Ali 01 January 2013 (has links)
This study is focused on developing a method to predict the dynamic behavior of mine tailings dams under earthquake loading. Tailings dams are a by-product of coal mining and processing activities. Mine tailings impoundments are prone to instability and failure under seismic loading as a result of the mechanical behavior of the tailings. Due to the existence of potential seismic sources in close proximity to the coal mining regions in the United States, it is necessary to assess the post-earthquake stability of these tailings dams. To develop the aforementioned methodology, 34 cyclic triaxial tests along with vane shear tests were performed on undisturbed mine tailings specimens from two impoundments in Kentucky. Therefore, the liquefaction resistance and the residual shear strength of the specimens were measured. The laboratory cyclic strength curves for the coal mine specimens were produced, and the relationship between plasticity, density, cyclic stress ratio, and number of cycles to liquefaction were identified. The samples from the Big Branch impoundment were generally loose samples, while the Abner Fork specimens were dense samples, older and slightly cemented. The data suggest that the number of loading cycles required to initiate liquefaction in mine tailings, NL, decreases with increasing CSR and with decreasing density. This trend is similar to what is typically observed in soil. For a number of selected specimens, using the results of a series of small-strain cyclic triaxial tests, the shear modulus reduction curves and damping ratio plots were created. The data obtained from laboratory experiments were correlated to the previously recorded geotechnical field data from the two impoundments. The field parameters including the SPT blow counts (N1)60, corrected CPT cone tip resistance (qt), and shear wave velocity (vs), were correlated to the laboratory measured cyclic resistance ratio (CRR). The results indicate that in general, the higher the (N1)60 and the tip resistance (qt), the higher the CSR was. Ultimately, practitioners will be able to use these correlations along with common state-of-practice geotechnical field methods to predict cyclic resistance in fine tailings to assess the liquefaction potential and post-earthquake stability of the impoundment structures.
318

[en] ELASTO-PLASTICITY MODELLING OF SOIL LIQUEFACTION / [pt] MODELAGEM ELASTO-PLÁSTICA DA LIQUEFAÇÃO DINÂMICA DE SOLOS

JORGE LUIS CARDENAS GUILLEN 22 February 2016 (has links)
[pt] Mudanças das propriedades dos solos devido à ação de carregamentos dinâmicos são responsáveis por danos significativos em geo-estruturas, tais como: barragens, estruturas de concentração, fundações, taludes, etc. A ocorrência do fenômeno da liquefação, em materiais suscetíveis como areias fofas saturadas, representa um tipo de resposta desastrosa de solos. O termo liquefação tem sido empregado para descrever uma variedade de fenômenos no qual tem em comum o desenvolvimento de altas poropressões em materiais saturados sem coesão devido a carregamentos monotônicos , transientes ou ciclios. A previsão da liquefação depende de uma adequada análise do comportamento não-drenado do material, em termos do incremento de poropressões e da perda da rigidez da mistura sólido-fluido, durante e após o período de movimento. O estabelecimento das equações governantes é essencial para elaboração de um modelo matemático realista para descrever o comportamento físico deste fenômeno. As equações a srem consideradas são: equação de movimento da fase sólida, a equação do movimento da mistura sólido-fluido , a equação de continuidade da fase fluida, as equações de acoplamento das fases e as equações constitutivas desses materiais. Nesta tese a resposta dinâmica do solo foi investigada numericamente mediante a técnica dos elementos finitos. A discretização espacial das equações governantes foi feita através de método de Galerkin e a discretização temporal pelo método de Newmark Generalizado. Um modelo constitutivo elasto-plástico foi considerado para descrever o comportamento mecânico da fase sólida, desenvolvido a partir de conceitos da generealização da teoria da plasticidade, que apresenta algumas vantagens em relação aos outros modelos baseados na teoria da plasticidade clássica. A implementação computacional foi escrito em fortran 90. Exemplos numéricos analisados nesta tese comprovam tanto a eficiência do modelo constitutivo na predição do comportamento do solo sobre liquefação como a confiabilidade do programa computacional elaborado nesta pesquisa, em termos da rapidez de processamento e da boa precisão dos resultados, quando comparados com soluções analíticas e outros valores numéricos obtidos por vários autores e diferentes modelos constitutivos. / [en] Changes in soil properties due to the action of dynamic loads are responsible for significant damage of geo-structures such as dams, retaining structures,building foundations, slopes, etc. The occurrence of liquefaction phenomena in susceptible materials, such as loose saturated, represents a type of disastrous response of soil, the term liquefaction has been used to refer to a group of phenomena wich have in common the development of high pore pressures in saturated cohesionless mterial due to monotonic, transient, or cyclic loads. The prediction of soil liquefaction depends of an adequate analysis of the behavior of undrained materials, in terms of increase of pore water pressure and weakening of the solid-fluid mixture, during and after the periodic motion. The establishment of the governing equations is essential to provide a realistic mathematical model to describe the physical behavior of this phenomenon. The system of equations to be considered are: the equilibrium equation of the solid phase, the equilibrium equation of the solid-fluid mixture, the conservation mass of the fluid phase, the coupling equation of phases, and the conservation equations of materials. In this thesis the soil dynamic response was numerically investigated by the finite element method. To obtain the spatial discretization in time was the Generalized Newmark method. An elastic-plastic constitutive model was used to describe the mechanical behavior of the solid phase. This model was developed in the framework of the generalized theory of plasticity, wich has some advantages when compared with other models based on the classical plasticity theory. The computacional implementation was written in fortran 90. Numerical examples considered in this thesis demonstrate the efficiency of the constitutive model to simulated the predicted behavior of soil under liquefaction as well as the reliability of the software developed in this research, in terms of computational effort and good accuracy of the results, when compared with some analytical solutions and other numerical values obtained by various authors and different constitutive models.
319

WELL-TO-WHEELS ANALYSIS OF HEAVY-DUTY TRUCK FUELS : A comparison between LNG, LBG and Diese

Nylund, Simon, Wenstedt, Niklas January 2019 (has links)
Heavy-duty trucks accounts for 25% CO2 emissions in Sweden and there is approximately 12.6 million heavy-duty vehicles in the EU with different types of fuel and utilization areas. EU is implementing increased legislations to reduce emissions and increase the use of biofuel and members of the EU is starting to ban the use of diesel trucks in local areas, which drives the need to find other suitable fuel. Therefore, to study and compare the emissions and energy demand in the heavy-duty truck industry a case study is created. Which focuses on production and processing, transportation, distribution and fuel consumption. Cultivation of maize and anaerobic digestion of maize, waste and manure is included as well. Data gathered from the collaboration between the European Commission’s Joint Research Centre, eucar and Concawe (JEC) is used to create scenarios and these are validated with previous studies. The case study includes seven LNG cases, three LBG cases and two diesel cases together with several other cases collected for verification. Furthermore, potential boil-off and leakage during maintenance is included to further estimate the possible emissions correlated with LNG and LBG vehicles. The Well-to-Wheels analysis resulted in most LNG and LBG cases having higher energy input compared to diesel. LBG has the lowest emissions of greenhouse gases. The transportation method and distance are the most important aspects for the Well-to-Tank analysis. The fuel consumption is the main source of emissions and energy input in the Tankto-Wheels analysis. In conclusion, the transportation and fuel consumption are the greatest contributors of emissions and energy demand in the complete Well-to-Wheels analysis.
320

Aplicação de processos oxidativos e digestão anaeróbia na estabilização de efluente da liquefação hidrotermal de Spirulina / Application of oxidative processes and anaerobic digestion in the stabilization of hydrothermal liquefaction of Spirulina wastewater

Quispe-Arpasi, Diana Elizabeth 19 October 2016 (has links)
O processo de liquefação hidrotermal (HTL) pode converter diversos tipos de biomassa em óleo bruto. Além do produto principal, é gerado um efluente (PHWW) com elevada carga orgânica, quantidades altas de nutrientes e compostos tóxicos. Para lidar com este tipo efluente tem-se sugerido a combinação de tratamentos físico-químicos e biológicos. O objetivo deste estudo foi avaliar a aplicação de processos oxidativos (por H2O2 e fotocatálise com TiO2) e digestão anaeróbia no tratamento do efluente da liquefação hidrotermal de Spirulina. Inicialmente caracterizou-se o efluente em termos de carga orgânica, nutrientes e compostos nitrogenados cíclicos (CNC). Posteriormente, avaliou-se a concentração de oxidante e o tempo de reação no processo de oxidação com H2O2. O tratamento fotocatalítico foi então avaliada no tratamento do efluente em questão, isoladamente, em sequência e combinada ao processo de oxidação por ação de H2O2. Finalmente combinaram-se os processos de oxidação por ação de H2O2 e digestão anaeróbia no tratamento de efluente de PHWW. O efluente da liquefação hidrotermal de Spirulina apresentou elevada carga orgânica, pH alcalino e concentrações altas de nutrientes (nitrogênio e fósforo). Verificou-se também a presença de CNC como pirazinas, &delta;-valerolactama, caprolactama e butirolactama. A aplicação do processo oxidativo por H2O2 no tratamento de PHWW apresentou efeitos positivos, principalmente para a descoloração que atingiu 93,8 %. A eficiência máxima de remoção de DQO foi de 15,3%. Foi percebida também redução nas concentrações dos CNC. A eficiência do processo de oxidação avançada por fotocatálise e H2O2 foi maior do que obtida quando estes processos foram aplicados separadamente. A aplicação dos processos combinados apresentou eficiência de remoção de cor e DQO semelhante às obtidas quando os processos foram aplicados em sequência, propiciando economia de tempo de reação. Por fim, verificou-se que a digestão anaeróbia do efluente pré-tratado com H2O2 apresentou maior produção de CH4 e remoção de matéria orgânica quando comparada com a digestão anaeróbia que o efluente in natura. Assim, conclui-se a utlização de processos oxidativos avançados ou a combinação da oxidação por H2O2 com a digestão anaeróbia são alternativas promissoras para o tratamento da PHWW. / The hydrothermal liquefaction process (HTL) can convert various types of biomass into bio-crude oil. In addition to the main product, wastewater (PHWW) is generated with high organic content, high amounts of nutrients and toxic compounds. To cope with this type of wastewater the combination of physicochemical and biological treatments has been suggested. The aim of this study was to evaluate the application of oxidative processes (using H2O2 and photocatalysis with TiO2) and anaerobic digestion in the treatment of hydrothermal liquefaction of Spirulina wastewater. Firstly, PHWW was characterized in terms of organic matter, nutrients and nitrogen heterocyclic compounds (CNC) concentrations. Secondly, the oxidant concentration and the reaction time in the oxidation process using H2O2 was evaluated. Photocatalytic treatment was then tested isolated, in sequence and combinated with the oxidation processo using H2O2. Finally, oxidation with H2O2 and anaerobic digestion were combinated and evaluated. The PHWW showed high organic load, alkaline pH and high concentrations of nutrients (nitrogen and phosphorus). The presence of CNC as pyrazines, &delta;-valerolactam, caprolactam and butyrolactam was also verified. The application of the oxidative process using H2O2 showed positive effects mainly for color removal, which reached 93.8%. The maximum efficiency of COD removal was 15.3%. Reduction in CNC concentrations was also observed . The efficiency of the advanced oxidation process (by combining photocatalysis and H2O2) was greater than that obtained when these processes were applied separately. The application of the combined process presented color and COD removal efficiencies similar to those obtained when the processes were applied in sequence, allowing reaction time savings. Finally, the anaerobic digestion of pre-treated (with H2O2) PHWW showed a greater CH4 production and higher organic matter removal, compared to anaerobic digestion of in natura PHWW. Thus it is possible to conclude that the utlization of advanced oxidation processes or the combination of oxidation with H2O2 and anaerobic digestion are promising alternatives for the treatment of PHWW.

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