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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
61

Direct measurement of pore fluid suction in gold mine tailings

Van Heerden, Jacobus Hendrik Francois 21 September 2005 (has links)
A vast amount and variety of mine tailings are produced around the world each day. In the gold¬mining industry in South Africa the residue of crushed are is disposed of in large tailings or hydraulic fill dams. The outer walls of these dams are built up of layers of material, each of which is allowed to dry before the next layer is placed. In order to study the stability of these walls, the appropriate engineering properties of the tailings must be ascertained. Due to the construction technique used in tailings dam construction, the outer walls are in an unsaturated state, which also means that suctions are generated within the tailings. Various techniques exist to measure suction, most of which are indirect methods. The recent development of the mid-¬plane suction probe at the University of Pretoria created the opportunity of measuring suctions directly on desiccating samples of gold mine tailings. A test method has been developed from which soil mechanics parameters can be derived from suction measurements. The experimental programme consisted of a series of these newly developed tests on fine and coarse samples of gold mine tailings, as well as on different particle size ranges. The experimental results were used in the development of a new method of predicting the air-entry value, with only the grading of the tailings known. A new method of predicting the soil-water characteristic curve up to the air-entry value was also proposed. The results of the research showed that the tailings remain saturated up to the air-entry value. The clay, fine silt and medium silt sized tailings was found to be the controlling particle size ranges in the development of suctions. The vast amount of parameters and information gained through the use of the proposed test method clearly indicates its effectiveness in studying the performance and characteristics of a material drying from saturation. The results also indicated the effectiveness of the mid-plane suction probe for the direct measurement of suction. / Dissertation (M Eng (Geotechnical Engineering))--University of Pretoria, 2006. / Civil Engineering / unrestricted
62

Fluxes, dynamics and chemistry of particulates in the ocean

Gardner, Wilford Dana January 1978 (has links)
Thesis. 1978. Ph.D.--Massachusetts Institute of Technology. Dept. of Earth and Planetary Sciences. / Microfiche copy available in Archives and Science. / Vita. / Includes bibliographies. / by Wilford D. Gardner. / Ph.D.
63

Diffusion of light by colloidal clay suspensions

Davis, James Edward January 1933 (has links)
The purpose of this work is to find a method of determining the average particle size in samples of clays and ceramical materials, and to attempt to classify their physical properties according to the size of the particles. Such data should be useful to compare the properties of clays, to match different samples for uniformity, and to better control processes where clays are used, as for instance in manufacture of paper, rubber, and burned wear. / M.S.
64

Dispersion analysis of nonlinear periodic structures

Manktelow, Kevin Lee 29 March 2013 (has links)
The present research is concerned with developing analysis methods for analyzing and exploring finite-amplitude elastic wave propagation through periodic media. Periodic arrangements of materials with high acoustic impedance contrasts can be employed to control wave propagation. These systems are often termed phononic crystals or metamaterials, depending on the specific design and purpose. Design of these systems usually relies on computation and analysis of dispersion band structures which contain information about wave propagation speed and direction. The location and influence of complete (and partial) band gaps is a particularly interesting characteristic. Wave propagation is prohibited for frequencies that correspond to band gaps; thus, periodic systems behave as filters, wave guides, and lenses at certain frequencies. Controlling these behaviors has typically been limited to the manufacturing stage or the application of external stimuli to distort material configurations. The inclusion of nonlinear elements in periodic unit cells offers an option for passive tuning of the dispersion band structure through amplitude-dependence. Hence, dispersion analysis methods which may be utilized in the design of nonlinear phononic crystals and metamaterials are required. The approach taken herein utilizes Bloch wave-based perturbation analysis methods for obtaining closed-form expressions for dispersion amplitude-dependence. The influence of material and geometric nonlinearities on the dispersion relationship is investigated. It is shown that dispersion shifts result from both self-action (monochromatic excitation) and wave-interaction (multi-frequency excitation), the latter enabling dynamic anisotropy in periodic media. A particularly novel aspect of this work is the ease with which band structures of discretized systems may be analyzed. This connection enables topology optimization of unit cells with nonlinear elements. Several important periodic systems are considered including monoatomic lattices, multilayer materials, and plane stress matrix-inclusion configurations. The analysis methods are further developed into a procedure which can be implemented numerically with existing finite-element analysis software for analyzing geometrically-complex materials.
65

Use of flow field-flow fractionation for the characterisation of humic substances

Assemi, Shoeleh, 1963- January 2000 (has links)
Abstract not available
66

A study of the phenomenon of bridging of sugarcane bagasse

January 1996 (has links)
This work reports the results of a systematic study of the factors that affect the bridging behaviour of bagasse. It shows that traditional bulk solids theory is inappropriate for predicting bagasse flow mainly because of the impossibility of obtaining a reliable measure of internal friction. It demonstrates the significant influence of fibre length and moisture content on its handling charateristics. Correlations of pertinent bulk properties such as compactibility, tensile strength, surface friction and translation of vertical into horizontal pressure have been developed. These were derived as a result of measurements in equipment that was designed for the purpose. Finally, an empirical model utilising these correlations is proposed by which the likelihood of bridge formation in any piece of bagasse handling equipment can be determined. The validity of the model is assessed by comparison with bridging tests that were performed under controlled conditions. / Thesis (Ph.D.)-University of Natal, 1996
67

Estimating particle size of hydrocyclone underflow discharge using image analysis

Uahengo, Foibe Dimbulukwa Lawanifwa 04 1900 (has links)
Thesis (MScEng)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: Hydrocyclones are stationary separating machines that separate materials based on centrifugal separation and are widely used in chemical engineering and mineral processing industries. Their design and operation, compact structure, low running costs and versatility all contribute to their applications in liquid clarification, slurry thickening, solid washing and classification. With any of these operations, the overall profitability of the process relies on the effective control of the process equipment. However, in practice, hydrocyclones are difficult to monitor and control, owing to the complexity and difficulty in measuring internal flows in the equipment. Several studies have indicated that hydrocyclone underflow images can be used to monitor process conditions. The research described in this thesis considers the use of image analysis to monitor particle size and solids concentration in the underflow discharge of a hydrocyclone. The experimental work consisted of laboratory and industrial-based case studies. The laboratory cyclone used was a 76 mm general laboratory cyclone. A Canon EOS 400D digital camera was used for the underflow imaging. Image features such as pixel intensity values, underflow discharge width and grey level co-occurrence matrix (GLCM) were extracted from the images using MATLAB Toolbox software. Linear discriminant analysis (LDA) and neural network (NN) classification models were used to discriminate between different PGM ore types based on features extracted from the underflow of the hydrocyclone. Likewise, multiple linear regression and neural network models were used to estimate the underflow solids content and mean particle size in the hydrocyclone underflow. The LDA model could predict the PGM ore types with 61% reliability, while the NN model could do so with a statistically similar 62% reliability. The multiple linear regression models could explain 56% and 40% of variance in the mean particle size and solids content respectively. In contrast, the neural network model could explain 67% and 45% of the variance of the mean particle size and solids content respectively. For the industrial system, a 100% correct classification was achieved with all methods. However, these results are regarded as unreliable, owing to the insufficient data used in the models. / AFRIKAANSE OPSOMMING: Hidrosiklone is stasionêre skeidingsmasjiene wat materiale skei op grond van sentrifugale skeiding en word algemeen gebruik in die chemiese ingenieurswese en mineraalprosessering industrieë. Hul ontwerp en werking, kompakte struktuur, lae bedryfskoste en veelsydigheid dra by tot hul gebruik vir toepassings in vloeistofsuiwering, slykverdikking, vastestof wassing en klassifikasie. In enige van hierdie prosesse hang die oorhoofse winsgewendheid van die proses af van die effektiewe beheer van die prosestoerusting. In die praktyk is hidrosiklone egter moeilik om te monitor en beheer weens die kompleksiteit en moeilikheidsgraad daarvan om die interne vloei in die apparaat te meet. Verskeie studies het aangedui dat hidrosikloon ondervloeibeelde gebruik kan word om die proseskondisies te monitor. Die navorsing beskryf in hierdie tesis maak gebruik van beeldanalise moniteringstegnieke om die ertstipes en grootte- verspreidingsgebiede/ klasse van die ondervloei afvoerpartikels te bepaal. Sodoende word ‘n grondslag gelê vir verbeterde sikloon monitering en beheer. Die eksperimentele werk het bestaan uit beide laboratorium en industrieel-gebaseerde studies. Die laboratorium sikloon wat gebruik is, was ‘n 76 mm algemene laboratorium sikloon. ‘n Canon EOS 400D digitale kamera is gebruik om die hidrosikloon ondervloei beelde vas te vang. Beeldeienskappe soos beeldelement intensiteitswaardes, ondervloei afvoerwydte en grysvlak mede-voorkoms matriks is onttrek uit die beelde deur gebruik te maak van MATLAB Toolbox sagteware. Lineêre diskriminantanalise (LDA) en neural netwerk (NN) klassifikasiemodelle is gebou om te onderskei tussen die verskillende PGM ertse en gebaseer op veranderlikes wat afgelei is uit beelde van die ondervloei van die sikloon. Net so is daar ook gebruik gemaak van lineêre regressie- en neural netwerkmodelle om die vasestofkonsentrasie en gemiddelde partikelgrootte in die ondervloei van die sikloon te beraam. Die LDA model kon die PGM ertstipes met 61% betroubaarheid voorspel, terwyl die neural netwerkmodel dit kon doen met statisties dieselfde betroubaarheid van 62%. Die lineêre regressiemodelle kon onderskeidelik 56% en 40% van die variansie in die gemiddelde partikelgrootte en vastestofkonsentrasie verduidelik. In teenstelling iermee, kon die neurale netwerkmodel 67% en 45% van die variansie in die gemiddelde partikelgrootte en vastestofkonsentrasie verduidelik. In die nywerheidstelsel kon beide tipe modelle perfekte onderskeid tref tussen die partikelgroottes wat gemeet is op opeenvolgende dae van die bedryf van die siklone. Hierdie resultate is egter nie betroubaar nie, a.g.v. die beperkte hoeveelheid data wat beskikbaar was vir modellering.
68

Microbial Activity in Sediments: Effects on Soil Behavior

Rebata-Landa, Veronica 23 August 2007 (has links)
Microorganisms have played a critical role in geological processes and in the formation of soils throughout geological time. It is hypothesized that biological activity can also affect soil properties in short engineering time-scales. Bioactivity in sediments is determined by the classical limiting factors (i.e., nutrients, water, C for biomass, temperature and pH) as well as by pore-size geometrical limits and mechanical interactions between bacterial cells and soil particles. These constraints restrict the range of grain size and burial depth where biomediated geochemical processes can be expected in sediments, affect the interpretation of geological processes and the development of engineering solutions such as bioremediation. When biological, geometrical and mechanical limiting factors are satisfied, bioactivity can be designed to alter the mechanical properties of a soil mass, including lowering the bulk stiffness of the pore fluid through controlled gas bio-generation, increasing the shear stiffness of the soil skeleton by biomineralization, and reducing hydraulic conduction through biofilm formation and clogging. Each of these processes can be analyzed to capture the bio-chemo-hydro-mechanical coupling effects, in order to identify the governing equations that can be used for process design. Design must recognize the implications of spatial variability, reversibility and environmental impacts.
69

Aplicação de tecnologias analíticas de processo e inteligência artificial para monitoramento e controle de processo de recobrimento de partículas em leito fluidizado / Application of process analytical technologies and artificial intelligence to monitor and control a fluidized bed coating process

Silva, Carlos Alexandre Moreira da, 1984- 27 August 2018 (has links)
Orientador: Osvaldir Pereira Taranto / Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Química / Made available in DSpace on 2018-08-27T00:40:14Z (GMT). No. of bitstreams: 1 Silva_CarlosAlexandreMoreirada_D.pdf: 33350422 bytes, checksum: 046e0a2c090474593621166c81042136 (MD5) Previous issue date: 2015 / Resumo: As indústrias química, alimentícia e farmacêutica têm empregado extensivamente a operação de fluidização em inúmeros processos, devido às suas características bastante atrativas, que possibilitam um contato efetivo entre a fase sólida e fluida, o que reflete na geração de altas taxas de transferência de calor e de massa. No entanto, o regime de fluidização borbulhante, o qual é condição de partida dos processos que envolvem esta operação, frequentemente é afetado pelas condições operacionais. As temperaturas elevadas, o conteúdo de umidade excessivo das partículas e a introdução de líquidos no leito fluidizado podem conduzir a instabilidades no regime fluidodinâmico e provocar o colapso parcial ou total do leito, reduzindo a eficiência do processo. A manutenção de condições estáveis do regime de fluidização durante processos de recobrimento de partículas em leitos fluidizados é de fundamental importância para garantir uma eficiência de recobrimento favorável e evitar a formação de zonas sem movimentação e aglomeração das partículas no leito, pois estes fatores indesejáveis comprometem a mistura entre as fases e conseqüentemente a qualidade do produto final. Dentro deste contexto, a utilização de um sistema de monitoramento e controle em tempo real de processos de recobrimento de partículas é extremamente desejável para permitir a operação de regimes de fluidização estáveis e garantir um filme de recobrimento uniforme e boas condições de escoabilidade dos sólidos. A presente proposta de tese de doutorado tem por objetivo aplicar a metodologia de análise espectral Gaussiana dos sinais de flutuação de pressão (Parise et al. (2008)), para o desenvolvimento de sistemas de controle baseados em inteligência artificial (Lógica Fuzzy), visando monitorar a estabilidade do regime de fluidização em processo de recobrimento de partículas. Comparações entre as condições fluidodinâmicas dos processos com e sem controle foram analisadas para operações em leito fluidizado em escala de laboratorio. Para avaliar a qualidade das partículas foi utilizada uma sonda de monitoramento in-line (Parsum IPP70), onde se pôde verificar os instantes iniciais da aglomeração indesejada. Com a aplicação desde sistema automatizado foi possível associar a estabilidade da fluidização em função do elevado grau de aglomeração. O ponto de parada do processo pôde ser definido em 420 µm (inicial em 360 µm) e a partir deste o mecanismo de recobrimento acontece simultaneamente com o de aglomeração. Os parâmetros de monitoramento do regime conseguiram não somente identificar a fase inicial da defluidização, como também foi possível a partir deles, controlar o processo por Lógica Fuzzy-PI e estabilizar a operação para altas taxas de suspensão atomizadas / Abstract: The chemical, food and pharmaceutical industries have extensively used fluidization operation in many cases, due to its very attractive features that enable effective contact between the solid and fluid phase, which reflects the generation of high heat and mass transfer rates. However, the bubbling fluidization regime, which is the starting condition of the processes involved in this operation is often affected by operating conditions. Elevated temperatures, excessive moisture content of the particles and introduction of liquid into the fluidized bed may lead to instabilities in the fluid-dynamic regime and cause partial or total collapse of the bed, reducing the process efficiency. The maintenance of stable conditions of the fluidization regime for particle coating processes in fluidized beds is of fundamental importance to ensure a favorable coating efficiency and to avoid zones without movement and agglomeration of particles in the bed, because these undesirable factors compromise the mixing between the phases and therefore the quality of the final product. Within this context, the use of a monitoring system and real-time control of particle coating processes is highly desirable to allow operation in stable fluidization regimes and to ensure a uniform coating film and good condition of flowability of the solids. This doctoral thesis aims to apply the Gaussian spectral analysis methodology of the pressure fluctuation signals (Parise et al. (2008)) , for the development of control systems based on artificial intelligence (Fuzzy Logic), to monitor the stability of fluidization regime particle coating process. Comparisons between the fluid dynamic conditions of the processes with and without control were analyzed for operations in fluidized bed laboratory scale. To assess early stages of unwanted agglomeration, a monitoring in-line probe (Parsum IPP70) was used. With the application of this automated system, it was possible to associate the stability of fluidization with a high degree of agglomeration. The process stopping point could be set at 420 µm (initial in 360 µm) and after, the coating mechanism takes place simultaneously with the agglomeration one. The monitoring parameters of the system were able to identify the initial phase of defluidization, as well as it was possible to control the process by using Fuzzy Logic and to stabilize the operation for high rates of the coating suspension atomized onto the bed / Doutorado / Engenharia de Processos / Doutor em Engenharia Química
70

Concepção e estudo de uma unidade compacta para tratamento preliminar de esgoto sanitário composta por separador hidrodinâmico por vórtice e grade fina de fluxo tangencial / Designing and study of a compact unit for sewage preliminary treatment made up of a hydrodynamic vortex separator and a tangential flux fine screen

Prado, Gustavo Silva do 15 September 2006 (has links)
Atualmente, existe uma tendência entre os projetistas brasileiros de valorizar a etapa de tratamento preliminar em projetos de novas estações de tratamento de esgoto (ETE). Neste ensejo foi concebido, construído e estudado um protótipo, em escala plena, de uma unidade composta de separador hidrodinâmico por vórtice (SHV) – empregado como desarenador – e grade fina cilíndrica de fluxo tangencial. Estudos acerca da hidrodinâmica da unidade, fundamentados em ensaios de estímulo-resposta com traçador (sal de cozinha) e simulações computacionais do padrão de escoamento em software de dinâmica dos fluidos computacional, demonstrou que ao se operar a unidade com taxas de aplicação superficial (TAS) de 764 'M POT.3'/'M POT.2'd; 1.146 'M POT.3'/'M POT.2'd e 1.528 'M POT.3'/'M POT.2'd o regime de macro-mistura do padrão de escoamento que se desenvolve no SHV aproximou-se do plug-flow, porém com certo grau de mistura que diminuiu com o aumento da TAS. Nesta pesquisa, foram desenvolvidos dois métodos um para determinação da concentração de areia no esgoto sanitário e outro para determinação da distribuição granulométrica dos grãos dessa areia. Ambos foram empregados na avaliação de desempenho da unidade de tratamento preliminar desenvolvida, que foi realizada na estação elevatória de ETE Jardim das Flores do município de Rio Claro, SP. Durante esta fase da pesquisa, o SHV demonstrou enorme potencialidade na remoção de areia para as TAS de 764 'M POT.3'/'M POT.2'd; 1.146 'M POT.3'/'M POT.2'd e 1.528 'M POT.3'/'M POT.2'd, porquanto, além de não remover significativamente matéria orgânica particulada (medida em termos de concentração de sólidos suspensos voláteis) presentes no esgoto sanitário, a unidade atingiu eficiências de remoção de grãos de areia de tamanho maior ou igual a 200 'mü'm entre 85% e 95%. Entretanto, a grade fina cilíndrica de fluxo tangencial (auto-limpante) revelou-se inviável. / Currently, there is a trend among the brazilian designers of valorizing the preliminary treatment in recently designed wastewater treatment plants (WWTP). In this context, a full scale prototype of a unit made up of a hydrodynamic vortex separator (HVS) – applied as a degritter – and a tangential flux fine screening was designed, built and evaluated. Research about the hydrodynamic of the prototype, based on stimulus-response essays with a salt tracer (sodium chloride) and computational simulations of the flow pattern using the computational fluid dynamic (CFD) software, showed that the macro mixture regime of the flow was similar to a plug-flow when the unit was operated with superficial loading rates (SLR) of 746 'M POT.3'/'M POT.2'd; 1.146 'M POT.3'/'M POT.2'd and 1.528 'M POT.3'/'M POT.2'd, however, the flow presented a certain mixture degree that reduced with the SLR increase. In this research, two methods were developed: one for the determination of grit concentration in sewage and another one for the assessment of grit grading. Both methods were used on the evaluation of the HVS prototype efficiency, which was carried out at Jardim das Flores WWT, in the city of Rio Claro, SP. During this phase of the research, the HVS presented a great potential for grit removal when the SLR of 746 'M POT.3'/'M POT.2'd; 1.146 'M POT.3'/'M POT.2'd and 1.528 'M POT.3'/'M POT.2'd were applied; for the reason that, besides not significantly removing the particulate organic matter present in sewage (measured as volatile suspended solids), the unit achieved grit removal efficiencies in the range of 85% to 95% for grit equal to or large than 200 'mü'm. However, the tangential flux cylindrical fine screening (self cleaning) did not reveal feasibility.

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