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Showing 1 to 8 of 8 (0.047 seconds)Spelling suggestions: "subject:"pentacarbonyl"" "subject:"pentacarbonyle""
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Synthesis, reactions and catalytic studies of homo- and heterometallic complexes using bi- and tri-dentate phosphine ligandsNawar, Nagwa Abd El-All January 1989 (has links)
No description available.
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Reactions of iron pentacarbonyl with organic compounds.Alper, Howard. January 1967 (has links)
No description available.
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Reactions of iron pentacarbonyl with organic compounds.Alper, Howard January 1967 (has links)
No description available.
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Experimental Studies on Iron-Based Catalytic Combustion of Natural GasPan, Kang January 2013 (has links)
Catalytic combustion is an efficient method to reduce pollutant emissions produced by a variety of fuels. In this thesis, the use of iron pentacarbonyl (Fe(CO)5) as a catalyst precursor in the combustion of natural gas is experimentally studied. The counter-flow diffusion flame burner is employed as the experimental apparatus. The products of combustion are analyzed by using a Gas Chromatograph (GC) to quantitate the effects of adding the catalyst.
The experimental setup is such that a mixture of methane (CH4) and nitrogen (N2) is fed from the bottom burner while a mixture of oxygen (O2) and air is supplied from the top burner. The combustion of natural gas without catalyst is first characterized. The oxidizer and fuel flow parameters are set up so that a stable, flat blue flame is formed close to the centre plane between the two burners upon ignition. The experimental results agree with the literature data and the numerical predictions from CHEMKIN software.
To investigate and evaluate the performance of iron-containing catalysts on emission reduction, a small amount of separated nitrogen flow is used to carry iron pentacarbonyl into the flame through the central port of the fuel-side burner. Catalytic combustion produces an orange flame. Compared with the non-catalytic combustion data, it is found that carbon monoxide (CO) and soot precursor acetylene (C2H2) are reduced by 80% to 95% when 7453ppm iron pentacarbonyl is added.
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Experimental Studies on Iron-Based Catalytic Combustion of Natural GasPan, Kang January 2013 (has links)
Catalytic combustion is an efficient method to reduce pollutant emissions produced by a variety of fuels. In this thesis, the use of iron pentacarbonyl (Fe(CO)5) as a catalyst precursor in the combustion of natural gas is experimentally studied. The counter-flow diffusion flame burner is employed as the experimental apparatus. The products of combustion are analyzed by using a Gas Chromatograph (GC) to quantitate the effects of adding the catalyst.
The experimental setup is such that a mixture of methane (CH4) and nitrogen (N2) is fed from the bottom burner while a mixture of oxygen (O2) and air is supplied from the top burner. The combustion of natural gas without catalyst is first characterized. The oxidizer and fuel flow parameters are set up so that a stable, flat blue flame is formed close to the centre plane between the two burners upon ignition. The experimental results agree with the literature data and the numerical predictions from CHEMKIN software.
To investigate and evaluate the performance of iron-containing catalysts on emission reduction, a small amount of separated nitrogen flow is used to carry iron pentacarbonyl into the flame through the central port of the fuel-side burner. Catalytic combustion produces an orange flame. Compared with the non-catalytic combustion data, it is found that carbon monoxide (CO) and soot precursor acetylene (C2H2) are reduced by 80% to 95% when 7453ppm iron pentacarbonyl is added.
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Synthesis, characterization and catalytic application of carbonyl complexes of molybdenum and tungsten in epoxidation of some alkenes0gweno, Aloice 0. January 2010 (has links)
>Magister Scientiae - MSc / In this thesis we describe the synthesis of several carbonyl complexes of molybdenum and tungsten, compounds (Cl-ClO). The compounds Cl- C4 are zero valent carbonyl complexes containing N-base ligands prepared by following a common synthetic procedure. Compounds Cl and C2 were metal pentacarbonyl of 3-(1-methylpyrrolidin-2-yl) pyridine while C3 and C4 are metal tetracarbonyl complexes of 3, 5- dimethylpyrazole, (M=Mo, W). The compounds C5-C10 are divalent metal carbonyl complexes. Compounds CS and C6 were 3,5-dimethylpyrazole dibromotricarbonyl metal complexes prepared from the dibromotetracarbonyl metal dimers at room temperature while the compounds C7 and C8 were cyclopentadienyl halogenoaryltricarbonyl complexes prepared from the cyclopentadienyl metal dimers. Compounds C9 and ClO were prepared from cyclopentadienyl metal dimers by reacting the [CpM(C0)3r anion with CCl4 to obtain [CpM(C0)3Cl] and further reacted with 3-(1- methylpyrrolidin-2-yl) pyridine. All the compounds, Cl-ClO, were characterized by the
standard analytical techniques such as FTIR, 1H, 13C NMR; and UV-Vis spectroscopy. Compound C4 was characterized by X-ray crystallography. The structure is depicted as having a distorted octahedral geometry around the metal centre. The compounds Cl-ClO were then tested towards the epoxidation of selected cyclic and straight chain alkenes. The substrates used were cis-cyclooctene (Cyg), 1-octene (C8) cyclohexene (Cy6), 1-hexene (C6) and styrene (Sty). The epoxidation reactions were carried out at a temperature of 55 °C using tertbutylhydroperoxide (TBHP) as the oxidant and dichloroethane (DCE) as the solvent. The metal carbonyl complexes were pre-activated by first reacting them with the oxidant TBHP to obtain the metal-oxo complexes which are the active compounds for epoxidation reactions. The products were analyzed using GC techniques. The compounds, Cl-ClO showed a promising activity towards epoxidation reactions owing to the high conversions obtained by these compounds. For example, conversions of 81% (1-octene), 90% (cis-cyclooctene) were obtained by compound C5, 87% (cis-cyclooctene-compound C3, 95% (cis-cyclooctene-compound · C7) and 69% (ciscyclooctene- compound C4) for an average period of 24 h. The divalent metal carbonyl complexes showed a higher activity but with poor selectivity towards the expected epoxides compared to the zero valent metal carbonyl complexes.
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Regioselektive Synthese oxygenierter Carbazole / Regioselective Synthesis of Oxygenated CarbazolesKrahl, Micha P. 05 January 2007 (has links) (PDF)
In der heutigen Wirkstoffforschung stellen vor allem multiresistente Krankheitserreger eine große Herausforderung an die Wissenschaft dar. Noch sterben z.B. an der Tuberkulose jährlich etwa 1.7 Millionen Menschen, davon 69000 allein in Europa (WHO-Angaben, 2004). Die Tuberkulose verursacht neben AIDS die meisten Todesfälle unter den Infektionskrankheiten. Ein großes Problem sind die zahlreichen Neuerkrankungen, die mit herkömmlichen Mitteln nicht mehr behandelt werden können, sowie zunehmende Medikamentenallergien. Somit ist ein wichtiges Gebiet der Wirkstoff-forschung, neben der Weiterentwicklung bekannter Medikamente, deren Neuentwicklung. Dabei leistet die Natur eine unentbehrliche Orientierungshilfe. So konnte aus asiatischen Medizinalpflanzen in letzter Zeit eine Reihe von Carbazolalkaloiden isoliert werden, die zweifelsfrei gegen das HI-Virus oder das Mycobakterium tuberculose, dem Erreger der Tuberkulose, aktiv sind.[1] Ziel der vorliegenden Arbeit war die regioselektive Synthese oxygenierter Carbazole. Dabei wurde das Konzept der eisenvermittelten Carbazolsynthese angewendet und darüber hinaus als Alternative die palladiumvermittelte Carbazolsynthese weiterentwickelt. Die für den Palladiumweg benötigten N,N-Diarylamine konnten über die BUCHWALD-HARTWIG-Aminierung, die Eisensalzkomplexe über eine katalytische Komplexierung ausgehend von Cyclohexadienen mit Pentacarbonyleisen hergestellt werden. Beide Methoden wurden gegenübergestellt und besonders hinsichtlich ihrer Ausbeuten und Syntheseeffizienz verglichen.
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Regioselektive Synthese oxygenierter CarbazoleKrahl, Micha P. 20 December 2006 (has links)
In der heutigen Wirkstoffforschung stellen vor allem multiresistente Krankheitserreger eine große Herausforderung an die Wissenschaft dar. Noch sterben z.B. an der Tuberkulose jährlich etwa 1.7 Millionen Menschen, davon 69000 allein in Europa (WHO-Angaben, 2004). Die Tuberkulose verursacht neben AIDS die meisten Todesfälle unter den Infektionskrankheiten. Ein großes Problem sind die zahlreichen Neuerkrankungen, die mit herkömmlichen Mitteln nicht mehr behandelt werden können, sowie zunehmende Medikamentenallergien. Somit ist ein wichtiges Gebiet der Wirkstoff-forschung, neben der Weiterentwicklung bekannter Medikamente, deren Neuentwicklung. Dabei leistet die Natur eine unentbehrliche Orientierungshilfe. So konnte aus asiatischen Medizinalpflanzen in letzter Zeit eine Reihe von Carbazolalkaloiden isoliert werden, die zweifelsfrei gegen das HI-Virus oder das Mycobakterium tuberculose, dem Erreger der Tuberkulose, aktiv sind.[1] Ziel der vorliegenden Arbeit war die regioselektive Synthese oxygenierter Carbazole. Dabei wurde das Konzept der eisenvermittelten Carbazolsynthese angewendet und darüber hinaus als Alternative die palladiumvermittelte Carbazolsynthese weiterentwickelt. Die für den Palladiumweg benötigten N,N-Diarylamine konnten über die BUCHWALD-HARTWIG-Aminierung, die Eisensalzkomplexe über eine katalytische Komplexierung ausgehend von Cyclohexadienen mit Pentacarbonyleisen hergestellt werden. Beide Methoden wurden gegenübergestellt und besonders hinsichtlich ihrer Ausbeuten und Syntheseeffizienz verglichen.
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