>Magister Scientiae - MSc / Clay diagenesis phenomenon and their effects on some petrophysical properties of lower cretaceous silliciclastic sandstones, offshore Orange basin have been established. Previous studies on Orange basin revealed that chlorite and quartz cements have significantly compromised the reservoir quality in this basin but it is expected that the reservoirs shows better improvement basinward, an analogy of this is displayed by tertiary sandstones deposit, offshore Angola. The main goal of this thesis is to perform reservoir quality evaluation by intergrating geological, geochemical and geophysical tools to substantiate the effects of clay minerals distribution and its subsequent diagenesis on the intrinsic properties (porosity, permeability and saturation) of reservoir intervals encountered within three wells in block 3A (deeper waters), offshore Orange basin. Five lithofacies were identified based on detailed core description from wells KF-1, KH-1 and AU-1 in this block. The facies were grouped based on colour and grain sizes, they are named : A1 (shale), A2 (sandstone), A3 (siltstone), A4 (dark coloured sandstone) and A5 (conglomerates).Depositional environment is predominantly marine, specifically, marine delta front detached bars and deepwater turbiditic sandstone deposit. Geophysical wire line logs of gamma ray, resistivity logs combo and porosity logs were interpreted, parameters and properties such as VCL, porosity, permeability and saturation were estimated from these logs and the values obtained were compared with values from conventional core analysis data, the values agreed well with each other. Detailed petrographic studies (SEM, XRD and thinsection) plus geochemical studies (CEC, EDS, pH, Ec) were carried out on twenty two core samples to establish if these clay minerals and other cements have pervasive effects on the reservoir quality or otherwise.

>Magister Scientiae - MSc / Pletmos Basin is a Mesozoic half graben located in the southern part of South Africa and has undergone numerous tectonic changes which involve alteration of structure and reworking of sediments. Clay diagenesis has become a more prominent factor affecting the quality of the tight shaly sandstone reservoirs in the southern Pletmos Basin. The present study focused on Block 11a as a primary area of interest .The tight sandstone reservoirs encountered in the four wells, viz. Ga-Q1, Ga- Q2, Ga-Z1 and Ga- E2 were studied using four different methods to incorporate and infer the overall diagenetic effect on the reservoirs, caused by materials of argillaceous origin. The methods adopted in the present research are formation evaluation using wireline logs and calibration of core data using Interactive Petrophysics software, thin section petrography, X-Ray Diffraction (XRD) and, Scanning Electron Microscope (SEM) along with Energy Dispersive X-Ray Spectroscopy (EDS). The availability of core samples were limited to wells Ga- Q1 and well Ga- Z1. Four reservoirs within the Cretaceous age were identified in each well and the best reservoirs were associated with facies B and D. / 2022-04-30

The development of hydrocarbon energy resources from shale, a fine-grained, low-permeability geological formation, has altered the global energy landscape. Constricting pressure exerted on a shale formation has a significant effect on the rock's apparent permeability. Gas flow in low-permeability shales is significantly different from liquid flow due to the Klinkenberg effect caused by gas molecule slip at the nanopore wall surfaces. This has the effect of increasing apparent permeability (i.e., the measured permeability). Optimizing the conductivity of the proppant assembly is another critical component of designing subsurface hydrocarbon production using hydraulic fracturing. Significant fracture conductivity can be achieved at a much lower cost than conventional material costs, according to the optimal partial-monolayer proppant concentration (OPPC) theory. However, hydraulic fracturing performance in unconventional reservoirs is problematic due of the complex geomechanical environment, and the experimental confirmation and investigation of the OPPC theory have been rare in previous studies. In this dissertation, a novel multiphysics shale transport (MPST) model was developed to account for the coupled multiphysics processes of geomechanics, fluid dynamics, and the Klinkenberg effect in shales. Furthermore, A novel multi-physics multi-scale multi-porosity shale gas transport (M3ST) model was developed based on the MPST model research to investigate shale gas transport in both transient and steady states, and a double-exponential empirical model was also developed as a powerful substitute for the M3ST model for fitting laboratory-measured apparent permeability. Additionally, throughout the laboratory experiment of fracture conductivity with proppant, the four visible stages documented the evolution of non-monotonic conductivity and proppant concentration. The laboratory methods and empirical model were then applied to the shale plugs from Central Appalachia to investigate the formation properties there. The benefits of developing these regions wisely include a smaller surface footprint, reduced infrastructure requirements, and lower development costs. The developed MPST, M3ST, double-exponential empirical models and research findings shed light on the role of multiphysics mechanisms, such as geomechanics, fluid dynamics and transport, and the Klinkenberg effect, in shale gas transport across multiple spatial scales in both steady and transient states. The fracture conductivity experiments successfully validate the theory of OPPC and illustrate that proppant embedment is the primary mechanism that causes the competing process between fracture width and fracture permeability and consequently the non-monotonic fracture conductivity evolution as a function of increasing proppant concentration. The laboratory experimental facts and the numerical fittings in this study provided critical insights into the reservoir characterization in Central Appalachia and will benefit the reservoir development using non-aqueous fracturing techniques such as CO2 and advanced proppant technologies in the future. / Doctor of Philosophy / Production of oil and gas from the extremely tight rock has changed the global energy industry, including job growth, energy security, and environment protection. However, the oil and gas production from the tight rock is difficult because of the complex rock properties. Hydraulic fracking can resolve the issue and contribute to the high production. The higher and safer production needs us to have a better understanding of oil and gas flow under the ground. A series of laboratory experiment were conducted, and a new shale gas transport model is introduced in this dissertation to explain the oil and gas flow under the complicated scenarios. The experimental results show that many factors can impact the oil and gas flow, and the model can match the experimental results very well. A few statistical methods are also used in the data analysis. The optimization of proppant pack is another important component of hydraulic fracking. Proppant particles are usually man-made ceramic tiny balls, which will be injected into the underground to keep the fractures from closing during the production. From the previous papers, it is possible to achieve high fracture conductivity at a much lower cost than traditional proppant costs. Many groups of laboratory experiment were conducted to demonstrate this guess. Many rock samples in the experiment are from Central Appalachian area, which can help the resource development in this area. The developed model and experimental research findings in this study provided critical insights into the role of the many physics mechanisms on shale gas transport, proppant optimization, and hydraulic fracking.

Reliable assessment of static and dynamic petrophysical properties of hydrocarbon-bearing reservoirs is critical for estimating hydrocarbon reserves, identifying good production zones, and planning hydro-fracturing jobs. Conventional well-log interpretation methods are adequate to estimate static petrophysical properties (i.e., porosity and water saturation) in formations consisting of thick beds. However, they are not as reliable when estimating dynamic petrophysical properties such as absolute permeability, movable hydrocarbon saturation, and saturation-dependent capillary pressure and relative permeability. Additionally, conventional well-log interpretation methods do not take into account shoulder-bed effects, radial distribution of fluid saturations due to mud-filtrate invasion, and differences in the volume of investigation of the various measurements involved in the calculations. This dissertation introduces new quantitative methods for petrophysical and compositional evaluation of water- and hydrocarbon-bearing formations based on the combined numerical simulation and nonlinear joint inversion of conventional well logs. Specific interpretation problems considered are those associated with (a) complex mineral compositions, (b) mud-filtrate invasion, and (c) shoulder-bed effects. Conventional well logs considered in the study include density, photoelectric factor (PEF), neutron porosity, gamma-ray (GR), and electrical resistivity. Depending on the application, estimations yield static petrophysical properties, dynamic petrophysical properties, and volumetric/weight concentrations of mineral constituents. Assessment of total organic carbon (TOC) is also possible in the case of hydrocarbon-bearing shale. Interpretation methods introduced in this dissertation start with the detection of bed boundaries and population of multi-layer petrophysical properties with conventional petrophysical interpretation results or core/X-Ray Diffraction (XRD) data. Differences between well logs and their numerical simulations are minimized to estimate final layer-by-layer formation properties. In doing so, the interpretation explicitly takes into account (a) differences in the volume of investigation of the various well logs involved, (b) the process of mud-filtrate invasion, and (c) the assumed rock-physics model. Synthetic examples verify the accuracy and reliability of the introduced interpretation methods and quantify the uncertainty of estimated properties due to noisy data and incorrect bed boundaries. Several field examples describe the successful application of the methods on (a) the assessment of residual hydrocarbon saturation in a tight-gas sand formation invaded with water-base mud (WBM) and a hydrocarbon-bearing siliciclastic formation invaded with oil-base mud (OBM), (b) estimation of dynamic petrophysical properties of water-bearing sands invaded with OBM, (c) estimation of porosity and volumetric concentrations of mineral and fluid constituents in carbonate formations, and (d) estimation of TOC, total porosity, total water saturation, and volumetric concentrations of mineral constituents in the Haynesville shale-gas formation. Comparison of results against those obtained with conventional petrophysical interpretation methods, commercial multi-mineral solvers, and core/XRD data confirm the advantages and flexibility of the new interpretation techniques introduced in this dissertation for the quantification of petrophysical and compositional properties in a variety of rock formations. / text

Les propriétés pétrophysiques des réservoirs silicoclastiques sont influencées par de nombreux facteurs sédimentaires et diagénétiques. Les principaux phénomènes diagénétiques affectant les réservoirs sont généralement la cimentation de quartz et les compactions mécanique et chimique. Des réservoirs gréseux ayant des contextes géologiques différents ont été considérés dans cette étude ; les réservoirs carbonifères d’origine deltaïque-marine du bassin des Palmyrides-Sud en Syrie et les réservoirs cambro-ordoviciens du bassin de Sbaa en Algérie. Cette thèse consiste à établir l’histoire diagénétique, déterminer les contrôles sédimentaires et structuraux influençant l’évolution des phénomènes diagénétiques, caractériser l’habitus des cristaux authigènes de quartz formés autour les grains détritiques et aussi mettre en relation les différentes contrôles sédimentaires et diagénétiques sur les caractéristiques des pores et ainsi que sur la variation de la perméabilité. L’histoire diagénétique entre le réservoir du bassin de Sbaa se caractérise par une forte cimentation de quartz composée de trois phases Q1, Q2 /et Q3, par tapissage illitique et ainsi par une importante compaction chimique liée à certains faciès glaciaires et également une cimentation d’argiles principalement en illite mais surtout dans les champs d’Oued Zine et de Bou Hadid. A l’exception du champ de Hassi Ilatou, où une faible cimentation de quartz composée de Q1 a eu lieu. Alors que la diagenèse des réservoirs gréseux du bassin des Palmyrides-Sud est représentée par une faible cimentation de quartz composée d’une seule phase Q1, une absence de compaction chimique, ainsi qu’une cimentation d’argiles dominée par la chlorite et les kaolins. Les analyses microthermométriques des inclusions fluides dans les surcroissances de quartz mettent en évidence une silicification se déroulant principalement entre 100 et 160°C dans les deux bassins. D’après la reconstitution de l’histoire thermique de bassin, cet intervalle de température a été atteint entre le Viséen et la fin du Namurien dans le bassin de Sbaa et au Crétacé supérieur-Paléocène dans le bassin des Palmyrides-Sud. Les analyses isotopiques indiquent une eau originelle météorique et marine, progressivement réchauffée lors de l’enfouissement, et s’enrichissant au fur et à mesure en ¹⁸O dans les pores intergranulaires et des fluides évolués et chauds à l’origine des filonnets. L’habitus des cristaux authigènes de quartz et la forme de croissance montrent une relation avec les phases de ciment de quartz, son taux et la présence/absence de gaz. En effet, des cristaux à prisme court, tronqués par des facettes additionnelles, et des cristaux trapus caractérisent les grès cimentés par une seule phase de quartz authigène, et une fréquence importante des cristaux de quartz à multiples nucléas est constatée dans ces grès. Des cristaux à prisme développé et rarement des cristaux à prisme court caractérisent les grès contenant deux phases du ciment de quartz. Des cristaux peu développés et limités à quelques faces sont présents dans les grès cimentés par trois phases du ciment de quartz dans la paléozone à eau du réservoir dans le champ ODZ. Une forme de croissance en escalier est présente uniquement dans ces derniers grès. La présence des inclusions à hydrocarbures dans les surcroissances de quartz dans la partie supérieure du réservoir ordovicien du champ de Oued Zine indique que la mise en place des hydrocarbures dans le réservoir a été contemporaine à la cimentation de quartz à des températures 100-140°C en raison de la paléostructure anticlinale dans ce champ. Un deuxième épisode a eu lieu suite à la fracturation hercynienne à des températures comprises entre 117-185°C qui augmente vers le nord-ouest du bassin. La composition du gaz dans les inclusions monophasées (92 ± 5 mole %) est comparable à la composition actuelle du gaz dans le réservoir. / Petrophysic properties of siliciclastic reservoirs are influenced by many sedimentary and diagenetic factors. The main diagenetic processes affecting the reservoir quality are quartz cementation and mechanical and chemical compaction. The cementing of quartz plays a role in reducing the porosity as it precipitates occupying intergranular porosity. However, its influence on the evolution of permeability is not well known because the morphology of authigenic quartz crystals and controls responsible for this morphology remain poorly understood. Sandstone reservoirs with different geological settings were considered in this study; Carboniferous reservoirs of deltaic-marine Palmyrides South Basin (fields: Arak, Debayate South, and Sukhneh) in Syria and the Cambro-Ordovician reservoirs Sbaa Basin (fields : Hassi Ilatou , Hassi Ilatou NE, Bou Hadid, Oued Zine, and Bou Hadid W) in Algeria. They have widely varying porosities both laterally and vertically and permeabilities. Thus, this thesis is to establish the diagenetic history, determine the sedimentary and structural controls influencing the evolution of diagenesis, characterize crystallographic habits of authigenic quartz formed around the detrital grains and to relate the different sedimentary controls and diagenetic on pore characteristics and as well as the variation of the permeability. In the Sbaa Basin, the presence of inclusions hydrocarbons allowed to reconstruct the history of gas migration. The diagenetic history of the Sbaa Basin is characterized by strong cementing quartz composed of three phases Q1, Q2 / Q3, illite coatings, significant chemical compaction, and also by illite cements, especially in the fields of Oued Zine and Bou Hadid. However, Hassi Ilatou field shows low quartz cementation (Q1). In addition, reservoir sandstones of the Palmyrides-South Basin show low quartz cementation composed of a single phase Q1, an absence of chemical compaction, as well as clay cementation dominated by chlorite and kaolin characterize the diagenesis history. Microthermometric analyzes of fluid inclusions located in quartz overgrowths show that the silicification occurred mainly between 100 and 160 °C in both basins. According to the reconstruction of the thermal history, these temperatures have been reached between the end of the Visean and Namurian for the Sbaa Basin and Upper Cretaceous-Paéocène for the Palmyrides-South Basin. Isotope analyzes indicate marine/meteoric water gradually heated during burial, and enriched in ¹⁸O in intergranular pores and evolved hot fluids are responsible for vein precipitation. The habits of quartz overgrowth crystals and growth forms observed in the studied sandstones show a relation with the number of quartz cement phases. Effectively, crystals with short prisms, truncated by supplementary faces, and large crystals characterize one-phased (Q1) cemented sandstones. In addition, quartz crystals of multiple nucleations are frequent in these sandstones. However, crystals with long prisms and rarely crystals with short prisms characterize two-phased (Q1 and Q2) cemented sandstones. Crystals of poorly developed faces are present in three-phased (Q1, Q2, and Q3) cemented sandstones. Step-like striation present only in these sandstones. Methane inclusions in the quartz overgrowths of the upper part of Ordovician reservoir of Oued Zine indicate that the gas emplacement into the reservoir occurred synchronically with early quartz cementation in the sandstones located near the contact with the Silurian gas-source rocks at 100-140°C during the Late Carboniferous period and the late Hercynian episode fracturing at temperatures between 117 and 185°C. Microthermometric data on gas inclusions reveal the presence of an average of 92 ± 5 mole % of CH4, which is similar to the present-day gas composition in the reservoirs.

Orientadores: Euclides Jose Bonet, Marco Antonio Schreiner Moraes / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecanica / Made available in DSpace on 2018-07-26T08:21:56Z (GMT). No. of bitstreams: 1 DeGasperi_PatriciaMartinsSilva_M.pdf: 13462853 bytes, checksum: cff9140cfbd41d9dc52865fb52425605 (MD5) Previous issue date: 1999 / Resumo: Este trabalho tem como objetivos o estudo e a aplicação do processo de estimativa de propriedades petrofisicas a partir de informações obtidas em imagens petrográficas bidimensionais. O método assume a hipótese da homogeneidade estatística, e utiliza a simulação estocástica para a reconstrução do modelo tridimensional do meio poroso. A caracterização geométrica do meio simulado permite a elaboração de um modelo de rede para a simulação do fluxo e a estimativa da permeabilidade, fator de formação, pressão capilar por injeção de mercúrio e relação índice de resistividade versus saturação de água. Esta metodologia é aplicada a quatro sistemas porosos com diferentes níveis de heterogeneidade. Os resultados demonstram que estimativas confiáveis dependem da utilização de uma resolução apropriada de aquisição das imagens, que permita a identificação de poros e gargantas que efetivamente controlem as propriedades de fluxo do sistema. As curvas de pressão capilar simuladas sugerem a necessidade da composição de escalas. As propriedades elétricas são afetadas pela porosidade das amostras e sua confiabilidade é restrita a sistemas preferencialmente molháveis pela água / Abstract: The aim of this work is to investigate and apply a method for predicting petrophysical properties ftom bidimensional petrographic image data. Based on the assumption of statistical homogeneity, the method uses stochastic simulation to reconstruct the porous media tridimensional structure. The geometrical characterization of the simulated media allows the construction of a network model to simulate fluid flow and estimate permeability, formation factor, mercury capillary pressure curves and resistivity index as function of water saturation. This method is applied to four porous systems with different heterogeneity levels. The results demonstrate that good predictions depend on the appropriate image aquisition resolution, which identifies pores and throats that effectively control the flow properties of the system. The capillary pressure curves suggest the necessity of scale composition. The electrical properties are affected by samples porosity, with reliable estimates being restricted to water-wet systems / Mestrado / Mestre em Engenharia de Petróleo

Thesis (MSc)--Stellenbosch University, 2011. / ENGLISH ABSTRACT: This study presents an outcrop characterisation and modelling of the excellently exposed Permian Kookfontein Formation of the Ecca Group in the Tanqua-Karoo sub-Basin. The sedimentary modelling (i.e. facies architecture and geometry) and petrophysical characterisation followed a hierarchical and deterministic approach. Quantitative outcrop data were based on the thirteen sedimentary cycles that characterise this stratigraphic succession at the Pienaarsfontein se Berg locality; and these data were analysed using a combination of detailed sedimentary log, gamma ray log and photopanel analysis, as well as petrographic thin-section and grain size-based petrophysical analysis. Based on texture and sedimentary structures, twelve depofacies are recognised which are broadly grouped into four lithofacies associations i.e. sandstone facies, heterolithic facies, mudstone facies and soft-sediment deformation facies; these depofacies and lithofacies form the basic building blocks for the flooding surface-bounded facies succession (i.e. cycle). Also, based on sediment stacking and cycle thickness patterns as well as relative position to the shelf break, the succession is sub-divided into: (1) the lower Kookfontein member (i.e. cycles 1 to 5) exhibiting overall upward thickening and coarsening succession with progradational stacking pattern; representing deposition of mid-slope to top-slope/shelf-margin succession, and (2) the upper Kookfontein member (i.e. cycles 6 to 13) exhibiting overall upward thickening and coarsening succession with aggradational stacking pattern; representing deposition of top-slope/shelf-margin to outer shelf succession. Lateral juxtaposition of observed vertical facies variations across each cycle in an inferably basinwards direction exhibits upward change in features, i.e. decrease in gravity effects, increase in waves and decrease in slope gradient of subsequent cycles. This systematic upward transition in features, grading vertically from distal to proximal, with an overall upward thickening and coarsening progradational to aggradational stacking pattern indicates a normal regressive prograding delta. However, in detail, cycles 1-3 show some anomalies from a purely thickening and coarsening upward succession. Deposition of each cycle is believed to result from: (1) primary deposition by periodic and probably sporadic mouthbar events governed by stream flow dynamics, and (2) secondary remobilisation of sediments under gravity. The facies distribution, architecture and geometry which governs the sedimentary heterogeneity within the deltaic succession is therefore mainly a consequence of the series of mouthbar flooding events governed by sediment supply and base-level changes. These series of flooding events resulted in the delineation of the studied stratigraphic interval into two main parasequence sets, i.e. transgressive sequence set and the overlying regressive sequence set. This delineation was aided through the identification of a maximum flooding surface (i.e. maximum landwards shift in facies) above Cycle 3 in the field. The architecture and geometry of the ensuing deposystem is interpreted to have been a river-dominated, gravitationally reworked and waveinfluenced shelf edge Gilbert-type delta. Widespread distribution of soft-sediment deformation structures, their growth-style and morphology within the studied succession are empirically related to progradation of Gilbert-type mouthbars over the shelf break as well as the slope gradients of the Kookfontein deltaic clinoformal geometry. Analysis of hypothetical facies stacking and geometrical models suggests that the Kookfontein sedimentary cyclicity might not be accommodation-driven but rather sediment supply-driven. The workflow employed for petrophysical evaluation reveals that the distribution of reservoir properties within the Kookfontein deltaic sandbody geometries is strongly influenced both by depositional processes and by diagenetic factors, the latter being more important with increased burial depth. The reservoir quality of the studied sandstones decreases from proximal mouthbar sands, intermediate delta front to distal delta front facies. The major diagenetic factors influencing the reservoir quality of the studied sandstones are mechanical compaction, chemical compaction (pressure solution) and authigenic pore-filling cements (quartz cement, feldspar alteration and replacement, calcite cement, chlorite and illite). Mechanical compaction was a significant porosity reducing agent while cementation by authigenic quartz and clay minerals (i.e. illite and chlorite) might play a major role in permeability distribution. The porosity-permeability relationship trends obtained for the studied sandstones show that there is a linear relationship between porosity and permeability. The relative timing of diagenetic events as well as the percentages of porosity reduction by compaction and cementation indicates that compaction is much more responsible for porosity reduction than cementation. The described internal heterogeneity in this work is below the resolution (i.e. mm-scale) of most conventional well-logs, and therefore could supplement well-log data especially where there is no borehole image and core data. The combination of ‗descriptive‘ facies model and schematic geological model for this specific delta, and petrophysical characterisation make the results of this study applicable to any other similar ancient deposystem and particularly subsurface reservoir analogue. / AFRIKAANSE OPSOMMING: Hierdie studie bied ‘n dagsoomkarakterisering en -modellering van die duidelik blootgelegde Permiese Kookfontein-formasie van die Ecca-groep in die Tankwa-Karoo-subkom. Wat die sedimentêre modellering (d.w.s. fasiesargitektuur en -geometrie) en petrofisiese karakterisering betref is ‘n hiërargiese en deterministiese benadering gevolg. Kwantitatiewe dagsoomdata is gebaseer op dertien sedimentêre siklusse wat hierdie stratigrafiese opeenvolging in die Pienaarsfontein se Berg-lokaliteit kenmerk; en die data is geanaliseer met behulp van ‘n kombinasie van gedetailleerde sedimentêre seksie, gammastraal-profiel en fotopaneelanalises, asook petrografiese slypplaatjie- en korrelgrootte-gebaseerde petrofisiese analises. Op grond van tekstuur en sedimentêre strukture is twaalf afsettingsfasies onderskei wat rofweg in vier assosiasies van litofasies gegroepeer kan word: sandsteenfasies, heterolitiese fasies, moddersteenfasies en sagtesediment-deformasiefasies. Hierdie afsettingsfasies en litofasies vorm die basiese boustene vir die fasiesopeenvolging (d.w.s. siklus) wat oorstromingsoppervlakgebonde is. Verder word die opeenvolging aan die hand van sedimentstapeling en skilusdiktepatrone, asook relatiewe posisie tot die rakbreuk, in die volgende onderverdeel: (1) die benede-Kookfontein-deel (d.w.s. siklus 1 tot 5), wat in die geheel ‘n opwaartse verdikkings- en vergrowwingsopeenvolging met ‘n progradasiestapelpatroon vertoon en die afsetting van middelhelling-tot-boonstehelling- of rakrand-opeenvolging verteenwoordig, en (2) die benede-Kookfontein-deel (d.w.s. siklus 6 tot 13) wat in die geheel ‘n opwaartse verdikkings- en vergrowwingsopeenvolging met ‘n aggradasiestapelpatroon vertoon en die afsetting van boonste helling- of rakrand-tot-buiterakopeenvolging verteenwoordig. Die laterale jukstaposisie van waargenome vertikale fasiesvariasies oor elke siklus heen, in ‘n afleibare komwaartse rigting, vertoon opwaartse verandering wat kenmerke betref, naamlik afname in gravitasiegevolge, toename in golwe en afname in die hellinggradiënt van daaropvolgende siklusse. Hierdie stelselmatige opwaartse oorgang van kenmerke, wat vertikaal van distaal tot proksimaal gradiënteer en in die geheel opwaartse verdikking en vergrowwing in ‘n progradasie-tot-aggradasie-stapelpatroon vertoon, dui op ‘n normale regressiewe progradasiedelta. Van naby beskou, vertoon siklus 1-3 egter bepaalde afwykings van ‘n suiwer opwaartse verdikkings- en vergrowwingsopeenvolging. Die afsettings van elke siklus is vermoedelik die gevolg van: (1) primêre afsetting deur periodieke en waarskynlik sporadiese mondversperringsgebeure wat deur stroomvloeidinamika beheer word, en (2) sekondêre hermobilisering van sedimente deur gravitasie. Die fasiesverspreiding, -argitektuur en -geometrie wat die sedimentêre heterogeniteit in die deltaïese opeenvolging beheer, is dus hoofsaaklik ‘n gevolg van die reeks oorstromingsgebeure by die mondversperring, wat deur sedimentvoorsiening en basisvlakveranderings beheer word. Hierdie reeks oorstromingsgebeure het gelei tot die delineasie van die bestudeerde stratigrafiese interval volgens twee hoofparasekwensie stelle, naamlik die transgressiewe opeenvolgings- en die oordekkende, regressiewe opeenvolgingsgroep. Dié delineasie word ondersteun deur die feit dat ‘n maksimum oorstromingsoppervlak (d.w.s. maksimum landwaartse verskuiwing in fasies) bo siklus 3 in die veld uitgeken is. Die argitektuur en geometrie van die daaropvolgende afsettingstelsel word geïnterpreteer as behorende tot ‘n Gilbert-rakranddelta wat deur ‘n rivier gedomineer, deur gravitasie herbewerk en deur golfwerking beïnvloed is. Die wye verspreiding van sagtesediment-deformasiestrukture, en die groeiwyse en morfologie daarvan binne die bestudeerde opeenvolging, is empiries verwant aan die progradasie van Gilbertmondversperrings oor die rakbreuk heen, asook aan die hellinggradiënte van die Kookfontein-deltaïese, klinoformele geometrie. Die analise van hipotetiese fasiesstapeling en geometriese modelle dui daarop dat die Kookfontein-sedimentêre siklisiteit dalk nie deur akkommodasieruimte gedryf word nie, maar deur sedimentvoorsiening. Die werkvloei wat vir petrofisiese evaluering gebruik is dui daarop dat die verspreiding van reservoir-eienskappe in die Kookfontein- deltaïese sandliggaam geometries sterk beïnvloed word deur afsettingsprosesse en diagenetiese faktore. Die diagenetiese faktore word belangriker op groter begrawing diepte. Die reservoir-aard van die bestudeerde sandgesteentes neem algaande af van proksimale mondversperring-sandsoorte tot intermediêre deltafront tot distale deltafrontfasies. Die hoof-diagenetiese faktore wat die reservoir-kenmerke van die bestudeerde sandsteensoorte beïnvloed is meganiese verdigting, chemiese verdigting (oplossingsdruk) en outigeniese porievullingsement (kwartssement, veldspaatomsetting en -vervanging, kalsietsement, chloriet en illiet). Meganiese verdigting is ‘n beduidende poreusheidreduseermiddel, terwyl sementering deur outigeniese kwarts- en kleiminerale (d.w.s. illiet en chloriet) moontlik ‘n belangrike rol by permeabiliteitsverspreiding kan speel. Die poreusheid-permeabiliteit-verhoudingstendense wat bekom is vir die bestudeerde sandsteensoorte dui daarop dat daar ‘n lineêre verhouding tussen poreusheid en permeabiliteit bestaan. Die relatiewe tydberekening van diagenetiese gebeure, asook die persentasie poreusheidvermindering deur verdigting en sementering, dui daarop dat verdigting baie meer as sementering tot poreusheidvermindering bydra. Die interne heterogeniteit wat in hierdie werk beskryf word, is onder die resolusie (d.w.s. mm-skaal) van die meeste konvensionele boorgatopnames, en kan dus boorgatopnamedata aanvul, veral waar daar geen boorgatafbeelding en kerndata bestaan nie. Die kombinasie van die 'deskriptiewe‘ fasiesmodel en skematiese geologiese model vir hierdie spesifieke delta, asook petrofisiese karakterisering, beteken dat die resultate van hierdie studie op enige ander soortgelyke antieke afsettingstelsels toegepas kan word, maar veral op suboppervlakreservoir-analoogstelsels.

3 ABSTRACT The work is focused on analysis of five structural well profiles penetrating sediments of the Bohemian Cretaceous Basin and the underlying Upper Palaeozoic continental basins to the crystalline basement. The objectives of well profile analysis are sedimentary formation evaluation from well log analysis and statistical analysis and evaluation of some physical properties of sedimentary rocks, which have been determined by measurements of drill cores. The aim of the work is to verify the possibility of porosity evaluation from well log analysis in the Bohemian Cretaceous Basin and the underlying Upper Palaeozoic continental basins. The next aim is to compare different geological environments with respect to physical properties of rocks. The content of the work involves presentation of well log curves, computation of porosity values and comparison between the resulting values of porosity from resistivity log, acoustic log and neutron-neutron log and from laboratory measurements of drill core samples. Data from five deep structural wells are used. Different geological environments were compared by statistical methods with respect to physical properties of rocks measured on well core samples from these five wells. Porosity evaluation from well log analysis is difficult but it is possible provided that...

Depuis une dizaine d'années, une volonté internationale de réduction des émissions de gaz à effet de serre s'est développée, afin de limiter leur concentration dans l'atmosphère. Ainsi, il est envisagé de récupérer le CO₂ issu d'activités humaines fortement émettrices afin de le réinjecter dans le sous-sol à l'état supercritique. Hors du panache de CO₂ supercritique, ce gaz se dissout dans la saumure et l'acidifie. Deux phénomènes ont alors lieu. Ils constituent la base des études menées au cours de cette thèse : (i) le devenir des espèces chimiques mobilisées par la dissolution des minéraux, et (ii) les variations des propriétés d'écoulements induites par la réactivité de la roche encaissante. Pour étudier ces phénomènes, des expériences ont été menées sur les carbonates de Lavoux et de St-Emilion. Ces deux échantillons naturels ont été sélectionnés pour leur composition minérale modèle qui assure une forte réactivité dans le contexte de l'étude, et l'absence d'argile et de matière organique qui limite la complexité du système géochimique. Les expériences menées sont de deux types. En autoclave, la compétition entre dissolution et sorption des éléments traces est mise en avant et permet d'investiguer des conditions variant de celles de la surface (20°C – 1 atm) à celles d'un site de stockage (40°C – 90 bar de CO₂) en passant par des intermédiaires de pression (30 et 60 bar). Les effets de la salinité de la saumure, de la concentration initiale en cations divalents ainsi que de l'état de l'échantillon solide (poudre, plug) sont étudiés. D'autre part, un dispositif expérimental a été développé au cours de cette thèse. Il permet d'étudier les propriétés de diffusion d'éléments traces à travers une carotte dans des conditions représentatives de celles d'un réservoir de stockage de CO₂. Les résultats expérimentaux obtenus mettent en évidence à la fois l'impact de la dissolution sur la mobilisation des espèces chimiques, la compétition entre différents cations pour la sorption et les conséquences de cette sélectivité sur le transport et la disponibilité des espèces chimiques. L'étude pétrophysique des échantillons réagis met en évidence une augmentation de la porosité, et une tendance à l'uniformisation du réseau de pore. Les données obtenues dans les expériences en batch permettent d'obtenir par simulation les paramètres de sorption du système pour les différents éléments traces, en fonction des conditions de pression. Grâce à ces différents résultats, la surveillance de sites de stockage géologique de CO₂ est possible dans différentes formations, et permet un suivi à la fois des flux des espèces chimiques et des propriétés d'écoulement. / Over the last decade, an international will to reduce the emissions of greenhouse gases in the atmosphere developed, in order to limit their atmospheric concentration. Thus, to deal with the large amounts of CO₂ produced by human activities, this gas is to be injected under supercritical state in the underground. Outside the CO₂ plume, this gas dissolves within brine and acidifies it. Two phenomena occurs then. They are the main subject of this work: (i) the fate of chemical species mobilized by mineral dissolution, and (ii) the evolution of flooding properties induced by mineral reactivity. To study those phenomena, experiments were carried out on the Lavoux and the Saint-Emilion carbonates. Those two natural samples were selected because their mineralogical composition ensures a high reactivity and limits the complexity of the geochemical system, as they contain neither clays nor organic matter. Two types of experiments were carried out. Competition between dissolution and sorption was studied in batch reactors, from conditions similar to those of the surface (20°C – 1 atm) to those of a storage site (40°C – 90 bar of CO₂), passing by intermediate pressures (30 and 60 bar). The parameters investigated are salinity, initial concentration of divalent cations, and the state of solid samples (powder, core). On the other hand, an experimental setting was developed during the thesis project. It allows the study of trace elements diffusion through a core in CO₂ geological storage conditions. The experimental results evidence the impact of dissolution on chemical species mobilization, competition between those species regarding sorption and consequences of this selectivity on transport and availability of those chemical species. The petrophysical study of reacted samples evidence a porosity increase and the homogenization of the porous network. The data resulting from the batch experiments are used as input data for simulations, in order to estimate sorption parameters of trace elements in the systems investigated. Thanks to those results, the monitoring of CO₂ geological storage sites is possible within several different geological formations, and allows to track both flux of chemical species and flooding properties evolution.

The understanding of multiphase flow properties is essential for the exploitation of hydrocarbon reserves in a reservoir; these properties in turn are dependent on the geometric properties and connectivity of the pore space. The determination of the pore size distribution in carbonate reservoirs remains challenging; carbonates exhibit complex pore structures comprising length scales from nanometers to several centimeters. A major challenge to the accurate evaluation of these reservoirs is accounting for pore scale heterogeneity on multiple scales. This is the topic of this thesis. Conventionally, this micron scale information is achieved either by building stochastic models using 2D images or by combining log and laboratory data to classify pore types and their behaviour. None of these capture the true 3D connectivity vital for flow characterisation. We present here an approach to build realistic 3D network models across a range of scales to improve property estimation through employment of X-ray micro-Computed Tomography (μCT) and Focussed Ion Beam Tomography (FIBT). The submicron, or microporous, regions are delineated through a differential imaging technique undertaken on x-ray CT providing a qualitative description of microporosity. Various 3-Phase segmentation methods are then applied for quantitative characterisation of those regions utilising the attenuation coefficient values from the 3D tomographic images. X-ray micro-CT is resolution limited and can not resolve the detailed geometrical features of the submicron pores. FIB tomography is used to image the 3D pore structure of submicron pores down to a scale of tens of nanometers. We describe the experimental development and subsequent image processing including issues and difficulties resolved at various stages. The developed methodology is implemented on cores from producing wackstone and grainstone reservoirs. Pore network models are generated to characterise the 3D interconnectivity of pores. We perform the simulations of petrophysical properties (permeability and formation resistivity) directly on the submicron scale image data. Simulated drainage capillary pressure curves are matched with the experimental data. We also present some preliminary results for the integration of multiscale pore information to build dual-scale network models. The integration of multiscale data allows one to select appropriate effective medium theories to incorporate sub-micron structure into property calculations at macro scale giving a more realistic estimation of properties.