Yuen Chi Yan = 有關光折變晶體中空間孤子、偏振轉動以及霍爾效應的研究 / 阮志仁. / Thesis submitted in: July 2004. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2005. / Includes bibliographical references (leaves 81-82). / Text in English; abstracts in English and Chinese. / Yuen Chi Yan = You guan guang zhe bian jing ti zhong kong jian gu zi, pian zhen zhuan dong yi ji Huoer xiao ying de yan jiu / Ruan Zhiren. / Acknowledgments --- p.i / Abstract --- p.ii / Table of Contents --- p.v / Chapter Chapter 1 --- Photorefractive Spatial Soliton --- p.1 / Chapter 1.1 --- Introduction --- p.1 / Chapter 1.2 --- Bright Spatial Soliton --- p.3 / Chapter 1.2.1 --- Experiment --- p.4 / Chapter 1.2.2 --- Results and Discussion --- p.6 / Chapter 1.2.2.1 --- Expansion --- p.6 / Chapter 1.2.2.2 --- Contraction --- p.10 / Chapter 1.3 --- Dark Spatial Soliton --- p.15 / Chapter 1.3.1 --- Experiment --- p.15 / Chapter 1.3.2 --- Results and Discussion --- p.20 / Chapter Chapter 2 --- Polarization Rotation --- p.23 / Chapter 2.1 --- Introduction --- p.23 / Chapter 2.2 --- Experiment --- p.24 / Chapter 2.3 --- Results and Discussion --- p.30 / Chapter 2.3.1 --- Effect of varying pump beam power --- p.30 / Chapter 2.3.2 --- Effect of different polarizations of signal beam --- p.41 / Chapter 2.3.3 --- Effect of signal beam size --- p.43 / Chapter 2.3.4 --- Effect of applied E-field --- p.46 / Chapter 2.3.5 --- Effect of signal beam and pump beam separation and perpendicularly --- p.52 / Chapter 2.3.6 --- Investigation of Δne using interferometer --- p.60 / Chapter 2.3.7 --- Computer Simulation --- p.69 / Chapter Chapter 3 --- Hall Effect --- p.72 / Chapter 3.1 --- Introduction --- p.72 / Chapter 3.2 --- Experiment --- p.75 / Chapter 3.3 --- Results and Discussion --- p.76 / Conclusion and Possible Further Works --- p.79 / References --- p.81

As the computer industry grows, so will the requirements for data storage. Magnetic memory has been the most stable method in terms of capacity and recording/reading speed. However, we have reached the point where a substantial increase in the capacity cannot be produced without increasing the size of the system. When compact discs (CDs) were introduced in the 1980�s they revolutionized the concept of data storage. While the initial force behind compact discs could easily be said to be the music industry, once recordable and rewritable discs became available they quickly found more use in the computer industry as backup devices. Since their inception, the capacity requirements have far exceeded what is available on a compact disc, and they are now following the same path as magnetic memories. Following this trend, it could be assumed that digital versatile discs or digital video discs (DVDs) have a limited lifetime as a storage medium. In fact it has been noted (Higuchi et al., 1999) that the maximum capacity of digital video discs will be reached in 3 � 5 years. The question then is, what comes next? The efficiency of conventional optical data storage is extremely poor. For an optically thick recording medium, both CDs and DVDs use less than 0.01% of the total volume to store the information. Three-dimensional bit optical data storage endeavors to increase the efficiency by recording information in a volume that is greater than 90% of the total volume. The concept of three-dimensional bit optical data storage was first proposed by Parthenopoulos and Rentzepis in 1989, where they demonstrated that capacities far exceeding that of compact discs could be achieved. Three-dimensional bit optical data storage relies on creating a highly localised chemical or physical change within a recording medium, such that further layers can be recorded without causing interference. Ideally the chemical/physical change in the material should be reversible to enable erasable/rewritable data storage. In order to create a highly localised effect nonlinear excitation can be used; whereby the excitation is limited to a small region around the focal spot. Depending on the material and recording method there are several techniques for reading the information such as transmission imaging or reflection confocal microscopy. However, all the recording and reading methods require focusing to a deep position within a recording medium, such focusing encounters spherical aberration as a result of the difference in the refractive indices between the immersion and recording media. This thesis has concentrated on several areas to understand and develop the concept of three-dimensional bit optical data storage. The photorefractive effect in crystals has been studied for many years and is now widely used in optoelectronic devices. The use of photorefractive polymers is a relatively new and exciting development in optical data storage. Until now they have been used solely in the area of holographic data storage. The research in this thesis was conducted using photorefractive materials that were fabricated in two polymer matrices, poly(N-vinylcarbazole) (PVK) and poly(Methyl Methacrylate) (PMMA). The recording samples also consisted of the following compounds in various proportions, 2,5-dimethyl-4-(p-nirtophenylazo)anisole (DMNPAA), 2,4,7-trinitro-9-fluorenone (TNF) and N-ethylcarbazole (ECZ). In this project two-photon excitation was used as the recording mechanism to achieve erasable/rewritable data storage in a photorefractive polymer. As a result of two-photon excitation, the quadratic dependence of excitation on the incident intensity produces an excitation volume that is confined to the focal region in both the transverse and axial directions. Therefore, focusing the laser beam above or below its previous position provides a method by which layers of information can be recorded in the depth direction of a material, without causing interference from neighbouring layers. The feasibility of two-photon excitation in photorefractive polymers is demonstrated in this thesis. The quadratic relationship between excitation and incident light in two-photon excitation requires high photon density to ensure efficient excitation. The use of ultra-short pulsed lasers, while effective, is not a practical solution for an optical data storage system. This thesis demonstrates the ability to produce three-dimensional erasable/rewritable data storage in a photorefractive polymer using continuous wave illumination. Using this technology it has been possible to achieve a density of 88 Gbits/cm3, which corresponds to a capacity of 670 Gbytes on a compact disc sized recording medium. This is an increase of 1000 times the capacity of a CD and 130 times the capacity of current DVDs. While erasable optical data storage is an exciting prospect there are problems associated with the deterioration of the information. For long term information storage a permanent recording process would be more practical. It is demonstrated that there is a point after which further increases in the recording power result in the formation of a micro-cavity. While two-photon excitation is the recording method for erasable data storage, the increase in power results in an increase in ultra-violet absorption such that multi-photon excitation may occur. This thesis demonstrates the ability to record multi-layered arrays of micro-cavities. The change in refractive index associated with an erasable bit is less than 1%. As a result only phase sensitive reading methods (transmission imaging or differential interference contrast (DIC) microscopy) can be used to image a recorded bit. Both transmission and DIC imaging systems have poor axial resolution and therefore limit the density of the recording system, as well as being large optical systems. The introduction of a split or quadrant detector reduces the size of the optical reading system and is demonstrated to be sensitive enough to detect the phase changes of a recorded bit. However, the change in refractive index across a micro-cavity is large enough that reflection confocal microscopy can be used to detect a bit. It is demonstrated in this thesis that multi-layered micro-cavity arrays can be read using reflection confocal microscopy. Focusing of light to deep positions within an optical thick recording medium has the effect of increasing spherical aberration resulting from the refractive index mismatching between the immersion and recording media. The work in this thesis illustrates the effect of spherical aberration on the performance of both the recording and reading systems. The work conducted in this thesis shows the ability to record multi-layered erasable/rewritable information in a photorefractive polymer using pulsed and continuous wave two-photon excitation. It has also been demonstrated that through multi-photon excitation multi-layered micro-cavity arrays can be fabricated. It has also been illustrated that while spherical aberration deteriorates the performance of the recording and reading systems it is possible to achieve a density of greater than 88 Gbits/cm3.

Thesis (Ph. D.)--University of Chicago, Department of Chemistry, 2002. / Includes bibliographical references. Also available on the Internet.

This work presents the recent advances in photorefractive polymers for use in updatable holographic displays. A model with which to predict the effect of coplanar electrode geometry on diffraction uniformity in photorefractive (PR) polymer display devices was developed. Assumptions made in the standard use cases with constant electric field throughout the bulk of the media are no longer valid in the regions of extreme electric fields present in this type of device. Using electric field induced second harmonic generation (EFISHG) observed with multiphoton microscopy, the physical response in regions of internal electric fields which fall outside the standard regimes of validity were probed. Adjustments to the standard model were made, and the results of the new model were corroborated by holographic four-wave mixing measurements. The recent development of a single mode fiber-based pulsed laser with variable pulse length, energy, and repetition rate has enabled the characterization of photorefractive devices in a previously inaccessible regime located between millisecond and nanosecond pulse recording. A pulse width range of nine orders of magnitude opens the door to device and supporting laser optimization for use in video-rate holographic display. Device optimization has resulted in 5x improvement in single pulse four-wave mixing diffraction efficiencies to 10 - 11.5 % at pulse widths ranging between 6 ns and 100 µs. The grating recording time was likewise reduced by 5x to 16 ms at an applied bias of 72.5 V/μm. These improvements support 30 Hz update rates, which combined with the 3.3 - 10 kHz repetition rate pulsed laser, pave the way for real-time updatable holographic display.

No description available.

Thesis (M. Eng.)--Carleton University, 1992. / Also available in electronic format on the Internet.

No description available.

No description available.

We measured the diffraction efficiency response of two photorefractive polymer devices according to the duration of the single laser pulse used to record the hologram. The pulse duration was varied from 6 nanoseconds to 1 second, while the pulse energy density was maintained constant at 30 mJ/cm(2). This changed the peak power from 5 x 10(9) mW to 30 mW. We observed a strong reciprocity failure of the efficiency according to the pulse duration, with a reduction as large as a factor 35 between 1 second and 30 mu s pulse duration. At even lower pulse duration (< 30 mu s), the efficiency leveled out and remained constant down to the nanosecond exposure time. The same behavior was observed for samples composed of the same material but with and without buffer layers deposited on the electrodes, and different voltages applied during the holographic recording. We explained these experimental results based on the charge transport mechanism involved in the photorefractive process. The plateau is attributed to the single excitation of the charge carriers by short pulses (T-p < 30 mu s). The increase of efficiency for longer pulse duration (T-p > 30 mu s) is explained by multiple excitations of the charge carriers that allows longer distance to be traveled from the excitation sites. This longer separation distance between the carriers increases the amplitude of the space-charge field, and improves the index modulation. The understanding of the response of the diffraction efficiency according to the pulse duration is particularly important for the optimization of photorefractive materials to be used at high refresh rate such as in videorate 3D display.

OBJETIVO: Avaliar a eficácia, estabilidade, previsibilidade e segurança da ceratectomia fotorrefrativa (PRK) guiada pelas frentes de onda corneana para o tratamento da hipermetropia secundária à ceratotomia radial (CR). MÉTODOS: Foram avaliados prospectivamente 61 olhos de 39 pacientes consecutivos, submetidos a PRK personalizado com o laser Esiris-Schwind. A técnica constou de desepitelização mecânica, fotoablação, e utilização de mitomicina C (MMC) 0,02% por 20 ou 40 segundos. A MMC foi aplicada por 40 segundos em 17 olhos (27,9%) que haviam sido submetidos a ablações mais profundas do que 100 ?m ou apresentavam córneas previamente suturadas. As avaliações pós-operatórias foram realizadas após sete dias, um, seis, 12 e 24 meses. Todos os olhos foram avaliados após um ano e dois anos. RESULTADOS: O intervalo médio entre a CR e o PRK foi de 18,8 anos ± 3,8 (DP); o equivalente esférico (EE) médio antes da ceratotomia radial era -4,10 dioptrias (D) ± 1,44. As medidas prévias ao PRK mostraram EE médio de +4,17 D ± 1,97; astigmatismo médio de -1,39 D ± 1,04; AV com correção (AVcc) média de 0,161 ± 0,137 (logMAR); e curvatura corneana média de 35,85 ± 3,60 D. Os resultados encontrados dois anos após a cirurgia foram: EE médio de 0,14 ± 0,99 D (p < 0,001); astigmatismo médio de -1,19 ± 1,02 D (p = 0,627); AV sem correção (AVsc) média de 0,265 ± 0,196 (p < 0,001); AVcc média de 0,072 ± 0,094 (p < 0,001); e curvatura corneana média de 39,01 ± 3,18 D (p < 0,001). AVsc igual ou melhor a 20/25 foi observada em 38% dos olhos e igual ou melhor a 20/40 em 69%. A AVcc melhorou em 62,3% dos olhos, sendo que 21 olhos (34,4%) melhoraram uma linha e outros 17 olhos (27,9%), duas ou mais linhas. Um olho (1,6%) perdeu duas linhas devido ao astigmatismo irregular ocasionado por opacificação corneana periférica. Outro olho perdeu três linhas pelo desenvolvimento de ectasia corneana entre seis e 24 meses, devido ao alargamento progressivo de uma incisão radial inferior, e foi posteriormente submetido à sutura da incisão. Houve 30 olhos (49,2%) entre ± 0,50 D do EE planejado e 45 (73,8%) entre ± 1,00 D. Entre seis e 24 meses, a regressão média do EE foi de +0,39 D (p < 0,05) e cinco olhos (8,3%) sofreram desvio hipermetrópico > 1,00 D. Ocorreu redução estatisticamente significante do coma (p = 0,001), trefoil (p = 0,008), aberração esférica (p < 0,001), astigmatismo secundário (p = 0,001) e quatrefoil (p < 0,001). Não houve mudança estatisticamente significativa da contagem endotelial (p = 0,161). Dois olhos (3,3%) desenvolveram opacificação corneana periférica grau 2 e um, grau 3. CONCLUSÃO: O PRK personalizado pelas frentes de onda corneana coadjuvado pela MMC foi eficaz, previsível e seguro pelo período de dois anos para a redução da hipermetropia após a CR. No pós-operatório observou-se melhora significativa da AVsc, AVcc e das aberrações corneanas. Constatou-se, entretanto, que a hipermetropia consecutiva à CR continua a progredir após o tratamento com o excimer laser. / PURPOSE: To assess the efficacy, stability, predictability and safety of corneal wavefront-guided photorefractive keratectomy (PRK) for correcting hyperopia after radial keratotomy (RK). METHODS: In a prospective study, 61 eyes of 39 consecutive patients were treated with PRK using an Esiris-Schwind excimer laser. Corneal epithelium was mechanically removed, followed by photoablation and use of 0.02% mitomycin C (MMC) for 20 or 40 seconds. MMC was used for 40 seconds in 18 eyes (27.9%) which underwent ablations deeper than 100 micron or had previous corneal sutures. Postoperative evaluations were performed after seven days, six, 12 and 24 months. All patients were followed up for two years. RESULTS: The mean time between RK and PRK was 18.8 years ± 3.8 (SD); mean spherical equivalent (SE) before RK was -4.10 diopters (D) ± 1.44. Before PRK, the mean SE was +4.17 D ± 1.97, mean astigmatism was -1.39 D ± 1.04, the mean best-corrected visual acuity (BCVA) was 0.161 ± 0.137 (logMAR) and the mean corneal curvature was 35.85 ± 3.60 D. At 24 months, mean SE was 0.14 ± 0.99 D (p < 0.001), mean astigmatism was -1.19 ± 1.02 D (p = 0.627), mean UCVA was 0.265 ± 0.196 (p < 0.001), mean BSCVA was 0.072 ± 0.094 (p < 0.001) and the mean corneal curvature was 39.01 ± 3.18 D (p < 0.001). UCVA was 20/25 or better in 38% of eyes and 20/40 or better in 69%. BCVA improved in 62.3% of eyes, with 21 (34.4%) gaining one line and 17 (27.9%), two or more lines. One eye (1.6%) lost two lines due to irregular astigmatism and peripheral haze. Another eye lost three lines due to keratectasia occurring between six and 24 months resulting from widening of an inferior radial incision that was later sutured. Thirty eyes (49.2%) were within ± 0.50 D of intended SE and 45 (73.8%) were within ± 1.00 D. From six to 24 months, the mean SE regression was +0.39 D (p < 0.05) and five eyes (8.3%) had a hyperopic shift > 1.00 D. A significant decrease in coma (p = 0.001), trefoil (p = 0.008), spherical aberration (p < 0.001), secondary astigmatism (p = 0.001) and quatrefoil (p < 0.001) was observed. Endothelial cell counts did not show a statistically significant decrease (p = 0.161). Two eyes (3.3%) developed peripheral haze grade 2 and one, grade 3. CONCLUSION: Corneal wavefront-guided PRK with MMC was effective, predictable and safe after two years for the treatment of hyperopia after RK. A significant improvement in UCVA, BSCVA and corneal aberrations was obtained. However, hyperopic shift after RK continued to progress after excimer laser surgery.