This thesis presents the outcome of investigations undertaken in the field of terrestrial spectral solar irradiance characterisation and its impact on photovoltaics. Spectral irradiance has not previously been widely researched in the context of photovoltaic applications. Long-term, natural environment spectral irradiance observations are practically non-existent with availability very limited in terms of covered period, temporal resolution and site location. The work presented concentrates on four major aspects of spectral irradiance: spectroradiometer calibration spectral irradiance calibration transfer standards natural spectral irradiance variability and its impact on photovoltaic device efficiency impact of reference sensor spectral mismatch on accuracy of reference irradiance measurements.

Transient photocapacitance (TPC) and transient photocurrent (TPI) spectroscopy have been used to examine the defect structure in the upper-half of the bandgap of CdTe solar cells, with an emphasis on understanding the effect of copper. TPC spectra reveal two defects in the CdTe devices at optical energies of 1.2eV and 0.9eV with respect to the valence band. The origin of the 1.2eV defect could not be associated with a particular element, although copper and zinc were ruled out as sources. TPI spectra were used to observe that the density of the 1.2eV defect was dramatically reduced by thermally annealing the devices, suggesting that the defect itself is annealed during the treatment. The set of CdTe samples examined used a rapid thermal processing treatment to control the amount of copper that diffused into the CdTe layer from the Cu:ZnTe interfacial layer at the back of the device. Comparison of devices with varying amounts of copper in the CdTe layer revealed that the 0.9eV defect seen in TPC was associated with the presence of copper in the absorber layer. TPI spectra confirmed the association of the 0.9eV with copper and showed that the magnitude of the 0.9eV defect signal increased as more copper was diffused into the CdTe layer. A proportional link between the density of the 0.9eV defect observed in TPI spectra and the amount of copper in the absorber layer observed via ToF-SIMS further established that copper is responsible for the existence of the defect. Numerical modeling of the CdTe devices was used to confirm that the spatial distribution of copper observed in ToF-SIMS was consistent with the relative variation of defect magnitudes observed in TPI. The fact that the copper-associated 0.9eV defect lies close to mid-gap suggests that it will act as an efficient recombination center in CdTe. Therefore, it is suggested that this work has detected the deep defect that is responsible for the decreased minority carrier lifetime that has been previously associated with the amount of copper in the CdTe layer

This thesis details an investigation into the factors that could be restricting the performance of tin sulfide thus far. It is shown that there is confusion in the literature with respect to the assignment of different tin sulfide phases, and that the presence of these phases cannot easily be discerned with routine diffraction methods. In order to better understand the behaviour of tin sulfide in devices, it is important to isolate these materials as separate components and to consider the distinct properties of each. %Indeed, even a fundamental property such as the colour of SnS is still subject to conflicting reports. Herein, the targeted synthesis of SnS, SnS2 and Sn2S3 by chemical vapour transport is used to produce phase-pure single crystals, which are characterised in terms of structural, optical and electrical properties. These are compared directly with results from modern simulation methods as well as the work of others to explore fully the possible origins of performance losses. It is found that the work function of SnS is significantly lower than those of alternate successful photovoltaic materials, which means that novel device architectures are necessary in order to unlock the full potential of this promising photo-absorber. Concerns are also raised regarding the stability of the tin monosulfide phase with respect to degradation and defect formation over time, processes that undoubtedly affect device performance and lifetimes if sufficient safeguards are not put in place to suppress them. Further results of this 3 year research project also provide a broader platform for achieving sustainable light harvesting devices from the abundant and cheap elements, tin and sulfur.

Widespread commercialization of photovoltaics (PVs) requires both higher power conversion efficiencies and low-cost, high throughput manufacturing. High efficiencies have been achieved in devices made from materials such as CuIn[subscript x]Ga₁₋[subscript x]Se₂ (CIGS). However, processing of these solar cells still requires high temperature and vacuum, driving up cost. A reduction in manufacturing costs can be achieved by utilizing colloidal nanocrystals. Semiconductor nanocrystals can be dispersed in solvents and deposited via simple and scalable methods under ambient conditions to form the absorber layer in low-cost solar cells. Efficiencies of ~3% have been achieved with CIGS nanocrystal PVs, but this must be improved substantially for commercialization. These devices suffer from poor charge transport in the nanocrystal layer. Here, the synthesis of nanowires and their utilization in solar cells was explored as a way to improve charge transport. CuInSe₂ (CIS) nanowires were synthesized via the solution-liquid-solid method. PV devices were fabricated using the nanowires as the light absorbing layer, and were found to exhibit a measureable power output. Earth-abundant materials were also explored, motivated by the material availability concerns associated with CIGS. Pyrite FeS₂ nanocrystals were synthesized via an arrested precipitation reaction to produce phase-pure particles 15 nm in size. These nanocrystals were spray coated to form the active layer in several different common device architectures. These devices failed to produce any power output. The material was determined to be slightly sulfur deficient, leading to a high carrier concentration and metallic behavior in the thin films, with conductivities measured to be ~5 S/nm. A nanocrystal synthesis of Cu₂ZnSnS₄ (CZTS) was also developed to produce highly dispersible crystalline particles ~11 nm in size. These nanocrystals were spray coated onto glass substrates to form the absorber layer in test PV devices, and an efficiency of 0.23% was achieved without high-temperature or chemical post-processing. Additional studies included the synthesis of CZTS nanorods and their incorporation into functioning solar cells. The selenization of CZTS nanocrystal films was also studied as a way to improve solar cell performance. High temperature annealing in a Se atmosphere was found to produce CZTS(Se) layers, which could be used in working PV devices. / text

Hybrid organic/inorganic solar cells such as ZnO/P3HT offer promise in increasing efficiency of organic-based devices. However there are many unresolved issues such as poor short-circuit current and open-circuit voltage that are hampering their widespread, commercial use. It is thought that surface trap states on ZnO are providing an open avenue for carrier recombination thus creating devices with poor current transport characteristics. Using self assembled monolayers (SAMs) may provide some key answers and solutions to this problem by passivating trap states. In the course of this work, benzoic acid, 4-aminobenzoic acid, 4-methoxybenzoic acid, phenylphosphonic acid, and 4-methoxyphenylphosphonic acid SAMs were studied in large part due to their commercial availability. It was found that the phenylphosphonic acids had a clear impact on decreasing dark current; therefore strongly suggesting that exciton recombination has been inhibited to some degree. These molecules also caused a decrease in efficiency by an order of magnitude as compared to a plain ZnO/P3HT bilayer cell (standard). There were pronounced negative effects on the other device parameters such as open circuit voltage and short circuit current. In the case of 4-methoxybenzoic acid and benzoic acid the effects are not so clear in that parts of the dark J-V curve indicate a decrease in dark current while other regions show an increase. Interestingly for the negative effect on efficiency and other device parameters was not as pronounced as the phenylphosphonic acids. In both cases it is hypothesized that because of their wide band gaps and poor energy level matching, they ultimately impact device performance negatively. In the future, use of simulations to determine optimal SAM molecular structures that can be synthesized in the lab or purchased commercially is suggested.

This thesis reports the functionalization of metal nanoparticles to allow for solubility in organic solvents used in solar cell fabrication. Functionalization of the nanoparticles using poly(ethylene glycol) methyl ether thiol (PEG-SH) allows for the phase transfer of the nanoparticles from aqueous solution to organic solvents. Once functionalized it was found that nanoprisms will undergo a shape change. This change in morphology was investigated using UV-Vis measurements, transmission electron microscopy (TEM), and X-ray Absorption Near Edge Structure (XANES) measurements and a mechanism for the shape degradation is presented. The PEG functionalization procedure can be applied to other types of metal nanoparticles and once soluble, these particles were incorporated into the active layer of the BHJ cells. It has been found that the PEG functionalized particles do not improve the cell efficiency, but they do affect the cell performance. The addition of the particles does not influence the open circuit voltage, but it does affect the current density of the devices. This suggests that the particles may be acting as electron traps, not allowing current to flow efficiently through the device. This shows that while the PEG-ylation of the particles is effective at solubilising them into useful organic solvents, the thickness of the PEG layer on the nanoparticles may not provide protection from electrons and allow for effective charge transfer throughout the solar cell.

No description available.

In this work, a size optimization approach for utility-scale solar photovoltaic (PV) systems is proposed. The purpose of the method is to determine the optimal solar energy generation capacity and optimal location by the minimizing total system cost subject to the constraint that the system reliability requirements. Due to the stochastic characteristic of the solar irradiation, the reliability performance of a power system with PV generation is quite different from the one with only conventional generation. Basically, generation adequacy level of power systems containing solar energy is evaluated by reliability assessment and the most widely used reliability index is the loss of load probability (LOLP). The value of LOLP depends on various factors such as power output of the PV system, outage rate of generating facilities and the system load profile. To obtain the LOLP, the Monte Carlo method is applied to simulate the reliability performance of the solar penetrated power system. The total system cost model consists of the system installation cost, mitigation cost, and saving fuel and operation cost. Mitigation cost is accomplished with N-1 contingency analysis. The cost function minimization process is implemented in Genetic Algorithm toolbox, which has the ability to search the global optimum with relative computational simplicity. / Master of Science

One of the most critical processes in CdTe device production is the activation process induced by cadmium chloride (CdCl2). In this thesis, the CdCl2 treatment has been optimized using both wet and thermal evaporation methods for close-spaced sublimated (CSS) devices. Maximum cell efficiencies of η=7.24% and η=9.37% respectively have been measured without the use of copper in the back contact. A clear link has been established between treatment conditions, electrical measurements and microstructure, where parameters such as the dwell annealing temperature for evaporated CdCl2 and the concentration of the solution for the wet treatment are varied. It has been shown that a certain concentration of chlorine is necessary to remove high densities of planar defects present in the as-deposited material. The CSS CdTe is deposited in a dual layer structure with smaller grains at the CdS interface and with larger grains developing towards the surface. The defects are initially removed in the smaller grains at the CdS interface. When the temperature and concentration increase, more grains recrystallize with the total removal of stacking faults. At a critical temperature and Cl concentration, the entire CdTe film recrystallizes into large grains with no stacking faults. The CdS grains and the interface with the CdTe also changes with sulphur migration into the CdTe. The results indicate that the recrystallization actually initiates at the CdS/CdTe junction. This has been observed clearly for both sputtered and electrodeposited CdTe. The recrystallization process gradually propagates towards the surface as the concentration of the CdCl2 solution in methanol is increased. This observation is not intuitive because the solution is initially in contact with the outer surface of the CdTe. Finally, the use of different chlorine containing compounds has been used as an alternative to CdCl2 and to further understand the role of chlorine in the process. All the samples treated with Cl containing compounds have shown the elimination of the dual layer structure and the recrystallization of the small grains at the interface. Tellurium tetrachloride (TeCl4) and zinc chloride (ZnCl2) have shown the most promising increase in conversion efficiency. The maximum efficiencies measured using these two solutions were 4.58% and 5.05% respectively. TeCl4 has shown an encouraging open circuit voltage of 594 mV, while the open circuit voltage using ZnCl2 was 494 mV. However, TeCl4 has shunting issues and low current density (17.9 mA/cm2), whereas ZnCl2 has the promising current density of 20.8 mA/cm2. This work has shown that alternatives to CdCl2 treatment exist, however further work is required to optimize the performance of these treatments to enable them to be competitive. Advanced materials characterization techniques are essential to understand and then enhance photovoltaic cell and module performance. New and improved tools are being developed to deliver fast, accurate and non-destructive characterization. One of these tools is coherence correlation interferometry (CCI) which has been developed by Taylor Hobson Ltd. This is a particular variant of scanning white light interferometry used for surface metrology with a high vertical resolution. In this thesis, it has been shown that the capability of the CCI can be extended to perform accurate thin film thickness measurements using the Helix Complex Field (HFC) function. The main attraction of this technique for thin film PV applications is that it allows surface metrology and thin film thickness measurements to be obtained simultaneously from the same area of the sample in the same system. The results obtained from CCI on a variety of materials, used in thin film PV, correlate very well the results obtained from other techniques such as ellipsometry, electron microscopy and atomic force microscopy. The CCI has also been used in the optimization of a new one-step interconnect process (OSI) for thin film PV module interconnects.

The shift towards more renewable energy sources is imminent, this shift is accelerated by the technological advancement and the rise of environmental awareness. However, this shift causes major operational problems to the current grid that is optimised for unidirectional power flow. Besides the operational problems, there are problems related to the optimal tariff scheme. In this thesis a study on the effect of the adoption of photovoltaic solar panels and the electric vehicles on the households' electricity demand profile is presented. The change on the demand profile is going to affect the current tariffs, this effect is also explored in this thesis. In this thesis real life data on household electricity use and photovoltaic power production was used. For electric vehicle charging simulated data was used. Besides that, a demand response scheme for electric vehicle is proposed in order to estimate the savings potential of this demand response on the electricity bill. The results show that the change in the demand profile is not merely a change in the total energy consumption, but it is a change in the power peaks as well. The peaks change significantly in condominiums and rental apartments, in this households' type it increases by around 80%, while in detached and row houses little change is noticed on the peaks, yet they still increase by around 10%. The demand response shows around 1- 12% savings in the distribution bill depending on the household, however it showed more incentives for condominiums and rental apartments. The current distribution tariffs perform asymmetrically with the various households. However, one tariff ensures 11.7 MSEK financial revenue for the distribution system operator, this is higher than the other tariffs' revenue by more than 28.5%. The new prospective situation requires totally different tariffs that ensure a balance between firstly a reasonable revenue for the distribution system operator and secondly incentives for consumers to self produce electricity as well as to reduce their peaks.