This work proposes minimally invasive solutions for spinal cord regeneration after trauma. In particular, injectable biomaterials can be precisely positioned in the lesion site, and eventually repetitively injected until the complete regeneration of the tissue. For this application, a silk fibroin functionalized with collagen type IV and laminin-derived peptides, called bio-inspired multifunctionalized silk fibroin (BMS), possessing piezoelectric properties, has been synthesized. Another approach that avoids damages to the spinal cord is proposed in the thesis as a multilayer hydrogel with piezoelectric properties that acts as a bridge between the healthy parts surrounding the injury. The multilayer hydrogel consists of i) a thin-layer of gelatin and fish collagen functionalized with VEGF for blood vessels formation, which helps the survival of the cells integrating with the pia mater of the spinal cord; ii) a BMS layer, which helps the adhesion, migration of neural stem cells and induces the sprouting of the axons thanks to the presence of Netrin (a chemoattractive protein); and iii) an adhesive layer of polydopamine (PDA) to fix the patch on the injured site. The adhesive patch exhibits a potential larger than an injectable hydrogel that could guarantee a long-term cell survival and help the axons to move towards a direction. The adhesive patch will be located on the surface of the spinal cord and the chemoattractive protein will induce the sprouting of the ascendant or descendant axons in the spinal cord to reach the axons present in the patch, restoring a signal connection. Even if not final, the results indicate that the above strategy could be explored further for the regeneration of the spinal cord.

No description available.

No description available.

Vibration-based energy harvesting has been investigated by several researchers over the last decade. The ultimate goal in this research field is to power small electronic components (such as wireless sensors) by using the vibration energy available in their environment. Among the basic transduction mechanisms that can be used for vibration-to-electricity conversion, piezoelectric transduction has received the most attention in the literature. Piezoelectric materials are preferred in energy harvesting due to their large power densities and ease of application. Typically, piezoelectric energy harvesters are cantilevered structures with piezoceramic layers that generate alternating voltage output due to base excitation. This work presents distributed-parameter electromechanical models that can accurately predict the coupled dynamics of piezoelectric energy harvesters. First the issues in the existing models are addressed and the lumped-parameter electromechanical formulation is corrected by introducing a dimensionless correction factor derived from the electromechanically uncoupled distributed-parameter solution. Then the electromechanically coupled closed-form analytical solution is obtained based on the thin-beam theory since piezoelectric energy harvesters are typically thin structures. The multi-mode electromechanical frequency response expressions obtained from the analytical solution are reduced to single-mode expressions for modal vibrations. The analytical solutions for the electromechanically coupled voltage response and vibration response are validated experimentally for various cases. The single-mode analytical equations are then used for deriving closed-form relations for parameter identification and optimization. Asymptotic analyses of the electromechanical frequency response functions are given along with expressions for the short-circuit and the open-circuit resonance frequencies. A simple experimental technique is presented to identify the optimum load resistance using only a single resistor and an open-circuit voltage measurement. A case study is given to compare the power generation performances of commonly used monolithic piezoceramics and novel single crystals with a focus on the effects of plane-stress material constants and mechanical damping. The effects of strain nodes and electrode configuration on piezoelectric energy harvesting are discussed theoretically and demonstrated experimentally. An approximate electromechanical solution using the assumed-modes method is presented and it can be used for modeling of asymmetric and moderately thick energy harvester configurations. Finally, a piezo-magneto-elastic energy harvester is introduced as a non-conventional broadband energy harvester. / Ph. D.

Ferroelectric and piezoelectric ceramic reinforced metal matrix composites are new materials being explored for vibration damping purposes. The high damping ability of ferroelectric and piezoelectric ceramics such as barium titanate (BaTiO3) and lead zirconate titanate (PZT) is due to the anelastic response of ferroelastic domain walls to applied external stress. In piezoelectric ceramics, vibration energy can also be dissipated through the direct piezoelectric effect if the appropriate electric circuit is connected across the ceramic. In this work we have examined the vibration damping behavior of BaTiO3, nickel-barium titanate (Ni-BaTiO3) composites and nickel-lead zirconate titanate (Ni-PZT) composites. BaTiO3 ceramics were fabricated by a combination of uniaxial pressing and cold isostatic pressing followed by sintering in air. Low frequency (0.1Hz-10Hz) damping capacity of BaTiO3, tanδ has been measured in three-point bend configuration on a dynamic mechanical analyzer. Tanδ has been found to increase with temperature up to the Curie temperature (Tc) of BaTiO3, after which there was a drop in damping capacity values due to the disappearance of ferroelectric domains above Tc. Furthermore within the frequency range tested, tanδ has been found to decrease with increasing vibration frequency. We also observed that tanδ decays with the number of vibration cycles (N). The decrease in tanδ with N, however, is fully recovered if BaTiO3 is heated above the Tc. Ni-BaTiO3 composite composed of a layer of BaTiO3 ceramic sandwiched between two layers of Ni were fabricated using a combination of electroless plating and electroforming. The damping behavior of the composite was analyzed in terms of the damping mechanisms below Tc and the damping mechanisms above Tc of BaTiO3. Below Tc, vibration damping ability of the composite was highly influenced by ferroelastic damping in the BaTiO3 component. Above the Curie temperature, the damping capacity was influence more by the inherent damping mechanisms in the nickel matrix. The damping mechanisms in Ni-PZT composites were evaluated at a low vibration frequency of 1Hz. In these composites we identified ferroelastic domain wall motion as the main damping mechanism active below the Tc of PZT. Using a poled PZT ceramic enhanced the damping capacity of the composite because of favorable ferroelastic domain orientation in the direction of applied stress. Based on our experimental results, we found no evidence of a direct piezoelectric damping mechanism in the Ni-PZT composites. / Ph. D.

This work focuses on the broadband attenuation of structural vibration and, in the process, employs a new perspective of vibrational energy harvesting devices. The first part of the research studies and develops a continuously distributed vibration control device which combines the benefits of point mass-spring-dampers at low frequencies as well as the resistive or dissipative influence of constraining treatments at high frequencies. This embodiment provides broadband passive vibration attenuation for a minimal cost in added mass, spanning the present divide between the ability to attenuate a single low frequency and the need to attenuate all frequencies. The second part adopts a vibration control perspective to energy harvesting analysis and considers the harvesting devices to be electromechanically stiffened and/or damped vibration absorbers. Rigorous analysis and experiments are carried out which show that vibration control and energy harvesting appear to be mutually beneficial given that maximum harvested energy from structural vibrations is achieved when the harvesters exert a finite dynamic influence on the host system. This suggests that vibration control concerns presently alleviated using tuned-mass-dampers are ideal energy harvesting applications. A generalized analytical model is derived which is applicable to both portions of the work. Continuously distributed vibration control devices are studied in depth and a superposition method is presented which allows for convenient implementation of a realistic device design into the numerical model. Tests carried out with the distributed device validate the model as well as show the device's competitive benefits compared with traditional, and much heavier, vibration control treatments. The inclusion of electromechanical coupling effects into the modeling is straightforward and numerous analyses are carried out to observe how electromagnetic and piezoelectric energy harvesting devices affect the dynamics of the host vibrating structure while the harvesters themselves convert the 'absorbed' energy into electrical power. Altering the device created in the first portion of the research to use a piezoelectric material as the distributed spring yields one such embodiment capable of both surface vibration control and energy harvesting. Tests carried out with the device additionally serve as model validation but also indicate that, for a given harvester, the attenuation of and energy harvesting from structural vibrations are nearly simultaneously maximized as modeling predicted. / Ph. D.

A mathematical model has been created based on J.D. Eshelby's equivalent inclusion method that can predict the elastic modulus and damping capability in the form of Joule heat for any piezoelectric ceramic-reinforced metal matrix composite system. Specifically, barium titanate (BaTiO₃), lead titanate (PbTiO₃), and zinc oxide (ZnO) piezoelectric ceramics have been modeled as dispersed particles shaped as spheres, prolate spheroids, and discs within a host of common structural metallic matrices including 304 stainless steel, mild steel, aluminum, brass, copper, lead, magnesium, nickel, Ni-20wt%Cr, tin, titanium, Ti-6Al-4V(at%), and tungsten. Composite systems that were predicted to exhibit the greatest level of damping capacity include copper, aluminum, and magnesium matrices reinforced with PbTiO₃, BaTiO₃, and ZnO, in descending order of damping magnitude. In general, higher-conducting, lower-stiffness metallic matrices coupled with more-piezoelectric, higher-stiffness ceramic reinforcement resulted in the greatest level of predicted damping capability and enhanced composite elastic modulus. Additionally, a Ni-20wt%Cr-30v%BaTiO₃ composite has been created using mechanical alloying processing. Specifically, pure constituent powders were combined stoichiometrically in a SPEX milling vial utilizing a charge ratio of 4:1 and subsequently milled for 24 hours. Separate composite powder samples were then annealed in a hydrogen tube furnace at 400°C, 500°C, and 600°C for one and five hours at each temperature. X-ray diffraction was performed on the as-milled and the annealed powders revealing that each was composed of the starting constituents in the appropriate proportions. Representative powders were mounted and polished using common metallographic procedures and microstructures were examined by optical microscopy, scanning electron microscopy, and transmission electron microscopy. All of the powders exhibited a good dispersion of BaTiO₃ particles ranging in diameter from 1μm to about 25nm with no noticeable difference between the as-milled and the annealed powders. / Master of Science

The purpose of this research is to characterize the response of an airfoil with an oscillatory morphing, Macro-fiber composite (MFC) trailing edge. Correlation of the airfoil lift with the oscillatory input is presented. Modal analysis of the test airfoil and apparatus is used to determine the frequency response function. The effects of static MFC inputs on the FRF are presented and compared to the unactuated airfoil. The transfer function is then used to determine the lift component due to cambering and extract the inertial components from oscillating airfoil. Finally, empirical wind tunnel data is modeled and used to simulate the deflection of airfoil surfaces during dynamic testing conditions. This research serves to combine modal analysis, empirical modeling, and aerodynamic testing of MFC driven, oscillating lift to formulate a model of a dynamic, loaded morphing airfoil. / Master of Science

This thesis presents a theoretical analysis of active control of sound radiation from elastic plates with the use of piezoelectric transducers as actuators. A strain-energy model (SEM), based upon the conservation of strain energy, for a laminate beam with attached or embedded finite-length spatially distributed induced strain actuators was first developed to determine the induced strain distribution. The equivalent axial force and bending moment induced by the embedded or surface bonded actuators were also calculated. The one-dimensional SEM was then extended to a two-dimensional model by employing the classical laminate plate theory and utilizing Heaviside functions to integrate the actuator influence on the substructure. The mechanics model can determine the structural coupling effect and predict the structural response as a result of piezoelectric actuation. A baffled simply-supported rectangular plate subjected to harmonic disturbances was considered as the plant. Piezoceramic materials bonded to the surfaces of the plate or point force shakers were applied as control actuators. Both microphones in the radiated far-field and accelerometers located on the plate were considered as error sensors. In addition, distributed sensors for pressure and structural motion were modelled. The cost function was formulated as the modulus squared of the error signal. Linear quadratic optimal control theory was then applied to minimize the cost function to obtain the optimal input voltages to the actuators. Both near-field and far-field pressure and intensity responses as well as plate displacement distributions were presented to show the effectiveness and mechanisms of control for various configurations of the actuators and sensors. Plate wavenumber analysis was also shown to provide a further insight into control technique. The results show that piezoelectric actuators perform very well as control sources, and that pressure sensors have many advantages over acceleration sensors while distributed sensors are superior to discrete sensors. The optimal placement of multiple fixed size piezoelectric actuators in sound radiation control is also presented. A solution strategy is proposed to calculate the applied voltages to piezoelectric actuators with the use of linear quadratic optimal control theory. The location of piezoelectric actuator is then determined by minimizing an objective function, which is defined as the sum of the mean square sound pressure measured by a number of error microphones. The optimal location of piezoelectric actuators for sound radiation control is found so as to minimize the objective function and shown to be dependent on the excitation frequency. In particular, the optimal placement of multiple piezoelectric actuators for on-resonance and off-resonance excitation is presented. Results show that the optimally placed piezoelectric actuators perform far better in sound radiation control than arbitrarily selected. This work leads to a design methodology for adaptive or intelligent material systems with highly integrated actuators and sensors. The optimization procedure also leads to a reduction in the number of control transducers. / Ph. D.

Fundação Carlos Chagas Filho de Amparo a Pesquisa do Estado do Rio de Janeiro / As cerâmicas piesoelétricas estudadas neste trabalho (Pb1,03Zr0,53Ti0,47O3, Pb1,03Zr0,525Nb0,05Ti0,465Fe0,005O3, Pb1,03Zr0,515Nb0,015Ti0,465Fe0,005O3, Pb1,03Zr0,525Nb0,005Ti0,455Fe0,015O3 e Pb1,03Zr0,515Nb0,015Ti0,455Fe0,015O3) foram sinterizadas a 1200oC e 1250oC por 3,5 h a fim de que suas propriedades piesoelétricas fossem investigadas. Nas composições dos PZT obtidas, a matriz e os dopantes empregaram óxidos como matérias primas. As misturas dos óxidos precursores foram calcinadas a 850oC por 3,5 h para obtenção da fase PZT. Os precursores, os pós e os corpos de prova de PZT foram caracterizados quanto às microestruturas, densidades e propriedades físicas. Após a conformação dos pós e a sinterização, os materiais cerâmicos foram polarizados para caracterização de suas propriedades piesoelétricas através de um impedancímetro na faixa de freqüência de 100 KHz a 200 KHz. Os resultados de dispersão de laser dos precursores revelaram aglomeração do óxido de chumbo e óxido de zircônio. As composições calcinadas apresentaram tamanho de partícula na faixa de 0,44 μm a 0,63 μm. As análises de densidade por método de Arquimedes indicaram uma boa densificação dos corpos de prova sinterizados e pouca influência da temperatura de sinterização com uma escala de valores de 95,73 a 97,65% da densidade teórica. As análises de microscopia eletrônica de varredura revelaram que os sinterizados contendo concentrações diferentes de dopantes exibem uma correlação do tipo e teor de dopante com a natureza da fratura, sendo transgranular, quando dopante ferro for predominante e intergranular, quando o dopante Nb for predominante. Também, o aumento da temperatura de sinterização resultou em fratura transgranular independente do tipo e da concentração de dopante, exceto para baixo teor de dopante da composição equimolar, cujos resultados não foram consistentes com a literatura sobre o material. No que diz respeito às propriedades piesoelétricas, revelou-se que a combinação da variação da composição com a temperatura foi favorável para o aumento dos valores da constante dielétrica da formulação equimolar com maior percentual de dopantes. Já o efeito da temperatura com a composição surtiu um efeito muito negativo para os valores de fator de qualidade mecânica da formulação dopada com mais ferro. Para os valores de constante de freqüência da formulação com maior percentagem de nióbio, o efeito da temperatura com a composição gerou um efeito positivo. / The piezoelectric ceramics studied in this work, Pb1.03Zr0.53Ti0.47O3, Pb1.03Zr0.525Nb0.05Ti0.465Fe0.005O3, Pb1.03Zr0.515Nb0.015Ti0.465Fe0.005O3, Pb1.03Zr0.525Nb0.005Ti0.455Fe0.015O3 and Pb1.03Zr0.515Nb0.015Ti0.455Fe0.015O3, were all of them sintered between 1200oC and 1250oC for 3.5h. After that, their piezoelectric properties were investigated. In the present work, oxides were used as raw material in both, matrices and dopants. The mixture of the precursor oxides were calcinaned at 850oC during 3.5h for obtaining the PZT phase. The precursor oxides, the powders and the PZT samples went through characterization tests in order to have their microstructures, densities and physical properties correctly determined. After the powders had been conformed and performed the sinterization process, the PZT ceramics were polarized and their piezoelectric properties determined by using an impedancemeter working in the frequency from 100 KHz to 200 KHz. The obtained results from laser dispersion had revealed agglomeration of lead and zirconium oxide. The calcined samples presented particle sizes from 0.44 μm to 0.63 μm. The density analyses using the Archimedes method indicated a good densification of the sintered samples and a weak influence of the sintering temperature on the obtained density values, whose values ranged from 95.73 to 97.65 % of the theoretical density value. Analysis performed using the scanning electron microscopy technique (MEV) revealed that the sintered samples had showed a correlation between the type and concentration of the dopant with their fracture mode, which were transgranular when Fe prevails over the Nb as dopant, and intergranular, when is the Nb that prevails over the Fe as dopant. By the other side, from increasing the sintering temperature resulted transgranular fractures, independently of which type and content of dopant had been used, except for the equimolar case with relatively low content of dopant, whose results were not consistent with the literature related to this material. About the piezoelectric properties, the results had showed that the combination of the dopant composition with the sintering temperature had brought better values of dielectric constant for the equimolar formulation with more content of dopant. Relating to the mechanical quality factor, from the combination of the dopant composition with the sintering temperature had decreased the factor when Fe prevails over Nb and increased the frequency factor when is the Nb that prevails over the Fe.