The recent substantial increase in world demand for energy and raw material resources has accelerated oil and gas exploration and production. At the same time, the depletion of onshore and shallow water oil resources presents a challenge to engineers to develop new means of harvesting and transporting oil and gas from harsh and remote areas. Sandwich Pipe (SP) is a relatively new design concept developed to address the transportation of oil in deep and ultra-deep waters as well as in cold environments. The main focus of this thesis is on the characterization of the structural performance of these novel systems. Deep and ultra-deep water offshore pipelines are subjected to excessive hydrostatic external pressure during installation and operation. In this research, an innovative analytical solution was developed to evaluate the external pressure capacity of SPs by calculating the linear eigenvalues of the characteristic equations of the system. In the proposed solution, the interface condition between the layers of the system is accounted for in the governing equations. As well, a set of comprehensive parametric studies using the Finite Element (FE) method was developed to investigate both the elastic and plastic buckling response of SPs. The influence of various structural parameters such as the material, geometrical and intra-layer interaction properties on the characteristic behavior and the buckling pressure of SPs was examined. In addition to the proposed analytical solution, two sets of semi-empirical equations based on the FE analysis results were recommended in calculating the elastic and plastic buckling pressure of SPs. As bending represents an important loading state in the installation and service life of SPs, it should be considered a governing loading scenario. In this thesis, the behavior of SPs under bending was investigated using a comprehensive set of parametric studies. SP systems with a wide practical range of physical parameters were analyzed using the FE method, and the influence of various structural parameters on the characteristic response and bending capacity of the system was explored, including pipe geometry, core layer properties, material yield anisotropy of high-grade steel pipes, and various intra-layer adhesion configurations.

A CO2 emission analysis and system investigation of a direct fuel cell waste energy recovery and power generation system (DFC-ERG) for pressure letdown stations was undertaken. The hybrid system developed by FuelCell Energy Inc. is an integrated turboexpander and a direct internal reforming molten carbonate fuel cell system in a combined circle. At pressure letdown stations, popularly called city gates, the pressure of natural gas transported on long pipelines is reduced by traditional pressure regulating systems. Energy is lost as a result of pressure reduction. Pressure reduction also results in severe cooling of the gas due to the Joule Thompson effect, thus, requiring preheating of the natural gas using traditional gas fired-burners. The thermal energy generated results in the emission of green house gases. The DFC-ERG system is a novel waste energy recovery and green house gas mitigation system that can replace traditional pressure regulating systems on city gates. A DFC-ERG system has been simulated using UniSim Design process simulation software. A case study using data from Utilities Kingston’s city gate at Glenburnie was analysed. The waste energy recovery system was modelled using the design specifications of the FuelCell Energy Inc’s DFC 300 system and turboexpander design characteristics of Cryostar TG120. The Fuel Cell system sizing was based on the required thermal output, electrical power output, available configuration and cost. The predicted performance of the fuel cell system was simulated at a current density of 140mA/cm2, steam to carbon ratio of 3, fuel utilization of 75% and oxygen utilization of 30%. The power output of the turboexpander was found to strongly depend on the high pressure natural gas flowrate, temperature and pressure. The simulated DFC-ERG system was found to reduce CO2 emissions when the electrical power generated by the DFC-ERG system replaced electrical power generated by a coal fired plant. / Thesis (Master, Chemical Engineering) -- Queen's University, 2010-08-31 02:02:11.392

Mémoire numérisé par la Division de la gestion de documents et des archives de l'Université de Montréal

In der vorliegenden Arbeit wurde die Eintretenswahrscheinlichkeit von Tagesbrüchen und das Risikomanagement am Beispiel von Rohrleitungen in tagesbruchgefährdeten Gebieten des Mitteldeutschen Braunkohlenreviers umfassend beleuchtet. Im ersten Schritt wurden die Möglichkeiten und Grenzen der verschiedenen Überwachungs- und Sicherungsmaßnahmen analysiert. Es wird gezeigt, dass kein Überwachungsverfahren in der Lage ist, das unmittelbare Bevorstehen eines Tagesbruchs hinreichend genau zu prognostizieren. Die Verfahren können in der Regel nur Hinweise geben, die dann durch einen Spezialisten zu interpretieren sind. Die vorgestellten Sicherungsverfahren sind zwar teilweise in der Lage, den Tagesbruch oder seine Auswirkungen auf Rohrleitungen auf ein ungefährliches Maß zu senken. Jedoch sind diese Verfahren meist in der flächendeckenden Anwendung viel zu teuer. Um solche Verfahren nur noch punktuell an den größten Gefährdungsschwerpunkten einsetzen zu müssen, ist eine zuverlässige Bewertung der Eintrittswahrscheinlichkeit eines Tagesbruchs notwendig. Mit der Methodik der Spezifischen Bruchwahrscheinlichkeit kann erstmals die Eintrittswahrscheinlichkeit von Tagesbrüchen in einem Grubenfeld quantifiziert werden, worin auch die wesentliche wissenschaftliche Bedeutung der Arbeit liegt. Die Entwicklung von praktischen Zahlenwerten ermöglicht es, das Tagesbruchrisiko objektiv zu quantifizieren und somit die sicherheitstechnische Zulässigkeit der geplanten Oberflächennutzung zu bewerten.

L'objectif de ce travail était d'élaborer la brique de base d'un convertisseur analogique numérique supraconducteur à architecture pipeline, fonctionnant à 30GHz de fréquence d'échantillonnage. Ce convertisseur est constitué d'un bloc de N comparateurs disposés en cascade le long d'une ligne de transmission. Chaque étage de comparaison est constitué d'un SQUID rf mutuellement couplé à un tronçon de ligne de transmission. Lorsque le signal à convertir arrive à la hauteur d'un comparateur, il génère un champ magnétique qui induit un courant dans le SQUID rf. Ce courant pourra faire commuter la jonction Josephson du SQUID rf dans certains cas, en fonction des caractéristiques internes de la jonction Josephson du SQUID et de son environnement. La commutation, qui s'accompagne de l'apparition d'une impulsion de tension quantifiée SFQ, a été étudiée de manière théorique et expérimentale en fonction des différents paramètres du problème.

La Non-Linéarité-Différentielle (NLD) et la Non-Linéarité-Intégrale (NLI) sont les performances statiques les plus importantes des Convertisseurs Analogique-Numérique (CAN) qui sont mesurées lors d'un test de production. Ces deux performances indiquent la déviation de la fonction de transfert du CAN par rapport au cas idéal. Elles sont obtenues en appliquant une rampe ou une sinusoïde lente au CAN et en calculant le nombre d'occurrences de chacun des codes du CAN.Ceci permet la construction de l'histogramme qui permet l'extraction de la NLD et la NLI. Cette approche requiert lacollection d'une quantité importante de données puisque chacun des codes doit être traversé plusieurs fois afin de moyenner le bruit et la quantité de données nécessaire augmente exponentiellement avec la résolution du CAN sous test. En effet,malgré que les circuits analogiques et mixtes occupent une surface qui n'excède pas généralement 5% de la surface globald'un System-on-Chip (SoC), leur temps de test représente souvent plus que 30% du temps de test global. Pour cette raison, la réduction du temps de test des CANs est un domaine de recherche qui attire de plus en plus d'attention et qui est en train deprendre de l'ampleur. Les CAN de type pipeline offrent un bon compromis entre la vitesse, la résolution et la consommation.Ils sont convenables pour une variété d'applications et sont typiquement utilisés dans les SoCs destinés à des applicationsvidéo. En raison de leur façon particulière du traitement du signal d'entrée, les CAN de type pipeline ont des codes de sortiequi ont la même largeur. Par conséquent, au lieu de considérer tous les codes lors du test, il est possible de se limiter à un sous-ensemble, ce qui permet de réduire considérablement le temps de test. Dans ce travail, une technique pour l'applicationdu test à code réduit pour les CANs de type pipeline est proposée. Elle exploite principalement deux propriétés de ce type deCAN et permet d'obtenir une très bonne estimation des performances statiques. La technique est validée expérimentalementsur un CAN 11-bit, 55nm de STMicroelectronics, obtenant une estimation de la NLD et de la NLI pratiquement identiques àla NLD et la NLI obtenues par la méthode classique d'histogramme, en utilisant la mesure de seulement 6% des codes.

The accurate determination of gender of biological samples has valuable applications in medical and forensic investigations. Gender determination based on length variations in the X-Y homologous amelogenin gene, is part of most commercial multiplex DNA profiling kits. The first report of a failure of the amelogenin sex test was in 1998 when two normal males were typed as female. Subsequently, several amelogenin Y (AMELY) negative males have been reported. This study represents the first report of this phenomenon in the black South African population. This study determined the size of the Y-chromosome deletion that resulted in the failure of the amelogenin sex test in two black South African AMELY-negative males by typing specific DNA markers surrounding the amelogenin locus. Through deletion size and Y-chromosome microsatellite haplotypes, the relationship between the samples was investigated. The samples were sequenced at the amelogenin gene and typed for thirteen sites on the short arm of the Y-chromosome. In order to determine the Y-chromosome haplotypes, eleven Y-chromosome microsatellite markers were typed. These samples had the same size deletion of approximately 3 Mb. The Y-chromosome haplotypes indicated that these were probably independent events. The frequency of AMELY-negative males is rare in this population sample of 8,344 individuals, with a frequency of 0.065% in the black South African sample population. Notwithstanding, tests performed for detecting the presence of male DNA based on the presence of the amelogenin gene alone should be reconsidered, as this study confirms that these deletions do occur in the African population. The impact of the results generated in this study on the medical and forensic practise of DNA testing is significant. / Thesis (Ph.D. (Biochemistry))--North-West University, Potchefstroom Campus, 2011.

There are many practical decision problems that fall into the category of network flow problems: numerous examples of applications can be found in areas such as telecommunications, logistics, distributions, engineering, computer science and so on. One of the most popular and valuable tools to solve network flow problems of a topological nature is the use of linear programming models. An important extension of these models is that of integer programming models that deal with problems where some, or all, of the variables are required to assume integer variables. A significant application in this class of problems is the knapsack problem that arises in different contexts such as loading containers in aircraft or satisfying the demand for various lengths of cloth which must be cut from fixed length bolts of fabric. In this study, the feasibility of representing a network flow model in a tree network model and subsequently solving it using a tree knapsack approach is investigated. To compare and validate the proposed technique, a specific case study was chosen from the literature that can be used as a basis for the research project. The said study was an oil pipeline design problem, addressed by Brimberg et al. (2003). This focuses on the optimal design of an oil pipeline network for the South Gabon oil field in Africa. The objective was to reduce oil transportation costs to a major port. Following an overview of different network flow and knapsack models, an overview of the said matter is presented. A description of the proposed tree knapsack approach and the application of this approach to the given problem is given. Results have indicated that it is feasible to apply a tree knapsack approach to solve network flow problems. / Thesis (M.Sc. (Computer Science))--North-West University, Potchefstroom Campus, 2011.

Starting with tensor calculus and the variational form of the Hamiltonian functional, a generalized theory is formulated for doubly curved thin shells. The formulation avoids geometric approximations commonly adopted in other formulations. The theory is then specialized for cylindrical and toroidal shells as special cases, both of interest in the modeling of straight and elbow segments of pipeline systems. Since the treatment avoids geometric approximations, the cylindrical shell theory is believed to be more accurate than others reported in the literature. By adopting a set of consistent geometric approximations, the present theory is shown to revert to the well known Flugge shell theory. Another set of consistent geometric approximations is shown to lead to the Donnell-Mushtari-Vlasov (DMV) theory. A general closed form solution of the theory is developed for cylinders under general harmonic loads. The solution is then used to formulate a family of exact shape functions which are subsequently used to formulate a super-convergent finite element. The formulation efficiently and accurately captures ovalization, warping, radial expansion, and other shell behavioural modes under general static or harmonic forces either in-phase or out-of-phase. Comparisons with shell solutions available in Abaqus demonstrate the validity of the formulation and the accuracy of its predictions. The generalized thin shell theory is then specialized for toroidal shells. Consistent sets of approximations lead to three simplified theories for toroidal shells. The first set of approximations has lead to a theory comparable to that of Sanders while the second set of approximation has lead to a theory nearly identical to the DMV theory for toroidal shells. A closed form solution is then obtained for the governing equation. Exact shape functions are then developed and subsequently used to formulate a finite element. Comparisons with Abaqus solutions show the validity of the formulation for short elbow segments under a variety of loading conditions. Because of their efficiency, the finite elements developed are particularly suited for the analysis of long pipeline systems.

The accurate determination of gender of biological samples has valuable applications in medical and forensic investigations. Gender determination based on length variations in the X-Y homologous amelogenin gene, is part of most commercial multiplex DNA profiling kits. The first report of a failure of the amelogenin sex test was in 1998 when two normal males were typed as female. Subsequently, several amelogenin Y (AMELY) negative males have been reported. This study represents the first report of this phenomenon in the black South African population. This study determined the size of the Y-chromosome deletion that resulted in the failure of the amelogenin sex test in two black South African AMELY-negative males by typing specific DNA markers surrounding the amelogenin locus. Through deletion size and Y-chromosome microsatellite haplotypes, the relationship between the samples was investigated. The samples were sequenced at the amelogenin gene and typed for thirteen sites on the short arm of the Y-chromosome. In order to determine the Y-chromosome haplotypes, eleven Y-chromosome microsatellite markers were typed. These samples had the same size deletion of approximately 3 Mb. The Y-chromosome haplotypes indicated that these were probably independent events. The frequency of AMELY-negative males is rare in this population sample of 8,344 individuals, with a frequency of 0.065% in the black South African sample population. Notwithstanding, tests performed for detecting the presence of male DNA based on the presence of the amelogenin gene alone should be reconsidered, as this study confirms that these deletions do occur in the African population. The impact of the results generated in this study on the medical and forensic practise of DNA testing is significant. / Thesis (Ph.D. (Biochemistry))--North-West University, Potchefstroom Campus, 2011.