The mass production of carbon nanotubes (CNTs) by a cost effective process is still a challenge for further research and application of CNTs. This research focussed on the deposition of CNTs on a continuously-fed carbon substrate via arc discharge at atmospheric pressure. In this work, modifications, control and optimization of the available arc-discharge reactor were conducted. New reactor support and new tape feeding mechanisms were added to the reactor for better temperature assessment, longer operating period and better control of the speed of the tape. The influence of inter-electrode gap, substrate velocity and arc current on the surface temperature were investigated. Multiwalled carbon nanotubes (MWNTs) were produced at lower currents (< 20 A) and at larger inter-electrode gaps. Further investigation shows that inter-electrode gap influenced both the arc characteristic and the anode surface temperature (Ts). Here, Ts was measured by an optical pyrometer. The inter-electrode gap was found to indirectly affect the formation of NTs. Anode surface temperature (Ts) varied with gap, reaching a minimum at an intermediate gap. Higher CNTs yield was found at this lowest Ts. This minimum Ts is consistent with the presence of a cloud of nanoparticles ejected by the heated graphite/carbon surfaces. These graphene fragments are thought to later fold and form nanotube “seeds” and then develop into multiwall nanotubes. This cloud of nanoparticles also may affect the electrical conductivity at the front of the anode. Simulation of the arc behaviour, i.e. temperature distributions and flow properties of the plasma, using a computer package Comsol Multiphysics 3.2, was stable only when the electrical conductivity of a dusty plasma near to the electrodes was included. Our experiments show that carbon nanotubes grew better at a Ts range of ~ 3650 K - 3700 K and at the tape speed of 3 mm/s. The results from our work also strongly suggested that tiny carbon crystallites are the main intermediates for CNT growth in an electric arc. The limiting factor for a solid state growth mechanism, therefore, is high temperature annealing of carbon or graphene fragments. Further work should aim to understand the growth mechanism of CNTs, produce comprehensive analysis on the arc plasma composition and also explore the possibility of producing CNTs at higher rates.

The plasma vertical position system on the COMPASS–D tokamak is studied in this thesis. An analogue P+D controller is used to regulate the plasma vertical position which is open loop unstable. Measurements from inside the vessel are used for the derivative component of the control signal and external measurements for the proportional component. Two main sources of disturbances are observed on COMPASS–D. One source is 600Hz noise from thyristor power supplies which cause large oscillations at the control amplifier output. Another source is impulse–like disturbances due to ELMs (Edge Localized Modes) and this can occasionally lead to loss of control when the control amplifier saturates. Models of the plasma open loop dynamics were obtained using the process of system identification. Experimental data is used to fit the coefficients of a mathematical model. The frequency response of the model is strongly dependent on the shape of the plasma. The effect of shielding by the vessel wall on external measurements when compared with internal measurements is also observed. The models were used to predict values of gain margins and phase crossover frequencies which were found to be in good agreement with measured values. The harsh reactor conditions on the proposed ITER tokamak preclude the use of internal measurements. On COMPASS–D the stability margins of the loop decrease when using only external flux loops. High order controllers were designed to stabilize the system using only external measurements and to reduce the effect of 600Hz noise on the control amplifier voltage. The controllers were tested on COMPASS–D and demonstrated the improved performance of high order controllers over the simple P+D controller. ELMs cause impulse–like disturbances on the plasma position. The optimal controller minimizing the peak of the impulse response can be calculated analytically for COMPASS–D. A multiobjective controller which combines a small peak impulse response with robust stability and noise attenuation can be obtained using a numerical search.

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Le travail effectué dans le cadre de cette thèse porte sur l'étude d'un atténuateur de rayonnement X à gaz et du plasma produit à l'intérieur. Un atténuateur à gaz est composé d'une chambre remplie du gaz, généralement argon ou krypton à quelques centaines de millibars, qui absorbe la partie de basse énergie d'un spectre de rayonnement X de synchrotron, en réduisant la puissance reçu par les éléments optiques en aval sans affecter les propriétés de la partie de haute énergie du spectre. L'absorption des photons crée une région de gaz chaud et ionisé autour du parcours du faisceau X, en réduisant la densité du gaz localement. A détaillé bilan énergétique entre tous les processus impliqués c'est nécessaire pour être capable de prédire l'absorption et opérer et dessiner atténuateurs a gaz efficacement. Un modèle hybride que combine techniques de modélisation Monte Carlo et fluides à été développé pour déterminer le bilan énergétique et simuler l'absorption de rayonnement X. Le modèle a été valide expérimentalement pas études incluant absorption de puissance, spectroscopie optique d'émission et spectroscopie d'absorption par laser à diodes. Les résultats des simulation et expériences montre un plasma confiné autour du parcours du faisceau X, recombinant dans le volume de gaz et avec une température maximale de plusieurs centaines de Kelvin. Le modèle a été capable de prédire l'absorption de rayons X avec un erreur de entre 10 et 20%, qui permettre son utilisation comme première approximation pour le dessin et opération de atténuateurs a gaz et aussi comme point de partie pour modèles plus affinées. / The work done in the context of this thesis focuses in the study of an X-ray gas attenuator and the plasma produced within. An X-ray gas attenuator consists on a vessel filled with gas, usually argon or krypton at a few hundreds millibars, that absorbs the low energy fraction of a synchrotron X-ray spectrum, reducing the power received by downstream optical elements without affecting the properties of the high energy part of the spectrum. The absorption of the photons creates a region of hot, ionized gas around the X-ray beam path, decreasing locally the gas density. A detailed energy balance between all the involved processes is required to be able to predict the absorption and operate and design gas attenuators efficiently. A hybrid model combining Monte Carlo and fluid modelling techniques has been developed to determine the energy balance and simulate the X-ray absorption. The model has been validated by experimental studies including power absorption, optical emission spectroscopy and tunable laser absorption spectroscopy. The results of both simulation and experiments show a plasma confined around the X-ray beam path, recombining in the bulk of the gas and with a maximum temperature of several hundreds of Kelvin. The model was able to predict the X-ray absorption within a 10-20% of error, which allows its use as a first approximation for the design and operation of gas attenuators, and also provides a starting point for more refined models.

Compte tenu de l'importance de maintenir une qualité optimale des cordons de soudure et l'impossibilité d'assurer tout risque de manque de pénétration et de fusion par des contrôles non-destructifs, cette thèse permettra de développer une expertise et des outils numériques pour la simulation numérique tridimensionnelle des procédés de soudage par fusion afin de prédire la géométrie finale du cordon. Pour ce faire, on implémente une méthode de suivi d'interface afin d'améliorer la prise en compte des phénomènes thermophysiques au niveau des surfaces libres déformables. Cela permettra en outre de prendre en compte les forces agissant à la surface du bain métallique telles que la tension de surface, la gravité et la pression d'arc. Puis, il est envisagé d'améliorer l'estimation du transfert thermique entre l'arc et les pièces à assembler via un couplage instationnaire des modèles de plasma et de bain de fusion pour ainsi simuler de façon optimale la forme finale du cordon de soudure. Cette thèse permettra de traiter certaines applications industrielles spécifiques à EDF, en particulier les soudures d'étanchéité de faible épaisseur, permettant des études approfondies sur les opérations de réparations par soudage en corniche. / In order to ensure total safety during maintenance operations within nuclear power plants, it is mandatory to preserve the optimal quality of the internal weld beads. To this end, we use Computational Magnetohydrodynamics to simulate adjacent phenomena within the plasma and the weld pool in order to improve the knowledge of welding operating process. One of the difficulties is to take into account the effects induced by the thermal gradient and the variations of surfactant element concentrations on the weld pool surface known as the Marangoni effect. In order to take into account all the physical phenomena at the plasma / weld pool interface, we use an interface tracking method (Arbitrary Lagrangian-Eulerian) to improve the simulation of weld pool with free surfaces. Subsequently, it enables to capture more precisely the interfacial forces such as the Marangoni effect, the arc pressure and the gravity, and improve vertical welding simulation. Thus, this work is part of the development of a tridimensional unsteady two-way coupling in order to overcome the Gaussian boundary condition used to model the heat transfer from plasma torch towards the work piece surface. Ultimately, we could obtain an unified model for an optimal welding process simulation.