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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
21

A dynamic regulation scheme with scheduler feedback information for multimedia network

Shih, Hsiang-Ren 11 July 2001 (has links)
Most proposed regulation methods do not take advantage of the state information of the underlying scheduler, resulting in a waste of resources. We propose a dynamic regulation approach in which the regulation function is modulated by both the tagged stream's characteristics and the state information fed-back from the scheduler. The transmission speed of a regulator is accelerated when too much traffic has been sent to the scheduler by the other regulators or when the scheduler's queue is empty. As a result, the mean delay of the traffic can be reduced and the scheduler's throughput can be increased. Since no complicated computation is involved, our approach is suitable for the use in high-speed networks.
22

New on-line mass spectrometric tools for studying urban organic aerosol sources

Reyes Villegas, Ernesto January 2018 (has links)
Atmospheric aerosols have been shown to have a significant impact on air quality and health in urban environments. Organic aerosols (OA) are one of the main constituents of submicron particulate matter. They are composed of thousands of different chemical species, which makes it challenging to identify and quantify their sources. OA sources have been previously studied; however quantitative knowledge of aerosol composition and their processes in urban environments is still limited. The results presented here investigate OA, their chemical composition and sources as well as their interaction with gases. On-line measurements of species in the particle and the gas phase were performed both from field-based and laboratory studies. Aerosol Mass Spectrometers (AMS) were used together with the Chemical Ionisation Mass Spectrometer (CIMS) and the Filter Inlet for Gases and AEROsols (FIGAERO). Two ambient datasets were analysed to develop methods for source apportionment, using the Multilinear Engine (ME-2), in order to gain new insights into aerosol sources in Manchester and London. Long-term measurements in London allowed the opportunity to perform seasonal analysis of OA sources and look into the relationship of hydrogen-like OA (HOA) and heavy- and light-duty diesel emissions. The seasonal analysis provided information about OA sources that was not possible to observe on the long-term analysis. During Bonfire Night in Manchester, with high aerosol concentrations, particularly biomass burning OA (BBOA), it was possible to identify particulate organic oxides of nitrogen (PON), with further identification of primary and secondary PON and their light absorbing properties. Through laboratory work, new insights into cooking organic aerosols (COA) were gained, a higher relative ion efficiency (RIEOA) value of around 3.3 for OA-AMS compared with the typical RIEOA of 1.4 was determined, which implies COA concentrations are overestimated when using the RIEOA value of 1.4. Dilution showed to have a significant effect on food cooking experiments, increasing both the gas/particle ratios and the O:C ratios. The data generated in this work, OA-AMS mass spectra and markers from both gas and particle phase identified with FIGAERO-CIMS, provide significant information that will contribute to the improvement of source apportionment in future studies. This work investigates OA, with a focus on primary organic aerosols originated from anthropogenic activities. These scientific findings increase our understanding of OA sources and can help to improve inventories and models as well as to develop plans and policies to mitigate the air pollution in urban environments.
23

Determination of Fine Particulate Matter Composition and Development of the Organic Aerosol Monitor

Cropper, Paul Michael 01 February 2016 (has links) (PDF)
Tropospheric fine particulate matter (PM) poses serious health risks and has a significant impact on global climate change. The measurement of various aspects of PM is challenging due to its complex chemical nature. This dissertation addresses various aspects of PM, including composition, measurement, and visibility. The U.S. Environmental Protection Agency (EPA) proposed a new secondary standard based on visibility in urban areas using 24-h averaged measurements of either light scatter or PM concentration. However shorter averaging times may better represent human perception of visibility. Data from two studies conducted in Lindon, UT, 2012, and Rubidoux, CA, 2003, were used to compare different techniques to estimate visibility, particularly the effect of relative humidity on visibility estimations. Particle composition was measured in Salt Lake City during January-February of 2009. One-hour averaged concentrations of several gas phase and particle phase inorganic species were measured. The results indicate ammonium nitrate averages 40% of the total PM2.5 mass in the absence of inversions and up to 69% during strong inversions. Also, the formation of ammonium nitrate is nitric acid limited, while the formation of ozone appears to be oxidant and volatile organic carbon (VOC) limited. Reduction of NOx will reduce ammonium nitrate secondary particle formation, however, a decrease in NOx may increase ozone concentration.Due to the complexity of PM it is poorly characterized. A large fraction of PM is composed of organic compounds, but these compounds are not regularly monitored due to limitations in current sampling techniques. The GC-MS Organic Aerosol Monitor (OAM) combines a collection device with thermal desorption, gas chromatography and mass spectrometry to quantitatively measure the carbonaceous components of PM on an hourly averaged basis. A compact GC and simple pre-concentrator were developed for the system to decouple separation from manual injection and enhance separation of environmentally-relevant polar organic compounds, such as levoglucosan. The GC-MS OAM is fully automated and has been successfully deployed in the field. It uses a chemically deactivated filter for collection followed by thermal desorption and GC-MS analysis. Laboratory tests show that detection limits range from 0.2 to 3 ng for many atmospherically relevant compounds. The GC-MS OAM was deployed in the field for semi-continuous measurement of the organic markers, levoglucosan, dehydroabietic acid, and several polycyclic aromatic hydrocarbons (PAHs) during winter (January to March), 2015 and 2016. Results illustrate the significance of this monitoring technique to more fully characterize the organic components of PM and identify sources of pollution.
24

Applications of Thermal and Laser-Based Methods for Monitoring Airborne Particulates in Coal Mines

Phillips, Kent Thomas 22 September 2017 (has links)
The purpose of this thesis is to examine applications of thermal and laser-based methods to monitor airborne particulates in underground coal mines. Specifically, coal and mixed mineral mine dust, as well as, diesel particulate matter (DPM). These particulates have historically, and continue to have, significant health impacts on underground miners. Chapters 1 and 2 of this thesis concentrate on using a novel method of thermogravimetric analysis (TGA) to characterize respirable coal and mixed mineral mine dust and presents the results of this method being applied to samples collected in Appalachia coal mines. Appalachia has been a geographic "hotspot" for the rise in occupational lung disease amongst underground coal miners, which began in 1990's after decades of steady decline. This has led researchers to propose there could be something unique about the respirable dust composition in Appalachia coal mines, which resulted in the surge of lung disease cases; however, the knowledge base regarding the actual composition of respirable coal mine dust is limited. The results of this thesis show that most of the mass fraction of respirable Appalachia coal mine dust is not coal, but rather carbonates and non-carbonate minerals (i.e. silica and silicates). These findings are significant as many researchers now suspect silica and silicates to be the true culprit in the occupational lung disease of coal miners. DPM presents an additional occupational health hazard to underground coal miners where diesel equipment is used and is difficult to monitor due to its complex nature. In underground metal/non-metal mines, airborne DPM is regulated and monitored using carbon surrogates. However, due to the potential interference from coal-sourced carbon, DPM in coal mines is monitored only by taking samples at the tailpipe of each piece of equipment. This thesis aims to investigate the potential for a laser-based instrument, the FLIR Airtec, to be used in underground coal mines. In particular, what effect the coal dust will have on the instrument, as it measures DPM by way of elemental carbon (EC). The results of this study show that while the Airtec will not over-estimate coal-sourced EC, there could be some sampling artifacts associated with its operation in coal mines, which may inhibit its effectiveness. / Master of Science
25

Improving the discrimination of primary and secondary sources of organic aerosol : use of molecular markers and different approaches / Amélioration de la discrimination des sources primaires et secondaires de l'aérosol organique : utilisation de marqueurs moléculaires et de différentes approches

Srivastava, Deepchandra 26 April 2018 (has links)
Les aérosols organiques (AO), issus de nombreuses sources et de différents processus atmosphériques, ont un impact significatif sur la qualité de l’air et le changement climatique. L’objectif de ce travail de thèse était d’acquérir une meilleure connaissance de l’origine des AO par l’utilisation de marqueurs organiques moléculaires au sein de modèles source-récepteur de type positive matrix factorization (PMF). Ce travail expérimental était basé sur deux campagnes de prélèvements réalisées à Grenoble (site urbain) au cours de l’année 2013 et dans la région parisienne (site péri-urbain du SIRTA, 25 km au sud-ouest de Paris) lors d’un intense épisode de pollution aux particules (PM) en Mars 2015. Une caractérisation chimique étendue (de 139 à 216 espèces quantifiées) a été réalisée et l’utilisation de marqueurs moléculaires primaires et secondaires clés dans la PMF a permis de déconvoluer de 9 à 11 sources différentes de PM10 (Grenoble et SIRTA, de façon respective) incluant aussi bien des sources classiques (combustion de biomasse, trafic, poussières, sels de mer, nitrate et espèces inorganiques secondaires) que des sources non communément résolues telles que AO biogéniques primaires (spores fongiques et débris de plantes), AO secondaires (AOS) biogéniques (marin, oxydation de l’isoprène) et AOS anthropiques (oxydation des hydrocarbures aromatiques polycycliques (HAP) et/ou des composés phénoliques). En outre, le jeu de données obtenu pour la région parisienne à partir de prélèvements sur des pas de temps courts (4h) a permis d’obtenir une meilleure compréhension des profils diurnes et des processus chimiques impliquées. Ces résultats ont été comparés à ceux issus d’autres techniques de mesures (en temps réel, ACSM (aerosol chemical speciation monitor) et analyse AMS (aerosol mass spectrometer) en différée) et/ou d’autres méthodes de traitement de données (méthodes traceur EC (elemental carbon) et traceur AOS). Un bon accord a été obtenu entre toutes les méthodes en termes de séparation des fractions primaires et secondaires. Cependant, et quelle que soit l’approche utilisée, la moitié de la masse d’AOS n’était toujours pas complètement décrite. Ainsi, une nouvelle approche d’étude des sources de l’AO a été développée en combinant les mesures en temps réel (ACSM) et celles sur filtres (marqueurs moléculaires organiques) et en utilisant un script de synchronisation des données. L’analyse PMF combinée a été réalisée sur la matrice de données unifiée. 10 facteurs AO, incluant 4 profils chimiques différents en lien avec la combustion de biomasse, ont été mis en évidence. Par rapport aux approches conventionnelles, cette nouvelle méthodologie a permis d’obtenir une meilleure compréhension des processus atmosphériques liés aux différentes sources d’AO. / Organic aerosols (OAs), originating from a wide variety of sources and atmospheric processes, have strong impacts on air quality and climate change. The present PhD thesis aimed to get a better understanding of OA origins using specific organic molecular markers together with their input into source-receptor model such as positive matrix factorization (PMF). This experimental work was based on two field campaigns, conducted in Grenoble (urban site) over the 2013 year and in the Paris region (suburban site of SIRTA, 25 km southwest of Paris) during an intense PM pollution event in March 2015. Following an extended chemical characterization (from 139 to 216 species quantified), the use of key primary and secondary organic molecular markers within the standard filter-based PMF model allowed to deconvolve 9 and 11 PM10 sources (Grenoble and SIRTA, respectively). These included common ones (biomass burning, traffic, dust, sea salt, secondary inorganics and nitrate), as well as uncommon resolved sources such as primary biogenic OA (fungal spores and plant debris), biogenic secondary AO (SOA) (marine, isoprene oxidation) and anthropogenic SOA (polycyclic aromatic hydrocarbons (PAHs) and/or phenolic compounds oxidation). In addition, high time-resolution filter dataset (4h-timebase) available for the Paris region also illustrated a better understanding of the diurnal profiles and the involved chemical processes. These results could be compared to outputs from other measurement techniques (online ACSM (aerosol chemical speciation monitor), offline AMS (aerosol mass spectrometer) analyses), and/or to other data treatment methodologies (EC (elemental carbon) tracer method and SOA tracer method). A good agreement was obtained between all the methods in terms of separation between primary and secondary OA fractions. Nevertheless, and whatever the method used, still about half of the SOA mass was not fully described. Therefore, a novel OA source apportionment approach has finally been developed by combining online (ACSM) and offline (organic molecular markers) measurements and using a time synchronization script. This combined PMF analysis was performed on the unified matrix. It revealed 10 OA factors, including 4 different biomass burning-related chemical profiles. Compared to conventional approaches, this new methodology provided a more comprehensive description of the atmospheric processes related to the different OA sources.
26

Impacts atmosphériques des activités portuaires et industrielles sur les particules fines (PM2.5) à Marseille / Atmospheric impacts of harbor and industrial activities on fine particles (PM2.5) in Marseille

Salameh, Dalia 21 July 2015 (has links)
Les particules fines (PM2.5) suscitent de plus en plus l’intérêt des pouvoirs publics en raison de leurs effets néfastes sur la qualité de l’air et la santé humaine. La mise en place des politiques de réductions efficaces des émissions requière une connaissance détaillée des contributions des principales sources aux concentrations ambiantes en PM. Ainsi, cette thèse a pour objectifs de caractériser la composition chimique des PM2.5, et de quantifier leurs sources d’émissions à Marseille. Pour se faire, une campagne de mesure d’un an (2011-2012) a été conduite sur le site de fond urbain de « Cinq avenues ». La spéciation chimique complète des filtres collectés a été réalisée, et 3 modèles-récepteurs ont été utilisés: CMB (Chemical Mass Balance), PMF (Positive Matrix Factorization), et ME-2 (Multilinear Engine). Bien que basés sur des concepts sensiblement différents, l’exercice d’intercomparaison des sorties de ces modèles a montré globalement un bon accord pour l’estimation des contributions de la combustion de biomasse (entre 23 et 33% en moyenne annuelle) et du trafic véhiculaire (14-26%). En revanche, des différences significatives sont observées pour la source industrielle (1-18%) et le sulfate d’ammonium (12-30%). Cette étude a mis en évidence une contribution importante de la matière organique (OM) qui représente en moyenne 42% des PM2.5. Quant à la quantification des sources, l’un des résultats marquants est la mise en évidence de deux types d’aérosols de combustion de biomasse, dont l’un provient très probablement du brûlage à l’air libre de déchets verts. Ce dernier peut même être considéré comme un contributeur majeur des PM2.5 à l’automne et en début d’hiver. / Fine particulate matter (PM2.5) has received considerable attention due to its impact on human health and air quality. Therefore, effective plans for human health protection require a detailed knowledge of the most relevant PM emission sources and their contributions to the ambient PM levels. Thus, this thesis aims to characterize the chemical composition of PM2.5 collected in Marseille area, and quantify the impacts of the main emission sources. To meet these objectives, a one-year monitoring campaign was conducted at the urban background site of “Cinq avenues” during the period of 2011-2012. A detailed chemical characterization of the collected PM2.5 filters was performed, and 3 receptor models were applied to this database: CMB (Chemical Mass Balance), PMF (Positive Matrix Factorization), and ME-2 (Multilinear Engine). Although based on significantly different concepts, the intercomparison exercise of the output data of the used models has generally showed a good agreement in estimating the source contributions of biomass burning (representing between 23 and 33% on annual average) and vehicular traffic (between 14 and 26%). In contrast, significant differences were observed for the industrial (1-18%) and ammonium sulfate (12-30%) sources. This study highlighted the significant contribution of organic matter (OM), which represents 42% of the PM2.5 mass, on average. Regarding the source apportionment results, one of the most striking findings is the identification of two types of biomass burning aerosol, one of which probably comes from open burning of green waste. The latter can even be considered a major contributor to the PM2.5 mass during fall and early winter
27

Chauffage au bois et qualité de l’air en Vallée de l’Arve : définition d’un système de surveillance et impact d’une politique de rénovation du parc des appareils anciens / Wood heating and air quality in the Arve Valley : definition of a surveillance system and impact of a renovation policy of old devices

Chevrier, Florie 23 November 2016 (has links)
La combustion de la biomasse est l’une des sources majoritaires de particules atmosphériques en périodes hivernales dans les vallées alpines, et particulièrement en vallée de l’Arve où des dépassements des seuils européens sont très régulièrement observés. Ceci a conduit à la mise en place d’un large programme de remplacement des dispositifs de chauffage au bois les moins performants dans le cadre d’une des actions du Plan de Protection de l’Atmosphère, le Fond Air Bois. Le projet DECOMBIO (DÉconvolution de la contribution de la COMbustion de la BIOmasse aux PM10 dans la vallée de l’Arve) a ainsi été mis en place en octobre 2013 afin de mesurer l’impact de cette politique de rénovation des appareils de chauffage au bois sur la qualité de l’air. C’est dans ce programme que s’inscrivent ces travaux de thèse dont l’objectif principal est de valider les méthodologies mises en place en routine pour permettre une déconvolution rapide de la combustion de la biomasse et mettre en relation les éventuels changements observés avec les avancées des remplacements de dispositifs de chauffage au bois domestiques.Pour mener à bien ce travail, trois sites, représentant les différentes situations de la vallée de l’Arve, ont été instrumentés (Marnaz, Passy et Chamonix) afin de suivre en continu, et tout au long du projet DECOMBIO, l’évolution des concentrations atmosphériques du Black Carbon (BC) et des traceurs moléculaires permettant de distinguer la contribution de la combustion de la biomasse des autres types de combustion. Un important jeu de données a été acquis entre novembre 2013 et octobre 2014 grâce à des prélèvements réguliers sur filtre permettant une caractérisation très fine de la composition chimique des particules atmosphériques. L’utilisation de l’approche statistique « Positive Matrix Factorization » (PMF) a permis de mieux appréhender les différentes sources entrant en jeu dans les émissions de particules au sein de cette vallée avec notamment un intérêt particulier pour les émissions de la combustion de la biomasse. Le développement de cette méthodologie d’attribution et de quantification des sources de particules basé sur l’utilisation de traceurs organiques spécifiques, de contraintes particulières appliquées à ce modèle et de données de déconvolution de la matière carbonée constitue une avancée importante dans la définition des facteurs sources issus de ce modèle.Les méthodologies développées au cours de ce travail, permettant une amélioration des connaissances et des contributions des sources, constituent donc des outils directement utilisables par les Associations Agréées de Surveillance de la Qualité de l’Air (AASQA), notamment pour l’évaluation quantitative des mesures prises pour améliorer la qualité de l’air dans le cadre de Plans de Protection de l’Atmosphère, entre autres celui de la vallée de l’Arve. / Biomass burning is one of the major sources of atmospheric particles during wintertime in Alpine valleys, and more especially in the Arve valley where exceedances of the European regulated limit value are regularly observed. This situation led to the establishment of an important program of replacement of old wood stoves with new ones as part of an action of an Atmospheric Protection Plan (APP), the “Fonds Air Bois”. The research program DECOMBIO (“DÉconvolution de la contribution de la COMbustion de la BIOmasse aux PM10 dans la vallée de l’Arve”) has been set up in October 2013 to estimate the impact of this wood stoves renewal policy on air quality. This thesis works be incorporated within this program and have for main objective to validate methodologies used in routine to enable a fast deconvolution of the biomass burning source and to compare any observed changes with progress of wood stove changeout.To complete this work, three sites, representing the different situations of the Arve valley, were instrumented (Marnaz, Passy and Chamonix) to monitor the continuing evolution of atmospheric concentrations of Black Carbon (BC) and molecular markers enabling to distinguish between the biomass burning contribution and that of other types of combustion. A large dataset was acquired between November 2013 and October 2014 thanks to regular filter samples enabling a vast chemical characterization of PM10. The use of statistical analysis “Positive Matrix Factorization” (PMF) has led to an enhanced appreciation of particle emission sources within this valley with a focus on biomass burning emissions. The development of this methodology of identification and source apportionment based on the use of specific organic markers, specific constraints and data from carbonaceous matter deconvolution is an important progress in definition of factors from this model.The developed methodologies during this work, enabling an improvement of knowledges and source apportionment, are tools directly usable by French Accredited Associations for Air Quality Monitoring, especially for the quantitative assessment of actions introduced to improve air quality as part of Atmospheric Protection Plans, for example the one in the Arve valley.
28

A atenção básica no município de Niterói: um estudo de caso

Bastos, Jaina Larissa Bastos Costa de January 2016 (has links)
Submitted by Ana Lúcia Torres (bfmhuap@gmail.com) on 2017-10-20T15:00:31Z No. of bitstreams: 2 license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Dissertação JAINA OLIVEIRA.pdf: 685670 bytes, checksum: af55fa07ae834cea2ed50ad3337b6e38 (MD5) / Approved for entry into archive by Ana Lúcia Torres (bfmhuap@gmail.com) on 2017-10-20T15:00:39Z (GMT) No. of bitstreams: 2 license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Dissertação JAINA OLIVEIRA.pdf: 685670 bytes, checksum: af55fa07ae834cea2ed50ad3337b6e38 (MD5) / Made available in DSpace on 2017-10-20T15:00:39Z (GMT). No. of bitstreams: 2 license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Dissertação JAINA OLIVEIRA.pdf: 685670 bytes, checksum: af55fa07ae834cea2ed50ad3337b6e38 (MD5) Previous issue date: 2016 / Faculdade de Medicina de Petrópolis. Faculdade Arthur Sá Earp Neto. Docente / Esta dissertação discute a atenção básica de Niterói, enfocando na transição do Programa Médico de Família (PMF) para Estratégia Saúde da Família (ESF). O PMF foi implantado em 1992 no município de Niterói e possui características próprias, relacionadas ao desenvolvimento desse nível de atenção no âmbito local. A ESF implantada com essa configuração a partir de 2006 tem como um dos seus principais objetivos, estruturar a atenção básica do país. O estudo buscou investigar: o que pensam os atores sociais (profissionais da saúde e da gestão), sobre a transição do PMF para ESF? A análise dos dados se processou com base na leitura e discussão dos relatórios finais das Conferências Municipais de Saúde (CMS); na observação da 7ªCMS e nas entrevistas realizadas. Para análise dos dados foram estabelecidas três categorias: modelo assistencial; participação da população e processo de trabalho, que emergiram com os dados do campo. Os resultados apontaram que o município está em transição, para implementação da ESF. Foram identificadas características do PMF e da ESF. Na categoria modelo assistencial, foram identificadas mudanças: o aumento da população adscrita, da cobertura, aumento da equipe, diminuição das atividades de campo e concomitância de modelos (o hegemônico e o alternativo com o PMF e a ESF). Na categoria participação da população, consta a diminuição desta e a falta de consenso com relação à cogestão. Na categoria processo de trabalho, foram identificadas questões sobre a forma de contratação, ligadas ao modelo de gestão e questões relacionadas às mudanças no processo de trabalho, com a diminuição de visitas domiciliares e o aumento da população atendida. Os dados da pesquisa indicam o cenário complexo que a atenção básica está se desenvolvendo no país. Revela-se particularidades na implementação da ESF que extrapolam uma noção única, visto que cada município tem uma singularidade na sua implantação. Sugerem-se mais estudos, considerando o nível local, a fim de captar as particularidades e o desenvolvimento da atenção básica nos diferentes municípios do país. Assim como, mais estudos sobre o acompanhamento dos modelos alternativos e sua relação com os processos de trabalho. Esta pesquisa pretende contribuir também com a memória da Atenção Básica de Niterói / This thesis discusses the structure of Niterói‘s basic health care, focusing on the transition from the Niterói`s Family Doctor Program (FDP) to the Family Health Strategy (FHS). The FDP was established in 1992 in the city and has its own characteristics, related to its attention level in the local scope. The FHS, which was deployed in this configuration since 2006, has as one of its main the objectives the Basic Health Care structuration in the country. The study aimed to investigate what the social stakeholders (health and management professionals) think about the transition from FDP to FHS. The data analysis takes place through the reading and discussion of the final reports of the Municipal Health Conference (CMS); on the 7ªCMS observation and on interviews with professionals and health managers. There were three categories established for data analysis that emerged with the field data. The results indicated that the city is in transition for FHS implementation. Characteristics have been identified from FDP and FHS. In the assistance model category, changes have been identified: the increase in registered population, the increase of the coverage, increased staff, reduction in field activities and concomitant models (the hegemonic and the alternative with the FDP and the FHS). In the population's participation category, the field data indicate that there has been a decrease in participation and a lack of consensus in relation to the co-management. In the work process category, questions were identified about the hiring process, linked to the management model and issues related to changes in the labor process, with a decrease on home visits and increased population served. The survey data indicate aspects of how this level of care is developing in this country. It revealed particularities on the FHS implementation that goes beyond a single notion, since each municipality has a singularity on the model implementation. It is suggested further studies considering the local level in order to capture the characteristics and the development of basic health care in the different municipalities of the country. As well as more studies on the monitoring of alternative models and its relation to the work processes. This study also aims to contribute to the memory of Niterói`s Basic Health Care
29

Constraining global biogenic emissions and exploring source contributions to tropospheric ozone: modeling applications.

Shim, Changsub 26 June 2006 (has links)
Biogenic isoprene plays an important role in tropospheric chemistry. We use HCHO column measurements by the Global Ozone Monitoring Experiment (GOME) to constrain isoprene emissions. Using the global Goddrad Earth Observing SystemChemistry (GEOS-Chem) as the forward model, a Bayesian inversion of GOME HCHO observations from September 1996 to August 1997 is conducted. Column contributions to HCHO from 12 sources including 10 terrestrial ecosystem groups, biomass burning, and industry are considered and inverted for 8 geographical regions globally. The a posteriori solution reduces the model biases for all regions, and estimates the annual global isoprene emissions of 566 Tg C yr-1, ~50% larger than the a priori estimate. Compared to the Global Emissions Inventory Activity (GEIA) inventory (~500 Tg C yr-1), the a posteriori isoprene emissions are generally higher at mid latitudes and lower in the tropics. This increase of global isoprene emissions significantly affects tropospheric chemistry, decreasing the global mean OH concentration by 10.8% to 0.95106 molecules/cm3. The atmospheric lifetime of CH3CCl3 increases from 5.2 to 5.7 years. Positive matrix factorization (PMF), an advanced method for source apportionment, is applied to TRAnsport of Chemical Evolution over the Pacific (TRACE-P) measurements and it is found that cyanogenesis in plants over Asia is likely an important emission process for CH3COCH3 and HCN. This approach also is applied to estimate source contributions to the tropospheric ozone (O3) with Tropospheric Ozone Production about the Spring Equinox (TOPSE) and TRACE-P measurements. The corresponding GEOS-Chem simulations are applied to the same factor-projected space in order to evaluate the model simulations. Intercontinental transport of pollutants is most responsible for increasing trend of springtime O3, while stratospheric influence is the largest contributions to troposperic O3 variability at northern middle and high latitudes. On the other hand, the overall tropospheric contributions to O3 variability are more important at northern low latitudes by long-range transport, biomass burning, and industry/urban emissions. In general, the simulated O3 variabilities are comparable with those of observations. However, the model underestimates the trends of and the contributions to O3 variability by long-range transport of O3 and its precursors at northern middle and high latitudes.
30

Continuous real-time measurement of the chemical composition of atmospheric particles in Greece using aerosol mass spectrometry

Φλώρου, Καλλιόπη 04 November 2014 (has links)
Atmospheric aerosol is an important component of our atmosphere influencing human health, regional and global atmospheric chemistry and climate. The organic component of submicron aerosol contributes around 50% of its mass and is a complex mixture of tens of thousands of compounds. Real-time aerosol mass spectrometry was the major measurement tool used in this work. The Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) can quantitatively measure the chemical composition and size distribution of non-refractory submicron aerosol (NR-PM1). The mass spectra provided by the instrument every few minutes contain information about aerosol sources and processes. This thesis uses the HR-ToF-AMS measurements in two areas of Greece to quantify the contributions of organic aerosol sources to the corresponding organic aerosol levels. Local and regional air pollution sources were monitored and characterized in two sites during intensive campaigns. The first campaign took place during the fall of 2011 (September 24 to October 23) in Finokalia, Crete, a remote-background coastal site without any major human activity. The aim of the study was to quantify the extent of oxidation of the organic aerosol (OA) during autumn, a season neither too hot nor cold, with reduced solar radiation in comparison to summer. The second one took place during the winter of 2012 (February 26 to March 5), in the third major city of Greece, Patras. The measurements were conducted in the campus of the Technological Educational Institute of Patras (TEI), in order to quantify the severity of the wintertime air pollution problem in the area and its sources. The contributions of traffic and residential wood burning were the foci of that study. The Finokalia site is isolated and far away from anthropogenic sources of pollution, making it ideal for the study of organic aerosol coming from different directions, usually exposed to high levels of atmospheric oxidants. The fine PM measured during the Finokalia Atmospheric Measurement Experiment (FAME-11) by the AMS and a Multi Angle Absorption Photometer (MAAP) was mostly ammonium sulfate and bisulfate (60%), organic compounds (34%), and BC (5%). The aerosol sampled originated mainly from Turkey during the first days of the study, but also from Athens and Northern Greece during the last days of the campaign. By performing Positive Matrix Factorization (PMF) analysis on the AMS organic spectra for the whole dataset the organic aerosol (OA) composition could be explained by two components: a low volatility factor (LV-OOA) and a semi-volatile one (SV-OOA). Hydrocarbon-like organic aerosol (HOA) was not present, consistent with the lack of strong local sources. The second field campaign took place in the suburbs of the city of Patras, 4 km away from the city center during the winter of 2012. During this 10-day campaign, organics were responsible for 70% during the day and 80% during the evening of the total PM1. The OA mean concentration during that period was approximately 20 μg m-3 and reaching hourly maximum values as high as 85 μg m-3. Sulfate ions and black carbon followed with 10% and 7% of the PM1. PMF analysis of the organic mass spectra of PM1 explained the OA observations with four sources: cooking (COA), traffic (HOA), biomass burning (BBOA), and oxygenated aerosol (OOA), related to secondary formation and long range transport. On average, BBOA represented 58% of the total OM, followed by OOA with 18%, COA and HOA, with the last two contributing of the same percentage (12%). / --

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