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The synthesis and electron capture negative ion mass spectrometry of polychlorinated diphenyl ethers and dibenzofuransChang, Yoon-seok 10 September 1990 (has links)
Graduation date: 1991
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Microbial dechlorination of polychlorinated dibenzo-p-dioxins and dibenzofurans pathways, kinetics and environmental implications.Liu, Fang1975-, January 2007 (has links)
Thesis (Ph. D.)--Rutgers University, 2007. / "Graduate Program in Environmental Sciences." Includes bibliographical references (p. 173-186).
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Dioxins and dioxin-like compounds in thermochemical conversion of biomass : formation, distribution and fingerprintsGao, Qiuju January 2016 (has links)
In the transition to a sustainable energy supply there is an increasing need to use biomass for replacement of fossil fuel. A key challenge is to utilize biomass conversion technologies in an environmentally sound manner. Important aspects are to minimize potential formation of persistent organic pollutants (POPs) such as dioxins and dioxin-like compounds. This thesis involves studies of formation characteristics of polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs) and naphthalenes (PCNs) in microwave-assisted pyrolysis (MAP) and torrefaction using biomass as feedstock. The research focuses are on their levels, distributions, fingerprints (homologue profiles and isomer patterns) and the underlying formation pathways. The study also included efforts to optimize methods for extracting chlorinated aromatic compounds from thermally treated biomass. The overall objective was to contribute better understanding on the formation of dioxins and dioxin-like compounds in low temperature thermal processes. The main findings include the following: Pressurized liquid extraction (PLE) is applicable for simultaneous extraction of PCDDs, PCDFs, PCNs, polychlorinated phenols and benzenes from thermally treated wood. The choice of solvent for PLE is critical, and the extraction efficiency depends on the degrees of biomass carbonization. In MAP experiments PCDDs, PCDFs and PCNs were predominantly found in pyrolysis oils, while in torrefaction experiments they were mainly retained in solid chars with minor fractions in volatiles. In both cases, highly chlorinated congeners with low volatility tended to retain on particles whereas the less chlorinated congeners tended to volatize into the gas phase. Isomer patterns of PCDDs, PCDFs and PCNs generated in MAP were more selective than those reported in combustion processes. The presence of isomers with low thermodynamic stability suggests that the pathway of POPs formation in MAP may be governed not only by thermodynamic stabilities but also by kinetic factors. Formation of PCDDs, PCDFs and PCNs depends not only on the chlorine contents in biomass but also the presence of metal catalysts and organic/metal-based preservatives. Overall, the results provide information on the formation characteristics of PCDDs, PCDFs and PCNs in MAP and torrefaction. The obtained knowledge is useful regarding management and utilization of thermally treated biomass with minimum environmental impact.
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Formation of Aromatic Compounds by Cyclopentadiene Moieties in Combustion ProcessesKim, Do Hyong 20 July 2005 (has links)
Polycyclic aromatic hydrocarbon (PAH) formation and growth from cyclopentadiene (CPD) moieties have been investigated using a laminar flow reactor and molecular modeling. The resonance-stabilized cyclopentadienyl radical is readily formed in flames and can participate in PAH growth to soot by reaction with the ??onds of aromatic species. Both CPD pyrolysis and computational results indicate that formation of indene and benzene is favored at low temperatures (below 750oC) and formation of naphthalene is favored at high temperatures. Reaction pathways from CPD have further been extended to PAH formation from the reaction of CPD and aromatic compounds with different types of ??onds. Results indicate that, while the major products from the pyrolysis of CPD, acenaphthylene, styrene and phenanthrene mixtures are from the reaction of CPD to itself rather than to these aromatic compounds with different ??onds, CPD does add to these compounds to produce larger PAH.
Polychlorinated naphthalene (PCN) formation from chlorinated phenols has also been studied. In combustion exhaust gas, chlorinated phenols can produce dioxin as well as PCNs. PCN and polychlorinated dibenzofuran (PCDF) congener product distributions were consistent with proposed pathways involving phenoxy radical coupling at unchlorinated ortho-carbon sites. Tautomerization of the phenoxy radical coupling and subsequent fusion via H2O loss results in PCDF formation. Competing with this reaction pathway, CO elimination and subsequent fusion via hydrogen and/or chlorine loss was found to produce PCNs. PCDF isomer distributions were found to be weakly dependent to temperature, whereas PCN isomer distributions were found to be more temperature sensitive with selectivity to particular isomers decreasing with increasing temperature.
Results of this research contribute to a better understanding of chemical mechanisms involved in the formation of toxic byproducts and soot in combustion systems.
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Gas phase formation pathways and mechanisms of polychlorinated dibenzo-p-dioxins and dibenzofuransAkki, Umesh 08 1900 (has links)
No description available.
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Temperature dependent PCDD/PCDF product distributions from phenolsYang, Yun 05 1900 (has links)
No description available.
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Dioxins in the marine environment sources, pathways, and fate of polychlorinated dibenzo-p-dioxins and dibenzofurans in Queensland, Australia /Gaus, Caroline. January 2002 (has links)
Thesis (Ph. D.)--Griffith University, 2002. / Title from PDF title page (viewed on Apr. 28, 2005). Includes bibliographical references.
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Origin of Dioxins in Queensland: Investigations into the Distribution and Sources of Polychlorinated Dibenzo-P-Dioxins in the Queensland Terrestrial EnvironmentPrange, Joelle, n/a January 2004 (has links)
Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) are persistent organic pollutants of global concern as they are persistent, toxic and can biomagnify through the food chain. PCDD/Fs are generally regarded as trace contaminants in a number of chemical products and they are formed as by-products from various industrial, chemical and combustion processes. The pollution with PCDD/Fs occurs with the release of these chemicals into the environment, resulting in the contamination of various compartments including; air, soil, sediment and biota. Studies that have investigated the distribution of PCDD/Fs in the environment suggest that the highest concentrations of these pollutants are found in locations with a history of industrial or chemical PCDD/F sources. Queensland is the north-eastern state of Australia. Queensland has a low population density, few industrial activities and is considered predominantly rural. Therefore it was somewhat surprising that elevated concentrations of PCDD/Fs (in particular the higher chlorinated PCDDs) have been observed in soil and sediments samples collected from various locations along the Queensland coast. The concentrations of PCDDs in Queensland samples were comparable to or higher than concentrations in similar matrices from highly polluted regions elsewhere. To investigate the origin of PCDDs in Queensland, the geographical distribution of PCDD/Fs in topsoil was investigated in the coastal and inland environments to provide information on the potential sources and to estimate the extent of the PCDD contamination. Distinct east-west gradients were detected in topsoil collected from bushland areas across the state with elevated PCDD concentrations confined to the coastal region. Within the coastal region, the contamination could not be associated with specific land uses. In fact, the PCDD/F congener profile was similar in the majority of samples from the coastal region, with a dominance of the higher chlorinated PCDDs (in particular OCDD), whereas PCDFs were low or below the limit of detection. The similarity in the PCDD/F congener profiles in the soils along the coastal region indicated that a source of PCDDs of similar origin has resulted in the contamination of soil extending more than 3000 km and estimations suggest that more than 50 tonnes of OCDD is stored in the topsoil of Queensland.s coastal region. Investigation into the vertical distribution of PCDDs in Queensland coastal soils revealed elevated concentrations of PCDDs, (in particular OCDD) in soils to at least 3.5 m. These results indicated that the extent of the PCDD contamination is significantly greater than anticipated and it was estimated that there is in the order of 3 000 tonnes of OCDD stored in Queensland's coastal soils. The specific PCDD/F congener profile in Queensland coastal soils is unlike known PCDD/F source profiles which led to the suggestion that some yet unidentified formation mechanism may have resulted in the contamination. Potential natural sources of PCDD/Fs, including forest fires, geogenic and biogenic processes were assessed as possible origins for the PCDD contamination in Queensland. Elevated concentrations of PCDDs were detected in the atmosphere during a 'prescribed burn'. This study demonstrated that although forest fires influence atmospheric PCDD/F concentrations substantially, forest fires are not the source of PCDDs in Queensland; rather they are an important mechanism for the redistribution of PCDDs and may have attributed to the widespread PCDD contamination. In this study geological materials (oil shale and kaolin) were analysed as a proxy to assess a geogenic origin of PCDDs. Elevated concentrations of PCDDs were observed in the kaolin samples, however similar and higher concentrations were detected in surface and sub-surface soils, suggesting that specific geogenic formation processes investigated are not the source of PCDDs in Queensland. A preliminary indication for a biogenic origin of PCDDs was identified during the anaerobic incubation of sugarcane irrigation sediments. An increase in the concentration of OCDD in the anaerobic treatment, compared to the control was observed after incubation for 90 days. In these same experiments, a dechlorination of OCDD to lower chlorinated (1,4,6,9-substituted) PCDDs was also observed. Similar transformation processes were observed in other anaerobic environments in Queensland, which led to the suggestion that a biogenic formation of PCDDs (possibly from a precursor) may be responsible for the origin of PCDDs in Queensland.
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Dioxins in the Marine Environment: Sources, Pathways and Fate of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans in Queensland, AustraliaGaus, Caroline, n/a January 2003 (has links)
Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans(PCDFs) are two groups of lipophilic, persistent organic pollutants that are produced as by-products of various anthropogenic and industrial processes. Due to their relatively high toxic potencies and potential to bioaccumulate and biomagnify in organisms and through the food chain, the contemporary widespread distribution of these compounds is a concern to the health of the environment, wildlife and humans. This study determined the distribution, pathways and fate of PCDD/Fs in the coastal zone of Queensland, Australia, including the inshore marine environment of the World Heritage Great Barrier Reef Marine Park. This ecosystem supports unique fauna and flora such as the marine herbivorous mammal dugong (Dugong dugon) and its food source, seagrass. Elevated PCDD/Fs were present in soils and sediments along the entire Queensland coastline. Highest concentrations were found in soil from agricultural irrigation drains and in sediments near the mouths of major rivers. Elevated concentrations were associated with rural and urban types of land-use, and PCDD/Fs were present even in locations remote from anthropogenic activities. PCDD/F congener-specific analysis revealed an unusual profile in all samples, dominated by OCDD, with PCDFs present in low concentrations or below the limit of detection. Distinct HxCDD isomer patterns were observed, with the 1,2,3,7,8,9-HxCDD/1,2,3,4,6,7-HxCDD isomer pair dominating the 2,3,7,8-substituted HxCDDs. Similar congener and isomer characteristics were reported in sediments, soil and clay samples from other continents, but could not be attributed to any known source. Possible PCDD/F sources in Queensland were assessed using segmented estuarine sediment cores, for which radiochemical chronologies were established for each depth. Variations of PCDD/F concentrations in the sediment cores over several centuries of depositional history were relatively small. Elevated PCDD levels were still present in sediment slices from the early 17th century. PCDD/F homologue profiles in sediments deposited during the last 350 years were almost identical and correlated well to the characteristic profiles observed in surface sediments and soils from the entire Queensland coastline. These results suggested the presence of an unidentified PCDD source prior to the production of commercial organochlorine products. To investigate the formation of the unusual PCDD/F profiles, congener and isomer specific analyses were undertaken in soils, sediments and dated sediment cores. The results demonstrated that specific transformation processes in the environment have resulted in the observed PCDD profile characteristics. Dechlorination of OCDD was proposed to result in distinct 1,4-pattern characteristics (i.e. formation of isomers chlorinated in the 1,4,6,9-positions). Consequently, the environmental samples do not reflect the signatures of the original source. An alternative hypothesis to natural formation is discussed evaluating these processes and their implications for possible source contributions. This hypothesis explores the potential for the influence of anthropogenic PCDD precursors (e.g. pentachlorophenol) during the 1940s to 1990s. Transport of PCDD/Fs from the land-based source via impacted tributary river systems, and subsequent deposition processes are proposed to result in PCDD/F accumulation in the inshore marine ecosystem. The extent of the sediment PCDD/F contamination governs the concentrations in the extensive inshore marine seagrass meadows of Queensland. Partitioning processes in the sediment-seagrass system lead to increased toxic equivalency (TEQ) in the seagrass, compared to sediment.The relationship between contaminated inshore sediments, seagrass and dugongs were evaluated using six dugong habitat regions along the coastline. PCDD/F body burdens in dugongs are governed by sediment (and seagrass) PCDD/F concentrations in their habitat. High seagrass (and incidental sediment) ingestion rates, selective retention of toxicologically potent congeners and relatively low PCDD/F elimination capacities in dugongs are proposed to result in elevated PCDD/F concentrations and TEQ levels in adult animals. Transfer efficiencies of 4 and 27% of maternal TEQ levels to foetuses and calves (respectively) during gestation and lactation result in relatively high exposure potentials to offspring. Compared to no-observed-adverse-effect-levels in other mammals, and based on the results of this study, a tolerable daily intake (TDI) of 10-24 pg TEQ kg-1 day-1 was estimated for dugongs. The results of the present study found that dugongs from some regions along the coastline of Queensland exceed this TDI by up to 20 fold, suggesting that these populations may be at risk from PCDD/F contamination in their habitat. These results have important implications for the health of the environment, wildlife and humans and were used to develop a conceptual understanding of the sources, pathways and fate of dioxins in Queensland, Australia.
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Fate and transport of POPs in the aquatic environment : with focus on contaminated sedimentsJosefsson, Sarah January 2011 (has links)
Persistent organic pollutants (POPs) are hydrophobic substances that readily sorb to organic matter in particles and colloids instead of being freely dissolved in the water phase. This sorption affects the bioavailability and environmental transport of the POPs. The major part of this thesis concerns the role of sediments as secondary sources of POPs. As the primary emissions decrease, contaminated sediments where POPs have accumulated can become the main source of contamination. If the contaminated sediment by time becomes covered with cleaner layers, the POPs are buried and no longer in contact with the aquatic environment. Experiments in this thesis showed, however, that new invading species can alter the sediment-water dynamics as a result of their bioturbation, i.e. mixing of sediment particles and pore-water. Marenzelleria spp., invading species in the Baltic Sea that burrow deeper than native species, were found to increase the remobilization of buried contaminants. The sediment-to-water flux was inversely related to the burial depth (2-10 cm) of the POP congeners (polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers) and also inversely related to the hydrophobicity of the congener. The flux was therefore most pronounced for less hydrophobic contaminants, which was linked to the bioirrigating behaviour of these species. Marenzelleria spp. also accumulated the buried POPs and increased concentrations in surface sediment. Contaminants previously considered buried at a ’safe’ depth can thus be remobilized as a result of the invasion of Marenzelleria spp. in the Baltic Sea. One method to decrease the remobilization of contaminants from sediments is ’capping’, i.e. a layer of clean material is placed as a cap on the sediment. By amending the cap with active materials, which sequester the POPs and decrease their availability, thinner layers can be used (’active capping’ or ’thin-layer capping’). Results from an experiment with thin-layer capping using different active materials (activated carbon (AC) and kraft lignin) showed that both the sediment-to-water flux and the bioaccumulation by benthic species of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), hexachlorobenzene (HCB) and octachlorostyrene (OCS) decreased with increased thickness of the cap layer (0.5-5 cm). Amendments with active materials further increased the cap efficiency. AC was more efficient than kraft lignin, and a 3 cm cap with 3.3% AC reduced the flux and bioaccumulation with ~90%. The reduction of the sediment-to-water flux was inversely related to the hydrophobicity of the POP, and reductions in the flux had similar magnitudes as reductions in the concentration in deep-burrowing polychaetes, demonstrating the importance of bioturbation for sediment-to-water transport. In a one-year study on the levels of PCDD/Fs, PCBs, and HCB in a coastal area of the Baltic Sea, the correlations between the POP levels and the levels of particles and organic carbon in the water were found to differ for POPs of different structure and hydrophobicity. The levels of PCDD/Fs decreased to one third in May, which could be related to the increased sedimentation, i.e. water-to-sediment transport, during spring bloom.
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