Temperature-dependent weight gain of Gulf coast and northern strain walleye Sander vitreus fingerlings was determined by rearing fish in flow-through aquaria at different water temperatures (range 15-32°C). Maximum growth of Gulf coast and northern strain walleye occurred between 20 and 26°C, and weight gain of northern walleye exceeded that of the Gulf coast strain by 1.5 times. An acclimated chronic exposure method to assess upper thermal limits determined that walleye survived 35, 9, and 1 days at 33, 34, and 35°C, respectively. A post pond-rearing feed-training practice (21 d) at a mean density of 6,290 ± 1,247 fish/m3 using formulated feeds was successful (32-85% survival), and walleye continued to consume a formulated diet feed after stocked at densities of 12,250 and 24,700/ha into 0.04 ha earthen ponds. After 125 days, survival in ponds was poor (< 30%) and production varied substantially.

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The choice of a suitable site for any aquaculture practice is a critical decision to make since it has a large impact on the economic profitability of the venture, considering the fact that location defines the amount of capital needed, production costs, yield and access to market. The limited public and private sector support for small-scale aquaculture can be optimized if farms are zoned into areas with relatively similar performance and needs. Considering the high rate at which aquaculture is increasing globally and its consequent impact on the environment, it is projected that improvements will be made in the practices employed in aquaculture. As these improvements are made, there is the need for the review of the location of aquaculture infrastructure and services in order to increase the productivity of the sector. Also, aquaculture statistics such as location of farms and production estimates are fundamental to policy making and development planning at both national and global levels. Aquaculture statistics are however chronically scanty or unreliable in developing countries such as Ghana. Thus, the goal of this study was to show the relative suitability of areas in Ghana for aquaculture and identify the key variables to be considered in the development (including improvement of existing farms) of the aquaculture sector of the country. I used satellite imagery and GIS data in combination with field observations and questionnaires, to develop a map of the feasibility of pond aquaculture in Ghana and provide a reliable estimate of the number of ponds, their areas, productivity and aggregate production in the country. The main factors that have influenced the current distribution of pond aquaculture in Ghana are population density (indicating the availability of markets, input and labor) and proximity to stream and road networks. My results show a gross underestimation of the number of fish ponds in the country and smaller sizes of ponds than existing records suggest. The average water depth of ponds in Ghana is only half of the recommended depth which explained over 80% of the variation in productivity among farms. I estimated the contribution of ponds to domestic fish production to be two to three times what has been previously reported, but still well below the potential. The results of this study will be vital to current national and international efforts to improve aquaculture enterprises in Ghana. / Master of Science

Sediment microbial fuel cell (SMFC) is a special type of microbial fuel cells that can be deployed in a natural water body for energy production and contaminant removal. This MS project aims to explore whether it will be viable to apply SMFCs for wastewater treatment. Experimental SMFCs were studied in several configurations and operational modes for organic removal, nitrate reduction, and energy recovery. When treating an artificial secondary effluent for nitrate removal, the SMFC could remove 44% of the nitrate, higher than that without electricity generation. The enhanced removal was attributed to the supply of electrons to nitrate reduction in the aqueous phase through oxidizing the organics in the sediment. The lack of a proper separator between the anode and the cathode led to the failure of the SMFC when treating an artificial raw wastewater. Ion exchange membranes were incorporated into the MFCs that were installed in a lab-scale open water pond (150 L in volume). Such a system achieved 100% COD removal and more than 75% removal of ammonium nitrogen. However, denitrification remained as a challenge because of a lack of anoxic zone. To reduce the cost of the cathode catalysts, a polymer-based carbon cloth was investigated and exhibited better performance than bare carbon cloth. The results of this MS project have demonstrated that SMFCs in the absence of a proper separator cannot be applied for wastewater treatment. A membrane-based MFC system integrated with open pond may function as a wastewater treatment system, though nitrogen removal efficiency must be improved. / Master of Science

Allochthonous nutrients were monitored during three storm events on one of the major tributaries entering the shallow VPI&SU Duck Ponds. Autochthonous nutrients were monitored for a period of ten months. During these storms, the stormwater runoff contributed large amounts of organic matter and fertilizer nutrients that settled in the ponds and during anoxic conditions, recycled to stimulate algal blooms. Alum was applied to one pond to reduce internal cycling of nutrients. A 25 mg/L dose of alum produced an aluminum hydroxide floc that settled to the bottom and afterwards, lowered othophosphate-phosphorus concentrations below 10 µg/L in the water column. The longevity of the one-time treatment in reducing the sediment-phosphate release rate is unknown because the monitoring program was not continued beyond July of 1988. A pond-treatment program involving copper sulfate was initiated to control algal blooms consisting mainly of the green alga, Chlamydomonas. Based on the complexing properties of the water, such as alkalinity and humics, a copper sulfate dose of 13.6 kg was determined to be a safe and effective dose that reduced algal densities but did not result in any visible adverse effects upon other aquatic life. Both of the pond management schemes were designed to aid managers of small urban ponds who have low operating budgets and a lack of technical equipment. / Master of Science

Climate change (CC) science has made significant progress in development of predictive models. Despite these recent advances, the assessment of CC impacts in urban watersheds remains an area of active research, in part due to the small temporal and spatial scales needed to adequately characterize urban systems. Urban watersheds have been the focus of considerable efforts to restore hydrology and water quality, and the aquatic habitat of receiving waters, yet CC impacts threaten to reduce the effectiveness of these efforts. Thus, assessing the impacts of CC in urban watershed assessment are essential for assuring the success of water quality improvement programs and is an important research need. Simulations of CC for the 2041-2068 period were developed using downscaled Global Climate Models (GCMs) from the North American Regional CC Assessment Program (NARCCAP) and Coupled Model Intercomparison Project Phase 5 (CMIP5) to forecast precipitation and temperature time series. This data were then used to force a Storm Water Management Model (SWMM) of the Difficult Run watershed of Fairfax County, Virginia, a tributary of Potomac River, which flows into Chesapeake Bay. NARCCAP uses a scenario represents a medium-high greenhouse gas emissions assumption, A2; the latter, uses five GCMs, and two Representative Concentration Pathways (RCP 4.5 and 8.5) scenarios in an ensemble approach to better assess variability of model predictions in presenting precipitation, temperature, runoff quantity and quality. Then, the effects of CC on runoff peak, volume, and nutrient and sediment loads delivered to the Chesapeake Bay and on the treatment performance of a very common stormwater control measure (SCM), retention ponds, was assessed. Rainwater Harvesting (RWH) systems are an unusual SCM in that they recycle and reuse stormwater, normally from rooftops, and increase water supply and reduce runoff. The efficiency of RWH systems for projected CC for these dual purposes was assessed. NARCAAP data for selected locations across the U.S. were statistically downscaled using a modified version of the equiratio cumulative distribution function matching method to create a time series of projected precipitation and temperature. These data were used to force a simulation model, the Rainwater Analysis and Simulation Program (RASP) to assess the impacts of CC on RWH with respect to the reliability of water supply and runoff capture. To support CC modeling, an easy-to-use software tool, RSWMM-Cost, was developed. RSWMM-Cost automates the execution of SWMM, which is commonly used for simulating urban watersheds. Several features were incorporated into the RSWMM-Cost tool, including automated calibration, sensitivity analysis, and cost optimization modules; the latter can assist in identifying the most cost-effective combination of SCMs in an urban watershed. As an example, RSWMM-Cost was applied to a headwater subcatchment the Difficult Run watershed. / Ph. D. / Urban watersheds have been the focus of considerable efforts to restore water quantity and quality, and the aquatic habitat of receiving waters, yet climate change impacts threaten to reduce the effectiveness of these efforts. The assessment of climate change impacts in urban watersheds remains an area of active research, in part due to the small temporal and spatial scales needed to adequately characterize urban systems. Thus, assessing the impacts of climate change in urban watershed assessment are essential for assuring the success of water quality improvement programs and is an important research need. In this study, simulations of climate change for the 2041-2068 period were developed to forecast precipitation and temperature data. These data were then used to force a hydrologic model for the Difficult Run watershed of Fairfax County, Virginia, a tributary of Potomac River, which flows into Chesapeake Bay. Then, the effects of climate change on runoff, nutrient and sediment loads delivered to the Chesapeake Bay and on the treatment efficiency of a very common management practice called retention ponds, was assessed. Rainwater harvesting systems are an unusual management practice that recycle and reuse stormwater, normally from rooftops, and increase water supply and reduce runoff. The efficiency of rainwater harvesting systems for projected climate change with respect to the reliability of water supply and runoff capture was assessed for the 2041-2068 period. To support climate change modeling, an easy-to-use tool, was also developed to select the most cost-optimized combination of best management practices in urban watersheds considering site constraints, limitations, and size. As an example, the tool was applied to a headwater subcatchment of the Difficult Run watershed. The ability to assess the impact of climate change on both hydrologic and water quality treatment could assist in the selection of the most appropriate management practices to address water management goals and conserve limited financial resources.

Urban and agricultural runoff is the principal contributor to non-point source (NPS) pollution and subsequent impairments of streams, rivers, lakes, and estuaries. Urban and agricultural runoff is a major source of sediment, nitrogen (N) and phosphorus (P) loading to receiving waters. Coastal waters in the southeastern U.S. are vulnerable to human impacts due to the proximity to urban an agricultural land uses, and hydrologic connection of the Coastal Plain to receiving waters. To mitigate the impacts of urban and agricultural runoff, a variety of stormwater control measures (SCMs) are implemented. Despite the importance of the Coastal Plain on water quality and quantity, few studies are available that focus on prediction of nutrient and sediment runoff loads from Coastal Plain watersheds. The overall goals of my dissertation are to assess the effect of urban and agricultural watershed on coastal waters through monitoring and modeling, and to characterize treatment performance of SCMs. These goals are addressed in four independent studies. First, we developed the Storm Water Management Model (SWMM) and the Hydrologic Simulation Program-Fortran (HSPF) models for an urbanized watershed to compared the ability of these two models at simulating streamflow, peak flow, and baseflow. Three separate monitoring and modeling programs were conducted on: 1) six urban land uses (i.e. commercial, industrial, low density residential, high density residential, transportation, and open space); 2) container nursey; and 3) a Coastal Plain retention pond. This study provides methods for estimating watershed pollutant loads. This is a key missing link in implementing watershed improvement strategies and selecting the most appropriate urban BMPs at the local scale. Results of these projects will help urban planners, urban decision makers and ecological experts for long-term sustainable management of urbanized and agricultural watersheds. / Doctor of Philosophy / Urban and agricultural runoff is a major source of sediment, nitrogen (N) and phosphorus (P) loading to receiving waters. When in excess, these pollutants degrade water quality and threaten aquatic ecosystems. Coastal waters in the southeastern U.S. are vulnerable to human impacts due to the proximity to urban an agricultural landuse. To mitigate the impacts of urban and agricultural runoff, a variety of stormwater control measures (SCMs) are implemented. The overall goals of my dissertation are to assess the effect of urban and agricultural watershed on coastal waters through monitoring and modeling, and to characterize treatment performance of SCMs. These goals are addressed in four independent studies. First, we developed two watershed models the Storm Water Management Model (SWMM) and the Hydrologic Simulation Program-Fortran (HSPF) to simulate streamflow, peak flow, and baseflow within an urbanized watershed. Three separate monitoring programs were conducted on: (1) urban land uses (i.e. commercial, industrial, low density residential, high density residential, transportation, and open space); (2) container nursey; and (3) a Coastal Plain retention pond. These studies provided methods for estimating watershed pollutant loads. Results of these projects will help urban planners and ecological experts for long-term sustainable management of urbanized and agricultural watersheds.

My thesis is a human intervention into the tranquil and natural environment of Pandapas Pond and the Jefferson National Forest. Although the form of the intervention embraces the landscape and natural land formations, its purpose is to take the visitor along a path that translates the experience from one of participation to that of observation of the parkâ s surroundings. This is both an investigation of an architectural integration with the site and a partial separation of the inhabiter from his/her natural surroundings. / Master of Architecture