Characterization of semi-permeable films promotes the systematic selection of membranes and process design. When acquiring the diffusive and sorption properties of gas transport in non-porous membranes, the time lag method is considered the conventional method of characterization. The time lag method involves monitoring the transient accumulation of species due to permeation on a fixed volume present in a downstream reservoir. In the thesis at hand, an alternative approach to the time lag technique is proposed, termed as the short cut method. The short cut method appoints the use of a two reservoir system, where the species decay in the upstream face of the membrane is monitored, in combination with the accumulation on the downstream end. The early and short time determination of membrane properties is done by monitoring the inflow and outflow flux profiles, including their respective analytical formulas. The newly proposed method was revealed to have estimated the properties at 1/10 the required time it takes for the classical time lag method, which also includes a better abidance to the required boundary conditions. A novel design of the upstream reservoir, consisting of a reference and working volume, is revealed, which includes instructional use, and the mechanics involved with its operation. Transient pressure decay profiles are successfully obtained when the reference and working volumes consisted of only tubing. However when tanks were included in the volumes, large errors in the decay were observed, in particular due to a non-instantaneous equilibration of the pressure during the start up. This hypothesis was further re-enforced by examining different upstream tank-based configurations. iii In the end, a validated numerical model was constructed for the purpose of simulating the two reservoir gas permeation system. A modified form of the finite differences scheme is utilized, in order to account for a concentration-dependent diffusivity of penetrants within the membrane. Permeation behavior in a composite membrane system was disclosed, which provided a new perspective in analyzing the errors associated with the practical aspect of the system.

Characterization of semi-permeable films promotes the systematic selection of membranes and process design. When acquiring the diffusive and sorption properties of gas transport in non-porous membranes, the time lag method is considered the conventional method of characterization. The time lag method involves monitoring the transient accumulation of species due to permeation on a fixed volume present in a downstream reservoir. In the thesis at hand, an alternative approach to the time lag technique is proposed, termed as the short cut method. The short cut method appoints the use of a two reservoir system, where the species decay in the upstream face of the membrane is monitored, in combination with the accumulation on the downstream end. The early and short time determination of membrane properties is done by monitoring the inflow and outflow flux profiles, including their respective analytical formulas. The newly proposed method was revealed to have estimated the properties at 1/10 the required time it takes for the classical time lag method, which also includes a better abidance to the required boundary conditions. A novel design of the upstream reservoir, consisting of a reference and working volume, is revealed, which includes instructional use, and the mechanics involved with its operation. Transient pressure decay profiles are successfully obtained when the reference and working volumes consisted of only tubing. However when tanks were included in the volumes, large errors in the decay were observed, in particular due to a non-instantaneous equilibration of the pressure during the start up. This hypothesis was further re-enforced by examining different upstream tank-based configurations. iii In the end, a validated numerical model was constructed for the purpose of simulating the two reservoir gas permeation system. A modified form of the finite differences scheme is utilized, in order to account for a concentration-dependent diffusivity of penetrants within the membrane. Permeation behavior in a composite membrane system was disclosed, which provided a new perspective in analyzing the errors associated with the practical aspect of the system.

Characterization of semi-permeable films promotes the systematic selection of membranes and process design. When acquiring the diffusive and sorption properties of gas transport in non-porous membranes, the time lag method is considered the conventional method of characterization. The time lag method involves monitoring the transient accumulation of species due to permeation on a fixed volume present in a downstream reservoir. In the thesis at hand, an alternative approach to the time lag technique is proposed, termed as the short cut method. The short cut method appoints the use of a two reservoir system, where the species decay in the upstream face of the membrane is monitored, in combination with the accumulation on the downstream end. The early and short time determination of membrane properties is done by monitoring the inflow and outflow flux profiles, including their respective analytical formulas. The newly proposed method was revealed to have estimated the properties at 1/10 the required time it takes for the classical time lag method, which also includes a better abidance to the required boundary conditions. A novel design of the upstream reservoir, consisting of a reference and working volume, is revealed, which includes instructional use, and the mechanics involved with its operation. Transient pressure decay profiles are successfully obtained when the reference and working volumes consisted of only tubing. However when tanks were included in the volumes, large errors in the decay were observed, in particular due to a non-instantaneous equilibration of the pressure during the start up. This hypothesis was further re-enforced by examining different upstream tank-based configurations. iii In the end, a validated numerical model was constructed for the purpose of simulating the two reservoir gas permeation system. A modified form of the finite differences scheme is utilized, in order to account for a concentration-dependent diffusivity of penetrants within the membrane. Permeation behavior in a composite membrane system was disclosed, which provided a new perspective in analyzing the errors associated with the practical aspect of the system.

Characterization of semi-permeable films promotes the systematic selection of membranes and process design. When acquiring the diffusive and sorption properties of gas transport in non-porous membranes, the time lag method is considered the conventional method of characterization. The time lag method involves monitoring the transient accumulation of species due to permeation on a fixed volume present in a downstream reservoir. In the thesis at hand, an alternative approach to the time lag technique is proposed, termed as the short cut method. The short cut method appoints the use of a two reservoir system, where the species decay in the upstream face of the membrane is monitored, in combination with the accumulation on the downstream end. The early and short time determination of membrane properties is done by monitoring the inflow and outflow flux profiles, including their respective analytical formulas. The newly proposed method was revealed to have estimated the properties at 1/10 the required time it takes for the classical time lag method, which also includes a better abidance to the required boundary conditions. A novel design of the upstream reservoir, consisting of a reference and working volume, is revealed, which includes instructional use, and the mechanics involved with its operation. Transient pressure decay profiles are successfully obtained when the reference and working volumes consisted of only tubing. However when tanks were included in the volumes, large errors in the decay were observed, in particular due to a non-instantaneous equilibration of the pressure during the start up. This hypothesis was further re-enforced by examining different upstream tank-based configurations. iii In the end, a validated numerical model was constructed for the purpose of simulating the two reservoir gas permeation system. A modified form of the finite differences scheme is utilized, in order to account for a concentration-dependent diffusivity of penetrants within the membrane. Permeation behavior in a composite membrane system was disclosed, which provided a new perspective in analyzing the errors associated with the practical aspect of the system.

Background: One part of manufacturing a Plate Heat Exchanger (PHE) is to leak test them before delivery. Today, helium is used extensively in leak testing. How-ever, it is unsustainable to use helium in leak testing, because of its non-renewability and therefore becoming more and more expensive. Also, this technology is relatively complex. At the same, PHEs are rising in demand due to lack of energy resources in Europe. Therefore, possibilities emerged for using air based leak testing technologies in upcoming test lines and that is why an evaluation needs to be done to find the most suitable technology. Objectives: The objective of this master’s thesis is to evaluate and identify the most suitable leak testing technology for validating the watertightness requirement of 10−3 mbar·l/s at 1 bar pressure difference. There is a scientific gap in comparing how different air based leak testing technologies perform with different volumes of the test vessels. This thesis will identify the most suitable air based leak testing technology by evaluating three technologies: Pressure Decay, Differential Pressure Decay and Vacuum Decay. With the main focus on how different volumes impacts the performance of each technology. Lastly, this study aims to determine an optimal test pressure that achieves the shortest cycle time for the selected test technology. Choosing the most suitable test technologies will result in fewer production break-downs and interruptions. Additional, being able to phase out helium in leak testing. Methods: The workflow for evaluating the different leak testing technologies began with the implementation and installation of each test setup and ensuring the reliability of the gathered data. After verifying the absence of leakage in the system, a simulated leak was calibrated to match the requirement’s leak rate. Four test vessels with original volumes of 0.10, 0.45, 1.66 and 2.50 l were utilized. Various tests were then performed to answer the research questions, including measurements of leak rate at different pressures, analysis of outgassing characteristics, and determination of cycle time. Finally, by utilizing concept scoring, the most suitable leak testing technology was identified with respect to the volume. Results: The exhibited results in this thesis manifest how the different leak testing technologies perform depending on the volume. The relationship between leak rates and overpressures was obtained, which was then utilized to derive the theoretical detection time. The cycle time and accuracy were determined across various volumes. According to concept scoring, Pressure Decay was deemed the most suitable leak testing technology in terms of six different criteria.   Conclusions: All three technologies were able to determine a leak rate corresponding to the watertightness requirement. From the evaluation, Pressure Decay was the most suitable technology to use across the majority of the volumes, with an accuracy below 15%. The test cycle times were optimizable by selecting an optimum testing pressure.  Therefore, being able to replace the helium leak testing in future test lines. / Bakgrund: En del i processen av att producera värmeväxlare är att de ska genomgå en täthetskontroll innan de levereras till kunden. I dagsläget används helium till största del för att göra täthetskontroller. Däremot är det inte hållbart att bruka helium för täthetskontroller, då det inte är förnyelsebart. Därför blir allt dyrare samtidigt som teknologin som används är komplex. Samtidigt har efterfrågan på värmeväxlare ökat markant till följd av brist på energiresurser i Europa. Som ett resultat av detta uppkom möjligheten att använda luftbaserade tätkontrolls teknologier i framtida testbanor och därför behövs en utvärdering göras av vilken metod som är lämpligast att använda. Syfte: Syftet med arbetet var att utvärdera och identifiera den mest lämpliga test-teknologin för att validera att vattentätskravet uppfylls. Det finns idag ett vetenskapligt gap på hur olika luftbaserade testteknologier presterar beroende på vilken volym som testas. Denna studie identifierade den mest lämpliga luftbaserade tätkontorllstekniken genom att utvärdera följande tre tekniker: Pressure Decay, Differential Pressure Decay och Vacuum Decay. Huvudfocus var på hur olika volymer påverkar tätkontrollens prestanda. Slutligen bestämms det optimala testtrycket som ger den lägsta cykeltiden för den valda testteknologin. Att välja den mest lämpliga test-tekniken kommer resultera i färre haverier och avbrott i produktionslinjen, samt ge möjligheten att byta ut helium som spårgas för täthetskontollerna. Metod: Arbetsflödet för att utvärdera de olika teknologierna för täthetskontroller började med att implementera och installera varje testuppställning och säkerställa att datan var trovärdig. Efter att ha verifierat att inga läckor fanns i systemen,kalibrerades en simulerad läcka för att matcha vattentätskravet läckhastighet. Fyra testobjekt användes med volymerna, 0.10, 0.45, 1.66 och 2.50 l. Olika tester ut-fördes sedan för att svara på forskningsfrågorna, samt gjordes en mätning av läck-hastigheten vid olika övertryck, analys av utgasningskarakteristiken och cykeltiden bestämdes. Slutligen, genom att använda concept scoring identifierades den mest lämpliga teknologin för täthetskontroller beroende på vilken volym som testas. Resultat: Resultatet i detta examensarbete visar hur olika testteknologier presterar beroende på volym. Relationen mellan läckhastighet och övertryck bestämdes och an-vändes för att härleda den teoretiska detektionstiden. Cykeltiden och noggrannheten bestämdes för olika volymer. Utifrån concept scoring var Pressure Decay den mest lämpliga testteknologin utifrån sex olika kriterier.   Slutsatser: Alla tre testteknologierna kunde hitta en läcka motsvarande vattentätskravet. Utifrån utvärderingen var Pressure Decay den mest lämpliga testteknologin för majoriteten av volymerna med en noggrannhet under 15%. Cykeltiden var optimerbar genom att välja det optimala testtrycket. Därför kan Pressure Decay användas som en ersättare för helium vid tätkontroller i framtida testbanor.

In the presented paper, the applicability of pressure-decay methods to determine the diffusivities of gases in hydraulic fluids is analysed. First, the method is described in detail and compared to other measurement methods. Secondly, the thermodynamics and the mass transfer process of the system are studied. This results in four different thermodynamic models of the gaseous phase in combination with two diffusion models. Thirdly, the influence of the models on the pressure-decay method is evaluated computationally by examining the diffusion process of air in water as all system parameters are available from literature. It is shown that ordinary pressure-decay methods are not applicable to gas mixtures like air and therefore a new method for calculating the diffusivities is suggested.