There are many studies about how the addition of lime and rice husk ash (RHA) gives the soil a better mechanical behavior, particularly on clayey soils, where usually fine particles reach more than 75%. However, the soils with a small presence of fine particles (59-60%) do not have much research. This analysis evaluates the influence that RHA has on this kind of soil stabilized with 3% of lime. After the initial mix of soil-lime, CBR increased 11.2 times its initial value; within the addition of the ash, the CBR averaged between 45-50% up until 28% of RHA was added, where the results decreased considerably. Soil workability improved and the specimens with more ash resulted in a more granular material, with a group index value 0 following the AASHTO standards. The greatest CBR record was obtained with the specimen of 16% RHA, 3% lime and soil, reaching a 51.3% CBR, 1.58g/cm3 of MDD and 16.5% of OMC. Yet, it only showed a 1.55% more resistance than the lime-soil specimen. The CBR with more presence of RHA tends to decrease its value, therefore for silica-rich clayey soils, the addition of lime by itself should be enough for an adequate performance.

Em cerâmicas refratárias, a formação de mulita (3Al2O3.2SiO2) \"in situ\", a partir da reação entre alumina e sílicas amorfas sintéticas (SAS´s) aumenta a resistência ao choque térmico e à corrosão destes materiais. Essa reação é fortemente afetada pelas características físico-químicas e morfológicas das SAS´s. Este estudo comparou a formação de mulita\"in situ\" a partir da combinação de alumina calcinada ultrafina (α-Al2O3) com quatro tipos de SAS´s obtidas por diferentes processos de sínteses (precipitação de silicato de sódio, extração da cinza da casca do arroz, extração da casca do arroz e precipitação de vapor de silício elementar) e com características variadas. Inicialmente, esses quatros tipos de SASs foram caracterizados em relação às suas propriedades físico-químicas, microestrutura e morfologia. Em seguida, após mistura com alumina, compactação e sinterização (1100-1500°C) assistida por dilatometria, as amostras foram caracterizadas em relação à sua porosidade, densidade, módulo elástico, resistência à flexão, microestrutura e fases presentes. Verificou-se que as propriedades das estruturas finais foram fortemente afetadas pela mudança de SAS´s. De forma geral e em comparação com as amostras de referência (100% alumina ou 100% mulita pré-formada por eletrofusão), houve significativo ganho de rigidez e tensão de ruptura em menores temperaturas e grande redução de porosidade final. Valores de tensão de ruptura e módulo elástico da ordem de 114 MPa e 308 GPa foram obtidos, respectivamente. A correlação das propriedades obtidas com as características prévias das sílicas mostrou que a área superficial e o volume de poros internos das partículas afetaram mais o ganho de rigidez e redução de porosidade do que o tamanho médio das partículas. Além desse aspecto, a presença de fases de baixo ponto de fusão (em especial nas amostras com microssílica) também contribuiu fortemente para densificação. / In refractories ceramics, the formation of mullite (3Al2O3.2SiO2) \"in situ\", from the reaction between alumina and synthetic amorphous silica (SAS\'s) increases the resistance to thermal shock and corrosion of these materials. This reaction is strongly affected by the physic-chemical and morphological features of SAS\'s. This study compared the mullite formation \"in situ\" from the combination of calcined alumina with four kinds of ultrafine\'s SASs obtained by various synthesis processes (precipitation of sodium silicate, from rice husk, extraction of rice husk ash and steam precipitation of silicon metal) and with varying characteristics. Initially, these four kinds of SAS´s were characterized in relation to their physicochemical properties, microstructure and morphology. After compaction and sintering (1100-1500°C) assisted by dilatometry, samples were characterized regarding their porosity, density, elastic modulus, flexural strength, microstructure and phases present. The properties of the final structure were strongly affected by the change of SAS\'s. In general, and in comparison with reference samples (100% alumina or 100% mullite preform for electrofusion), a significant stiffness gain of strength at low temperature and lower final porosity, respectively. Value of rupture and elastic modulus of the order of 114 MPa and 308 GPa were obtained. The correlation of properties obtained with the prior characterization of SAS´s showed that surface area and the volume of the internal poros of the particles affect the gain more stiffness and lower porosity than the average particle size. Aparts from this, the presence of phases of low melting point (especially in samples with microssilica) also contributed strongly to densification.

Made available in DSpace on 2014-06-11T19:25:21Z (GMT). No. of bitstreams: 0 Previous issue date: 2009-04-13Bitstream added on 2014-06-13T19:12:01Z : No. of bitstreams: 1 silva_ej_me_ilha.pdf: 3783689 bytes, checksum: 33016836c826eae75c76a0b521c81b78 (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / A presente pesquisa contribui para a utilização de cinza de casca de arroz (CCA) na construção civil abordando dois aspectos importantes ainda em discussão na literatura. O primeiro aspecto compreende uma análise da influência que a forma de plantio, clima, solo, cultivares e fonte/quantidade de fertilizantes à base de nitrogênio, utilizados na cultura do arroz, exercem na composição química e nas propriedades cristalográficas da CCA. O segundo aspecto foi aplicar em pastas, argamassas e concretos de alto desempenho uma CCA com baixo teor de carbono, de elevado caráter pozolânico, na condição natural (sem moagem), produzida de uma maneira simples e sem controle de temperatura. De acordo com os resultados obtidos neste trabalho, verifica-se a importância de efetuar ensaios rotineiros de análises químicas e de Difração de Raio-X para manter o controle de qualidade das CCAs produzidas, pois em situação de produção de CCA em larga escala, poderiam ser utilizadas cascas de diferentes origens. Neste trabalho, também ficou comprovada a viabilidade técnica e científica do método de produção de CCA utilizado. O método produz CCA que, dependendo da forma de amassamento dos compósitos, pode dispensar o emprego de moinhos para aumentar a finura e/ou reatividade de CCAs. / This research contributes to the use of rice husk ash (RHA) in the civil building covering two important aspects that still under discussion in the literature. The first one includes an analysis of the influence that the form of planting, climate, soil, rice and source/amount of nitrogen-based fertilizers used in rice cultivation in performing crystallographic properties and chemical composition of the rice husk ash. The second one was to aplicate to the pastes, mortar and concrete of high performance a RHA with low carbon, high pozzolanic character, in the natural physical state (without grinding), produced in a simple way and without control of temperature. According to the results obtained in this research, it is important to do routine testing of chemical analysis and X-ray Diffraction to keep quality control of RHAs produced, because at industrial production in large scale it can be used husks of different origins. This research was also demonstrated the feasibility technical and scientific method of production of RHA used. The method produces RHA that depending on the form of production of the composite may eliminate the use of grinders to increase the fineness and/or reactivity of RHAs.

Em cerâmicas refratárias, a formação de mulita (3Al2O3.2SiO2) \"in situ\", a partir da reação entre alumina e sílicas amorfas sintéticas (SAS´s) aumenta a resistência ao choque térmico e à corrosão destes materiais. Essa reação é fortemente afetada pelas características físico-químicas e morfológicas das SAS´s. Este estudo comparou a formação de mulita\"in situ\" a partir da combinação de alumina calcinada ultrafina (α-Al2O3) com quatro tipos de SAS´s obtidas por diferentes processos de sínteses (precipitação de silicato de sódio, extração da cinza da casca do arroz, extração da casca do arroz e precipitação de vapor de silício elementar) e com características variadas. Inicialmente, esses quatros tipos de SASs foram caracterizados em relação às suas propriedades físico-químicas, microestrutura e morfologia. Em seguida, após mistura com alumina, compactação e sinterização (1100-1500°C) assistida por dilatometria, as amostras foram caracterizadas em relação à sua porosidade, densidade, módulo elástico, resistência à flexão, microestrutura e fases presentes. Verificou-se que as propriedades das estruturas finais foram fortemente afetadas pela mudança de SAS´s. De forma geral e em comparação com as amostras de referência (100% alumina ou 100% mulita pré-formada por eletrofusão), houve significativo ganho de rigidez e tensão de ruptura em menores temperaturas e grande redução de porosidade final. Valores de tensão de ruptura e módulo elástico da ordem de 114 MPa e 308 GPa foram obtidos, respectivamente. A correlação das propriedades obtidas com as características prévias das sílicas mostrou que a área superficial e o volume de poros internos das partículas afetaram mais o ganho de rigidez e redução de porosidade do que o tamanho médio das partículas. Além desse aspecto, a presença de fases de baixo ponto de fusão (em especial nas amostras com microssílica) também contribuiu fortemente para densificação. / In refractories ceramics, the formation of mullite (3Al2O3.2SiO2) \"in situ\", from the reaction between alumina and synthetic amorphous silica (SAS\'s) increases the resistance to thermal shock and corrosion of these materials. This reaction is strongly affected by the physic-chemical and morphological features of SAS\'s. This study compared the mullite formation \"in situ\" from the combination of calcined alumina with four kinds of ultrafine\'s SASs obtained by various synthesis processes (precipitation of sodium silicate, from rice husk, extraction of rice husk ash and steam precipitation of silicon metal) and with varying characteristics. Initially, these four kinds of SAS´s were characterized in relation to their physicochemical properties, microstructure and morphology. After compaction and sintering (1100-1500°C) assisted by dilatometry, samples were characterized regarding their porosity, density, elastic modulus, flexural strength, microstructure and phases present. The properties of the final structure were strongly affected by the change of SAS\'s. In general, and in comparison with reference samples (100% alumina or 100% mullite preform for electrofusion), a significant stiffness gain of strength at low temperature and lower final porosity, respectively. Value of rupture and elastic modulus of the order of 114 MPa and 308 GPa were obtained. The correlation of properties obtained with the prior characterization of SAS´s showed that surface area and the volume of the internal poros of the particles affect the gain more stiffness and lower porosity than the average particle size. Aparts from this, the presence of phases of low melting point (especially in samples with microssilica) also contributed strongly to densification.

The work presented in this thesis deals with the development of self-consolidating high performance concrete (SCHPC) incorporating rice husk ash (RHA) as a supplementary cementing material. Various SCHPCs were produced using the water-binder (W/B) ratios of 0.30, 0.35, 0.40 and 0.50, and RHA content in the range of 0 to 30% of cement by weight. In addition, a number of pastes and mortars formulated from the concretes were prepared and tested for the filling ability. The paste and mortar filling abilities were tested with respect to flow time and flow spread, respectively, at various dosages of high-range water reducer (HRWR). Also, the mortars were tested for the air content at various dosages of air-entraining admixture (AEA). It was observed that the flow time of the pastes increased with lower W/B ratio and higher RHA content, whereas the flow spread of the mortars decreased with higher W/B ratio and greater RHA content. Both paste and mortar filling abilities increased with higher HRWR dosages. In addition, the air content of the mortars decreased with lower W/B ratio and higher RHA content for given AEA dosages. The fresh SCHPCs were tested for filling ability, passing ability, air-void stability, segregation resistance, unit weight and air content. The filling ability was determined with respect to slump and slump flow, inverted slump cone flow time and spread, and orimet flow time and spread. The passing ability was measured with regard to slump and slump flow with J-ring, inverted slump cone flow spread with J-ring, and orimet flow spread with J-ring. The air-void stability in several fresh SCHPC mixtures was investigated with respect to re-mixing of concrete and subsequent measurement of air content at different test stages. The test results obtained for the fresh properties showed that the inverted slump cone and orimet flow times increased with lower W/B ratio and greater RHA content. In addition, the slump flow, inverted slump cone flow spread, and orimet flow spread with and without J-ring increased considerably with lower W/B ratio and greater RHA content. However, the increases in slump with and without J-ring at lower W/B ratio and higher RHA content were not significant. The unit weight of concrete slightly decreased with higher W/B ratio and greater RHA content, and with higher air content. Achieving the target air content required greater AEA dosages for lower W/B ratio and higher RHA content. However, the presence of RHA had no adverse effect on the air-void stability of concrete. The segregation resistance of various SCHPCs was investigated by visual inspection of concrete in mixer pan, and during and after different flow tests. Slight bleeding and a thick layer of paste were noticed in mixer pan for several concretes. The dynamic segregation in the form of discontinuity or blockage of flow did not occur during the orimet and inverted slump cone flow tests for any concrete. No aggregate pile appeared in the slump flow, and orimet and inverted slump cone flow spreads of any concrete. But minor to severe mortar halos were noticed in the periphery of the flow spread of several concretes, particularly in the presence of high RHA content. The results of visual inspection suggest that both lower W/B ratio and greater RHA content improved the dynamic segregation resistance of concrete. In contrast, the higher RHA content resulted in a lower static segregation resistance, which was overcome in the presence of viscosity-enhancing admixture (VEA). The static segregation resistance of several SCHPCs was quantitatively determined by sieve and column apparatus. The segregation index given by the sieve increased with lower W/B ratio and higher RHA content, thus indicating a reduced static segregation resistance. In contrast, the segregation factor given by the column apparatus decreased with lower W/B ratio suggesting an increased static segregation resistance. However, the segregation factor increased with higher RHA content, and thus revealed a reduction in static segregation resistance. In the presence of VEA, both segregation index and segregation factor decreased significantly, indicating an improvement in the static segregation resistance of concrete. The hardened SCHPCs were tested for compressive strength, ultrasonic pulse velocity, water absorption, total porosity and electrical resistivity. Test results revealed that the compressive strength, ultrasonic pulse velocity and true electrical resistivity increased, whereas the water absorption and total porosity decreased with lower W/B ratio and higher RHA content. The entrained air-voids decreased the compressive strength, ultrasonic pulse velocity, water absorption and total porosity, but slightly increased the electrical resistivity of concrete. In general, the hardened properties indicated good durability of the concretes. The empirical models for the filling ability (slump flow) and compressive strength of SCHPC were derived and verified with test data from this study and other data taken from the literature. The slump flow and compressive strength computed from the models were coherent with the measured values. Both filling ability and strength models were useful to develop a mixture design method for SCHPC with and without RHA.

The work presented in this thesis deals with the development of self-consolidating high performance concrete (SCHPC) incorporating rice husk ash (RHA) as a supplementary cementing material. Various SCHPCs were produced using the water-binder (W/B) ratios of 0.30, 0.35, 0.40 and 0.50, and RHA content in the range of 0 to 30% of cement by weight. In addition, a number of pastes and mortars formulated from the concretes were prepared and tested for the filling ability. The paste and mortar filling abilities were tested with respect to flow time and flow spread, respectively, at various dosages of high-range water reducer (HRWR). Also, the mortars were tested for the air content at various dosages of air-entraining admixture (AEA). It was observed that the flow time of the pastes increased with lower W/B ratio and higher RHA content, whereas the flow spread of the mortars decreased with higher W/B ratio and greater RHA content. Both paste and mortar filling abilities increased with higher HRWR dosages. In addition, the air content of the mortars decreased with lower W/B ratio and higher RHA content for given AEA dosages. The fresh SCHPCs were tested for filling ability, passing ability, air-void stability, segregation resistance, unit weight and air content. The filling ability was determined with respect to slump and slump flow, inverted slump cone flow time and spread, and orimet flow time and spread. The passing ability was measured with regard to slump and slump flow with J-ring, inverted slump cone flow spread with J-ring, and orimet flow spread with J-ring. The air-void stability in several fresh SCHPC mixtures was investigated with respect to re-mixing of concrete and subsequent measurement of air content at different test stages. The test results obtained for the fresh properties showed that the inverted slump cone and orimet flow times increased with lower W/B ratio and greater RHA content. In addition, the slump flow, inverted slump cone flow spread, and orimet flow spread with and without J-ring increased considerably with lower W/B ratio and greater RHA content. However, the increases in slump with and without J-ring at lower W/B ratio and higher RHA content were not significant. The unit weight of concrete slightly decreased with higher W/B ratio and greater RHA content, and with higher air content. Achieving the target air content required greater AEA dosages for lower W/B ratio and higher RHA content. However, the presence of RHA had no adverse effect on the air-void stability of concrete. The segregation resistance of various SCHPCs was investigated by visual inspection of concrete in mixer pan, and during and after different flow tests. Slight bleeding and a thick layer of paste were noticed in mixer pan for several concretes. The dynamic segregation in the form of discontinuity or blockage of flow did not occur during the orimet and inverted slump cone flow tests for any concrete. No aggregate pile appeared in the slump flow, and orimet and inverted slump cone flow spreads of any concrete. But minor to severe mortar halos were noticed in the periphery of the flow spread of several concretes, particularly in the presence of high RHA content. The results of visual inspection suggest that both lower W/B ratio and greater RHA content improved the dynamic segregation resistance of concrete. In contrast, the higher RHA content resulted in a lower static segregation resistance, which was overcome in the presence of viscosity-enhancing admixture (VEA). The static segregation resistance of several SCHPCs was quantitatively determined by sieve and column apparatus. The segregation index given by the sieve increased with lower W/B ratio and higher RHA content, thus indicating a reduced static segregation resistance. In contrast, the segregation factor given by the column apparatus decreased with lower W/B ratio suggesting an increased static segregation resistance. However, the segregation factor increased with higher RHA content, and thus revealed a reduction in static segregation resistance. In the presence of VEA, both segregation index and segregation factor decreased significantly, indicating an improvement in the static segregation resistance of concrete. The hardened SCHPCs were tested for compressive strength, ultrasonic pulse velocity, water absorption, total porosity and electrical resistivity. Test results revealed that the compressive strength, ultrasonic pulse velocity and true electrical resistivity increased, whereas the water absorption and total porosity decreased with lower W/B ratio and higher RHA content. The entrained air-voids decreased the compressive strength, ultrasonic pulse velocity, water absorption and total porosity, but slightly increased the electrical resistivity of concrete. In general, the hardened properties indicated good durability of the concretes. The empirical models for the filling ability (slump flow) and compressive strength of SCHPC were derived and verified with test data from this study and other data taken from the literature. The slump flow and compressive strength computed from the models were coherent with the measured values. Both filling ability and strength models were useful to develop a mixture design method for SCHPC with and without RHA.

Thailand is one of the largest rice producing nations in the world. Moreover, there is a trend for Thai rice exports to increase. This could imply that if the trend continues, there will be an increased quantity of rice husk in the future. Rice husk is a co-product of rice products generated in the rice milling process, accounting for about 23 percent of the total paddy weight. To make use of this large quantity of rice husk, the husk has traditionally been used as an energy source in the rice mills themselves. More recently, the Thai government has promoted the use of biomass to substitute for fossil fuel consumption and to reduce the environmental impacts caused by using fossil fuels. Therefore, rice husk, which is one of the main sources of biomass in Thailand, has already been used on a commercial scale. However, the environmental impacts associated with different rice husk applications have not yet been widely investigated in the Thai context. While there is a need to find ways of dealing with rice husk disposal, it is also important to ensure that this husk is used in ways that harm the environment least. This research aims to identify the most environmentally friendly use of rice husk for Thailand. To achieve this, the research is divided into three main stages; identification of main current and potential uses of rice husk in Thailand; data collection; and data analysis using Life Cycle Analysis approach. A range of methods such as literature review, questionnaires with rice mill owners, and interviews with industry personnel, were used to help in identifying the current and potential uses of rice husk. The major current and potential rice husk uses chosen to be examined in this research are those uses of rice husk in electricity generation, in cement manufacture and in cellulosic ethanol production. The second stage is to collect detailed data about the processes of the selected rice husk uses to be examined. This was undertaken by literature review, questionnaires and interviews with involved industry personnel. The last stage is to analyse the data collated. Life Cycle Assessment (LCA) approach and the L CA software package SimaPro (version 7.1.6) were used to assess the environmental impacts of the selected rice husk uses. Results from the LCA are reviewed in the context of critical policy issues, including the Thai government biomass policies; the capacity of the production process of rice husk use options; and the infrastructure availability and practicality of the rice husk use options. Based on the goal and scope of the study, the data available for this study and the review of the issues just mentioned, it is concluded that, in the short term, the most practical environmentally friendly use of rice husk across the three uses investigated is the use of rice husk in electricity generation. However, with expected oil shortages in the future, rice husk should also be considered for use in cellulosic ethanol production, as this option helps to save some amount of petrol.

The continuous population increase in recent years requires a greater number of households to be built quickly, with good materials and produced under quality standards that guarantee their manufacturing process. The prefabricated concrete, produced and supplied by concrete plants, is poured into the different structural elements, the mezzanine slabs being the most careful surfaces in the appearance of fissures; because being horizontal and having larger dimensions, the dimensional changes in the concrete appear more frequently due to the rapid loss of water from the surface of the concrete before setting; which generates superior stresses to the resistant capacity of the concrete at early ages, which affect the durability and reduce the resistance of the structures, causing greater economic expenses in maintenance and repairs. In the present investigation, 5%, 10% and 15% of rice husk ash was used as a replacement for cement and 900g/m3 of polypropylene fiber; The results indicate that as the percentage of rice husk ash increases, there is a reduction in the slump and the crack fissures, and that the resistance to compression and flexion decreases, with respect to the concrete pattern.

This document studies the stabilization of the soil used as a subgrade, by adding locally available materials such as rice husk ash (RHA) and sugarcane bagasse ash (SCBA). These aggregates were added to the soil in substitution by weight between 5%, 7.5% and 10%. By adding these, the expansiveness is reduced while the maximum dry density increases, in addition the tendency of CBR is increasing and then tends to decrease proportionally to the addition of the aforementioned aggregates. This indicates a peak in CBR and expandability. The best result obtained from CBR was 33.75% with the 5% replacement mixtures.

The construction of road works in the world has always been a challenge for engineering, especially in areas where the conditions and types of soil are not adequate for the execution of this type of projects. The present investigation has as main objective to determine the influence that has the rice husk ash (RHA) to stabilize the subgrade layer of a pavement, composed of a low resistance clayey soil. RHA is a waste and pollutant material for the environment; therefore that its use can be considered as an economic and ecological alternative. Thus, several tests were carried out where it proved the value of CBR increased from 4.30% to 20.70%, by adding a 20% RHA dosage, achieving its optimum value to be considered a very good subgrade. In this way, it is possible to affirm that the addition of RHA improves the geotechnical properties of the soil.