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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
211

Syntheses, spectroscopy and photophysics of ruthenium(II) carbene complexes and diimine complexes with functionalized ligands formolecular recognition and organized assembly

Chu, Wai-kin, 朱煒堅 January 2000 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
212

Studies on epoxidation of olefins by IN SITU generated N-sulfonyloxaziridine and ruthenium catalyzed oxidative cleavage ofolefins

Zhang, Chi, 張弛 January 2001 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
213

Ruthenium-catalyzed carbon-nitrogen bond formations

Liang, Jianglin., 梁江林. January 2003 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
214

Structure and properties of self-assembled coordination compounds: homoleptic d10-metal aryl/alkylacetylides, ruthenium n-heterocyclesand picolinates

Ng, Fei-yeung., 吳飛洋. January 2006 (has links)
published_or_final_version / abstract / Chemistry / Doctoral / Doctor of Philosophy
215

Asymmetric organic oxidation by chiral ruthenium complexes containing D2 and D4 symmetric porphyrinato ligands

Zhang, Rui, 張瑞 January 2000 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
216

Synthesis, characterization and reactivities of bis(imido)-ruthenium(vi) and -osmium(vi) porphyrins

區詩敏{272b21}, Au, Sze-man, Vanessa. January 1999 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
217

Syntheses, reactivities and biological activities of ruthenium azido, nitrido and nitrosyl complexes supported by tetradentate tertiaryamine ligands

Leung, Hiu-chi., 梁曉詞. January 2010 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
218

Studies in organodimetallic chemistry

Dennett, James N. L. January 2000 (has links)
No description available.
219

Exploring the Reactivity and Decomposition of Ruthenium Nitrosyl Complexes for the Production of Nitrogen Oxides

Hannon, Andrew Michael January 2012 (has links)
Nitric oxide (NO) has been shown to both suppress and promote tumor growth, depending in part on concentration. Exogenous delivery of NO may lead to tumor suppression. Recent studies have proposed ruthenium nitrosyl complexes as catalytic donors of NO in reductive environments. Catalytic donation can provide a long-term, elevated NO flux compared to single use donors. Site-specific delivery is desirable to reduce systemic side effects, such as lowering of blood pressure. Three new ruthenium nitrosyl complexes were synthesized to impart site-specificity through amide coupling to polymers, silica nanoparticles, iron oxide nanoparticles and antibodies. The catalytic activity of new and existing compounds was then assessed. However, upon one-electron reduction of ruthenium nitrosyl complexes, insignificant amounts of NO were detected, suggesting an alternative mechanism than that proposed in prior reports. The mechanism of [Ru(EDTA)NO]²⁻ decay was more thoroughly analyzed. Spectrophotometric decay of [Ru(EDTA)NO]²⁻ indicates that one or multiple nitrogen oxide species are released. Previous studies have suggested a disproportionation mechanism leading to the generation of more highly reduced species such as N₂ and NH₄⁺. Experiments were designed to analyze possible decomposition products such as [Ru(EDTA)NO]⁻ and [Ru(EDTA)H₂O]²⁻. A disproportionation mechanism was determined likely. Decomposition of [Ru(EDTA)NO]²⁻ was also observable following reductive nitrosylation of [Ru(EDTA)H₂O]⁻ in the presence of HNO. The decomposition product, [Ru(EDTA)H₂O]²⁻, was observed through the binding of pyrazine (pz) or dipyridine (bipy) and formation of [Ru(EDTA)pz]²⁻ or [Ru(EDTA)bipy]³⁻. Formation of [Ru(EDTA)bipy]³⁻ or [Ru(EDTA)pz]²⁻ via reductive nitrosylation of [Ru(EDTA)H₂O]⁻ also provides an indirect method of HNO detection that is selective from NO.
220

Synthesis and characterisation of new metallo phthalocyanines and sub-phthalocyanines

Mogay-Batalla, Carlos January 2001 (has links)
No description available.

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