Includes bibliography.

This study investigated the association between family socioeconomic status, family race/ethnicity, quality of services and the impact of those services on the family for families who had participated in a northeastern state's IDEA, Part C Early Intervention Program. Data for this study came from 1,108 families who responded to a survey distributed by the state's Early Intervention Program. The survey contained two Rasch-based measurement scales designed to yield measures of family perceptions of the quality of early intervention services they had received and the impact of those services on their family. Results of the study indicated that measures of quality of services were significantly and positively related to family outcomes. However, neither family race/ethnicity nor socioeconomic status was associated with quality of services. Results related to the strong association between quality of services and positive family outcomes are interpreted in light of previous research on the outcomes of family-centered care models. Results related to the parity of service quality across racial/ethnic and socioeconomic groups are interpreted in relation to two important characteristics of high-quality programs: cultural competency and service coordination.

Thesis (M.S.) -- University of Tennessee, Knoxville, 2006. / Title from title page screen (viewed on Feb. 5, 2007). Thesis advisor: Paris Lambdin. Vita. Includes bibliographical references.

Ph.D. / Electrical Engineering / Nanometer-scale devices have attracted great attention as the ultimate evolution of silicon integrated circuit technology. However, fabrication of nanometer-scale silicon based devices has met great difficulty because it places severe constraints on process technology. This is especially true for SiGe/Si heterostructures because they are particularly sensitive to strain relaxation and/or process induced defects. Recently developed Pulsed Laser Induced Epitaxy (PLIE) offers a promising approach for the fabrication of nanometer- scale SiGe/Si devices. It possesses the advantage of ultra-short time, low thermal budget and full compatibility with current silicon technology. The selective nature of the process allows epitaxial growth of high quality, localized SiGe layers in silicon. In this thesis, a process to fabricate SiGe nanowires in silicon using PLIE is described. In particular, Ge nanowires with a cross-section of ~6 x 60 nm² are first formed using a lift-off process on the silicon substrate with e-beam lithography, followed by a thin low-temperature oxide deposition. Defect-free SiGe nanowires with a cross-section of ~25 x 95 nm² are then produced by impinging the laser beam on the sample. We thus demonstrate PLIE is a suitable fabrication technique for SiGe/Si nanostructures. Fabrication of Ge nanowires is also studied using Focused Ion Beam (FIB) micromachining techniques. Based on the SiGe nanowire process, we propose two advanced device structures, a quantum wire MOSFET and a lateral SiGe Heterojunction Bipolar Transistor (HBT). MEDICI simulation of the lateral SiGe HBT demonstrates high performance of the device. In order to characterize the SiGe nanowires using cross-sectional transmission electron microscopy, an advanced versatile focused ion beam assisted sample preparation technique using a multi-layer stack scheme for localized surface structures is developed and described in this thesis.

Over the course of normal oil well operations, pipes used downhole in the oil and petroleum industry tend to accumulate a mineral deposit on their interior, which restricts the flow of oil. This deposit, termed scale, will eventually occlude the interior diameter of the pipe making removal from service and descaling a cost effective option. The pipes are sent to cleaning yards where they remain until descaling can be performed. This storage period can potentially create a health concern not only because of the external radiation exposure but also because of the radon gas emissions, both of which are due to the radioactive minerals contained in the scale. It was believed that the structure of the scale is formed tightly enough to prevent much of the radon from becoming airborne. The goal of this research was to determine the emanation fractions for the rattled scale samples from three formations. A high purity germanium detector was used to measure the activities of the parents and progeny of radon, and electret ion chambers were used to measure the concentration of radon emanated from the scale. The emanation fractions of between 4.9x10-5 and 1.08x10-3 for radon were a factor of approximately 100 smaller than previous research results. For thoron, the fractions were and 5.72x10-8 and 4.92x10-7 for thoron with no previous research to compare. However, information that pertains to the temperature dependence of emanation was included in this research and was not available for previous, similar research. Therefore, differences in the environment (e.g., temperature, humidity, etc.) in which the previous experiments were conducted, as well as differences in the scale formation types used, could account for the discrepancy. In addition, measuring the emanation fractions of the rattled scale was a method of determining whether surface to volume ratio dependence existed. After acquiring the emanation fractions, insufficient evidence of any surface to volume ratio dependence could be found.

This thesis reports on the procedure, results and analysis of four full scale fire tests that were performed at the University of Waterloo's Live Fire Research Facility. The purpose of these tests was to investigate the thermal characteristics of one room of the Burn House structure. Comparisons were made of Burn House experimental data to previous residential fire studies undertaken by researchers from the University of Waterloo. This analysis showed similarities in growth rate characteristics, illustrating that fire behaviour in the Burn House is typical of residential structure fire behaviour. The Burn House experimental data was also compared to predictions from a fire model, CFAST. Recommendations were made for future work in relation to further investigation of the fire characteristics of the Burn House.

The nematode Caenorhabditis elegans is a model organism for understanding sensory molecules of multicellular organisms. Ovulating hermaphrodites produce putative pheromone(s) that cause male attraction. Because pheromones are produced in such small quantities, adult conditioned-media from large-scale synchronous culture is necessary to analyze these pheromones. Current protocols for culture synchronization have volume constraints that limit large-scale synchronous cultures and current methodology for adult conditioned-media production is impractical. Modification of Tangential Flow Filtration (TFF) systems was investigated for use as a method to increase the volume limits of bleach egg harvest for C. elegans culture synchronization. Also, an adult retention device built within the culture vessel was investigated to optimize the environment for aseptic conditioned-media production from dense large-scale C. elegans cultures. During this investigation, we have shown that synchronous C. elegans cultures for adult conditioned-media production can be grown at scales larger than reported before, with potential for further scale up. Our growth methodologies have also yielded denser cultures than previously achieved at large scales. Since rapid bleach harvesting appears to be the bottleneck for large-scale production of synchronous C. elegans cultures, our approach of using modified TFF systems with mesh to retain C. elegans eggs increased the amount of eggs that could be bleach harvested at one time. Using this method we have been able to achieve up to 5x103 synchronous C. elegans per mL at a 50L scale. Since scale-up of TFF is straightforward, our results suggest that the technique reported here can easily be applied to larger scale systems for production of adult conditioned-media for C. elegans. Further, the adult retention device within the culture vessel can ensure that the whole process remains aseptic.

This thesis reports on the procedure, results and analysis of four full scale fire tests that were performed at the University of Waterloo's Live Fire Research Facility. The purpose of these tests was to investigate the thermal characteristics of one room of the Burn House structure. Comparisons were made of Burn House experimental data to previous residential fire studies undertaken by researchers from the University of Waterloo. This analysis showed similarities in growth rate characteristics, illustrating that fire behaviour in the Burn House is typical of residential structure fire behaviour. The Burn House experimental data was also compared to predictions from a fire model, CFAST. Recommendations were made for future work in relation to further investigation of the fire characteristics of the Burn House.

Over the course of normal oil well operations, pipes used downhole in the oil and petroleum industry tend to accumulate a mineral deposit on their interior, which restricts the flow of oil. This deposit, termed scale, will eventually occlude the interior diameter of the pipe making removal from service and descaling a cost effective option. The pipes are sent to cleaning yards where they remain until descaling can be performed. This storage period can potentially create a health concern not only because of the external radiation exposure but also because of the radon gas emissions, both of which are due to the radioactive minerals contained in the scale. It was believed that the structure of the scale is formed tightly enough to prevent much of the radon from becoming airborne. The goal of this research was to determine the emanation fractions for the rattled scale samples from three formations. A high purity germanium detector was used to measure the activities of the parents and progeny of radon, and electret ion chambers were used to measure the concentration of radon emanated from the scale. The emanation fractions of between 4.9x10-5 and 1.08x10-3 for radon were a factor of approximately 100 smaller than previous research results. For thoron, the fractions were and 5.72x10-8 and 4.92x10-7 for thoron with no previous research to compare. However, information that pertains to the temperature dependence of emanation was included in this research and was not available for previous, similar research. Therefore, differences in the environment (e.g., temperature, humidity, etc.) in which the previous experiments were conducted, as well as differences in the scale formation types used, could account for the discrepancy. In addition, measuring the emanation fractions of the rattled scale was a method of determining whether surface to volume ratio dependence existed. After acquiring the emanation fractions, insufficient evidence of any surface to volume ratio dependence could be found.

Physical and chemical heterogeneities cause the porous media transport parameters to vary with scale, and between these two types of heterogeneities geological heterogeneity is considered to be the most important source of scale-dependence of transport parameters. Subsurface processes associated with chemical alterations result in changing reservoir properties with interlinked spatial and temporal scale, and there is uncertainty in the evolution of those properties and the chemical processes. This dissertation provides a framework and procedures to quantify the spatiotemporal scaling characteristics of reservoir attributes and transport processes in heterogeneous media accounting for chemical alterations in the reservoir. Conventional flow scaling groups were used to assess their applicability in scaling of recovery and Mixing Zone Length (MZL) in presence of chemical reactivity and permeability heterogeneity through numerical simulations of CO₂ injection. It was found out that these scaling groups are not adequate enough to capture the scaling of recovery and transport parameters in the combined presence of chemical reactivity and physical heterogeneity. In this illustrative example, MZL was investigated as a function of spatial scale, temporal scale, multi-scale heterogeneity, and chemical reactivity; key conclusions are that 1) the scaling characteristics of MZL distinctly differ for low permeability and high permeability media, 2) heterogeneous media with spatial arrangements of both high and low permeability regions exhibit scaling characteristics of both high and low permeability media, 3) reactions affect scaling characteristics of MZL in heterogeneous media, 4) a simple rescaling can combine various MZL curves by merging them into a single MZL curve irrespective of the correlation length of heterogeneity, and 5) estimates of MZL (and consequently predictions of oil recovery) will fluctuate corresponding to displacements in a permeable medium whose lateral length is smaller than the correlation length of geological formation. We illustrate and extend the procedure of estimating Representative Elementary Volume (REV) to include temporal scale by coupling it with spatial scale. The current practice is to perform spatial averaging of attributes and account for residual variability by calibration and history matching. This results in poor predictions of future reservoir performance. The proposed semi-analytical technique to scale-up in both space and time provides guidance for selection of spatial and temporal discretizations that takes into account the uncertainties due to sub-processes. Finally, a probabilistic particle tracking (PT) approach is proposed to scale-up flow and transport of diffusion-reaction (DR) processes while addressing multi-scale and multi-physics nature of DR mechanisms and also maintaining consistent reservoir heterogeneity at different levels of scales. This multi-scale modeling uses a hierarchical approach which is based on passing the macroscopic subsurface heterogeneity down to the finer scales and then returning more accurate reactive flow response. This PT method can quantify the impact of reservoir heterogeneity and its uncertainties on statistical properties such as reaction surface area and MZL, at various scales. / text