Doctor of Philosophy / Department of Physics / Bruce M. Law / We have studied two critical binary liquid mixtures in the mixed phase regime with x-ray and neutron reflectometry to verify universal critical scaling at a non-critical interface. We compared our results with previous results obtained with ellipsometry. At a solid-liquid or liquid-vapor interface of an AB binary liquid mixture the component with the lower surface tension will dominate that interface. If the surface tension differential between the components of the mixture is large enough the composition of the surface layer will loose its dependence on. This case is referred to as strong adsorption. We study the case of strong adsorption for a binary liquid mixture at the critical composition with respect to the demixing phase transition. Sufficiently close to the critical temperature Tc the influence of bulk critical behavior is expected to dominate the way the surface adsorption layer decays with depth z from the surface composition to the bulk composition. The length scale of the decay profile is expected to be proportional to the composition correlation length, and is expected to scale with a universal composition scaling function. In a neutron reflectometry study of a critical mixture of D2O and 3-methylpyridine against a quartz substrate we verify universal critical scaling using a scaling function previously used to describe ellipsometry data. In an x-ray reflectometry study of the liquid-vapor interface of a critical mixture of n-dodecane and 1,1,2,2 tetrabromoethane, which had previously been studied with ellipsometry, we find that we are able to describe all data by using the same scaling function provided that we account for non-critical, system dependent surface structure as well. We are also able to simulate ellipsometry with our mathematical profile model and compare the simulation to the previous ellipsometry data.

This thesis investigates multiple-input-multiple-output (MIMO) channel modelling for a wideband indoor environment. Initially the theoretical basis of geometric modelling for a typical indoor environment is looked at, and a space-time model is formulated. The transmit and receive antenna correlation is then separated and is expressed in terms of antenna element spacing, the scattering parameter, mean angle of arrival and number of antenna elements employed. These parameters are used to analyze their effect on the capacity for this environment. Then the wideband indoor channel operating at center frequencies of 2.4 GHz and 5.2 GHz is investigated. The concept of MIMO frequency scaling is introduced and applied to the data obtained in the measurement campaign undertaken at the University of Pretoria. Issues of frequency scaling of capacity, spatial correlation and the joint RX/TX double direction channel response for this indoor environment are investigated. The maximum entropy (ME) approach to MIMO channel modelling is investigated and a new basis is developed for the determination of the covariance matrix when only the RX/TX covariance is known. Finally, results comparing this model with the established Kronecker model and its application for the joint RX/TX spatial power spectra, using a beamformer, are evaluated. Conclusions are then drawn and future research opportunities are highlighted. / Thesis (PhD)--University of Pretoria, 2008. / Electrical, Electronic and Computer Engineering / unrestricted

Functional morphologists have extensively used measurements of performance to investigate the relationship among form, function and ecology through ontogeny. Among different measurements of performance bite force play a crucial role influencing fitness. Although, bite force has been thoroughly investigated among vertebrates, the majority of the studies on fishes have been concentrated only in small species. Consequently, this is the first study that compares the bite force performance in two large marine predators, the great barracuda (Sphyraena barracuda) and bull shark (Carcharhinus leucas). Values of posterior bite force in S. barracuda varied from 3 - 258 N for an ontogenetic series of 27 individuals (23 - 130 cm, TL). Bite force as well as the majority of the biomechanical variables that contribute to it scaled with isometry in S. barracuda. Values of posterior bite force in C. leucas varied from 170 - 5,914 N for and ontogenetic series of 16 individuals (73 - 285 cm, TL). Bite force at the most anterior bite point scaled with positive allometry as well as the majority of the subdivisions of the adductive musculature that greatly contribute to bite force. Bite force performance in this two species showed strong differences, where S. barracuda has one of the lowest relative values of bite force among fishes and C. leucas has one of the largest ones. Additionally, the scaling patterns for bite force and most of the biomechanical variables investigated in this study differed among these two species. These results suggest that predatory success may be acquired by different strategies, and that the same ecological role in a marine ecosystem may be reached by having different bite force performance.

Modern smartphones are being designed with increasing processing power, memory capacity, network communication, and graphics performance. Although all of these features are enriching and expanding the experience of a smartphone user, they are significantly adding an overhead on the limited energy of the battery. This thesis aims at enhancing the energy efficiency of modern smartphones and increasing their battery life by minimizing the energy consumption of smartphones Graphical Processing Unit (GPU). Smartphone operating systems are becoming fully hardware-accelerated, which implies relying on the GPU power for rendering all application graphics. In addition, the GPUs installed in smartphones are becoming more and more powerful by the day. This raises an energy consumption concern. We present a novel implementation of GPU Scaling Governors, a Dynamic Voltage and Frequency Scaling (DVFS) scheme implemented in the Android kernel to dynamically scale the GPU. The scheme includes four main governors: Performance, Powersave, Ondmand, and Conservative. Unlike previous studies which looked into the power efficiency of mobile GPUs only through simulation and power estimations, we have implemented our approach on a real modern smartphone GPU, and acquired actual energy measurements using an external power monitor. Our results show that the energy consumption of smartphones can be reduced up to 15% using the Conservative governor in 2D rendering mode, and up to 9% in 3D rendering mode, with minimal effect on the performance.

Magister Scientiae (Medical Bioscience) - MSc(MBS) / Introduction: Nosocomial infections are infections that occur 48 hours after receiving care for an unrelated condition in a clinic or a hospital environment, many of which are resistant to at least one of the drugs most commonly used to treat them. The dental clinical settings are reservoirs for the transmission of microbes through aerosols produced by routine dental procedures.

Polymer gels undergo a volume phase transition in solvent in response to an infinitesimal environmental change. This remarkable phenomenon has resulted in many potential applications of polymer gels. The understanding of its mechanical properties has both scientific and technological importance. For this purpose, we have developed a novel method for measuring Poisson's ratio, which is one of the most important parameters determining the mechanical property of gels. Using this method, Poisson's ratio in N-isopropyacrylamide (NIPA) and polyacrylamide (PAAM) gels has been studied.

Principal surfaces are smooth two-dimensional surfaces that pass through the middle of a p-dimensional data set. They minimise the distance from the data points, and provide a nonlinear summary of the data. The surfaces are nonparametric and their shape is suggested by the data. The formation of a surface is found using an iterative procedure which starts with a linear summary, typically with a principal component plane. Each successive iteration is a local average of the p-dimensional points, where an average is based on a projection of a point onto the nonlinear surface of the previous iteration. Biplots are considered as extensions of the ordinary scatterplot by providing for more than three variables. When the difference between data points are measured using a Euclidean embeddable dissimilarity function, observations and the associated variables can be displayed on a nonlinear biplot. A nonlinear biplot is predictive if information on variables is added in such a way that it allows the values of the variables to be estimated for points in the biplot. Prediction trajectories, which tend to be nonlinear are created on the biplot to allow information about variables to be estimated. The goal is to extend the idea of nonlinear biplot methodology onto principal surfaces. The ultimate emphasis is on high dimensional data where the nonlinear biplot based on a principal surface allows for visualisation of samples, variable trajectories and predictive sets of contour lines. The proposed biplot provides more accurate predictions, with an additional feature of visualising the extent of nonlinearity that exists in the data.

The purpose for this study was to develop guidelines for the implementation of Goal Attainment Sealing (a mental health measurement technique) in the medical care setting. As a graduate student of social work, I have become involved in the delivery of medical care and am interested in the dynamics of psycho-social variables as they affect the structure, delivery, and outcome of medical services.

No description available.

Owing to the maldistribution of precipitation in the harsh climatic region has resulted in the deficit between freshwater demand and natural supply or water scarcity in these countries. Seawater desalination has emerged as one of the most reliable methods to bridge this gap. However, the thermal desalination (MED and MSF) process faces challenges related to surface scaling phenomena, such as temperature and seawater concentration. Innovative thermodynamic processes and technologies have the potential to overcome these limitations. On one hand, the top brine temperature (TBT) limit can be raised by partially removing the multivalent ions such as SO42-, Mg2+, Ca2+, Cl-, and Na+ dissolved in the seawater. One of the main drawbacks of the current MED processes is their vulnerability to scaling at temperatures above 70°C.. This limitation deprives the technology to be energy efficient and reduces its optimal productivity. However, by implementing an optimized pre-treatment of seawater feed using NF membranes, the efficiency of the process can be significantly improved. In the pilot plant, the experiment was conducted to investigate the efficacy of NF (nanofiltration) as a physical pre-treatment method for partially removing undesirable ions of dissolved salts in Red Sea water, thereby mitigating scaling issues beyond the upper TBT limit in thermal desalination systems. Utilizing the NF-270 membrane, the optimal operating feed pressure of 15 bar was determined to ensure effective ion removal while minimizing operational expenditures (OpEx). The results demonstrated high removal rates, with 97% removal of Sulfate (SO42-), 73% removal of Magnesium (Mg2+), 49% removal of Calcium (Ca2+), 17% removal of Sodium (Na+), and 16% removal of Chloride (Cl-). By employing NF as a pre-treatment method, the concentrations of these ions were significantly reduced, allowing for thermal desalination plants to operate at higher temperatures, with a maximum TBT of 120°C. This, in turn, has the potential to substantially increase water production yield in thermally driven plants by incorporating a greater number of stages in a green new design plant or by exploiting larger temperature differences in existing plants.