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Master of Science / Department of Psychology / Lester C. Loschky / The effect of blur/clarity contrast on selective attention was investigated in terms of how unique blur and/or clarity guides attention. Visual blur has previously been suggested to be processed preattentively using a dual-task paradigm (Loschky et al., 2014). Experiments 1 and 2 used rotated L and T visual search tasks with blur/clarity contrast being manipulated such that it was non-predictive of the target’s location. Each experiment was preceded by a legibility control study such that blurred and clear letters had similar accuracy and reaction times. This allowed for the results to be interpreted as changes in attention rather than difficulty identifying the letters because they were blurry. Results suggest that when non-predictive of target location, unique blur plays a passive role in selective attention in which it is ignored, neither capturing nor repelling attention to its spatial location, whereas unique clarity captures attention. The findings provide insight to the role that blur/clarity contrast plays in guiding visual attention, which can be implemented in visual software to help guide selective attention to critical regions of interest displayed on a computer screen.

This study examined the changes that occur in spontaneous speech when speakers are distracted by background audio. Forty young adults answered open ended questions under five audio conditions (pink noise, movie dialogue, heated debate, classical music, and contemporary music) and a silent condition. Acoustic parameters assessed during the sessions included mean and variability of the fundamental frequency (F0), mean and variability of intensity, speaking time ratio, and disfluency ratio. It was hypothesized that there would be significant increases in the mean and variability of F0 as well as the mean and variability of intensity. There were statistically significant increases in mean and variability of intensity and mean F0 across most audio conditions. There were no significant changes in variability of intensity in the pink noise condition and no significant changes in variability of F0 in any audio condition. We hypothesized that the speaking time ratio would decrease in the presence of background audio compared to the silent baseline. Results demonstrate significant increases in speaking time ratio except for the classical music condition. It was expected that the disfluency ratio of speech production for each participant would increase in the presence of background audio, with informational masking demonstrating the most increase. Results revealed a significant increase in disfluency ratios across background audio conditions except for the pink noise and classical music conditions. Participants reported the heated debate and contemporary music to be the most distracting. These results have potential clinical implications regarding the type of environment where therapy is given, and what type of everyday situations might cause the most difficulties with fluency as well as the processing and production of speech.

Consists mainly of offprints of articles by the author / Includes bibliographies / 1 v. (various pagings) : / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (D. Sc.)--University of Adelaide, Faculty of Science, 1985

Thesis (Ph. D.)--University of Texas at Dallas, 2006. / Includes vita. Includes bibliographical references (leaves 253-256).

The accomplishment of the γ-alkylation reaction from β-keto esters of tropinone and the enantioselective aziridine formation from nortropinone is first reported. This opened two new paths to develop tropinone enolate chemistry. One is indirect α-alkylation of tropinone, another is the nucleophilic attack from α-C enolate to the nitrogen atom.<p>Seven interesting chiral amines have been synthesized and applied into the enolate chemistry of two interesting precursors of synthesis of natural products: 1,4- cyclohexanedione monoethylene ketal and tropinone.<p>The aldol reaction between the lithium enolate of 1,4-cyclohexanedione monoethylene ketal and benzaldehyde demonstrated the high diastereoselectivity (up to 98% de) and the moderate to high enantioselectivity (up to 75% ee) induced by those chiral lithium amides. On the other hand, high diastereoselectivity (up to 100% de) and the low enantioselectivity were obtained from the aldol reaction of tropinone enolate with benzaldehyde differentiated by chiral lithium amides with extra electron donor atoms.<p>An analysis method to determine enantioselectivity from racemic α-hydroxytropinone was developed. That will, no doubt, benefit the further enantioselective α-hydroxylation reaction of tropinone.

Dessertation describes of the first reported syntheses of the natural products lairdinol A and depsilairdin. The key steps in the synthesis of depsilairdin were N-terminal extension (C←N) of the protected proline fragment, hydrolysis of the tetrapeptide fragment with free secondary alcohol in the proline moiety and esterification of the HOBt ester of tetrapeptide fragment with the bromomagnesium alkoxide of lairdinol A.

The accomplishment of the γ-alkylation reaction from β-keto esters of tropinone and the enantioselective aziridine formation from nortropinone is first reported. This opened two new paths to develop tropinone enolate chemistry. One is indirect α-alkylation of tropinone, another is the nucleophilic attack from α-C enolate to the nitrogen atom.<p>Seven interesting chiral amines have been synthesized and applied into the enolate chemistry of two interesting precursors of synthesis of natural products: 1,4- cyclohexanedione monoethylene ketal and tropinone.<p>The aldol reaction between the lithium enolate of 1,4-cyclohexanedione monoethylene ketal and benzaldehyde demonstrated the high diastereoselectivity (up to 98% de) and the moderate to high enantioselectivity (up to 75% ee) induced by those chiral lithium amides. On the other hand, high diastereoselectivity (up to 100% de) and the low enantioselectivity were obtained from the aldol reaction of tropinone enolate with benzaldehyde differentiated by chiral lithium amides with extra electron donor atoms.<p>An analysis method to determine enantioselectivity from racemic α-hydroxytropinone was developed. That will, no doubt, benefit the further enantioselective α-hydroxylation reaction of tropinone.

Dessertation describes of the first reported syntheses of the natural products lairdinol A and depsilairdin. The key steps in the synthesis of depsilairdin were N-terminal extension (C←N) of the protected proline fragment, hydrolysis of the tetrapeptide fragment with free secondary alcohol in the proline moiety and esterification of the HOBt ester of tetrapeptide fragment with the bromomagnesium alkoxide of lairdinol A.

<p>The field of metamaterials has gained much attention within the scientific community over the past decade. With continuing advances and discoveries leading the way to practical applications, metamaterials have earned the attention of technology based corporations and defense agencies interested in their use for next generation devices. With the fundamental physics developed and well understood, current research efforts are driven by the demand for practical applications, with a famous example being the well-known microwave "invisibility cloak." Gaining exotic electromagnetic properties from their structure as opposed to their</p><p>intrinsic material composition, metamaterials can be engineered to</p><p>achieve tailored responses not available using natural materials. With typical designs incorporating resonant and dispersive elements much smaller than the operating wavelength, a homogenization scheme is possible, which leads to the meaningful interpretation of effective refractive index, and hence electric permittivity and magnetic permeability. The typical metamaterial is composed of arrays of scattering elements embedded in a host matrix. The scattering elements are typically identical, and the electromagnetic properties of the medium can be inferred from the properties of the unit cell. This convenience allows the designer to engineer the effective electromagnetic parameters of the medium by modifying the size, shape, and composition of the unit cell.</p><p>This dissertation summarizes several key projects related to my research efforts in metamaterials. The main focus of this dissertation is to develop practical approaches to frequency tunable and reconfigurable metamaterials. Chapter one serves as a background and introduction to the field of metamaterials. The purpose of chapters two, three and four is to develop different methods to realize tunable metamaterials - a broad class of controllable artificially engineered metamaterials. The second chapter develops an approach to characterizing metamaterials loaded with RF MEMS switches. The third chapter examines the effects of loading</p><p>metamaterial elements with varactor diodes and tunable ferroelectric</p><p>thin film capacitors (BST) for external tuning of the effective medium parameters, and chapter four develops a more advanced method to control the response of metamaterials using a digitally addressable control network. The content of these chapters leads up to an interesting application featured in chapter five - a reconfigurable frequency selective surface utilizing tunable and digitally addressable tunable metamaterials. The sixth and final chapter summarizes the dissertation and offers suggestions for future work in tunable and reconfigurable metamaterials. It is my hope that this dissertation will provide the foundation and motivation for new researchers in the field of metamaterials. I am confident that the reader will gain encouragement from this work with the understanding that very interesting and novel practical devices can be created using metamaterials. May this work be of aid and motivation to their research pursuits.</p> / Dissertation