Die vorliegende Arbeit befasst sich mit der Synthese, Charakterisierung und Reaktivität von Nebengruppen-Metallkomplexen, die mindestens einen pi-koordinierenden Liganden tragen. Im ersten Abschnitt liegt der Fokus auf heteroleptischen Systemen mit carbocyclischen Liganden, zu deren Synthese die gängige Methodik der Salzeliminierung herangezogen wird. Das Metallierungsverhalten dieser Komplexe, sowie die Reaktivität von Komplexen mit reduktionsstabilen funktionellen Gruppen an den Ligandensystemen wird untersucht. Der zweite Abschnitt behandelt die Redox- und Koordinationseigenschaften des CAAC-stabilisierten 1,4 Diborabenzols, wobei Alkali-Metalle, Gruppe 10 Metalle, Lanthanoide, sowie die Actinoide Thorium und Uran untersucht werden. / The present work deals with the synthesis, characterization and reactivity studies of subgroup metal complexes bearing at least one sandwich-type carbo- or heterocyclic ligand. The first chapter covers studies on the synthesis of heteroleptic sandwich complexes employing the well-established salt-metathesis strategy. The metalation properties as well as the reactivity of the complexes is investigated. The second chapter of this work discusses further studies on the redox and coordination properties of neutral, CAAC-stabilized 1,4-diborabenze. To this end reactions with alkali and group 10 metals, elements of the lanthanides as well as the actinide metals Thorium and Uranium are reviewed.

Saab Kockums har på länge tillämpat kompositmaterial i uppbyggande av deras nya fartyg. Detta medför många fördelar kopplat till stealth teknik men samtidigt utgör vissa andra utmaningar gällande installationer ombord. Arbetet utfördes därför med syfte att undersöka möjligheten för användning av lastskenor för standardiserat montage på dessa fartyg. Vidare skulle det utvecklas en standardlösning för montaget där användarvänlighet står som fokus.   Arbetet inleds med en undersökning av produkter från marknaden där också utvecklingspotential identifierades. Fokus med undersökningen var att hitta den optimala utseende för montaget. Dessa punkter användes därefter för att generera idéer för samtliga delar. Den bästa idéen filtreras fram genom poängsättning kopplat till utsatta kravställningen. För infästning av konstruktion bestämdes det med hjälp av olika litteraturstudier tillsammans med dragprovsdata som tillhandahålls av Kockums. Litteraturstudien omfattades studie på egenskaper hos sandwichkonstruktioner samt dragproven på olika lastfallen som utfördes på andra rapporter. Sist verifierades konceptet utifrån olika aspekter baserat på olika sätt. Hållfasthetmässigt är baserade på FEM/manuella beräkningar, tillverkning är baserade på intervju och monteringen baserad på 3D-utskrift.   En konstruktion på montaget erhölls som resultatet av arbetet där den klarade samtliga krav som ställdes. Konstruktionen består av förmonterade skena som har ett homogen utseende tillsammans med vinkelbeslag för montering av eventuella bäddar eller dämpare. Konstruktionen fästs på skottet med M8 blindnitsmuttrar för områden utan stötkrav och M10 muttrar tillsammans med laminatsförstärkning för områden med stötkrav. Som bevisat är det möjligt att tillverka dessa med några enkla steg av standardprofiler från marknaden. Det är även enkelt att montera ombord på fartygen. / Saab Kockums has long time used composite materials in the construction of their new ships. This brings many advantages linked to stealth technology, but at the same time poses some other challenges regarding installations on board. This thesis was therefore performed with the aim of investigating the possibility of using cargo rails for standardized assembly on these ships. Furthermore, a developed standard solution for assembly where ease of use is the focus for this study.  The work begins with an analysis of products from the market and potential development is identified. The focus of the investigation was to find the optimal design for the montage. These potentials were then used to generate ideas for parts in the design. The best idea is filtered through scoring linked to the set of requirements. For attachment of the construction, it was determined with the help of various literature studies along with tensile test data provided by Kockums. The literature study included studies on properties of sandwich constructions as well as tensile tests on different load cases that were carried out on other reports. Finally, the concept is verified based on different aspects. The durability is based on FEM/manual calculations, the manufacturing is based on interview and finally the assembly is based on 3D printing.  A construction of the assembly was obtained as the result of the work and met all the requirements that were set. The construction consists of pre-assembled cargo rails that have a homogeneous appearance together with angle fittings for mounting any foundations or dampers. The structure shall be attached to the bulkhead with M8 blind rivet nuts for areas without impact requirements and M10 nuts together with laminate reinforcement for areas with impact requirements. As proven, it is possible to manufacture these in a few simple steps from standard profiles from the market and easily fit on board the ships.

Projektet syftar till att föreslå en rimlig riktning för hur additiva produktionsmetoder, alltså tillverkningsmetoder som använder lager-på-lager-teknik, kan tänkas påverka arkitekturen, att försöka sätta sig in i teknikerna och komma fram till vilken riktning som upplevs mest givande eller gångbar. Hur ska man nyttja potentialen med den nya tekniken på ett bra sätt? Jag har försökt ta fram en produkt som nyttjar potentialen hos de additiva produktionsmetoderna och som upplevs tänkbar för fullskalig realisering i byggsektorn i en närliggande framtid. Produkten består av en metod för framställning av en sandwichkonstruktion med hög trähalt och troligen lång livslängd. Metoden minskar byggsektorns klimatbelastning och kan ge stora rumsliga kvaliteter och formgivningsmöjligheter. Jag har genom fysiska experiment och utforskande av olika digitala fabrikationsmetoder försökt att visualisera och identifiera möjligheter med dessa nya tekniska hjälpmedel. Genom praktiska tester har jag prövat mina föreställningar av hur dessa metoder kan användas på effektiva sätt. Projektet vidga-des från att initialt omfatta additiva produktionsmetoder till att senare under tillämpningsfasen även omfatta digitala hjälpmedel såsom fotogrammetri och verktyg för parametrisk design. Projektet har resulterat i ett tillvägagångsätt för printning av cellulosabaserade sandwichkonstruktioner i printade formverk av återvinningsbar biokomposit. / The project aims to propose a direction for how additive manufacturing methods can influence architecture, to study the techniques and find out which direction could be perceived as most rewarding or viable. How to use the potential of the new technology in a good way? I have tried to develop a product that utilizes the potential of the additive manufacturing methods and which is conceivable for full-scale realization in the construction sector in the near future. The product consists of a method for producing long lasting sandwich constructions with high wood content. The method reduces the building industry's climate impact and can provide great spatial qualities and design possibilities. Through physical experiments and exploration of various digital fabrication methods, I have tried to visualize and identify possibilities with these new technological aids. Through practical tests, I have tested my ideas of how these methods can be used effectively. The project was expanded from initially studying additive production methods to, later during the application phase, also include digital aids such as photogrammetry and tools for parametric design. The project has resulted in a strategy for printing cellulose-based sandwich constructions in printed molds of recyclable biocomposite.

This study will present the Experimental, numerical and analytical characterizations of composite sandwich structures needed to optimize structure design. In this study, the effects of varying honeycomb core ribbon orientation and varying face sheet thickness’s have on the flexural behavior of honeycomb sandwich structures was investigated. Honeycomb sandwich panels were constructed using Hexcel 6367 A250-5H carbon fiber face sheets and Hexcel Nomex HRH-10-1/8-5 honeycomb cores. The mechanical properties of the constituent materials were discovered experimentally using ASTM standards and theoretical models using honeycomb mechanics and classical beam and plate theory are described. A failure mode map for loading under three point bending is developed from previous works by Triantafillou and Gibson26, showing the dependence of failure mode on face sheet to core thickness and honeycomb core ribbon orientation. Beam specimens are tested with the effects of Honeycomb core ribbon orientation and unequal face sheet thickness’s examined. Experimental data sufficiently agrees with theoretical predictions. A finite element model was developed in ABAQUS/CAE to validate experimental and analytical analysis and produced agreeable results. Optimal bending stiffness and strength with respect to minimum weight was analyzed. The results reveal an important role core ribbon orientation has in a sandwich beam’s bending behavior, and design of unequal ply count face sheets can produce higher stiffness to weight ratios than conventional symmetric sandwich structures of similar weight when subjected to a single static load.

No description available.

No description available.

Sandwichväggar med ett bärande skikt dimensioneras vanligen så att enbart innerskalet bidrar tillbärförmågan, medan klimatskärmen (isolering, armeringsstege och ytterskalet) statiskt settuteslutande betraktas som en last.I denna uppsats undersöks möjligheten att utnyttja klimatskärmens förstyvande effekt påinnerskalet vid dimensioneringen av bärförmågan. Arbetet har delvis genomförts medelst enlitteraturstudie som har undersökt material som behandlar sandwichväggar och inbegrep även enkunskapsfördjupning inom betongens egenskaper som konstruktionsmaterial.En beräkning av exempelväggens bärförmåga utförs initialt utan klimatskärmens förstyvandeeffekter som därefter genomförts separat. Resultaten för ett antal väggvariationer redovisas iform av diagram och analyseras.Beräkningen ger relativt små förstyvningstillskott samtidigt som litteraturstudien visar attutnyttjandet av förstyvningen ökar risken för sprickor i fasadskivan. Således dras slutsatsen att detej är rekommendabelt att försöka utnyttja eventuella tillskott. / The dimension of sandwich walls with one structural wythe is normally determined so that onlythe inner wythe contributes to the elements load capacity. Whereas the insulation, trussconnector and outer wythe only constitute a load from a structural point of view.The possibility to take advantage of the structural stiffening effects these elements have on theinner wythe is examined in this essay. This is partly achieved by researching the existing literaturethat deals with sandwich walls and also further studies of the structural qualities of concrete.The load capacity of an example wall is calculated initially without any stiffening effects, whichare thereafter calculated separately. The results for several variations of the sandwich wall arepresented in the form of diagrams and analyzed.The calculations give relatively small increases in load capacity, while the literary researchindicates a higher risk of crack occurrence in the façade. Therefor the conclusion is made that itis not recommendable to attempt using potential gains in load capacity.

The use of composite materials in vehicle structures could reduce the weight and thereby the fuel consumption of vehicles. As the road safety of the vehicles must be ensured, it is vital that the energy absorbing capability of the composite materials are similar to or better than the commonly used steel structures. The high specific bending stiffness of sandwich structures can with advantage be used in vehicles, provided that the structural behaviour during a crash situation is well understood and possible to predict. The purpose of this thesis is to identify and if possible to describe the failure initiation and progression in in-plane compression loaded sandwich panels. An experimental study on in-plane compression loaded sandwich panels with two different material concepts was conducted. Digital speckle photography (DSP) was used to record the displacement field of one outer face-sheet surface during compression. The sandwich panels with glass fibre preimpregnated face-sheets and a polymer foam core failed due to disintegration of the face-sheets from the core, whereas the sandwich panels with sheet molding compound face-sheets and a balsa core failed in progressive end-crushing. A simple semi-empirical model was developed to describe the structural response before and after initial failure. The postfailure behaviour of in-plane compression loaded sandwich panels was studied by considering the structural behaviour of sandwich panels with edge debonds. A parametrical finite element model was used to determine the influence of different material and geometrical properties on the buckling and postbuckling failure loads. The postbuckling failure modes studied were debond crack propagation and face-sheet failure. It could be concluded that the postbuckling failure modes were mainly determined by the ratio between the fracture toughness of the face-core interface and the bending stiffness of the face-sheets. / QC 20101111

Yes / Half-sandwich metal complexes are of considerable interest in medicine, material, and nanomaterial chemistry. The design of libraries of such complexes with particular reactivity and properties is therefore a major quest. Here, we report the unique and peculiar reactivity of eight apparently 16-electron half-sandwich metal (ruthenium, osmium, rhodium, and iridium) complexes based on benzene-1,2-dithiolato and 3,6-dichlorobenzene-1,2-dithiolato chelating ligands. These electron-deficient complexes do not react with electron-donor pyridine derivatives, even with the strong σ-donor 4-dimethylaminopyridine (DMAP) ligand. The Ru, Rh, and Ir complexes accept electrons from the triphenylphosphine ligand (σ-donor, π-acceptor), whilst the Os complexes were found to be the first examples of non-electron-acceptor electron-deficient metal complexes. We rationalized these unique properties by a combination of experimental techniques and DFT/TDFT calculations. The synthetic versatility offered by this family of complexes, the low reactivity at the metal center, and the facile functionalization of the non-innocent benzene ligands is expected to allow the synthesis of libraries of pseudo electron-deficient half-sandwich complexes with unusual properties for a large range of applications.

An efficient interaction formula and a semi-analytical method are developed for calculating the ultimate strength of steel-elastomer sandwich panels under combined in-plane compression and lateral pressure. By using the Galerkin method and extending the semi-analytical method to clamped sandwich panels, the governing equations of sandwich panels have been solved by the Galerkin method. The material nonlinearity is treated by iteration and a three-dimensional mesh. For the load case of pure lateral pressure, the ultimate strength from the semi-analytical method is similar to that from hinge line theory and finite element analysis (FEA). However, the semi-analytical method requires about as much computation as FEA, and it is therefore not suitable for design. Finite element modeling and nonlinear analysis are performed to calculate the ultimate strength of sandwich panels under combined load. The results agree with experimental results. This verifies the accuracy of the current finite element model. The verified finite element model is used to obtain the results for a large set of sandwich panels with various dimensions and load combinations. The FEA results for pure lateral pressure load cases are used to derive a correction factor for the hinge line formula. Statistical analysis confirms that the generalized hinge line formula gives accurate values of ultimate strength of sandwich panels under pure lateral pressure. Except for the pressure-only FEA data points, the other FEA data points are corrected so as not to count the in-plane load carried by the elastomer core. Based on the corrected FEA data points, a general expression is developed for an interaction equation. The resulting equation has a bias of -0.003 and a standard deviation of 0.029. Since the radius of the interaction curve is close to 1, this standard deviation is of the order of 3%, which shows that the ultimate strength given by the equation is very close to the FEA results. The interaction equation is so simple that the ultimate strength of clamped sandwich panels under combined in-plane compression and lateral pressure can be easily calculated. / Ph. D.