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In this thesis, colloidal nanocrystalline silicon (ncSi) capped with allylbenzene (AB) groups, is created using a sol-gel method. This novel material, AB-ncSi, is size separated and its optical, structural, and electrical characteristics are investigated in detail. For optical characterization, the photoluminescence (PL) peak is located for each fraction of the nanoparticles to determine its diameter. The AB-ncSi samples have diameters ranging from 2.89 nm to 7.65 nm. Ellipsometry and scanning electron microscopy (SEM) are used to estimate the film thickness and average distance between the particles, respectively, for structural characterization. No correlation was found between AB-ncSi size and film thickness however the estimated average distance between the particles decreased with decreasing diameter. Finally, for electrical characterization, conductivity of size-separated samples is measured and the temperature dependent conductance is analyzed. The results emerging from these analyses suggest that the charge transport mechanism for AB-ncSi is nearest-neighbor hopping (NNH) albeit VRH is also a potential contributor.

In this thesis, colloidal nanocrystalline silicon (ncSi) capped with allylbenzene (AB) groups, is created using a sol-gel method. This novel material, AB-ncSi, is size separated and its optical, structural, and electrical characteristics are investigated in detail. For optical characterization, the photoluminescence (PL) peak is located for each fraction of the nanoparticles to determine its diameter. The AB-ncSi samples have diameters ranging from 2.89 nm to 7.65 nm. Ellipsometry and scanning electron microscopy (SEM) are used to estimate the film thickness and average distance between the particles, respectively, for structural characterization. No correlation was found between AB-ncSi size and film thickness however the estimated average distance between the particles decreased with decreasing diameter. Finally, for electrical characterization, conductivity of size-separated samples is measured and the temperature dependent conductance is analyzed. The results emerging from these analyses suggest that the charge transport mechanism for AB-ncSi is nearest-neighbor hopping (NNH) albeit VRH is also a potential contributor.

Digital-to-Analog Converters (DAC) form the feedback element in sigma-delta modulators. Any non-linearity in the DAC directly degrades the linearity of the modulator at low and medium frequencies. Hence, there is a need for designing highly linear DACs when used in high performance sigma-delta modulators. In this work, the impact of current mismatch on the linearity performance (IM3 and SQNR) of a 4-bit current steering DAC is analyzed. A selective calibration technique is proposed that is aimed at reducing the area occupancy of conventional linearization circuits. A statistical element selection algorithm for linearizing DACs is proposed. Current sources within the required accuracy are selected from a large set of current sources available. As compared with existing calibration techniques, this technique achieves higher accuracy and is more robust to variations in process and temperature. In contrast to existing data weighted averaging techniques, this technique does not degrade SNR performance of the ADC. A 5th order, 500 MS/s, 20 MHz sigma-delta modulator macro-model was used to test the linearity of the DAC.

This thesis presents both theoretical and experimental investigations of the performance and capabilities of frequency selective surfaces (FSS) applied at THz frequencies. The aim is to explore and extend the use of FSS, traditionally limited to microwave frequencies, towards the THz regime of the spectrum, where interesting applications such as imaging, sensing and communications exist. The contribution of this work lies in three main areas within the scope of THz FSS, namely, performance, prototyping and applications. Unlike microwave FSS where extensive research has been performed to evaluate the performance of different FSS designs, particular problems arise at THz frequencies, significantly, the ohmic losses. While a few notable studies can be found on the issue of ohmic losses, part of this thesis investigates, for the first time, the power dissipation due to the presence of both ohmic and dielectric losses, in relation to the power stored in the vicinity of the FSS, the currents induced in the elements of the array and the array’s terminal impedance. By doing so, a better understanding of the performance of THz FSS has been given in terms of their quality factor, allowing for design guidelines previously unavailable. In order to demonstrate multiband operation experimentally, a novel fabrication process has been designed and developed to manufacture capacitive or dipole-based THz FSS on a dielectric layer. Dry deep-reactive ion etching has been employed in order to avoid the use of wet etching to provide better control of etch characteristics. Various FSS operating around 15THz have been demonstrated experimentally. In addition, THz FSS have been investigated theoretically in the realm of three different applications, namely, multiband operation, sensing capability and reconfigurability. Multiband characteristics using single-screen FSS have been achieved by perturbed dipole FSS exhibiting up to four resonances due to the excitation of even and odd current modes. After studying the near-fields in perturbed FSS, it has been found that this type of FSS represent a very attractive candidate for sensing applications due to the revealed near-field enhancement phenomena related to the excitation of the odd mode, where currents flow in opposite directions. Finally, a novel tunability approach to reach frequency reconfigurability by varying the near-field coupling between two closely spaced layers in a dual-layer configuration has been proposed. A MEMS movable four-arm membrane has been suggested to vary the distance between the two layers mechanically, leading to the frequency tuning effect. This approach has been shown to be particularly suitable for THz frequencies, and has been applied to demonstrate theoretically tunable FSS and other periodic structures, such as artificial magnetic conductors and dielectric gratings.

The growing popularity of wireless communications networks has resulted in greater bandwidth contention and therefore spectrally efficient transmission schemes are highly sought after by designers. Space-time block codes (STBCs) in multiple-input, multiple-output (MIMO) systems are able to increase channel capacity as well as reduce error rate. A general linear space-time structure known as linear dispersion codes (LDCs) can be designed to achieve high-data rates and has been researched extensively for flat fading channels. However, very little research has been done on frequency-selective fading channels. The combination of ISI, signal interference from other transmitters and noise at the receiver mean that maximum likelihood sequence estimation (MLSE) requires high computational complexity. Detection schemes that can mitigate the signal interference can significantly reduce the complexity and allow intersymbol interference (ISI) equalization to be performed by a Viterbi decoder. In this thesis, detection of LDCs on frequency-selective channels is investigated. Two predominant detection schemes are investigated, namely linear processing and zero forcing (ZF). Linear processing depends on code orthogonality and is only suited for short channels and small modulation schemes. ZF cancels interfering signals when a sufficient number of receive antennas is deployed. However, this number increases with the channel length. Channel decay profiles are investigated for high-rate LDCs to ameliorate this limitation. Performance improves when the equalizer assumes a shorter channel than the actual length provided the truncated taps carry only a small portion of the total channel power. The LDC is also extended to a multiuser scenario where two independent users cooperate over half-duplex frequency-selective channels to achieve cooperative gain. The cooperative scheme transmits over three successive block intervals. Linear and zero-forcing detection are considered.

The primary aim of this dissertation is to address an important issue of individual susceptibility to false memories. Specifically, what is the role inhibitory control (IC) in children’s and adult’s propensity to producing false memories? Inhibitory control within the context of the current study is defined on the basis of performance on selective attention tasks. Inhibitory control is discussed within this dissertation as it is reflected in two selective attention tasks, Stroop and Negative Priming. While the false memory effect, as reflected in the Deese/Roediger and McDermott paradigm (Roediger & McDermott, 1995), is one of the most widely studied memory phenomenon, the current study is important as it provides some insights into the relation between attention and memory. An interesting finding in the DRM false memory effect is that participants often report having a clear false memory of having seen or heard the non-presented critical lure item (CL item). Such memory illusions have been informative on how memory works. The current study adds to this body of research by providing converging evidence of how individual differences in the sensitivity to the false memory effect may occur, and how this sensitivity may reflect the same IC mechanisms involved in selective attention tasks. The basic notion examined within this dissertation is that when recognition memory is tested in the DRM paradigm, individuals have to select information that was studied and simultaneously inhibit highly activated yet non-presented information in memory, in order to correctly reject the CL item. If the notion that individual differences in sensitivity to the false memory effect is indeed related to a basic IC mechanism, then a relationship should be found between measures of IC in selective attention tasks and rates of false memories in the DRM test. The current study incorporates three experiments. Experiments 1 and 2 are broken down into parts ‘a’ and ‘b’, with each part varying in respect to the IC measure. In part a, participants were assigned to an inhibitory control group (IC group) on the basis of Stroop interference. In part b, participants are assigned to IC groups on the basis of a combined measure of inhibitory control that is, Stroop and Negative Priming. The third experiment assigned participants on the basis of a combined measure of IC, and then considered the relation between the duration of IC over a number of DRM word-lists presented simultaneously prior to the recognition test. Experiment 3 also compared the robust effect of IC on the propensity to produce false memories across all three experiments. The results of this study can be summarized as follows. In each experiment there was clear evidence of a relation between IC estimates and proportion of false memories. As predicted, individuals assigned to a Less IC group produced a higher proportion of false memories than those assigned to the More IC group. Inhibitory control differences did not modulate differences in correct or incorrect recognition in general (hits and false alarms to unrelated distractors). This second finding is important because it suggests a specific effect of IC in false memories, rather than a general breakdown in memory processes. The IC effect in false memories occurred in children (8-year olds and 10-year olds) as well as adults. Furthermore, the IC effect appeared to be additive with age; i.e., all groups produced a similar pattern across all three experiments. Last, the combined estimate of IC was found to be a more sensitive measure of false memories than a single index of IC; however, this was found in relation to adults but not for children. A number of additional manipulations and measures of interest were also included. Experiment 2 found clear evidence of an effect of IC on remember responses, not only were Less IC individuals more likely to produce false alarms to critical lure items, they were also more likely to distinctly respond they “remembered” the CL item as opposed to only “knowing” the CL had been presented. Examination of reaction times (RTs) to false alarms as a function of IC group found the Less IC group were faster to make false alarm responses to CL items, whereas the More IC group were slower to make false responses CL items. As predicted the relation between IC and the false memory effect was modulated by the random versus blocked presentation manipulation in Experiment 3. Specifically, decreased rates of false memories were found in the random presentation format compared to the blocked format. Interestingly however, a small effect of IC group in false memories was found even in the random condition. From this study it can be concluded that individual susceptibility to the false memory effect is in part modulated by inhibitory control. Individuals who demonstrate less effective IC show a greater propensity to false memories than those who demonstrate more effective IC. The IC effect of false memories was found to be robust, with converging evidence found across all three experiments. In relation to the development of inhibitory control, consistent with the research of Pritchard and Neumann (2004, 2009), and Lechuga and colleagues (2006), the results of this study suggest IC is fully developed in young children. However, their ability to accurately encode, retain and retrieve information would appear to develop at a different rate than IC. Specifically, it may be that while younger children are able to utilize IC in memory processes, they have yet to fully develop a richly interconnected semantic network. On the other hand, older children and adults would appear to have a more fully developed semantic network. This series of experiments presents a novel demonstration of the relation between inhibitory control and false memories. As such, this study has the potential to provide new insight into a cognitive mechanism that may be responsible for both developmental trends and for individual differences in the regulation of false memories. Moreover, if the mechanism responsible for mediating false memories is causally linked to performance on selective attention tasks in the systematic way that is proposed, it may be possible in the future to utilize IC measures to assist in identifying individuals who have an exaggerated propensity to form false memories, as well as those more prone to resist them.

Recent earthquakes have highlighted the vulnerability of existing structure to seismic loading. Current seismic retrofit strategies generally focus on increasing the strength/stiffness in order to upgrade the seismic performance of a structure or element. A typical drawback of this approach is that the demand on the structural and sub-structural elements can be increased. This is of particular importance when considering the foundation capacity, which may already be insufficient to allow the full capacity of the existing wall to develop (due to early codes being gravity load orientated). In this thesis a counter intuitive but rational seismic retrofit strategy, termed "selective weakening" is introduced and investigated. This is the first stage of an ongoing research project underway at the University of Canterbury which is focusing on developing selective weakening techniques for the seismic retrofit of reinforced concrete structures. In this initial stage the focus is on developing selective weakening for the seismic retrofit of structural walls. This is performed using a series of experimental, analytical and numerical investigations. A procedure for the assessment of existing structural walls is also compiled, based on the suggestions of currently available code provisions. A selective weakening intervention is performed within an overall performance-based retrofit approach with the aim of improving the inelastic behaviour by first reducing the strength/stiffness of specific members within the structural system. This will be performed with the intention of modifying a shear type behaviour towards a flexural type behaviour. As a result the demand on the structural member will be reduced. Once weakening has been implemented the designer can use the wide range of techniques and materials available (e.g. use of FRP, jacketing or shotcrete) to ensure that adequate characteristics are achieved. Whilst performing this it has to be assured that the structure meets specific performance criteria and the principles of capacity design. A target of the retrofit technique is the ability to introduce the characteristics of recently developed high performance seismic resisting systems, consisting of a self centring and dissipative behaviour (commonly referred to as a hybrid system). In this thesis, results of experimental investigations performed on benchmark and selectively weakened walls are discussed. The investigations consisted of quasi-static cyclic uni-directional tests on two benchmark and two retrofitted cantilever walls. The first benchmark wall is detailed as typical of pre-1970's construction practice. An equivalent wall is retrofitted using a selective weakening approach involving a horizontal cut at foundation level to allow for a rocking response. The second benchmark wall represents a more severe scenario where the inelastic behaviour is dominated by shear. A retrofit solution involving vertically segmenting the wall to improve the ductility and retain gravity carrying capacity by inducing a flexural response is implemented. Numerical investigations on a multi-storey wall system are performed using non linear time history analysis on SDOF and MDOF lumped plasticity models, representing an as built and retrofitted prototype structure. Calibration of the hysteretic response to experimental results is carried out (accounting for pinching and strength degradation). The sensitivity of maximum and residual drifts to p-delta and strength degradation is monitored, along with the sensitivity of the peak base shear to higher mode affects. The results of the experimental and analytical investigations confirmed the feasibility and viability of the proposed retrofit technique, towards improving the seismic performance of structural walls.

This research contributes to the employee selection literature by examining the various aspects of value creation derived from systematic approaches to selective hiring and onboarding best practices. These best practices covering the end-to-end spectrum of talent acquisition activities from pre-recruitment to post-hiring performance management are examined through the construct of employee selection bundles. A rigorous type of employee selection bundle called Topgrading is examined across six case studies. This research builds on the employee selection literature by exploring the cross section of organizational learning theory, goal setting theory, and process management theory on the employee selection bundle as a mechanism that positively impacts firm performance.