Thesis (Ph.D.)--University of Delaware, 2006. / Principal faculty advisor: Mary E. Galvin-Donoghue, Dept. of Materials Science & Engineering. Includes bibliographical references.

Thesis (Ph. D.)--University of Delaware, 2006. / Principal faculty advisor: Darrin J. Pochan, Dept. of Materials Science & Engineering. Includes bibliographical references.

Thesis (Ph. D.)--University of Chicago, Department of Chemistry, August 2003. / CD-ROM reproduces the entire dissertation in PDF format. Includes bibliographical references. Also available on the Internet.

Not available / text

As the feature size of new devices continues to decrease so too does the feasibility of top-down methods of patterning them. In many cases bottom-up methods are replacing the existing methods of assembly, as having building blocks self-organize into the desired structure appears, in many cases, to be a much more advantageous route. Self-assembled nanoparticulate films have a wide range of potential applications; high-density magnetic media, sensing arrays, meta-materials and as seeds for 3D photonic crystals to name a few. Thus, it is critical that we understand the fundamental dynamics of pattern formation on the nanoparticulate and colloidal scale so that we may have better control over the formation and final quality of these structures. We study computationally the self-organization of colloidal particles in 2D using both Monte Carlo and dynamic simulation We present 3 studies employing Monte Carlo simulation. In the first study, Monte Carlo simulations were used to understand the experimental observation of highlyordered 2D arrays of bidisperse, stabilized gold nanoparticles. It was shown that the LS lattice forms with the addition of interparticle forces and a simple compressive force, revealing that bidisperse lattice formation is, in fact, a dynamic process. It was evident that the LS lattice forms in large part because the particles within the lattice reside in their respective interparticle potential wells. In the second Monte Carlo study, this information was used to predict size-ratios and surface coverages for novel lattice structures. These predictions are intended to guide experimentalists in their search for these exciting new structures. In the third study it was shown that polydisperse amounts of amorphous-silicon nanoparticles could form 2D clusters exhibiting long-range orientational order even in the absence of translational order. Monte Carlo simulations were performed, which included lateral capillary forces and a simple stabilizing repulsion, resulting in structures that were strikingly similar to the experimentally observed In the fourth study we used dynamic simulation to study the hydrodynamicallyassisted self-organization of DNA-functionalized colloids in 2D. It was shown that hydrodynamic forces allow a more thorough sampling of phase space than through thermal or Brownian forces alone.

Polyvinyl alcohol (PVA) has been widely used in fibre and paper industries. Due to its excellent biocompatibility, biodegradability, water solubility and gas permeability, PVA has recently attracted enormous interest in special applications such as biochemical, biomedical and environmental-friendly packaging materials. However, its poor thermal aging resistance, miserable solvent resistance and insufficient mechanical property have greatly restricted PVA’s further applications. / To overcome these drawbacks of PVA, in the present study, silica nanoparticles are introduced into PVA matrix to prepare a polyvinyl alcohol/silica (PVA/SiO²) nanocomposite by incorporating self-assembly and solution compounding techniques. Different from other conventional processes for preparing nanocomposites such as sol-gel process, intercalation and physical blending, the process developed in this study is simple, universal, low cost, yet effective, and easy to be scaled up for industrial exploitation. / Thesis (PhD)--University of South Australia, 2006.

Thesis (Ph. D.)--University of Texas at Austin, 2007. / Vita. Includes bibliographical references.

Thesis (Ph. D.)--University of Washington, 2007. / Vita. Includes bibliographical references (leaves 111-116).

Thesis (Ph. D.)--State University of New York at Binghamton, Dept. of Chemistry, 2007. / Includes bibliographical references.

Thesis (Ph. D.)--University of Delaware, 2007. / Principal faculty advisor: Darrin J. Pochan, Dept. of Materials Science & Engineering. Includes bibliographical references.