The aerodynamic performance of lifting surfaces operating at low Reynolds number conditions is impaired by laminar separation. Understanding of the physical mechanisms and hydrodynamic instabilities that are associated with laminar separation and the formation of laminar separation bubbles (LSBs) is key for the design and development of effective and efficient active flow control (AFC) devices. For the present work, laminar separation and its control were investigated numerically by employing highly-accurate direct numerical simulations (DNS).For a LSB on a curved plate, the primary and secondary instability of the uncontrolled flow were investigated. An inviscid Kelvin-Helmholtz (KH) instability was found to be responsible for the shedding of predominantly two-dimensional (2D) vortices. The onset of transition was caused by temporally-growing three-dimensional (3D) disturbances inside the separated region, which were supported by elliptical and hyperbolic secondary instabilities. The hyperbolic instability was demonstrated to be of absolute/global nature. High-amplitude forcing using pulsed vortex generator jets and 2D time-periodic blowing was found to exploit the KH instability and lead to a significant reduction in bubble size. In addition, the 2D forcing was found to suppress the secondary instabilities such that transition to turbulence was delayed.The role of free-stream turbulence (FST) in the transition process was investigated for a LSB on a flat plate. FST was shown to cause the formation of streamwise-elongated streaks inside the boundary layer. For the uncontrolled LSB, increasing the FST levels led to accelerated transition and a reduction in bubble size. The stage of linear disturbance growth due to the inviscid KH instability was not ``bypassed''. Flow control by means of 2D periodic excitation was found to remain effective, since it could exploit the KH instability and suppress secondary absolute instabilities. Transition was initiated by an interaction of the 2D wave introduced by the forcing and the streamwise boundary-layer streaks. The interaction led to a spanwise modulation of the 2D wave, which was amplified due to a convective elliptical instability.

In recent years, political legitimacy as a concept distinct from full justice has received much attention. Yet in addition to querying the specific conditions legitimacy requires, there is a more general question: What is legitimacy even about? How ought we identify and conceptualize these conditions? According to the regnant justificatory liberal (JL) approach, legitimate legal coercion is based on reasons all reasonable persons can accept and JL is explicated in terms of a hypothetical procedure. Alas, Part I explains why JL is inadequate. First, I argue that it de-legitimizes all coercion. Second, it undercuts the proposition that there are certain basic rights which must be protected for legitimacy. Third, I suggest that JL structurally involves paternalism. Where should theorists turn? My perhaps surprising proposal is that they turn to the Christian Reformed (CR) tradition of social thought. As I take it, this tradition is composed of such figures as Augustine and Calvin, Abraham Kuyper and Herman Dooyeweerd, and, more recently, Francis Schaeffer. It has long theorized such issues as church-state separation and permissible coercion, and is replete with conceptual resources. Thus, Part II reconstructs an alternative legitimacy framework out of these resources. The central CR insight is this: legitimacy is a function of preventing basic wrongs. Legal coercion is only necessary "by reason of sin". I develop this insight in terms of three ideas. First, those wrongs which must prevented as conditions of legitimacy are objective wrongs, obtaining universally regardless of consent. Second, they presuppose some view of basic teleology. A teleological view is needed to elaborate contentful basic rights non-arbitrarily, but only a basic teleological view insofar as legitimacy is distinct from full justice. Third, I suggest these wrongs are fruitfully understood as constituting an exogenous standard, one that is neither the product of actual nor hypothetical self-legislation. Part III brings JL and CR legitimacy into dialogue. Understanding legitimacy in terms of objective, teleological, and exogenous wrongs, respectively, helps us avoid each of the unacceptable consequences of JL covered in Part I. Legitimacy is better conceptualized in CR terms; preventing such wrongs is what legitimacy is about. / Thesis (Ph.D, Philosophy) -- Queen's University, 2013-11-13 04:18:01.642

The photosynthetic process has the unique ability to capture energy from sunlight and accumulate that energy in sugars and starch. This thesis deals with the light driven part of photosynthesis. The aim has been to investigate how the light-absorbing protein complexes Photosystem I (PS I) and Photosystem II (PS II), react upon illumination of light with lower energy (far-red light; 700-850 nm) than the absorption peak at respective primary donor, P700 and P680.  The results were unexpected. At 295 K, we showed that both PS I and PS II were able to perform photochemistry with light up to 130 nm above its respective primary donor absorption maxima. As such, it was found that the primary donors’ action spectra extended approximately 80 nm further out into the red-region of the spectrum than previously reported.  The ability to perform photochemistry with far-red light was conserved at cryogenic temperatures (< 77 K) in both photosystems. By performing EPR measurements on various photosystem preparations, under different illumination conditions the origin of the effect was localized to their respective reaction center. It is also likely that underlying mechanism is analogous for PS I and PS II, given the similarities in spatial coordination of the reaction center pigments. For PS II, the results obtained allowed us to suggest a model involving a previously unknown electron transfer pathway. This model is based upon the conclusion that the primary cation from primary charge separation induced by far-red light resides primarily on ChlD1 in P680. This is in contrast to the cation being located on PD1, as has been suggested as for visible light illumination. The property to drive photochemistry with far-red wavelengths implies a hither to unknown absorption band, probably originating from the pigments that compose P700 and P680. The results presented here might clarify how the pigments inside P680 are coupled and also how the complex charge separation processes within the first picoseconds that initiate photosynthetic reactions occur.

Darbo apimtis 53 puslapiai, tame tarpe 43 paveikslai, 1 lentelė. Literatūros sąraše 45 šaltiniai. Darbo pradžia 2008 09 01, pabaiga 2010 05 10. Objektas. Grūdų separacijos intensyvinimas kūlimo aparate, kai pobūgnio galinėje dalyje sukuriamas papildomas oro srautas. Tikslas. Ištirti grūdų separacijos intensyvinimo, naudojant papildomą oro srautą, efektyvumą. Literatūros apžvalgoje atlikta kukurūzų burbuolių nuėmimo ir kūlimo proceso tyrimų analizė. Atlikta pobūgnių konstrukcijų, grūdų separacijos ir masės judėjimo pobūgnio paviršiumi mokslinių tyrimų apžvalga. Laboratoriniais tyrimais nustatytas kukurūzų grūdų kritinis greitis. Eksperimentiniais tyrimais nustatyta grūdų separacija pro pobūgnį, kai pobūgnio trečiojoje dalyje sukuriamas papildomas oro srautas. Įvertinta kukurūzų burbuoles gaubiančių lapų įtaka burbuolių kūlimui ir grūdų separacijai pro pobūgnį. Taip pat įvertinta tiekiamo burbuolių srauto įtaka grūdų separacijai pro pobūgnį. Tyrimų rezultatais pagrįsta, kad pobūgnio trečiojoje dalyje sukuriamas papildomas oro srautas grūdų separacijai teigiamos įtakos neturėjo, tačiau įgalino sumažinti kūlimo grūdų nuostolius. / This work consists of 53 pages, including 43 figures and 1 table. There are 45 entries in the references. This work was started on the 1st of September 2008 and it was finished on the 10th of May 2010. The object of the work. Grain separation intensification of the threshing apparatus, when in the rear providing of the concave is additional air flow. The aim of the research. To examine the intensification of grain separation, using additional air flow in threshing apparatus. The analysis studies of corn cobs‘ harvesting and threshing process is made in the literature review. The research work review of concaves structures, grain separation and mass movement of concaves surface is also done. The critical speed of maize grain is established by laboratory studies. Experimental studies have shown the influence of grain separation through the concave when the additional air flow is made in the 3rd part of the concave. Furthermore, the influence of leaves that cover corn cobs on grain separation is investigated in this work as well. Considering grain damage and their threshing loss, the rational space between the threshing drum and the concave is determined. This work also assessed the influence of the supply of pulp to the threshing machine of high quality grain separation through the concave.

Due to the ever increasing need for sustainable development, the chemical and allied industries have been at the focus of much change. Decreasing tolerances on pollution via waste streams has resulted in a re-examination of many chemical processes. This has ushered in the era of 'green chemistry' which incorporates the synthesis of a process in both a sustainable and economically viable manner. In the petroleum and chemical industries, this has led to the search for alternatives to volatile organic compounds. Ionic liquids provide one such alternative. With a wide liquid phase and no measurable vapour pressure, ionic liquids have been found to be successful as a medium for reactions. Ionic liquids differ from high-temperature molten salts in that they have a significantly lower melting point. This work investigates the use of ionic liquids as solvents in separations. The work focuses on the separation of alpha-olefins from complex mixtures. The ionic liquids used in this study were: • l-methyl-3-octyl-imidazolium chloride • 4-methyl-N-butyl-pyridinium tetrafluoroborate • trihexyl-tetradecyl-phosphonium chloride Three experimental techniques used to evaluate ionic liquids were: • gas-liquid chromatography • liquid-liquid equilibria measurements • vapour-liquid equilibria measurements l-Methyl-3-octyl-imidazolium chloride ((MOIM)C1) was used as a stationary phase in gas-liquid chromatography. The solutes used were: • Alkanes: n-Pentane; n-Hexane; n-Heptane; n-Octane • Alkenes: 1-Hexene; 1-Heptene; l-Octene • Alkynes: l-Hexyne; l-Heptyne; 1-0ctyne • Cycloalkanes: Cyclopentane; Cyclohexane; Cycloheptane • Aromatics: Benzene; Toluene Activity coefficients at infinite dilution were measured at temperatures (298.15, 308.15 and 318.15) K. Values at 298.15 K ranged from 1.99 for benzene to 26.1 for n-octane. From the temperature dependence of the activity coefficients, the partial excess molar enthalpies at infinite dilution were calculated. These range from 2.0 kJ.mol'l for l-octyne to 7.3 kJ.mol·1 for n-pentane. (MOIM)C1 shows reasonable ability to separate 1-hexene from the longer n-alkanes and aromatics. 4-Methyl-N-butyl-pyridinium tetrafluoroborate (BuMePyBF) was used as a solvent in liquid-liquid equilibria measurements. The following systems were measured at 298.2 K: • LLE System 1: BuMePyBF4 + 1-Hexene + Toluene • LLE System 2: BuMePyBF4 + 1-Hexene + Ethanol • LLE System 3: BuMePyBF4 + 1-Hexene + 2-Butanone • LLE System 4: BuMePyBF4 + 1-0ctene + Ethanol LLE System 1 is a type 11 system and the other systems being type I. All systems exhibit a large two-phase region. LLE System 1 shows low distribution. LLE System 3 show almost equal distribution between phases resulting in a distribution ratio of close to 1. LLE Systems 2 and 4 show high distribution ratios at low concentrations of solute. LLE Systems 1 and 3 show low to moderate selectivity of the solvent towards the solute. LLE Systems 2 and 4 show high to moderate selectivity, but decrease exponentially with increasing solute concentration in the organic phase. For all systems investigated, the solvent shows no miscibility with feed solutions of low to medium solute concentration. The binodial curves were correlated to the Hlavaty equation, the beta function and the log gamma function. The correlations yielded acceptable results for LLE Systems 2, 3 and 4. The tie-lines were correlated to the NRTL model, with LLE systems 2 and 4 giving acceptable results and LLE systems 1 and 3 give excellent results. The following binary vapour-liquid equilibrium systems were measured: • Acetone + Methanol at 99,4 kPa • l-Hexene + 2-Butanone at 74.8 kPa The acetone + methanol system exhibits a minimum boiling azeotrope at 0.78 mole fraction acetone. The l-hexene + 2-butanone system exhibits a minimum boiling azeotrope at 0.83 mole fraction l-hexene. Trihexyl-tetradecyl-phosphonium chloride (CJ3C1PhCl was then added to the above systems in order to evaluate it as a solvent in extractive distillation. (CJ3C1PhCI shifts the azeotrope of the acetone + methanol system to a higher acetone concentration, but does not remove it altogether. (CJ3C1PhCI has a negative effect on the relative volatility of the l-hexene + 2-butanone, thus rendering it ineffective as an extractive distillation solvent for this system. Another aspect that was considered in this work was the production of an ionic liquid. Synthesis steps and experimental considerations were discussed. A major factor in the use of ionic liquids is the cost of the ionic liquid itself. The major problem associated with ionic liquids is the general lack of available information that is necessary for them to be implemented in a process. Ionic liquids show potential as solvents in liquid-liquid extraction for a number of systems. Their potential as solvents in extractive distillation is probably limited, due to their miscibility/immiscibility properties, to systems involving slightly polar to highly polar compounds. / Thesis (M.Sc.Eng.)-University of Natal, Durban, 2003.

Syftet med min undersökning var att ta reda på hur pedagoger tillsammans med barnen på förskolor med Grön Flagg certifikat arbetar med nedskräpningsfrågor och källsortering. Jag använde mig av semistrukturerade intervjuer och sex pedagoger som arbetar på Grön Flagg förskolor. Av resultaten framgår att man på Grön Flagg förskolor arbetar relativt kontinuerligt med nedskräpningsfrågor och källsortering tillsammans med barnen. Pedagogerna anser att det är två bra sätt att arbeta med miljö då det är konkret och något som kan väcka intresse för miljöfrågor hos barnen. Resultatet visar också vikten av att låta barnen vara delaktiga och ha inflytande över arbetet med nedskräpningsfrågor och källsortering. Något som också framkommer av undersökningen är att barnen har blivit mer intresserade och medvetna om miljön tack vare deras arbete med miljöcertifieringen Grön Flagg. / The purpose of this study was to examine how pre-school teachers at pre-schools with Green Flag certification work together with the children concerning questions about littering issues and recycling. I used semi-structured interviews and six teachers were interviewed, all working at pre-schools with Green Flag certificate. The results show that they work relatively constantly with littering issues and source separation with the children. Pre-school teachers believe that these are two good activities because they are tangible and something that can spark interest in environmental issues among children. The results also show the importance of allowing children to be involved and have a say in the work of littering issues and recycling. What also emerges from the survey is that children have become more interested and aware of the environment through their work with Green Flag.

Steam distillation is the most widely accepted process for the large scale production of volatile essential oils from herbaceous material and is also regarded as the standard practice throughout the flavour and fragrance industry. A mobile essential oil distillation unit for the extraction of oils from herbaceous materials would be extremely valuable to the essential oil industry in South Africa. Using a mobile platform, the extraction technology could be taken to rural areas where essential oil crops are grown in order to extract and then analyse the oils produced. Existing systems in South Africa are static distillation units which are usually owned by commercial growers that are generally positioned large distances away from the rural areas. The objective of this project was to design, construct and test a prototype mobile distillation unit for the extraction of essential oils from herbaceous materials. The unit was to have a charge vessel capacity of approximately 250 kg of plant material and should be able to perform in-field distillations in areas where electricity is not available. A literature review on all the essential oil extraction methods, the theory behind steam distillation and oil isolation and the effect that each of the distillation components have on the distillation process was performed. A small test distillation unit was set up in a laboratory in order to investigate the effects of varying steam flow . rates on the distillation time, oil yield and oil quality. A double charge vessel unit was designed, constructed and mounted onto a frame which in turn was fixed onto a trailer to be hauled by a light delivery vehicle (LDV). The steam generator with all its ancillary equipment was fixed onto a separate trailer. The unit could thus be easily transported and in-field distillations on various crops could be conducted. Field distillations were conducted with two crop types, namely rose geranium and lemon grass. Satisfactory results were obtained as the oil yields were within the expected oil yield range. / Thesis (M.Sc.)-University of KwaZulu-Natal, 2005.

Reuse of software designs, experience and components is essential to making substantial improvements in software productivity, development cost, and quality. However, the many facets of reuse are still rarely used in the various phases of the software development lifecycle because of a lack of adequate theories, processes, and tools to support consistent application of reuse concepts. There is a need for approaches including definitions, models and properties of reuse that would provide explicit guidance to a software development team in applying reuse. In particular there is a need to provide abstractions that clearly separate the various functional concerns addressed in a software system. Separating concerns simplifies the identification of the software components that can benefit from reuse and can provide guidance on how reuse may be applied. In this thesis we present an extended model related to the separation of concerns in object-oriented design. The model, called views, indicates how an object-oriented design can be clearly separated into objects and their corresponding interfaces. In this model objects can be designed so that they are independent of their environment, because adaptation to the environment is the responsibility of the interface or view. The view can be seen as expressing the semantics for the 'glue' that joins components or objects together to create a software system. Informal versions of the views model have already been successfully applied to operational and commercial software systems. The objective of this thesis is to provide the views notion with a theoretical foundation to address reuse and separation of concerns. After clearly defining the views model we show the formal approach to combining the objects, interfaces (views), and their interconnection into a complete software system. The objects and interfaces are defined using an object calculus based on temporal logic, while the interconnections among object and views are specified using category theory. This formal framework provides the mathematical foundation to support the verification of the properties of both the components and the composite software system. We then show how verification can be mechanized by converting the formal version of the views model into higher-order logic and using PVS to support mechanical proofs.

As reserves of conventional crude oil are depleted, there is a growing need to develop unconventional oils such as heavy oil and bitumen from oil sands. In terms of recoverable oil, Canadian oil sands are considered to be the second largest oil reserves in the world. However, the upgrading of bitumen from oil sands to synthetic crude oil (SCO) requires nearly ten times more hydrogen (H₂) than the conventional crude oils. The current H₂ demand for oil sands operations is met mostly by steam reforming of natural gas. With the future expansion of oil sands operations, the demand of H₂ for oil sand operations is likely to quadruple in the next decade. As natural gas reforming involves significant carbon dioxide (CO₂) emissions, this sector is likely to be one of the largest emitters of CO₂ in Canada. <br> <br>In the current H₂ plants, CO₂ emissions originate from two sources, the combustion flue gases from the steam reformer furnace and the off-gas from the process (steam reforming and water-gas shift) reactions. The objective of this study is to develop a process that captures CO₂ at minimum energy penalty in typical H₂ plants. <br> <br>The approach is to look at the best operating conditions when considering the H₂ and steam production, CO₂ production and external fuel requirements. The simulation in this study incorporates the kinetics of the steam methane reforming (SMR) and the water gas shift (WGS) reactions. It also includes the integration of CO₂ capture technologies to typical H₂ plants using pressure swing adsorption (PSA) to purify the H₂ product. These typical H₂ plants are the world standard of producing H₂ and are then considered as the base case for this study. The base case is modified to account for the implementation of CO₂ capture technologies. Two capture schemes are tested in this study. The first process scheme is the integration of a monoethanolamine (MEA) CO₂ scrubbing process. The other scheme is the introduction of a cardo polyimide hollow fibre membrane capture process. Both schemes are designed to capture 80% of the CO₂ from the H₂ process at a purity of 98%. <br> <br>The simulation results show that the H₂ plant with the integration of CO₂ capture has to be operated at the lowest steam to carbon (S/C) ratio, highest inlet temperature of the SMR and lowest inlet temperatures for the WGS converters to attain lowest energy penalty. H₂ plant with membrane separation technology requires higher electricity requirement. However, it produces better quality of steam than the H₂ plant with MEA-CO₂ capture process which is used to supply the electricity requirement of the process. Fuel (highvale coal) is burned to supply the additional electricity requirement. The membrane based H₂ plant requires higher additional electricity requirement for most of the operating conditions tested. However, it requires comparable energy penalty than the H₂ plant with MEA-CO₂ capture process when operated at the lowest energy operating conditions at 80% CO₂ recovery. <br> <br>This thesis also investigates the sensitivity of the energy penalty as function of the percent CO₂ recovery. The break-even point is determined at a certain amount of CO₂ recovery where the amount of energy produced is equal to the amount of energy required. This point, where no additional energy is required, is approximately 73% CO₂ recovery for the MEA based capture plant and 57% CO₂ recovery for the membrane based capture plant. <br> <br>The amount of CO₂ emissions at various CO₂ recoveries using the best operating conditions is also presented. The results show that MEA plant has comparable CO₂ emissions to that of the membrane plant at 80% CO₂ recovery. MEA plant is more attractive than membrane plant at lower CO₂ recoveries.

The focus of this thesis is the study of turbulent solid-liquid stirred suspensions, which are involved in many common unit operations in the chemical, pharmaceutical and food industries. The studies of two-phase flows present a big challenge to researchers due to the complexity of experiments; hence there is a lack of quantitative solid and liquid hydrodynamic measurements. Therefore, an investigation of turbulence modulation by dispersed particles on the surrounding fluid in stirred vessels has been carried out, via two-phase fluorescent Particle Image Velocimetry (FPIV) and micromixing experiments. The main property of interest has been the local dissipation rate, as well as root-mean-square (rms) velocities and turbulent kinetic energy (TKE) of the fluid. Initially a single-phase PIV study was conducted to investigate the flow field generated by a sawtooth (EkatoMizer) impeller. The purpose of this study was to gain insight into various PIV techniques before moving on to more complex two-phase flows. Subsequently stereo-, highspeed and angle-resolved measurements were obtained. The EkatoMizer formed a good case study as information regarding its hydrodynamics is not readily available in literature, hence knowledge has been extended in this area. An analysis of the mean flow field elucidated the general structure of fluid drawn into the impeller region axially and discharged radially; the latter characterised the impeller stream. The radial rms velocity was considered to represent best the system turbulence, even though the tangential rms velocity was greater close to the blade; however the radial component was more prevalent in the discharge stream. Due to differences in rms velocities, TKE estimates obtained from two and three velocity components deviated, being greater in the latter case. Integral (1-D and 2-D) length scales were overestimated by the quantity W / 2 in the impeller region. Ratios of longitudinal-to-lateral length scales also indicated flow anisotropy (as they deviated from 2:1). The anisotropy tensor showed that the flow was anisotropic close to the blade, and returned to isotropy further away from the impeller. Instantaneous vector plots revealed vortices in the discharge stream, but these were not associated with flow periodicity. Alternatively, the vortex structures were interpreted as low frequency phenomena between 0-200 Hz; macro-instabilities were found to have a high probability of occurrence in the discharge stream. Dissipation is the turbulent property of most interest as it directly influences micromixing processes, and its calculation is also the most difficult to achieve. Its direct determination from definition requires highly resolved data. Alternative methods have been proposed in the literature, namely dimensional analysis, large eddy simulation (LES) analogy and deduction from the TKE balance. All methods were employed using 2-D and 3-D approximations from stereo-PIV data. The LES analogy was deemed to provide the best estimate, since it accounts for three-dimensionality of the flow and models turbulence at the smallest scales using a subgrid scale model. (Continues...).