The ability of surface-treated silica nanoparticles to stabilize oil/water emulsions presents us with many interesting avenues of study. The goal of this research is to assess the ability of a dispersion of specially surface-treated nanoparticles to stabilize an oil/water emulsion of prescribed internal structure created by flow within a fracture. We hypothesize that for a set of conditions (nanoparticle concentration, salinity, aqueous to organic phase ratio) a critical shear rate exists. That is, for flow rates that exceed this critical shear rate, an emulsion can be created. Flow experiments were conducted within fractured Boise sandstone and cement cylinders. The Boise sandstone core (D = 1 in and L = 12 in) was cut down its length and propped open to a specific aperture with beads. The fracture was saturated with dodecane then displaced with nanoparticle dispersion, and vice versa while pressure drop across the fracture was recorded. Class H cement cylinders (D = 1 in and L = 3 in) were allowed to set, then failed in compression to create a rough-walled fracture along their length. These fractured cement cylinders were then sealed and encased in epoxy to isolate the fractures. CT scans of the encased fractures were used to determine the aperture width, which is utilized when calculating the shear rate inside of the fracture maintained during an experiment. A dispersion of surface-modified silica nanoparticles and decane were coinjected into both the Boise sandstone and cement fractures and the pressure drop was measured across the fractures at a variety of shear rates. The effluent of each experiment was collected in sample tubes. Observation of the effluent and pressure drop data both support our hypothesis of emulsion generation being possible once a critical shear rate has been reached. Alteration of the injected phase ratio and increased residence time of the two phases inside of a fracture both affect the amount of emulsification occurring within the fractures. Increasing the residence time of both phases within a fracture allows for more opportunities for emulsification to occur, resulting in a greater amount of emulsion to be generated. Injection of high or low volumetric ratios of nanoparticle dispersion to organic phase results in little amounts of emulsion generation; however, between the nanoparticle dispersion to organic phase ratios of 0.25:1 and 2:1 significant amounts of emulsion are generated. / text

published_or_final_version / abstract / toc / Civil Engineering / Doctoral / Doctor of Philosophy

published_or_final_version / Civil Engineering / Master / Master of Philosophy

published_or_final_version / Civil and Structural Engineering / Doctoral / Doctor of Philosophy

No description available.

Our study was designed to test the hypothesis that flowfield properties such as WSS are closely related to cardiovascular disease. The spatial distribution patterns of several hemodynamic indices (gradient of WSS) were examined and compared with the (known) locations of plaque formation in human aorta. The part of the aorta on which we focused is ascending, aortic arch and descending aorta. Blood flow is influenced by vessel wall motion. Fluid Structure Interaction (FSI) is also investigated and discussed during the description of hemodynamic environment that leads to plaque formation in human aorta. Our Data were DICOM files from Computed Tomography (CT) scans. Using Vascular Modeling Toolkit (VMTK) and these scans as the input, we choose level set segmentation method to extract the geometry of the vessel needed for the simulation. ANSYS CFX Solver was used for the simulation of blood flow. The present numerical study revealed a direct correlation between low WSS values and atherosclerotic plaque localization. The results indicate also that Oscillating Shear Index (OSI) shows clearly points where the possibility of atherogenesis is high enough to be ignored. FSI provides unimportant details when we focused on plaque formation. / Η παρούσα εργασία μελετά την υπόθεση που συνδέει τις ιδιότητες του πεδίου ροής, όπως οι διατμητικές τάσεις (Wall Shear Stresses), με καρδιαγγειακές παθήσεις. Η χωρική κατανομή διάφορων δεικτών αιμοδυναμικής φύσεως (όπως η βάθμωση των διατμητικών τάσεων) μελετήθηκε και τα σημεία που εντοπίστηκαν ως ύποπτα για την ανάπτυξη αθηρωματικών πλακών συγκρίθηκαν με γνωστές από τη βιβλιογραφία περιοχές σχηματισμού τέτοιων φλεγμονών στην ανθρώπινη αορτή. Το τμήμα της αορτής στο οποίο εστιάσαμε είναι η ανιούσα, το αορτικό τόξο και η κατιούσα αορτή. Εξετάστηκε απίσης το ενδεχόμενο να επηρεάζεται η ροή του αίματος από την κίνηση του αρτηριακού τοιχώματος.

Scour around various structures obstructing flow in an open channel is a common problem; therefore a better understanding of how turbulent flow affects sediment transport is needed. Additionally, is it the mean flow or the turbulence properties that are more important in contributing to bed shear stress? To this end, an experimental study was conducted in a fixed-bed flume containing a series of dikes. Turbulence intensities and Reynold's stresses were calculated from 3-D velocity measurements gathered with a microADV. Results showed that the maximum shear stress was nearly 12-20 times that of the approach flow, while maximum turbulence intensities were about 3-5 times those of the incoming flow. Highest magnitudes of both were seen at the tip of the second dike in the three-dike series. The mean velocity appeared to have no relation to the formation of scour near the tips of the dikes but the turbulence intensities did.

In this thesis we will investigate the role of diapycnal mixing on the ocean general circulation. This thesis is divided into three main parts. In the first part we show that there exists an almost infinite number of pathways to turbulence in oceanic energetic shear zones at high Reynolds number. Such a large number of accessible routes to truly chaotic motion is not typical of most of the existing body of laboratory and numerical experiments of shear-induced diapycnal mixing, but is shown to be of relevance to diapycnal mixing in geophysical flows. A key finding is that the use of generally accepted empirical relations based on laboratory experiments for the quantification of diapycnal mixing leads to large inaccuracies. In the second part we perform high resolution numerical experiments of diapycnal mixing in the oceanographically relevant high Reynolds number parameter range. Through detailed analysis of the flow energetics and mixing properties of these flows, we show that the net buoyancy flux facilitated by turbulence, the efficiency of diapycnal mixing, and the resultant effective diffusivity, all depend in non-trivial ways on the specific route to turbulence for each individual mixing event. This has important implications for practical methods of estimating an effective diapycnal mixing diffusivity from observations as well as for parametrization of mixing in ocean general circulation models. We show quantitatively that such methods can be inaccurate to the extent that they will need to be completely revised or replaced. In the third and final part of the thesis we investigate the sensitivity of the meridional overturning circulation of the abyssal ocean to the intensity and spatial variations of diapycnal mixing. We show that changes in intensity of mixing by factors well within the errors associated with practical estimates (as discussed above) lead to significant changes in ocean circulation. We show that enhanced abyssal mixing, surface winds, and meso-scale eddies play leading roles in driving the abyssal ocean circulation and in setting the stratification. As an example of the application of our analysis we show that proper parametrization of enhanced abyssal mixing leads to realization of the important role of the (often neglected) geothermal heat flux in driving the Antarctic Bottom Water circulation.

Shear wave (SW) imaging is an ultrasound elastogrpahy technique for estimating the elastic properties of biological tissues. Increasing the frequency would improve both the confinement of the radiation force generating the shear wave, and the imaging spatial resolution. The objectives of the study were to realize a simple high frequency (HF) system for the generation and detection of SW propagation and to implement this system to develop and characterize tissue-mimicking gelatin phantoms (TMGP) for HF SWI with elastic properties in the range of those encountered in biological tissue. A 5 MHz and 10 MHz focused transducer were used to induced SW’s in TMGP ranging from 4% to 12% gelatin with 3% silica for scattering and a 25 MHz single-element focused transducer recorded pulse-echo signals in order to capture the SW. The shear wave speeds in the TMGP were found to range linearly from 1.59-4.59 m/s in the 4% to 12% gelatin samples.

The objective of this research was to further understand the behavior of the soil under the action of a tillage tool, with the purpose of finding a relation between the tool geometry and the resultant soil seed bed. Thus the problem consisted of understanding the mechanics of producing soil break up and to find a logical method of analyzing it. / The problem was solved using fundamental principles of soil mechanics and force equilibrium analyzis. As a result, a mathematical model was developed which describes three failure zones within the cut soil volume. The model can be programmed into a computer to generate maps of normal and shear stresses to visualize the three failure zones. / The failure zones are the shear failure zone, the tensile fracturing zone and the no failure zone. The tensile fracturing zone is delimited by the tensile stress reaching the tensile strength of the soil at the given soil moisture content and soil density. The tensile strength of the soil was measured using an apparatus and method designed in this research. / The mathematical model gives an explanation of the mechanics of crumbling and the shape of the failed volume, but it does not give information concerning soil aggregate quality and arrangement within the soil furrow. Then, a method of analyzing the formed aggregates was developed which considers some soil physical properties of aggregates. / The study concluded that the smaller tool width and the smaller tool rake angle, among the ones used in this research, produced the most efficient geometry in producing the largest amount of soil break up, the most uniform aggregate formation and the most stable aggregate arrangement. The same tool geometry requires less energy per unit volume of soil disturbed. The best performance is produced at the lowest soil water content among those tested.